公开(公告)号：US4617335A

公开(公告)日：1986-10-14

申请号：US758149

申请日：1985-07-23

申请人： Fumio Okada ,  Toshio Oba ,  Morizo Nakazato ,  Kenichi Isobe

发明人： Fumio Okada ,  Toshio Oba ,  Morizo Nakazato ,  Kenichi Isobe

IPC分类号： C08L101/00 ,  C08G18/61 ,  C08G18/62 ,  C08G77/00 ,  C08G77/04 ,  C08G77/14 ,  C08G77/22 ,  C08K5/5415 ,  C08L7/00 ,  C08L21/00 ,  C08K5/24

CPC分类号： C08K5/5415

摘要： The invention provides an efficient method for releasing a shaped body of a polymeric material such as a foamed polyurethane resin from a mold in which the body has been molded without the problem of adhesion to the mold. The inventive method comprises admixing the polymeric material with a specific organopolysiloxane represented by the structural formulaR.sup.1.sub.3 Si--O--SiR.sup.2.sub.2 --O).sub.m (SiR.sup.2 A--O).sub.n SiR.sup.1.sub.3,in which A is a substituent group represented by the general formula --C.sub.x H.sub.2x --O--R, R being a monovalent hydrocarbon group having 8 to 30 carbon atoms but free from terminal unsaturation and x being zero or a positive integer not exceeding 4, R.sup.1 is a monovalent hydrocarbon group or the same group as A, R.sup.2 is a hydrogen atom or the same group as R.sup.1, and m and n are each zero or a positive integer with the proviso that at least one group denoted by A is contained in a molecule of the organopolysiloxane.

摘要翻译： 本发明提供了一种用于从模具中释放聚合物材料如发泡聚氨酯树脂的成形体的有效方法，其中已经模制了本体，而没有粘附到模具的问题。 本发明的方法包括将聚合物材料与由结构式R 13 Si-O-SiR 22 -O）m（SiR 2 A-O）n SiR 13表示的特定有机聚硅氧烷混合，其中A是由通式-C x H 2 x -OR表示的取代基， R为碳原子数为8〜30，不含末端不饱和单价烃基，x为零或不超过4的正整数，R1为单价烃基或与A相同的基团，R2为氢原子或相同 基团为R 1，m和n各自为零或正整数，条件是由A表示的至少一个基团包含在有机聚硅氧烷的分子中。

公开(公告)号：US4670309A

公开(公告)日：1987-06-02

申请号：US882018

申请日：1986-07-03

申请人： Fumio Okada ,  Toshio Oba ,  Morizo Nakazato

发明人： Fumio Okada ,  Toshio Oba ,  Morizo Nakazato

IPC分类号： B05D5/00 ,  B05D7/08 ,  B05D7/12 ,  C08G77/04 ,  C08J7/04 ,  C09D183/04 ,  C09K3/00 ,  C09K3/18 ,  B05D3/02

CPC分类号： C08J7/047 ,  C08G77/04 ,  B05D2201/00 ,  B05D2203/24 ,  B05D7/12 ,  C08J2483/00

摘要： The invention provides a method for protecting the surface of various kinds of shaped articles made of an organic polymeric material such as rubbers, leathers, woods, plastics and the like against weathering caused by exposure to ultraviolet light, ozone, moisture, etc. The method comprises providing the surface with a coating layer of a specific organopolysiloxane composed of difunctional, tetrafunctional and nonofunctional siloxane units in a limited molar proportion of 50-85%, 10-30% and 5-20%, respectively.

摘要翻译： 本发明提供一种保护由有机聚合材料如橡胶，皮革，木材，塑料等制成的各种成型制品的表面的方法，以防止由于暴露于紫外线，臭氧，水分等引起的风化。 包括为表面提供由分别为50-85％，10-30％和5-20％的有限摩尔比例的由双功能，四官能和非官能的硅氧烷单元组成的特定有机聚硅氧烷的涂层。

公开(公告)号：US4496687A

公开(公告)日：1985-01-29

申请号：US574669

申请日：1984-01-27

申请人： Fumio Okada ,  Toshio Oba ,  Morizo Nakazato

发明人： Fumio Okada ,  Toshio Oba ,  Morizo Nakazato

IPC分类号： C08L83/06 ,  C08J3/03 ,  C08K13/02 ,  C08L83/00 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  C08L83/02

CPC分类号： C08J3/03 ,  C08K13/02 ,  C08K3/36 ,  C08K5/09 ,  C08K5/54 ,  C08G77/16 ,  C08J2383/04 ,  Y10S528/901

摘要： The invention provides a novel organopolysiloxane-containing aqueous emulsion composition which, upon removal of water by drying at room temperature, can give a cured rubbery elastomer having excellent mechanical properties and exhibiting strong adhesion to the substrate on which it has been cured. The inventive composition is prepared by blending (A) an aqueous emulsion of an organopolysiloxane having silicon-bonded hydroxy groups and emulsified in water by use of an anionic surface active agent, (B) a mixture of a reaction product of a carboxylic acid anhydride with an amino-functional organosilane and a colloidal silica in the form of an aqueous suspension and (C) a curing catalyst in limited proportions.

摘要翻译： 本发明提供了一种新型的含有机聚硅氧烷的水性乳液组合物，其在室温下干燥除去水后，可得到具有优异的机械性能并对其已经固化的基材具有强粘合性的固化的橡胶弹性体。 本发明的组合物通过将（A）具有硅键合的羟基的有机聚硅氧烷的水性乳液与阴离子表面活性剂共混而制备，（B）将羧酸酐的反应产物与 氨基官能的有机硅烷和水性悬浮液形式的胶体二氧化硅，（C）有限比例的固化催化剂。

公开(公告)号：US06437008B1

公开(公告)日：2002-08-20

申请号：US09592860

申请日：2000-06-13

申请人： Teruki Ikeda ,  Sachiko Yamada ,  Morizo Nakazato

发明人： Teruki Ikeda ,  Sachiko Yamada ,  Morizo Nakazato

IPC分类号： B01F308

CPC分类号： A61Q5/12 ,  A61K8/375 ,  A61K8/416 ,  A61K8/463 ,  A61K8/466 ,  A61K8/585 ,  A61K8/60 ,  A61K8/86 ,  A61K8/891 ,  A61K8/90 ,  A61Q5/00 ,  A61Q5/02 ,  C08G77/14 ,  C08G77/16 ,  C08G77/26 ,  C08G77/28 ,  C08G77/70 ,  C08L83/04 ,  Y10S516/924 ,  C08L83/00

摘要： Disclosed is an aqueous organopolysiloxane emulsion for use as an adjuvant to hair-care treatment toiletry preparations suitable in respect of the good storage stability and relatively large average diameter of the organopolysiloxane droplets of 0.1 to 1.0 mm despite the high viscosity of the organopolysiloxane and the high content of the organopolysiloxane. The organopolysiloxane emulsion consists of: (A) 70 to 90% by weight of an organopolysiloxane having a viscosity of 1×105 mPa·s or higher; (B) 1 to 15% by weight of a surface active agent; and (C) 5 to 25% by weight of water.

摘要翻译： 公开了一种水性有机基聚硅氧烷乳液，用作头发护理治疗化妆品制剂的辅助剂，适合于良好的储存稳定性和0.1至1.0mm的有机聚硅氧烷液滴的相对大的平均直径，尽管有机聚硅氧烷的高粘度和高 有机聚硅氧烷的含量。 有机聚硅氧烷乳液由以下组成：（A）70〜90重量％的粘度为1×10 5 mPa·s以上的有机聚硅氧烷; （B）1〜15重量％的表面活性剂; 和（C）5〜25重量％的水。

公开(公告)号：US5871761A

公开(公告)日：1999-02-16

申请号：US928671

申请日：1997-09-12

申请人： Satoshi Kuwata ,  Morizo Nakazato ,  Yoshinori Inokuchi

发明人： Satoshi Kuwata ,  Morizo Nakazato ,  Yoshinori Inokuchi

IPC分类号： A61K8/04 ,  A61K8/891 ,  A61K8/892 ,  A61K8/895 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q19/00 ,  A61K6/00 ,  A61K7/00 ,  A61K7/06

CPC分类号： A61Q19/00 ,  A61K8/025 ,  A61K8/891 ,  A61K8/895 ,  A61K2800/412 ,  A61K2800/81 ,  A61Q5/00 ,  A61Q5/02

摘要： Proposed is a reliable method for the preparation of a water-base hair-care or skin-care toiletry preparation capable of imparting the hair or skin of the user with excellent touch feeling of smoothness and sleekness. The method comprises (a) preparing an aqueous dispersion of globular particles of a cured silicone rubber having a specified average particle diameter by the in situ crosslinking hydrosilation reaction in liquid droplets of a vinyl group-containing dimethylpolysiloxane and an organohydrogenpolysiloxane in combination in the presence of a surface active agent and (b) admixing a base mixture consisting of the principal ingredients of a water-base toiletry composition with a specified amount of the aqueous dispersion of the cured silicone rubber particles.

摘要翻译： 提出了一种制备能够赋予使用者的头发或皮肤的优异的平滑度和光滑感的水性护发或护肤化妆品制剂的可靠方法。 该方法包括：（a）通过在含乙烯基的二甲基聚硅氧烷和有机氢聚硅氧烷的液滴中的原位交联氢化硅烷化合物，在具有特定平均粒径的固化硅橡胶的存在下， 表面活性剂和（b）将由水性盥洗用组合物的主要成分组成的碱性混合物与规定量的固化的硅橡胶粒子的水分散液混合。

公开(公告)号：US5788884A

公开(公告)日：1998-08-04

申请号：US827447

申请日：1997-03-28

申请人： Satoshi Kuwata ,  Morizo Nakazato ,  Hideki Hagiwara ,  Teruki Ikeda

发明人： Satoshi Kuwata ,  Morizo Nakazato ,  Hideki Hagiwara ,  Teruki Ikeda

IPC分类号： A61K8/06 ,  A61K8/41 ,  A61K8/891 ,  A61Q5/00 ,  C08J3/03 ,  B01J13/00 ,  A61K7/075 ,  A61K7/08

CPC分类号： A61Q5/00 ,  A61K8/062 ,  A61K8/416 ,  A61K8/891 ,  C08J3/03 ,  C08J2383/04 ,  Y10S516/924

摘要： A novel aqueous organopolysiloxane emulsion composition of the oil-in-water type suitable as an additive ingredient in toiletry preparations for hair-care treatment, of which the organopolysiloxane particles have a relatively large volume-average particle diameter of 3 to 100 .mu.m as emulsified by using a quaternary ammonium chloride as a cationic surface active agent. The emulsion composition is advantageous in respect of the improved stability of the emulsion and increased retention on the hair treated with the hair-care composition. The emulsion composition is prepared in a process comprising the steps of: mixing the organopolysiloxane and the cationic surface active agent with a relatively small volume of water; vigorously agitating the mixture so as to cause phase inversion into an oil-in-water base emulsion; and diluting the base emulsion with an additional volume of water, optionally, containing the cationic surface active agent.

摘要翻译： 一种新型的水包油型有机聚硅氧烷乳液组合物，其适用于头发护理处理的化妆品制剂中的添加成分，其中有机聚硅氧烷颗粒具有相对较大的体积平均粒径为3至100μm的乳化剂 通过使用季铵氯化物作为阳离子表面活性剂。 乳液组合物在改善乳液稳定性和增加毛发护理组合物处理毛发上的保留性方面是有利的。 乳液组合物的制备方法包括以下步骤：将有机聚硅氧烷和阳离子表面活性剂与相对小体积的水混合; 大力搅拌混合物，使其相转化成水包油乳液; 并用额外体积的水稀释基础乳液，任选地含有阳离子表面活性剂。

公开(公告)号：US5705445A

公开(公告)日：1998-01-06

申请号：US488010

申请日：1995-06-07

申请人： Tsuneo Chikaraishi ,  Yasushi Masuda ,  Hiroshi Ohashi ,  Yoshinobu Takahashi ,  Morizo Nakazato ,  Takeshi Fukuda

发明人： Tsuneo Chikaraishi ,  Yasushi Masuda ,  Hiroshi Ohashi ,  Yoshinobu Takahashi ,  Morizo Nakazato ,  Takeshi Fukuda

IPC分类号： B60R21/16 ,  B60R21/235 ,  C08L83/02 ,  C08L83/04 ,  C09D183/04 ,  D06M11/79 ,  D06M13/02 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  D06M15/65 ,  D06N3/12 ,  B32B27/12 ,  B32B27/28

CPC分类号： B60R21/235 ,  C09D183/04 ,  D06M11/79 ,  D06M15/643 ,  D06M15/6436 ,  D06M15/65 ,  D06N3/128 ,  Y10T428/1362 ,  Y10T442/2369 ,  Y10T442/2385

摘要： Disclosed is a base fabric for automobile air bags having excellent flexibility to ensure compact folding of the air bag and high flame retardancy for safety in hazard, which consists of a woven fabric web and a rubbery coating layer formed thereon from a silicone-based coating composition in the form of an aqueous emulsion comprising: (a) 100 parts by weight of an organopolysiloxane represented by the general formula X--�--SiR.sup.1.sub.2 --O--!.sub.m --�--SiZ.sub.2 --O--!n-SiR.sup.1.sub.2 --X, in which R.sup.1 is a monovalent hydrocarbon group having 1 to 20 carbon atoms, Z is R.sup.1, OR.sup.2 or --(--O--SiR.sup.1.sub.2 --).sub.k --OR.sup.2, R.sup.2 being a hydrogen atom or R.sup.1 and k being a positive integer not exceeding 1000, X is R.sup.1 or OR.sup.2, m is a positive integer of 100 to 10,000 and n is 0 or a positive integer not exceeding 1,000 and which contains at least two OR.sup.2 groups in a molecule; (b) from 0.5 to 50 parts by weight of an organohydrogen polysiloxane having, in a molecule, at least three silicon-bonded hydrogen atoms; (c) from 0.5 to 100 parts by weight of a finely divided silica filler or a powder of an polyorganosilsesquioxane; (d) from 0.1 to 20 parts by weight of an alkoxy silane compound having, in a molecule, at least one amido group and at least one carboxyl group or a partial hydrolysis-condensation product thereof: (e) from 0.1 to 20 parts by weight of an alkoxy silane compound having, in a molecule, at least one epoxy or amino group or a partial hydrolysis-condensation product thereof; and (f) from 0.01 to 10 parts by weight of a curing catalyst for the composition.

摘要翻译： 公开了一种用于汽车气囊的基底织物，其具有优异的灵活性，以确保气囊的紧凑折叠和用于安全危险的高阻燃性，其由织造纤维网和由硅氧烷基涂料组合物形成在其上的橡胶状涂层组成 其包含：（a）100重量份由通式X - [-SiR 12 -O] m - [-SiZ 2 -O-] n -SiR 12-X表示的有机聚硅氧烷，其中 R1为碳原子数1〜20的一价烃基，Z为R1，OR2或 - （ - O-SiR12-）k-OR2，R2为氢原子或R1，k为不超过1000的正整数，X为 R1或OR2，m为100〜10000的正整数，n为0或不超过1000的正整数，并且在分子中含有至少两个OR 2基团; （b）0.5至50重量份的分子中至少有三个与硅键合的氢原子的有机氢聚硅氧烷; （c）0.5-100重量份细碎二氧化硅填料或聚有机倍半硅氧烷粉末; （d）0.1〜20重量份在分子中具有至少一个酰胺基和至少一个羧基的部分水解缩合产物的烷氧基硅烷化合物或其部分水解缩合产物：（e）0.1至20份 在分子中具有至少一个环氧基或氨基或其部分水解缩合产物的烷氧基硅烷化合物的重量; 和（f）0.01至10重量份的用于该组合物的固化催化剂。

公开(公告)号：US5500148A

公开(公告)日：1996-03-19

申请号：US091116

申请日：1993-07-13

申请人： Toshio Ohba ,  Naomi Sato ,  Masahiko Ogawa ,  Morizo Nakazato

发明人： Toshio Ohba ,  Naomi Sato ,  Masahiko Ogawa ,  Morizo Nakazato

IPC分类号： B01F17/54 ,  C08K5/09 ,  C08L83/04 ,  C08L83/10

CPC分类号： C08K5/09 ,  C08L83/04 ,  C08G77/045 ,  C08G77/12 ,  C08G77/20

摘要： Proposed is an improved aqueous silicone emulsion composition for surface-release treatment comprising a vinyl-containing organopolysiloxane and an organohydrogenpolysiloxane emulsified is an aqueous medium with addition of a platinum compound as a catalyst for the hydrosilation reaction between the silicon-bonded vinyl groups and silicon-bonded hydrogen atoms. Different from conventional silicone emulsion compositions of this type having a pH value of around neutrality, the inventive silicone emulsion composition has a pH value not higher than 5 so that a quite unexpected advantage can be obtained that the stability of the emulsion composition in the curability and other properties after a long period of storage and against mechanical working can be greatly improved.

摘要翻译： 提出了一种用于表面释放处理的改进的水性硅氧烷乳液组合物，其包含含乙烯基的有机聚硅氧烷和乳化的有机氢聚硅氧烷，其是添加铂化合物作为硅键合的乙烯基和硅键合的乙烯基之间的硅氢化反应的催化剂的水性介质， 键合的氢原子。 不同于具有大约中性的pH值的这种类型的常规硅氧烷乳液组合物，本发明的硅氧烷乳液组合物的pH值不高于5，因此可以获得非常意想不到的优点，即乳液组合物在固化性和 经过长时间的储存和机械加工后的其他性能可以大大提高。

公开(公告)号：US06290942B1

公开(公告)日：2001-09-18

申请号：US09320268

申请日：1999-05-27

申请人： Morizo Nakazato ,  Hisashi Aoki

发明人： Morizo Nakazato ,  Hisashi Aoki

IPC分类号： A61K706

CPC分类号： A61K8/893 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12 ,  C08G77/14 ,  C08L83/06

摘要： The invention provides an emulsion comprising an organopolysiloxane of the formula: R1xR2yR3zSiO(4−x−y−z)/2 wherein R1 is a monovalent C1-20 hydrocarbon group, R2 is as defined for R1 or OX wherein X is hydrogen or a monovalent C1-6 hydrocarbon group, R3 is —R4COOH wherein R4 is a divalent C1-20 hydrocarbon group, 0

摘要翻译： 本发明提供一种乳液，其包含下式的有机聚硅氧烷：其中R1是一价C 1-20烃基，R 2如R1或OX所定义，其中X是氢或一价C 1-6烃基，R 3是-R 4 COOH其中R 4 是二价C 1-20烃基，0

公开(公告)号：US5973066A

公开(公告)日：1999-10-26

申请号：US192581

申请日：1998-11-17

申请人： Koji Sakuta ,  Morizo Nakazato ,  Teruki Ikeda

发明人： Koji Sakuta ,  Morizo Nakazato ,  Teruki Ikeda

IPC分类号： A61K8/06 ,  A61K8/34 ,  A61K8/41 ,  A61K8/58 ,  A61K8/891 ,  A61K8/894 ,  A61K8/895 ,  A61Q5/00 ,  C08J3/03 ,  C08L83/04 ,  B01J13/00

CPC分类号： A61K8/894 ,  A61K8/062 ,  A61K8/345 ,  A61K8/416 ,  A61K8/585 ,  A61K8/891 ,  A61Q19/00 ,  C08J3/03 ,  A61Q5/12 ,  C08J2383/04

摘要： An oil-in-water aqueous organopolysiloxane emulsion suitable as an adjuvant, in particular, in a toiletry preparation such as a hair-care treatment preparation is disclosed by using a unique emulsification system including a quaternary ammonium chloride as a cationic surface active agent, in order to provide a solution for the problem of a dilemma between the use of a C.sub.16 or lower-alkyl quaternary ammonium salt having high emulsification power but exhibiting irritativeness to the human body and the use of a higher-alkyl quaternary ammonium salt having lower emulsification power but exhibiting no irritativeness. The emulsion composition comprises: (A) a high-polymeric organopolysiloxane mixed with and diluted by an organopolysiloxane of a lower viscosity; (B) a quaternary ammonium chloride having 1 or 2 stearyl or behenyl groups; (C) a polyoxyalkylene-modified organopolysiloxane or a polyhydric alcohol as an activity-promoting agent for the component (B); and (D) water each in a specified weight proportion. The emulsion can be prepared by first forming a water-in-oil emulsion from the respective ingredients though with a reduced amount of water, then effecting phase inversion of the emulsion by continued agitation from the water-in-oil emulsion to an oil-in-water emulsion; and diluting the emulsion with an additional amount of water.

摘要翻译： 通过使用包含季铵氯化物作为阳离子表面活性剂的独特的乳化系统，公开了适合作为助剂的水包油水有机聚硅氧烷乳液，特别是在化妆品制剂例如护发剂处理制剂中， 为了提供使用具有高乳化能力但对人体具有刺激性的C16或低级烷基季铵盐之间的困境的问题的解决方案，以及使用具有较低乳化能力的高级烷基季铵盐 但没有刺激性。 该乳液组合物包含：（A）与较低粘度的有机聚硅氧烷混合并稀释的高聚物有机聚硅氧烷; （B）具有1或2个硬脂基或二十二烷基的季铵氯化物; （C）作为组分（B）的活性促进剂的聚氧化烯改性的有机聚硅氧烷或多元醇; 和（D）水以指定的重量比例。 乳液可以通过首先用相应成分形成油包水乳液来制备，尽管通过减少量的水，然后通过从油包水乳液继续搅拌到油包水进行相转化 水乳液 并用额外量的水稀释乳液。