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公开(公告)号：US20110020214A1
公开(公告)日：2011-01-27
申请号：US12610322
申请日：2009-11-01
CPC分类号： B01J12/007 , B01J19/2485 , B01J21/04 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/50 , B01J23/52 , B01J37/0201 , B01J2219/00006 , B01J2219/00063 , B01J2219/00094 , B01J2219/00117 , B01J2219/00155 , C01B3/22 , C01B2203/0277 , C01B2203/04 , C01B2203/048 , C01B2203/1023 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1217 , C01B2203/1288 , C01B2203/148 , C01B2203/1619 , C01B2203/1623 , C01B2203/169
摘要： There is disclosed a surprising reaction of an alkane thiol with a catalyst and heat to become dehydrogenated and form a thiophene rather than an expected desulfurization reaction to form the corresponding alkane or alkene. Moreover, there are disclosed surprising results regarding the form of a catalyst to allow a reaction of an alkane thiol to form the dehydrogenated thiophene at lower temperatures and at higher conversion percentages to allow for more efficient recovery of thiophenes to allow for recycling and reuse of thiophenes to hydrogenate to form alkane thiols. Further still, there is disclosed a set of reaction conditions and catalyst presentation that allows for recovery of usable diatomic hydrogen gas from a dehydrogenation reaction of substituted or unsubstituted cyclic thioethers to substituted or unsubstituted thiophene.
摘要翻译： 公开了烷烃硫醇与催化剂和热量的惊人反应，使其脱氢并形成噻吩，而不是预期的脱硫反应以形成相应的烷烃或烯烃。 此外，已经公开了关于催化剂形式的令人惊奇的结果，该催化剂允许烷烃硫醇在较低温度下反应形成脱氢噻吩并且以较高的转化百分数进行反应，以允许更有效地回收噻吩以允许噻吩的再循环和再利用 氢化形成烷硫醇。 此外，还公开了一组反应条件和催化剂表现，其允许从取代或未取代的环状硫醚脱氢反应到取代或未取代的噻吩中回收可用的双原子氢气。
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公开(公告)号：US09623393B2
公开(公告)日：2017-04-18
申请号：US12610322
申请日：2009-11-01
IPC分类号： B01J19/00 , C01B3/22 , B01J12/00 , B01J19/24 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/50 , B01J23/52 , B01J37/02 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/18
CPC分类号： B01J12/007 , B01J19/2485 , B01J21/04 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/50 , B01J23/52 , B01J37/0201 , B01J2219/00006 , B01J2219/00063 , B01J2219/00094 , B01J2219/00117 , B01J2219/00155 , C01B3/22 , C01B2203/0277 , C01B2203/04 , C01B2203/048 , C01B2203/1023 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1217 , C01B2203/1288 , C01B2203/148 , C01B2203/1619 , C01B2203/1623 , C01B2203/169
摘要： There is disclosed a surprising reaction of an alkane thiol with a catalyst and heat to become dehydrogenated and form a thiophene rather than an expected desulfurization reaction to form the corresponding alkane or alkene. Moreover, there are disclosed surprising results regarding the form of a catalyst to allow a reaction of an alkane thiol to form the dehydrogenated thiophene at lower temperatures and at higher conversion percentages to allow for more efficient recovery of thiophenes to allow for recycling and reuse of thiophenes to hydrogenate to form alkane thiols. Further still, there is disclosed a set of reaction conditions and catalyst presentation that allows for recovery of usable diatomic hydrogen gas from a dehydrogenation reaction of substituted or unsubstituted cyclic thioethers to substituted or unsubstituted thiophene.
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公开(公告)号：US20120282151A1
公开(公告)日：2012-11-08
申请号：US13442739
申请日：2012-04-09
申请人： David O'Connor , Esmaeel Naeemi
发明人： David O'Connor , Esmaeel Naeemi
IPC分类号： B01J8/02
CPC分类号： H05B3/48 , B01J19/249 , B01J2219/2453 , B01J2219/2458 , B01J2219/2462 , B01J2219/2482 , B01J2219/30219 , H05B2203/014
摘要： The current application is directed to a packed-bed reactor comprising a housing; and section portions contained within the housing, each comprising a spiral-wound heater. The spiral-wound heaters together comprise a catalyst-disk stack.
摘要翻译： 目前的应用涉及包括壳体的填充床反应器; 以及包含在所述壳体内的部分部分，每个部分包括螺旋卷绕加热器。 螺旋缠绕的加热器一起包括催化剂 - 盘堆叠。
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公开(公告)号：US07186396B2
公开(公告)日：2007-03-06
申请号：US10997368
申请日：2004-11-23
申请人： Buddy D. Ratner , Esmaeel Naeemi
发明人： Buddy D. Ratner , Esmaeel Naeemi
IPC分类号： C01B3/02
CPC分类号： H01M8/0612 , C01B3/26 , F02M21/0206 , F02M21/0224 , F02M21/0227 , F17C11/005 , H01M8/04201 , H01M8/04208 , H01M8/04216 , H01M2250/20 , Y02E60/321 , Y02E60/36 , Y02P90/45 , Y02T10/32 , Y02T90/32
摘要： The present invention relates to hydrogen production for the generation of energy. The invention describes methods, devices and assemblies involving hydrogen production including reacting hydrogen producing compounds, such as organothiol compounds, with a reactive metal substrate to produce hydrogen gas and utilizing the hydrogen gas to generate energy. The present invention further describes regenerating spent compound to a form suitable for hydrogen production by reacting the spent compound with hydrogen. Hydrogen storage and production, as described herein, is useful for producing hydrogen for energy production in hydrogen consuming devices, such as combustible engines and fuel cells, for example, as located on a hydrogen powered vehicle.
摘要翻译： 本发明涉及用于产生能量的氢气生产。 本发明描述了涉及氢生产的方法，装置和组件，包括使产生氢的化合物如有机硫醇化合物与活性金属底物反应以产生氢气并利用氢气产生能量。 本发明进一步描述了通过使废化合物与氢反应而将废化合物再生成适于氢生产的形式。 如本文所述，氢储存和生产可用于在氢消耗装置（例如可燃发动机和燃料电池）中产生用于能量产生的氢，例如位于氢动力车辆上。
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5.发明申请公开(公告)号：US20170342205A1
公开(公告)日：2017-11-30
申请号：US15678581
申请日：2017-08-16
IPC分类号： C08G63/08 , C08G63/91 , A61L31/10 , A61L31/06 , C07D319/12 , C09D167/04 , C08J3/28
CPC分类号： C08G63/08 , A61L31/06 , A61L31/10 , C07D319/12 , C08G63/6822 , C08G63/912 , C08J3/28 , C08J2377/02 , C09D167/04
摘要： Halogenated cyclic diesters, halogenated polymers derived from the cyclic diesters, and methods for making the halogenated cyclic diesters and related halogenated polymers.
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公开(公告)号：US20100210878A1
公开(公告)日：2010-08-19
申请号：US12707658
申请日：2010-02-17
申请人： Esmaeel Naeemi , David G. O'Connor
发明人： Esmaeel Naeemi , David G. O'Connor
IPC分类号： C07C209/42 , B01J8/18
CPC分类号： B01J19/249 , B01J8/009 , B01J8/0214 , B01J8/0221 , B01J2208/00053 , B01J2208/00407 , B01J2208/00415 , C01B3/22 , C01B3/501 , C01B2203/0277 , C01B2203/041 , C01B2203/048 , C01B2203/066 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C07C253/00 , C07C255/03
摘要： There is disclosed a process for hydrogen release and chemical storage by dehydrogenating low molecular weight aliphatic amines and di-amines to produce their corresponding nitriles in a reactor system containing a hydrogen fractionation membrane (or sweep gas) to quickly remove any and all hydrogen generated during the dehydrogenation reaction. This disclosure further provides a process for hydrogen recovery using bi- and tri-functional amines that produce corresponding nitriles and high density hydrogen release.
摘要翻译： 公开了一种通过使低分子量脂族胺和二胺脱氢以在含有氢分馏膜（或吹扫气体）的反应器系统中产生它们相应的腈的氢释放和化学储存的方法，以快速除去在 脱氢反应。 本公开进一步提供了使用产生相应的腈和高密度氢释放的二官能胺和三官能胺进行氢气回收的方法。
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公开(公告)号：US20070003476A1
公开(公告)日：2007-01-04
申请号：US11403484
申请日：2006-04-12
申请人： Buddy Ratner , Esmaeel Naeemi
发明人： Buddy Ratner , Esmaeel Naeemi
CPC分类号： H01M8/0612 , C01B3/26 , F02M21/0206 , F02M21/0224 , F02M21/0227 , F17C11/005 , H01M8/04201 , H01M8/04208 , H01M8/04216 , H01M2250/20 , Y02E60/321 , Y02E60/36 , Y02P90/45 , Y02T10/32 , Y02T90/32
摘要： The present invention relates to hydrogen production for the generation of energy. The invention describes methods, devices and assemblies involving hydrogen production including reacting hydrogen producing compounds, such as organothiol compounds, with a reactive metal substrate to produce hydrogen gas and utilizing the hydrogen gas to generate energy. The present invention further describes regenerating spent compound to a form suitable for hydrogen production by reacting the spent compound with hydrogen. Hydrogen storage and production, as described herein, is useful for producing hydrogen for energy production in hydrogen consuming devices, such as combustible engines and fuel cells, for example, as located on a hydrogen powered vehicle.
摘要翻译： 本发明涉及用于产生能量的氢气生产。 本发明描述了涉及氢生产的方法，装置和组件，包括使产生氢的化合物如有机硫醇化合物与活性金属底物反应以产生氢气并利用氢气产生能量。 本发明进一步描述了通过使废化合物与氢反应而将废化合物再生成适于氢生产的形式。 如本文所述，氢储存和生产可用于在氢消耗装置（例如可燃发动机和燃料电池）中产生用于能量产生的氢，例如位于氢动力车辆上。
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公开(公告)号：US10577456B2
公开(公告)日：2020-03-03
申请号：US15678581
申请日：2017-08-16
IPC分类号： C08G63/02 , C08G63/08 , C07D319/12 , C08G63/682 , A61L31/06 , A61L31/10 , C08G63/91 , C08J3/28 , C09D167/04
摘要： Halogenated cyclic diesters, halogenated polymers derived from the cyclic diesters, and methods for making the halogenated cyclic diesters and related halogenated polymers.
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9.发明申请CONTROLLED POROUS CATALYSTS TO PRODUCE HYDROGEN GAS BY DEHYDROGENATING ORGANIC COMPOUNDS 审中-公开通过脱氢有机化合物生产氢气的控制多孔催化剂公开(公告)号：US20120302428A1
公开(公告)日：2012-11-29
申请号：US13442719
申请日：2012-04-09
申请人： Esmaeel Naeemi , David O'Connor
发明人： Esmaeel Naeemi , David O'Connor
CPC分类号： B01J37/082 , B01J23/75 , B01J35/023 , B01J37/0018 , B01J37/04 , B01J37/12
摘要： The current application discloses a method for producing a porous catalyst, the method comprising providing a powder of metal particles with a specific size; mixing into the powder of metal particles spacer spheres with a fixed diameter less than that of the metal particles; placing the metal-particle/spacing-sphere mixture in a ceramic container; heating the mixture in an oven, furnace or microwave oven to sinter the metal particles and fuse them to a solid matrix; and removing the spacing spheres either by solvolysis or pyrolysis.
摘要翻译： 本申请公开了一种生产多孔催化剂的方法，该方法包括提供具有特定尺寸的金属颗粒的粉末; 将固定直径小于金属颗粒的金属颗粒间隔球的粉末混合; 将金属颗粒/间隔球混合物放置在陶瓷容器中; 在烘箱，炉子或微波炉中加热混合物以烧结金属颗粒并将其熔合成固体基质; 并通过溶剂分解或热解除去间隔球体。
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公开(公告)号：US20120258020A1
公开(公告)日：2012-10-11
申请号：US13442694
申请日：2012-04-09
申请人： David O'Connor , Esmaeel Naeemi
发明人： David O'Connor , Esmaeel Naeemi
IPC分类号： B01J19/00
CPC分类号： B01J19/0093 , B01J2219/00783 , B01J2219/00806 , B01J2219/00815 , B01J2219/00824 , B01J2219/00835 , B01J2219/00873 , B01J2219/00876 , B01J2219/0088 , B01J2219/00882 , B01J2219/00961
摘要： In one example disclosed in the current application, by supplying just enough heat to the channel walls to replace the reaction heat removed during the reaction, a reactor exhibits tighter temperature tolerances with respect to the desired reaction temperature. In other words, the surface temperature can be more closely matched to the desired reaction temperature. Also, having a design where the channels can be scaled in both geometry and number allows control of the rate of mass transport through the channels to minimize unwanted side reactions.
摘要翻译： 在本申请中公开的一个实例中，通过向通道壁提供足够的热量来代替在反应期间除去的反应热，反应器相对于所需的反应温度显示更严格的温度公差。 换句话说，表面温度可以更接近于所需的反应温度。 此外，具有设计，其中通道可以在几何形状和数量上进行缩放，从而可以控制通过通道的质量传输速率以最小化不必要的副反应。
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