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公开(公告)号:US6161879A
公开(公告)日:2000-12-19
申请号:US948422
申请日:1997-10-10
申请人: Hans Ries , Frank Lorenz , Guido Schmitz
发明人: Hans Ries , Frank Lorenz , Guido Schmitz
CPC分类号: F16L47/24
摘要: A connector for connecting an assembly to a pipe, which is highly leakproof with respect to the medium to be transported and is secure against separation under axial load. The connector comprises two materials A and B which swell to different degrees. A part comprising the more strongly swelling material A has, at the junction with the material B, a peripheral connecting lip which is substantially enclosed by the less swelling material B, so that a positive connection is achieved.
摘要翻译: 一种用于将组件连接到管道的连接器,其相对于要运输的介质是高度防漏的,并且在轴向负载下是防止分离的。 连接器包括膨胀到不同程度的两种材料A和B。 包含较强膨胀材料A的部分在与材料B的接合处具有基本上被较小膨胀材料B包围的周边连接唇缘,从而实现了正的连接。
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2.
公开(公告)号:US20080317986A1
公开(公告)日:2008-12-25
申请号:US10588487
申请日:2005-08-10
申请人: Guido Schmitz , Harald Hager , Hans Ries
发明人: Guido Schmitz , Harald Hager , Hans Ries
CPC分类号: C08L23/04 , B32B1/08 , B32B3/28 , B32B7/12 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/322 , B32B27/34 , B32B2250/24 , B32B2264/0207 , B32B2270/00 , B32B2307/202 , B32B2307/558 , B32B2307/7242 , B32B2307/7265 , B32B2439/40 , B32B2597/00 , B32B2605/08 , C08L23/10 , C08L77/02 , C08L77/06 , C08L2666/04 , C09J177/02 , C09J177/06 , F16L9/133 , Y10S138/01 , Y10S138/07 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31732 , C08L2666/20
摘要: A multilayer composite which comprises the following layers: I. an interior layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding agent layer II which has the following composition: a) from 0 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of polyamide, c) from 0 to 85 parts by weight of a polymer selected from among fluoropolymers and polyolefins, with the sum of the parts by weight of a), b) and c) being 100, and, in addition, the sum of the components a) and b) comprising at least 20 parts by weight of monomer units derived from caprolactam and/or the combination hexamethylenediamine/adipic acid, hexamethylenediamine/suberic acid, hexamethylenediamine/sebacic acid, hexamethylenediamine/dodecanedioic acid, hexamethylenediamine/isophthalic acid or hexamethylenediamine/terephthalic acid and d) not more than 50 parts by weight of additives selected from among impact-modifying rubber and customary auxiliaries and additives; III. a layer III comprising an EVOH molding composition, has improved adhesion of the layers.
摘要翻译: 一种多层复合材料,其包含以下层:I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二, 具有以下组成的粘合剂层II:a)0至80重量份的聚胺 - 聚酰胺接枝共聚物,b)0至85重量份的聚酰胺,c)0至85重量份的 选自含氟聚合物和聚烯烃的聚合物,其中a),b)和c)的重量份的总和为100,另外,组分a)和b)的总和包含至少20份 衍生自己内酰胺和/或六亚甲基二胺/己二酸,六亚甲基二胺/辛二酸,六亚甲基二胺/癸二酸,六亚甲基二胺/十二烷二酸,六亚甲基二胺/间苯二甲酸或六亚甲基二胺/对苯二甲酸的单体单元的重量和d)不超过50份 选自改性橡胶和常规助剂和添加剂的添加剂的重量; 三, 包含EVOH模塑组合物的层III具有改善的层的粘附性。
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公开(公告)号:US08048504B2
公开(公告)日:2011-11-01
申请号:US11357971
申请日:2006-02-22
申请人: Guido Schmitz , Harald Haeger , Hans Ries , Wilfried Bartz
发明人: Guido Schmitz , Harald Haeger , Hans Ries , Wilfried Bartz
CPC分类号: B32B27/34 , B32B1/02 , B32B1/08 , B32B3/28 , B32B27/08 , B32B27/28 , B32B27/306 , B32B27/32 , B32B2250/03 , B32B2250/24 , B32B2250/40 , B32B2270/00 , B32B2272/00 , B32B2307/202 , B32B2307/308 , B32B2307/50 , B32B2307/714 , B32B2307/7242 , B32B2307/7244 , B32B2307/7265 , B32B2323/04 , B32B2331/04 , B32B2377/00 , B32B2439/40 , B32B2439/70 , B32B2597/00 , B32B2605/08 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31732 , Y10T428/3175
摘要: A layered composite which includes the following layers (I) and (II), wherein layer (I) includes (a) from 0 to 80 part by weight of at least one particular polyamide; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer; and (c) from 0 to 80 parts by weight of at least one particular polyamide which is different from (a), wherein various monomer units are present in at least 20 parts by weight of the entirety of (a) and (b) and various other monomer units are present in at least 20 parts by weight of the entirety of (b) and (c); and layer (II) includes at least one ethylene-vinyl alcohol copolymer.
摘要翻译: 包括以下层(I)和(II)的层状复合材料,其中层(I)包括(a)0至80重量份的至少一种特定聚酰胺; (b)0-100重量份的至少一种聚胺 - 聚酰胺共聚物; 和(c)0至80重量份的至少一种与(a)不同的特定聚酰胺,其中各种单体单元以(a)和(b)的全部至少20重量份存在,以及 各种其它单体单元存在于(b)和(c)全部的至少20重量份中; 和层(II)包括至少一种乙烯 - 乙烯醇共聚物。
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公开(公告)号:US20060141188A1
公开(公告)日:2006-06-29
申请号:US11357971
申请日:2006-02-22
申请人: Guido Schmitz , Harald Hager , Hans Ries , Wilfried Bartz
发明人: Guido Schmitz , Harald Hager , Hans Ries , Wilfried Bartz
IPC分类号: B32B1/08
CPC分类号: B32B27/34 , B32B1/02 , B32B1/08 , B32B3/28 , B32B27/08 , B32B27/28 , B32B27/306 , B32B27/32 , B32B2250/03 , B32B2250/24 , B32B2250/40 , B32B2270/00 , B32B2272/00 , B32B2307/202 , B32B2307/308 , B32B2307/50 , B32B2307/714 , B32B2307/7242 , B32B2307/7244 , B32B2307/7265 , B32B2323/04 , B32B2331/04 , B32B2377/00 , B32B2439/40 , B32B2439/70 , B32B2597/00 , B32B2605/08 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31732 , Y10T428/3175
摘要: The present invention provides a layered composite, which includes the following layers: (I) a layer I composition including: (a) from 0 to 80 part by weight of at least one polyamide selected from the group including PA6, PA66, PA6/66 and mixtures thereof; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer that includes the following monomer units: (α) from 0.5 to 25% by weight, based on the weight of the polyamine-polyamide copolymer, of at least one polyamine having at least 4 nitrogen atoms and having a number-average molar mass Mn of at least 146 g/mol, and (β) at least one polyamide-forming monomer selected from the group including lactam, ω-aminocarboxylic acid, equimolar combination of diamine and dicarboxylic acid, and mixtures thereof; and (c) from 0 to 80 parts by weight of at least one polyamide selected from the group including PA11, PA12, PA612, PA1012, PA1212 and wherein, in the layer I, a total of the parts by weight of (a), (b) and (c) is 100; wherein within an entirety of (a) and (b), at least 20 parts by weight of the entirety include monomer units selected from the group including caprolactam, combination of hexamethylenediamine/adipic acid, and mixtures thereof; and wherein within an entirety of (b) and (c), at least 20 parts by weight of the entirety include monomer units selected from the group including ω-aminoundecanoic acid, laurolactam, combination of hexamethylenediamine/1,12-dodecanedioic acid, combination of 1,10-decanediamine/1,12-dodecanedioic acid, combination of 1,12-dodecanediamine/1,12-dodecanedioic acid, and mixtures thereof; and (II) a layer II composition which includes at least one ethylene-vinyl alcohol copolymer.
摘要翻译: 本发明提供一种层状复合材料,其包括以下层:(I)I层组合物,其包含:(a)0至80重量份的至少一种选自包括PA6,PA66,PA6 / 66的聚酰胺 及其混合物; (b)0至100重量份的至少一种聚胺 - 聚酰胺共聚物,其包含以下单体单元:基于多胺 - 聚酰胺共聚物的重量计,0.5至25重量%的(α)至少 一种具有至少4个氮原子并具有至少146g / mol的数均摩尔质量M n N的多胺,和(β)至少一种选自包括内酰胺的聚酰胺形成单体 ,ω-氨基羧酸,二胺和二羧酸的等摩尔组合,及其混合物; 和(c)0至80重量份的至少一种选自PA11,PA12,PA612,PA1012,PA1212的聚酰胺,其中,在层I中,(a), (b)和(c)为100; 其中在(a)和(b)的整体中,至少20重量份的整体包括选自包括己内酰胺,六亚甲基二胺/己二酸的组合及其混合物的单体单元; 并且其中在(b)和(c)的整体中,至少20重量份的整体包括选自包括ω-氨基十一烷酸,月桂内酰胺,六亚甲基二胺/ 1,12-十二烷二酸的组合,组合 1,10-癸二胺/ 1,12-十二烷二酸,1,12-十二烷二胺/ 1,12-十二烷二酸的组合及其混合物; 和(II)包含至少一种乙烯 - 乙烯醇共聚物的II族组合物。
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5.
公开(公告)号:US20060083882A1
公开(公告)日:2006-04-20
申请号:US11240493
申请日:2005-10-03
申请人: Guido Schmitz , Harals Hager , Hans Ries
发明人: Guido Schmitz , Harals Hager , Hans Ries
CPC分类号: C08L77/00 , A22C13/0013 , A22C2013/0053 , A22C2013/0059 , B32B1/08 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2250/24 , B32B2307/718 , B32B2307/7242 , B32B2307/7265 , B32B2597/00 , B32B2605/08 , C08L67/02 , C08L77/06 , Y10T428/1321 , Y10T428/1334 , Y10T428/1352 , Y10T428/1372 , Y10T428/1386 , Y10T428/1393 , Y10T428/3154 , Y10T428/31544 , Y10T428/31736 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , Y10T428/31786 , Y10T428/31938 , C08L2666/02 , C08L2666/06
摘要: A multilayer composite which has improved adhesion between the layers, comprising the following layers: I. an inner layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding layer II which has the following composition: a) from 2 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of a polyester, c) from 0 to 85 parts by weight of a polymer selected from among polyamides, fluoropolymers and polyolefins, where the sum of the parts by weight of a), b) and c) is 100; d) not more than 50 parts by weight of additives; III. a layer III of a polyester molding composition.
摘要翻译: 具有改善的层之间的粘附性的多层复合材料,包括以下层:I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二, 具有以下组成的粘合层II:a)2至80重量份的聚胺 - 聚酰胺接枝共聚物,b)0至85重量份的聚酯,c)0至85重量份的 选自聚酰胺,含氟聚合物和聚烯烃的聚合物,其中a),b)和c)的重量份之和为100; d)不超过50重量份的添加剂; 三, 聚酯模塑组合物的层III。
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6.
公开(公告)号:US08221890B2
公开(公告)日:2012-07-17
申请号:US11240493
申请日:2005-10-03
申请人: Guido Schmitz , Harald Haeger , Hans Ries
发明人: Guido Schmitz , Harald Haeger , Hans Ries
IPC分类号: B32B1/08 , B32B27/06 , B32B25/16 , B32B27/00 , B32B27/04 , B32B27/08 , B32B27/28 , B32B27/32 , B32B27/34 , B32B27/36 , B32B37/00 , B29C47/06 , B29C45/00
CPC分类号: C08L77/00 , A22C13/0013 , A22C2013/0053 , A22C2013/0059 , B32B1/08 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2250/24 , B32B2307/718 , B32B2307/7242 , B32B2307/7265 , B32B2597/00 , B32B2605/08 , C08L67/02 , C08L77/06 , Y10T428/1321 , Y10T428/1334 , Y10T428/1352 , Y10T428/1372 , Y10T428/1386 , Y10T428/1393 , Y10T428/3154 , Y10T428/31544 , Y10T428/31736 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , Y10T428/31786 , Y10T428/31938 , C08L2666/02 , C08L2666/06
摘要: A multilayer composite which has improved adhesion between the layers, with the following layers: I. an inner layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding layer II which has the following composition: a) from 2 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of a polyester, c) from 0 to 85 parts by weight of a polymer selected from among polyamides, fluoropolymers and polyolefins, where the sum of the parts by weight of a), b) and c) is 100; d) not more than 50 parts by weight of additives; III. a layer III of a polyester molding composition.
摘要翻译: 具有改进的层之间的粘合性的多层复合材料,具有以下层:I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二, 具有以下组成的粘合层II:a)2至80重量份的聚胺 - 聚酰胺接枝共聚物,b)0至85重量份的聚酯,c)0至85重量份的 选自聚酰胺,含氟聚合物和聚烯烃的聚合物,其中a),b)和c)的重量份之和为100; d)不超过50重量份的添加剂; 三, 聚酯模塑组合物的层III。
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公开(公告)号:US06783821B2
公开(公告)日:2004-08-31
申请号:US10024379
申请日:2001-12-21
申请人: Hans Ries , Guido Schmitz , Harald Haeger
发明人: Hans Ries , Guido Schmitz , Harald Haeger
IPC分类号: B32B102
CPC分类号: C08L77/00 , B32B27/34 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/1393 , Y10T428/31562 , Y10T428/31728 , Y10T428/31732
摘要: A good layer adhesion can be achieved in a composite having two or more layers wherein a layer I is obtained from a molding composition which has the following components: a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof; b) from 0.05 to 100 parts by weight of a polyamine-polyamide copolymer; and c) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA11, PA12, PA612, PA1012, PA1212 and a mixture thereof; wherein a total of the parts by weight of components a), b) and c) is 100; wherein at least 20 parts by weight of components a) and b) is a monomer unit which is obtained from caprolactam and/or from a combination of hexamethylenediamine/adipic acid; and wherein at least 20 parts by weight of components b) and c) is a monomer unit which is obtained from &ohgr;-aminoundecanoic acid, laurolactam, a mixture of hexamethylenediamine and 1,12-dodecanedioic acid, a mixture of 1,10-decanediamine and 1,12-dodecanedioic acid, and/or a mixture of 1,12-dodecanediamine and 1,12-dodecanedioic acid.
摘要翻译: 在具有两层或更多层的复合材料中可以实现良好的层粘合性,其中层I由具有以下组分的模塑组合物获得:a)0至80重量份选自PA6, PA66,PA6 / 66及其混合物; b)0.05-100重量份的聚胺 - 聚酰胺共聚物; 和c)0至80重量份选自PA11,PA12,PA612,PA1012,PA1212的聚酰胺及其混合物;其中组分a),b)和c)的总重量份, 为100;其中至少20重量份的组分a)和b)是由己内酰胺和/或六亚甲基二胺/己二酸的组合获得的单体单元; 并且其中至少20重量份的组分b)和c)是由ω-氨基十一烷酸,月桂内酰胺,六亚甲基二胺和1,12-十二烷二酸的混合物得到的单体单元,1,10-癸二胺和 1,12-十二烷二酸和/或1,12-十二烷二胺和1,12-十二烷二酸的混合物。
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公开(公告)号:US07175896B2
公开(公告)日:2007-02-13
申请号:US10681279
申请日:2003-10-09
申请人: Guido Schmitz , Harald Haeger , Hans Ries , Wilfried Bartz
发明人: Guido Schmitz , Harald Haeger , Hans Ries , Wilfried Bartz
CPC分类号: B32B27/34 , B32B1/02 , B32B1/08 , B32B3/28 , B32B27/08 , B32B27/28 , B32B27/306 , B32B27/32 , B32B2250/03 , B32B2250/24 , B32B2250/40 , B32B2270/00 , B32B2272/00 , B32B2307/202 , B32B2307/308 , B32B2307/50 , B32B2307/714 , B32B2307/7242 , B32B2307/7244 , B32B2307/7265 , B32B2323/04 , B32B2331/04 , B32B2377/00 , B32B2439/40 , B32B2439/70 , B32B2597/00 , B32B2605/08 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31732 , Y10T428/3175
摘要: A layered composite contains the following layers: (I) a layer I composition containing (a) from 0 to 80 parts by weight of at least one polyamide; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer; and (c) from 0 to 80 parts by weight of at least one polyamide; and (II) a layer II composition containing at least one ethylene-vinyl alcohol copolymer.
摘要翻译: 层状复合物包含以下层:(I)含有(a)0至80重量份的至少一种聚酰胺的层I组合物; (b)0-100重量份的至少一种聚胺 - 聚酰胺共聚物; 和(c)0至80重量份的至少一种聚酰胺; 和(II)含有至少一种乙烯 - 乙烯醇共聚物的层II组合物。
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公开(公告)号:US20060099478A1
公开(公告)日:2006-05-11
申请号:US11246206
申请日:2005-10-11
申请人: Guido Schmitz , Harald Hager , Hans Ries , Olivier Farges
发明人: Guido Schmitz , Harald Hager , Hans Ries , Olivier Farges
CPC分类号: B32B27/34 , B32B1/08 , B32B27/08 , B32B27/18 , B32B27/306 , B32B27/32 , B32B2250/24 , B32B2307/21 , B32B2307/718 , B32B2307/7242 , B32B2307/7265 , B32B2457/18 , B32B2597/00 , B32B2605/08 , F16L9/12 , Y10T428/31728 , Y10T428/31757
摘要: An element of a line system of a fuel cell, in which the part which is in contact with the medium being conveyed comprises a polyamide molding composition and, in addition, at least one further layer selected from among: a) a layer II of a further polyamide molding composition; b) a layer III of a molding composition comprising a functionalized polyolefin; c) a layer IV of a polyolefin molding composition in which the polyolefin is not functionalized; and d) a layer V of an EVOH molding composition, is present, can be produced inexpensively and has a good barrier action against the medium being conveyed.
摘要翻译: 燃料电池的线路系统的元件,其中与所传送的介质接触的部分包括聚酰胺模制组合物,另外还有至少一个选自以下的另外的层:a) 进一步的聚酰胺模塑组合物; b)包含官能化聚烯烃的模塑组合物的层III; c)聚烯烃模塑组合物的层IV,其中聚烯烃未被官能化; 和d)存在EVOH模塑组合物的层V,可以廉价地生产并且对被输送的介质具有良好的屏障作用。
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公开(公告)号:US06680093B1
公开(公告)日:2004-01-20
申请号:US09079696
申请日:1998-05-15
申请人: Hans Ries , Michael Schlobohm , Guido Schmitz
发明人: Hans Ries , Michael Schlobohm , Guido Schmitz
IPC分类号: B29C4706
CPC分类号: B32B27/08 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2327/06 , B32B2367/00 , B32B2377/00 , B32B2439/00 , B32B2597/00 , C08L27/16 , C08L33/06 , C08L67/02 , C08L77/00 , F16L9/12 , F16L11/12 , F16L2011/047 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/3154 , Y10T428/31544 , Y10T428/31565 , Y10T428/31721 , Y10T428/31728 , Y10T428/31736 , Y10T428/31743 , Y10T428/31797 , C08L2666/02 , C08L2666/18 , C08L27/12
摘要: A multilayer composite comprises a layer configuration A/C/B or A/C/B/C/A, wherein I. each layer A comprises a molding composition that comprises at least 50% by weight of a polymer A containing amino groups; II. layer B comprises a molding composition that consists of at least 50% by weight of a thermoplastic polyester or fluoropolymer B; III. each layer C comprises a molding composition that consists essentially of the following components a)-c): a) from 5 to 95 parts by weight of the polymer A, b) from 95 to 5 parts by weight of the polymer B, and c) from 1 to 90 parts by weight of a compatibilizer comprising an alkyl acrylate polymer.
摘要翻译: 多层复合材料包括层构型A / C / B或A / C / B / C / A,其中I。 每个层A包括包含至少50重量%的含氨基的聚合物A的模塑组合物; II。 层B包括由至少50重量%的热塑性聚酯或含氟聚合物B组成的模制组合物; III。 每个层C包含基本上由以下组分组成的模制组合物a)-c):a)5至95重量份的聚合物A,b)95至5重量份的聚合物B,和c) 1至90重量份的包含丙烯酸烷基酯聚合物的增容剂。
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