公开(公告)号：US06570048B1

公开(公告)日：2003-05-27

申请号：US09602488

申请日：2000-06-23

申请人： Gerry D. Getman ,  Wood E. Hunter ,  Rudolph H. Moyer

发明人： Gerry D. Getman ,  Wood E. Hunter ,  Rudolph H. Moyer

IPC分类号： A62D300

CPC分类号： A62D3/38 ,  A62D2101/02 ,  A62D2101/26

摘要： Organophosphorous compounds containing C—P chemical bonds are oxidized with alkaline peroxysulfate to yield orthophosphates. For example, phosphinates, including certain chemical warfare agents, as well as phosphinate salts produced by the solvated electron reduction of the chemical warfare agents, are oxidized to orthophosphates.

摘要翻译： 含有C-P化学键的有机磷化合物用碱性过氧硫酸盐氧化，得到正磷酸盐。 例如，包括某些化学战剂在内的次膦酸盐以及化学战剂的溶剂化电子还原产生的次膦酸盐被氧化为正磷酸盐。

公开(公告)号：US6121506A

公开(公告)日：2000-09-19

申请号：US329533

申请日：1999-06-10

申请人： Albert E. Abel ,  Robert W. Mouk ,  Gerry D. Getman ,  Wood E. Hunter

发明人： Albert E. Abel ,  Robert W. Mouk ,  Gerry D. Getman ,  Wood E. Hunter

IPC分类号： A62D3/00 ,  A62D3/30 ,  A62D3/34 ,  A62D3/36 ,  A62D3/37 ,  A62D101/02 ,  A62D101/06 ,  A62D101/22 ,  A62D101/26 ,  A62D101/28 ,  F42B33/00

CPC分类号： A62D3/36 ,  A62D3/30 ,  A62D2101/02 ,  A62D2101/06 ,  A62D2101/26 ,  Y10S149/124

摘要： Energetic materials, such as nitrocellulose, TNT, RDX, and combinations thereof, optionally in combination with chemical warfare agents, such as mustard gas, Lewisite, Tabun, Sarin, Toman, VX, and combinations thereof, are destroyed when chemically reacted according to the method of the invention. The method comprises reacting the energetic materials and chemical warfare agents, of present, with solvated electrons which are preferably produced by dissolving an active metal such as sodium in a nitrogenous base such as anhydrous liquid ammonia.

摘要翻译： 与化学战剂（如芥子气，Lewisite，Tabun，Sarin，Toman，VX及其组合）相结合的能量物质如硝酸纤维素，TNT，RDX及其组合在化学反应时被破坏， 本发明的方法。 该方法包括使能量材料和化学战剂与溶剂化电子反应，溶剂化电子优选通过将诸如钠的活性金属溶解在诸如无水液氨的含氮碱中而产生。

公开(公告)号：US6049021A

公开(公告)日：2000-04-11

申请号：US248879

申请日：1999-02-11

申请人： Gerry D. Getman ,  Jon E. Rogers ,  Wood E. Hunter

发明人： Gerry D. Getman ,  Jon E. Rogers ,  Wood E. Hunter

IPC分类号： A62D3/00 ,  A62D3/32 ,  A62D3/34 ,  A62D3/36 ,  A62D101/06 ,  A62D101/20 ,  A62D101/22 ,  A62D101/24 ,  A62D101/26 ,  A62D101/28 ,  B01D11/00 ,  B01J8/00 ,  B09B3/00 ,  B09C1/02 ,  B09C1/08 ,  C02F1/70 ,  G21F20060101 ,  G21F9/00 ,  G21F9/28

CPC分类号： B09C1/08 ,  G21F9/001 ,  G21F9/30

摘要： Methods for decontaminating toxic waste, particularly solid carrier materials, such as soil contaminated with a toxin, or solid mixed wastes are more efficiently decontaminated with solvated electrons by first extracting the toxin from the carrier with a nitrogenous base at elevated temperatures, followed by a temperature reduction before initiating chemical reduction of the toxin with solvated electrons. Pre-extraction of the toxin at elevated temperatures followed by temperature reduction minimizes competing side reactions, improves selectivity of solvated electrons for the toxin and improves the economics of the process with more efficient metal utilization. The process can be performed without separation of the toxin from the extraction vessel holding the solid carrier material. Alternatively, elevated temperatures can be used to perform one or more extractions of toxin with nitrogenous base followed by reduction with solvated electrons by performing the reaction in a separate reactor. The processes of the invention are useful in the destruction of virtually any chemically reducible hazardous substance.

摘要翻译： 用有毒废物，特别是固体载体材料（如毒素污染的土壤）或固体混合废物进行净化的方法，通过首先在高温下用含氮碱从载体中提取毒素，再用溶剂化电解进行更有效的净化，然后加入温度 在用溶剂化电子开始化学还原毒素之前还原。 在升高的温度下预先提取毒素，随后进行温度降低，使竞争性副反应最小化，提高溶剂化电子对毒素的选择性，并通过更有效的金属利用来改善该方法的经济性。 该过程可以在不将毒素从保持固体载体材料的萃取容器中分离的情况下进行。 或者，升高的温度可用于用含氮碱进行一次或多次毒素提取，然后通过在单独的反应器中进行反应而用溶剂化电子还原。 本发明的方法可用于几乎任何化学还原性有害物质的破坏。

公开(公告)号：US5998691A

公开(公告)日：1999-12-07

申请号：US61603

申请日：1998-04-16

申请人： Albert E. Abel ,  Robert W. Mouk ,  Alan F. Heyduk ,  Bentley J. Blum ,  Gerry D. Getman ,  Mark D. Steskal

发明人： Albert E. Abel ,  Robert W. Mouk ,  Alan F. Heyduk ,  Bentley J. Blum ,  Gerry D. Getman ,  Mark D. Steskal

IPC分类号： A62D3/00 ,  A62D3/36 ,  A62D3/37 ,  A62D3/38 ,  A62D101/02 ,  A62D101/22 ,  A62D101/24 ,  A62D101/26 ,  A62D101/28 ,  A62D101/45 ,  B01J19/00 ,  B01D11/02 ,  B01J10/00

CPC分类号： A62D3/38 ,  A62D3/37 ,  A62D2101/02 ,  A62D2101/22 ,  A62D2101/24 ,  A62D2101/26 ,  A62D2101/28 ,  A62D2101/45 ,  A62D2203/02 ,  A62D2203/10 ,  Y10S149/124 ,  Y10S588/90

摘要： Chemical warfare agents, including vesicants and nerve agents distributed throughout the world, are destroyed when chemically reacted according to the method and utilizing the apparatus of this invention. The method comprises reacting the chemical warfare agents with nitrogenous base, optionally containing solvated electrons which are conveniently produced by dissolving an active metal like sodium in a nitrogenous base such as anhydrous liquid ammonia.

摘要翻译： 分散在世界各地的化学战剂，包括发泡剂和神经毒剂在根据本发明的方法和利用本发明的装置进行化学反应时被破坏。 该方法包括使化学战剂与含氮碱反应，任选地含有溶剂化电子，其通过将诸如钠的活性金属溶解在诸如无水液态氨的含氮碱中方便地制备。

公开(公告)号：US07851653B2

公开(公告)日：2010-12-14

申请号：US11386485

申请日：2006-03-22

申请人： Gerry D. Getman ,  Matt Bootman ,  Donald Wagner, Jr. ,  Thomas Ward

发明人： Gerry D. Getman ,  Matt Bootman ,  Donald Wagner, Jr. ,  Thomas Ward

IPC分类号： C07C211/00

CPC分类号： C08G77/26 ,  A01N25/34 ,  A01N33/12 ,  A01N55/00 ,  C08G73/0246 ,  C09D183/08 ,  Y10T428/24909 ,  Y10T428/25 ,  Y10T428/257 ,  Y10T428/259 ,  Y10T428/31663 ,  Y10T428/31942 ,  Y10T428/31993 ,  A01N2300/00

摘要： An antimicrobial polymer is disclosed containing silicon-containing quaternary ammonium groups, the polymer including in its structure repeating units of Formula II: R3N+R0nSiX′4-nY−  (II) wherein each R and each R0 is independently a non-hydrolysable organic group; each X′ is —OR′, —OH or —O—Si, wherein R′ is an alkyl group of 1 to about 22 carbon atoms, or an aryl group of 6 carbon atoms; n is an integer of 0 to 3; and Y is an anionic moiety suitable to form the salt of the repeating units of Formula II. Also disclosed are methods of making such a polymer and imparting sustained antimicrobial properties to a substrate using the polymer.

摘要翻译： 公开了含有含硅季铵基团的抗微生物聚合物，该聚合物在其结构中包含其结构式II的重复单元：R3N + R0SiSiO4-nY-（Ⅱ），其中每个R和每个R0独立地是不可水解的有机基团 ; 每个X'为-OR'，-OH或-O-Si，其中R'为1至约22个碳原子的烷基或6个碳原子的芳基; n为0〜3的整数， 并且Y是适于形成式II重复单元的盐的阴离子部分。 还公开了制备这种聚合物并使用聚合物赋予基材持续抗微生物性能的方法。

公开(公告)号：US07858141B2

公开(公告)日：2010-12-28

申请号：US11386348

申请日：2006-03-22

申请人： Gerry D. Getman ,  Matt Bootman ,  Donald Wagner, Jr. ,  Thomas Ward

发明人： Gerry D. Getman ,  Matt Bootman ,  Donald Wagner, Jr. ,  Thomas Ward

IPC分类号： B05D3/00

CPC分类号： C08G77/26 ,  A01N25/34 ,  A01N33/12 ,  A01N55/00 ,  C08G73/0246 ,  C09D183/08 ,  Y10T428/24909 ,  Y10T428/25 ,  Y10T428/257 ,  Y10T428/259 ,  Y10T428/31663 ,  Y10T428/31942 ,  Y10T428/31993 ,  A01N2300/00

摘要： A method of imparting sustained antimicrobial properties throughout a material or substrate using an antimicrobial polymerizable silicon-containing quaternary ammonium salt monomer in a solvent to form a quaternary ammonium salt solution; and mixing the silicon-containing quaternary ammonium salt solution with at least a second monomer or a polymer or coating a solid polymer. Depending on the nature of the second monomer or polymer and the reaction conditions; a copolymer with the first monomer or a homopolymer will form, such that a polymeric material, substrate or formed plastic product comprising the copolymer or homopolymer or blended with the coated concentrate will have sustained antimicrobial properties. This method can be used to make formed plastic products, thin layer films and other products having sustained antimicrobial properties.

摘要翻译： 一种在溶剂中使用抗微生物聚合性含硅季铵盐单体在整个材料或基底上赋予持续抗微生物性以形成季铵盐溶液的方法; 并将含硅季铵盐溶液与至少第二单体或聚合物混合或涂覆固体聚合物。 取决于第二单体或聚合物的性质和反应条件; 将形成与第一单体或均聚物的共聚物，使得包含共聚物或均聚物或与被包被的浓缩物混合的聚合材料，基底或成形塑料产品将具有持续的抗微生物性质。 该方法可用于制成成型塑料制品，薄膜等具有持久抗菌性能的产品。

公开(公告)号：US06175051B1

公开(公告)日：2001-01-16

申请号：US09542167

申请日：2000-04-04

申请人： Gerry D. Getman

发明人： Gerry D. Getman

IPC分类号： G21F910

CPC分类号： C01D3/04 ,  C22B3/0002 ,  C22B3/14 ,  C22B3/44 ,  C22B26/10 ,  G21F9/10 ,  G21F9/30 ,  Y02P10/234

摘要： Liquid metal coolants, such as alkali metal used in nuclear reactor systems can be safely deactivated to form a disposable solid waste material. The alkali metal is dissolved in an ammoniacal liquid, such as anhydrous liquid ammonia to form a reaction mixture comprising alkali metal cations and solvated electrons. A precipitating agent that ionizes in the liquid ammonia is introduced into the reaction mixture to combine with the alkali metal cations and/or solvated electrons to form a precipitating alkali metal salt. Additionally, solidified alkali metal remaining within the coolant system after initial drainage of liquid alkali metal can be dissolved by circulating an ammoniacal liquid within the coolant system. Removal of the liquid ammonia having the alkali metal dissolved therein is combined with a ionizable precipitating agent to form a alkali metal salt.

摘要翻译： 液态金属冷却剂，例如在核反应堆系统中使用的碱金属可以安全地失活以形成一次性固体废料。 将碱金属溶解在诸如无水液氨的氨水中以形成包含碱金属阳离子和溶剂化电子的反应混合物。 将引入液态氨的沉淀剂引入反应混合物中以与碱金属阳离子和/或溶剂化电子结合形成析出的碱金属盐。 此外，液态碱金属初始排放后残留在冷却剂系统内的固化碱金属可以通过使氨液体循环在冷却剂系统内来溶解。 将其中溶解有碱金属的液氨的除去与可电离沉淀剂组合以形成碱金属盐。

公开(公告)号：US07972408B2

公开(公告)日：2011-07-05

申请号：US10557941

申请日：2004-05-20

申请人： Bruce L. Bruso ,  Gerry D. Getman

发明人： Bruce L. Bruso ,  Gerry D. Getman

IPC分类号： C05B9/00 ,  C02F1/68 ,  A62D3/36 ,  C05C5/00 ,  C05D9/00 ,  C05D1/02 ,  B09C1/08

CPC分类号： C02F11/08 ,  B09C1/02 ,  B09C1/08 ,  C02F11/004 ,  C02F2103/20 ,  C02F2201/008 ,  C05F5/004 ,  C05F7/00 ,  Y02A40/209 ,  Y02A40/213

摘要： An apparatus and a method for treating a composition containing toxic materials or biosolids, wherein the apparatus has a hydraulically sealable top that can be opened to allow loading of the composition or closed to seal the apparatus. The apparatus also includes a reagent injection system for injecting a reagent into the apparatus, a mixing device for mixing the composition with the reagent, a heater system for heating the composition, or the mixture of the composition and the reagent, an internal vapor recovery system for recovering gases, vapors, and odors from the toxic materials or biosolids, or from the reagents, a reagent recovery system for recovering the reagent after it has been mixed with the composition, a discharge mechanism for discharging the treated composition, and a control panel comprising temperature and pressure measurements.

摘要翻译： 一种用于处理含有有毒材料或生物固体的组合物的装置和方法，其中所述装置具有液压可密封的顶部，所述顶部可打开以允许所述组合物的装载或封闭以密封所述装置。 该装置还包括用于将试剂注入到装置中的试剂注入系统，用于将组合物与试剂混合的混合装置，用于加热组合物的加热器系统或组合物和试剂的混合物，内部蒸气回收系统 用于从有毒材料或生物固体或者试剂中回收气体，蒸汽和气味，或者用于将试剂与组合物混合后用于回收试剂的试剂回收系统，用于排出处理过的组合物的排放机构和控制面板 包括温度和压力测量。