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18 条记录 (耗时 0.043 秒)

    Abrasion wear resistant polymeric substrate product
    8.
    发明授权
    Abrasion wear resistant polymeric substrate product 失效
    耐磨聚合物基材

    公开(公告)号：US5190807A

    公开(公告)日：1993-03-02

    申请号：US600210

    申请日：1990-10-18

    申请人： Fred M. Kimock ,  Bradley J. Knapp ,  Steven J. Finke

    发明人： Fred M. Kimock ,  Bradley J. Knapp ,  Steven J. Finke

    IPC分类号： B32B7/02 ,  B32B9/00 ,  C23C16/02 ,  C23C16/26 ,  C23C16/27 ,  G02B1/04 ,  G02B1/10 ,  G02C7/02

    CPC分类号： C23C16/006 ,  C23C16/0272 ,  C23C16/26 ,  G02B1/105 ,  Y10S428/913 ,  Y10T428/24975 ,  Y10T428/265 ,  Y10T428/30 ,  Y10T428/31663 ,  Y10T428/31678

    摘要： A substantially optically transparent coated substrate product with a highly adherent, abrasion-resistant diamond-like hard carbon coating is disclosed. The substrate product is comprised of a polymeric substrate, an adhesion-mediating polysiloxane polymer layer, one or more intermediate layers and an outer layer of diamond-like hard carbon. In another embodiment of the invention a thin metallic interlayer is disposed between a first interlayer layer and subsequent interlayers and/or diamond-like hard carbon. The invention also allows for the production of adherent thin film interference layer coatings (i.e. quarter wavelength stacks and anti-reflection coatings) using diamond-like hard carbon as the high refractive index layer and the interlayer(s) as the low refractive index layer or, alternatively, using diamond-like hard carbon as the low refractive index layer and the interlayer(s) as the high refractive index layer. The invention further discloses a method for fabricating the coated substrate product. The substrate product, exhibiting excellent resistance to abrasion and chemical attack, is particularly useful for commercial plastic articles such as optical lenses and sunglass lenses made of polycarbonate, CR-39.RTM., or acrylic plastics.

    摘要翻译： 公开了具有高粘附性，耐磨损的类金刚石硬质碳涂层的基本上光学透明的涂覆基材产品。 基底产品由聚合物基底，粘附介导性聚硅氧烷聚合物层，一个或多个中间层和金刚石状硬碳外层组成。 在本发明的另一个实施方案中，薄金属中间层设置在第一中间层和随后的夹层和/或类金刚石硬碳之间。 本发明还允许使用金刚石状硬碳作为高折射率层和作为低折射率层的中间层来制造粘附薄膜干涉层涂层（即四分之一波长叠层和抗反射涂层），或 ，或者，使用类金刚石硬碳作为低折射率层和中间层作为高折射率层。 本发明还公开了一种用于制造涂覆的基底产品的方法。 表现出优异的抗磨损和化学侵蚀性的基材产品对于诸如由聚碳酸酯，CR-39 TM或丙烯酸塑料制成的光学透镜和太阳眼镜片的商业塑料制品特别有用。

    Highly durable and abrasion-resistant dielectric coatings for lenses
    9.
    发明授权
    Highly durable and abrasion-resistant dielectric coatings for lenses 失效

    公开(公告)号：US5846649A

    公开(公告)日：1998-12-08

    申请号：US632610

    申请日：1996-04-15

    申请人： Bradley J. Knapp ,  Fred M. Kimock ,  Rudolph Hugo Petrmichl ,  Brian Kenneth Daniels

    发明人： Bradley J. Knapp ,  Fred M. Kimock ,  Rudolph Hugo Petrmichl ,  Brian Kenneth Daniels

    IPC分类号： B05D7/24 ,  B29C59/16 ,  C23C14/02 ,  C23C16/02 ,  C23C16/30 ,  C23C16/32 ,  C23C16/34 ,  C23C16/44 ,  C23C16/513 ,  G02B1/10 ,  B32B9/04

    CPC分类号： B05D1/62 ,  C08J7/123 ,  C23C14/02 ,  C23C14/024 ,  C23C16/0245 ,  C23C16/0272 ,  C23C16/30 ,  C23C16/308 ,  C23C16/325 ,  C23C16/345 ,  C23C16/513 ,  G02B1/105 ,  B29C59/16 ,  Y10T428/263 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31598 ,  Y10T428/31663

    摘要： An abrasion-resistant dielectric composite product is described comprising a substrate and an abrasion wear resistant coating material comprising carbon, hydrogen, silicon, and oxygen and a dielectric material. An improved method is provided for the deposition of highly durable and abrasion-resistant multilayer dielectric antireflective coatings and reflective colored mirror coatings onto plastic lenses such as ophthalmic lenses, safety lenses, sunglass lenses, and sports optics. An adhesion-enhancing polymer layer may be deposited onto the plastic substrate prior to deposition of the abrasion-resistant first coating layer. The multilayer dielectric coating structure consists of a transparent, highly abrasion-resistant first coating, and a second dielectric coating composed of at least one layer of dielectric material. The abrasion-resistant first coating layer is deposited by ion-assisted plasma deposition from mixtures of organosiloxane or organosilazane precursor gases and oxygen, and has the properties of Nanoindentation hardness in the range of about 2 GPa to about 5 GPa, a strain to microcracking greater than about 1.5% and less than about 3.5%, a transparency greater than 85% throughout the visible spectrum, and an abrasion resistance greater than or equal to the abrasion resistance of glass. The preferred method for deposition of the abrasion-resistant first coating layer is plasma ion beam deposition using an organosiloxane precursor gas and oxygen. Optimum abrasion-resistance is obtained when the first coating layer thickness is in the range of about 5 microns to about 20 microns. The thickness, refractive index, and number of the dielectric layers in the second coating are chosen to produce the desired optical effects of either antireflection, or reflected color. Optimum environmental durability and abrasion-resistance is obtained by producing highly dense dielectric coatings by ion beam assisted electron beam evaporation, magnetron sputtering, ion beam assisted magnetron sputtering, ion beam sputtering, and ion-assisted plasma deposition, including plasma ion beam deposition, from precursor gases.