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    METHOD FOR PHOTOCATALYTIC WATER PURIFICATION
    1.
    发明申请
    METHOD FOR PHOTOCATALYTIC WATER PURIFICATION 审中-公开
    光化学水净化方法

    公开(公告)号：US20120091068A1

    公开(公告)日：2012-04-19

    申请号：US13378100

    申请日：2010-06-23

    申请人： Florina Corina Patcas ,  Grigorios Kolios ,  Götz-Peter Schindler ,  Peter Pfab ,  Reinhard Hess

    发明人： Florina Corina Patcas ,  Grigorios Kolios ,  Götz-Peter Schindler ,  Peter Pfab ,  Reinhard Hess

    IPC分类号： C02F1/32

    CPC分类号： C02F1/32 ,  C02F1/725 ,  C02F2103/10 ,  C02F2103/28 ,  C02F2103/36 ,  C02F2103/365

    摘要： The present invention relates to a process for the purification of a contaminant-containing stream by bringing the stream to be purified into contact with a heterogeneous photocatalyst with irradiation with light, where the bringing into contact takes place in the presence of at least one compound dissolved in the stream and comprising at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese and mixtures thereof, and to the use of a heterogeneous photocatalyst for the purification of a contaminant-containing stream, where, in the stream to be purified, at least one compound comprising at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese and mixtures thereof is present in dissolved form.

    摘要翻译： 本发明涉及一种通过使待纯化物流与异质光催化剂接触的方法，该方法是用光照射进行，其中在存在至少一种溶解的化合物的情况下进行接触 并且包含至少一种选自铁，铬，镍，钴，锰及其混合物的金属，以及使用异相光催化剂来净化含污染物流，其中在 要纯化的物流，至少一种包含至少一种选自铁，铬，镍，钴，锰及其混合物的金属的化合物以溶解的形式存在。

    Preparation of butadiene
    3.
    发明授权
    Preparation of butadiene 有权
    丁二烯的制备

    公开(公告)号：US07482500B2

    公开(公告)日：2009-01-27

    申请号：US10584758

    申请日：2004-12-30

    申请人： Thorsten Johann ,  Götz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Regina Benfer ,  Thomas Hill ,  Mark Duda

    发明人： Thorsten Johann ,  Götz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Regina Benfer ,  Thomas Hill ,  Mark Duda

    IPC分类号： C07C5/327 ,  C07C5/32

    CPC分类号： C07C5/333 ,  C07C5/48 ,  C07C11/167

    摘要： The disclosure relates to a process for preparing butadiene. The process involves nonoxidatively catalytically dehydrogenating butane to obtain a product gas stream containing butane, 1-butene, 2-butene, butadiene, hydrogen and secondary constituents. The 1-butene and 2-butene of the product gas stream is then oxidatively dehydrogenated to give a second gas stream containing butane,2-butene, butadiene, hydrogen, steam and secondary constituents. Next, the butane,2-butene and butadiene are separated from the second gas stream and the butane and 2-butene are then separated from the butadiene product. The butane and 2-butene are then recycled into the nonoxidative catalytic dehydrogenating zone.

    摘要翻译： 本公开涉及一种制备丁二烯的方法。 该方法涉及非氧化催化脱氢丁烷，以获得含有丁烷，1-丁烯，2-丁烯，丁二烯，氢和二次成分的产物气流。 然后将产物气流的1-丁烯和2-丁烯氧化脱氢，得到含有丁烷，2-丁烯，丁二烯，氢气，蒸汽和二级成分的第二气流。 接下来，将丁烷，2-丁烯和丁二烯与第二气流分离，然后从丁二烯产物中分离丁烷和2-丁烯。 然后将丁烷和2-丁烯循环到非氧化催化脱氢区。

    Method for the production of butadiene
    7.
    发明授权
    Method for the production of butadiene 有权
    生产丁二烯的方法

    公开(公告)号：US07488858B2

    公开(公告)日：2009-02-10

    申请号：US10584785

    申请日：2004-12-30

    申请人： Thorsten Johann ,  Götz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Mark Duda

    发明人： Thorsten Johann ,  Götz-Peter Schindler ,  Andreas Brodhagen ,  Sven Crone ,  Mark Duda

    IPC分类号： C07C5/333

    CPC分类号： C07C5/333 ,  C07C5/48 ,  C07C11/167

    摘要： The disclosure involves a process for preparing butadiene from n-butane. In the process, n-butane is first dehydrogenated autothermally under nonoxidative conditions to form a gas stream. The gas stream is then oxidatively dehydrogenated to form a second gas stream. From the second gas stream, a third gas stream containing n-butane, 2-butene and butadiene is obtained. From the third gas stream, a butadiene/butaine product stream is obtained and remaining n-butane and 2-butene is recycled into the first dehydrogenation zone.

    摘要翻译： 本公开涉及从正丁烷制备丁二烯的方法。 在此过程中，正丁烷首先在非氧化条件下自热脱氢形成气流。 然后将气流氧化脱氢以形成第二气流。 从第二气流中获得含有正丁烷，2-丁烯和丁二烯的第三气流。 从第三气流中获得丁二烯/丁内酯产物流，并将剩余的正丁烷和2-丁烯再循环到第一脱氢区中。

    Method for producing 1-butene
    8.
    发明授权
    Method for producing 1-butene 失效
    1-丁烯的制备方法

    公开(公告)号：US07485761B2

    公开(公告)日：2009-02-03

    申请号：US10595551

    申请日：2004-10-27

    申请人： Götz-Peter Schindler ,  Andreas Brodhagen ,  Thorsten Johann ,  Thomas Hill ,  Marcus Sigl ,  Regina Benfer

    发明人： Götz-Peter Schindler ,  Andreas Brodhagen ,  Thorsten Johann ,  Thomas Hill ,  Marcus Sigl ,  Regina Benfer

    IPC分类号： C07C5/333

    CPC分类号： C07C5/333 ,  C07C5/05 ,  C07C5/2506 ,  C07C7/08 ,  C07C11/08

    摘要： A process for preparing 1-butene, which includes nonoxidatively, catalytically dehydrogenating n-butane to obtain a product gas stream of n-butane, 1-butene, 2-butene, butadiene, hydrogen, and secondary constituents; removing hydrogen and the secondary constituents to obtain a C4 product gas stream; separating the C4 product stream into a recycle stream of n-butane and a stream of 1-butene, 2-butene and butadiene by extractive distillation, and recirculating the recycle stream to the dehydrogenation zone; introducing the 1 -butene, 2-butene and butadiene stream into a selective hydrogenation zone and selective hydrogenation of butadiene to 1-butene and/or 2-butene to obtain a stream of 1-butene and 2-butene; introducing the 1-butene and 2-butene stream, and a circulating stream of 1-butene and 2-butene into a distillation zone and isolation of a product stream; and introducing the 2-butene-containing stream into an isomerization zone to obtain a circulating stream of 1-butene and 2-butene, and recirculating the circulating stream to the distillation zone.

    摘要翻译： 一种制备1-丁烯的方法，其包括非氧化催化脱氢的正丁烷，以获得正丁烷，1-丁烯，2-丁烯，丁二烯，氢和二次成分的产物气流; 除去氢气和次要成分以获得C4产物气流; 通过萃取蒸馏将C4产物流分离成正丁烷和1-丁烯，2-丁烯和丁二烯的再循环流，并将再循环流再循环到脱氢区; 将1-丁烯，2-丁烯和丁二烯流引入选择性氢化区，并将丁二烯选择性氢化成1-丁烯和/或2-丁烯，得到1-丁烯和2-丁烯的物流; 将1-丁烯和2-丁烯流以及1-丁烯和2-丁烯的循环流引入蒸馏区并分离产物流; 并将含2-丁烯的物流引入异构化区以获得1-丁烯和2-丁烯的循环流，并将循环流再循环到蒸馏区。

    Method for producing 4-vinylcyclohexene, ethyl benzole and styrene
    10.
    发明授权
    Method for producing 4-vinylcyclohexene, ethyl benzole and styrene 失效
    制备4-乙烯基环己烯，乙基苯和苯乙烯的方法

    公开(公告)号：US07193121B2

    公开(公告)日：2007-03-20

    申请号：US10501876

    申请日：2003-02-17

    申请人： Christian Walsdorff ,  Götz-Peter Schindler ,  Klaus Harth ,  Hartmut Hibst

    发明人： Christian Walsdorff ,  Götz-Peter Schindler ,  Klaus Harth ,  Hartmut Hibst

    IPC分类号： C07C5/32

    CPC分类号： C07C5/367 ,  C07C2/52 ,  C07C13/20 ,  C07C15/073 ,  C07C15/46

    摘要： The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.

    摘要翻译： 本发明涉及一种制备4-乙烯基环己烯的方法，其包括步骤（A）提供含正丁烷的进料气流，（B）将含正丁烷的进料气流进料至至少一个脱氢区和 将正丁醇脱氢成丁二烯，得到包含丁二烯，正丁烷，可能的1-丁烯和2-丁烯以及可能的水蒸气和其他二次成分的产物流，（C）如果适当，将脱离后的产物流从分离出来 水蒸气和次要成分，进入二聚化区域并催化二聚丁二烯，得到包含4-乙烯基环己烯，正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流，和（D）将4-乙烯基环己烯从 来自二聚和再循环的正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流到脱氢区。