Zirconium Hydroxide
    3.
    发明申请
    Zirconium Hydroxide 有权
    氢氧化锆

    公开(公告)号:US20090005239A1

    公开(公告)日:2009-01-01

    申请号:US12278074

    申请日:2007-01-24

    摘要: This invention relates to an improved amorphous zirconium hydroxide and a method for its production. The hydroxide has a surface area of at least 300 m2/g, a total pore volume of at least 0.70 cm3/g and an average pore size of between 5 nm and 15 nm, and is prepared by a process which comprises the steps of: a) preparing an aqueous solution comprising sulphate anions and a zirconium salt such that the ZrO2:SO3 ratio is 1:0.40 to 1:0.52, (b) chilling the solution to below 25° C., (c) adding an alkali in order to precipitate the amorphous zirconium hydroxide, (d) filtering and washing the precipitated zirconium hydroxide with water or an alkali to remove residual sulphate and chloride, (e) hydrothermally treating the zirconium hydroxide at a pressure of less than 3 barg, and (f) drying the zirconium hydroxide. The zirconium hydroxide of the present invention, which can be doped, is particularly useful in catalytic applications.

    摘要翻译: 本发明涉及一种改进的无定形氢氧化锆及其制备方法。 氢氧化物具有至少300m 2 / g的表面积,至少0.70cm 3 / g的总孔体积和5nm至15nm的平均孔径,并且通过包括以下步骤的方法制备: a)制备包含硫酸根阴离子和锆盐的水溶液,使得ZrO 2 :SO 3比为1:0.4至1:0.52,(b)将溶液冷却至低于25℃,(c)依次加入碱 (d)用水或碱过滤和洗涤沉淀的氢氧化锆以除去残余的硫酸盐和氯化物,(e)在小于3巴的压力下水热处理氢氧化锆,和(f) 干燥氢氧化锆。 可以掺杂的本发明的氢氧化锆在催化应用中特别有用。

    Zirconium hydroxide
    4.
    发明授权
    Zirconium hydroxide 有权
    氢氧化锆

    公开(公告)号:US07794687B2

    公开(公告)日:2010-09-14

    申请号:US12278074

    申请日:2007-01-24

    IPC分类号: C01G25/02

    摘要: This invention relates to an improved amorphous zirconium hydroxide and a method for its production. The hydroxide has a surface area of at least 300 m2/g, a total pore volume of at least 0.70 cm3/g and an average pore size of between 5 nm and 15 nm, and is prepared by a process which comprises the steps of: a) preparing an aqueous solution comprising sulphate anions and a zirconium salt such that the ZrO2:SO3 ratio is 1:0.40 to 1:0.52, (b) chilling the solution to below 25° C., (c) adding an alkali in order to precipitate the amorphous zirconium hydroxide, (d) filtering and washing the precipitated zirconium hydroxide with water or an alkali to remove residual sulphate and chloride, (e) hydrothermally treating the zirconium hydroxide at a pressure of less than 3 barg, and (f) drying the zirconium hydroxide. The zirconium hydroxide of the present invention, which can be doped, is particularly useful in catalytic applications.

    摘要翻译: 本发明涉及一种改进的无定形氢氧化锆及其制备方法。 氢氧化物具有至少300m 2 / g的表面积,至少0.70cm 3 / g的总孔体积和5nm至15nm的平均孔径,并且通过包括以下步骤的方法制备: a)制备包含硫酸根阴离子和锆盐的水溶液,使得ZrO 2 :SO 3比为1:0.4至1:0.52,(b)将溶液冷却至低于25℃,(c)依次加入碱 (d)用水或碱过滤和洗涤沉淀的氢氧化锆以除去残余的硫酸盐和氯化物,(e)在小于3巴的压力下水热处理氢氧化锆,和(f) 干燥氢氧化锆。 可以掺杂的本发明的氢氧化锆在催化应用中特别有用。

    INORGANIC OXIDES FOR CO2 CAPTURE FROM EXHAUST SYSTEMS
    6.
    发明申请
    INORGANIC OXIDES FOR CO2 CAPTURE FROM EXHAUST SYSTEMS 审中-公开
    无机氧化物对排气系统的二氧化碳捕获

    公开(公告)号:US20130174739A1

    公开(公告)日:2013-07-11

    申请号:US13822503

    申请日:2011-09-19

    IPC分类号: F01N3/08

    摘要: This invention relates to the utilization of regenerable water tolerant solid materials for the abatements of CO2 emissions from internal combustion engine exhaust streams through repetitive sorption/desorption cycles. The system, which is designed to be used in a gasoline, lean gasoline, diesel passenger car, diesel truck, stationary engine with 50 Hz or 60 Hz electrical frequency, or a SOFC, will contain a solid sorbent which contains zirconium and will be able to reduce on board the average carbon emissions by up to 10 wt %. The preferred materials have been selected from the class of hydrotalcite type compounds and/or earth and alkaline earth zirconates.

    摘要翻译: 本发明涉及可再生耐水固体材料的利用,用于通过重复吸附/解吸循环减少来自内燃机排气流的二氧化碳排放。 该系统设计用于汽油,稀薄汽油,柴油客车,柴油卡车,50Hz或60Hz电气频率的固定式发动机或SOFC,将包含含有锆的固体吸附剂,并且能够 将平均碳排放量减少高达10重量%。 优选的材料选自水滑石类化合物和/或土壤和碱土金属锆酸盐。