摘要:
The present invention is directed to pure polyurethanes which are biocompatible. These pure polyurethanes comprise the reaction product of:a) a pre-adduct containing NCO groups and comprising the reaction product ofi) a diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof, withii) a macrodiol having a molecular weight of from 500 to 10,000 wherein said components i) and ii) reacted at temperatures of from 90.degree.-150.degree. C.; withb) a chain extender having a molecular weight of from 62 to 400 and being selected from the group consisting of aliphatic diols, cycloaliphatic diols, and mixtures thereof, and optionally,c) additional diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof,wherein said component c), when added, is added either simultaneously with component b) or separately from component b), the quantities of components a)i), a)ii), and c) being such that the molar ratio of diisocyanate to macrodiol is from 1.5:1 to 22:1, and the reaction of components a) and b) and optionally component c) is conducted at temperatures of from 90.degree. to 230.degree. C., with the proviso that the reaction conditions are maintained until said polyurethane has a melt viscosity of at least 2500 mPa.s at 120.degree. C.
摘要:
The invention relates to thermoplastic polyurethanes modified with segmented siloxane block copolymers which are based on relatively high molecular weight dihydroxy compounds, diisocyanates, and difunctional chain extenders. The application also relates to their use in the medical field, and particularly as a catheter material.
摘要:
A process for the preparation of a polyurethane-urea elastomer having a mole ratio of NCO groups to all active hydrogen atoms in the range of 0.9 to 1.2 is disclosed. The process comprise reacting (A), (B) and (C.2) for form an NCO-containing prepolymer and then reacting said prepolymer with (C.1) and (D). Accordingly (A) is 5-isocyanato-1-(isocyanatomethyl)-1,1,3-trimethylcyclohexane or bis-(4-isocyanatocyclohexyl)-methane,(B) is polytetrahydrofuran or hexanediol polycarbonate and (C.2) is a chain extender. (C.1) is 5-amino-3-amino-methyl-1,3,3-trimethylcyclohexane or bis-(4-aminocyclohexyl)-methane and (D) is a molecular weight regulator. The elastomer thus produced is particularly suitable for the preparation of moldings, films, flexible tubing (for medical purposes) and catheters.
摘要:
The invention relates to a transparent thermoplastic material, containing 0.0001 to 2 wt. % of substantially flat metal identification platelets with a largest length elongation of less than 200 μm and a thickness of 2-10 μm, a round or n-angled shape where n≧4, wherein the metal identification platelets do not have any recesses or have recesses that lie substantially in the center of the metal identification platelet, do not come closer than 20 μm to the circumferential outer edge of the metal identification platelet, and do not account for more than 30% of the surface area of the metal identification platelet. The invention also relates to the production thereof and the use for producing films for personalization of a card layer composite and data carriers in card form, especially smart cards, magnetic strip cards, identification cards and the like.
摘要:
A document (2) containing: electronic components (14) and/or diffractive security elements; at least one protective layer (4, 5) being arranged on one side or two protective layers (4, 5) being arranged on both sides of the electronic components (14) and/or of the diffractive security element, said protective layers being formed of a first base polymer, polymer layers (8, 9, 12, 13), being formed of a second base polymer being different from the first base polymer, into which the electronic components (14) and/or the diffractive security element with the protective layers (4, 5) are laminated; and adhesive layers with a latent-reactive adhesive (10, 11) being arranged at least between the polymer layers (8, 9, 12, 13) and the protective layers (4, 5), and wherein the core layer or protective layers are formed of a thermoplastic elastomer.
摘要:
The invention relates to a method for producing a polymer layer composite that comprises a plurality of polymer layers and at least one polymer layer contains a laser-sensitive component, said method consisting of the following steps: A) first personalized information is applied to at least one of the polymer layers by means of an inkjet printing method as a colored inkjet printed layer, B) the polymer layer with the colored inkjet printed layer is then joined to the other polymer layers, the polymer layer with the colored inkjet printed layer being arranged between two other polymer layers, C) second personalized information is inscribed into the polymer layer composite obtained in step B) by means of laser engraving. The invention also relates to a thus obtained polymer layer composite, a security and/or valuable document comprising a polymer layer composite of said type and to a method for producing a security and/or valuable document of said type.
摘要:
Linear polycarbonate resin virtually free of surface defects that impair the suitability of the resin for demanding optical application is disclosed. Also disclosed is a process for the manufacture of the resin. The surface defects included in the resin are in the form of transparent fluorescing particles, the particle count of which portion that are 15 and 250 μm in size, is up to 1.8 counts/g, said count being determined by exciting the residue remaining after filtering a solution of said polycarbonate in methylene chloride through a Teflon filter of 5 μm pore size at a wavelength of 400-440 nm, 25× overall magnification and illumination time of 40 millisec. The polycarbonate is suitable for making films of improved optical properties.
摘要:
The invention relates to the use of a preparation comprising A) 0.1 to 20 wt % of a binding agent with a polycarbonate derivative based on a geminally disubstituted dihydroxydiphenyl cycloalkane, B) 30 to 99.9 wt % of an organic solvent or of a mixture of solvents, C) 0 to 10 wt %, referred to dry mass, of a dye or of a mixture of dyes, D) 0 to 10 wt % of a functional material or of a mixture of functional materials, E) 0 to 30 wt % of additive and/or auxiliary substances, or of a mixture of such substances, the relative amounts of the components A) to E) always totaling 100 wt %, as an ink jet printing dye.
摘要:
A solid sheet comprising transparent polycarbonate matrix, particles of a transparent polymer and an antistatic agent is disclosed. Characterized in that the refractive index of said matrix differs from that of said polymer, the sheet is suitable in making diffuser plate in flat screens.
摘要:
The present invention relates to an identification document having layer A), B) and C), wherein A) is a thermoplastic, B) is a layer produced from a stable, latent-reactive adhesive, and C) is a thermoplastic.