Pure, in particular catalyst-free polyurethanes
    1.
    发明授权
    Pure, in particular catalyst-free polyurethanes 失效
    纯的,特别是无催化剂的聚氨酯

    公开(公告)号:US5374704A

    公开(公告)日:1994-12-20

    申请号:US166760

    申请日:1993-12-14

    摘要: The present invention is directed to pure polyurethanes which are biocompatible. These pure polyurethanes comprise the reaction product of:a) a pre-adduct containing NCO groups and comprising the reaction product ofi) a diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof, withii) a macrodiol having a molecular weight of from 500 to 10,000 wherein said components i) and ii) reacted at temperatures of from 90.degree.-150.degree. C.; withb) a chain extender having a molecular weight of from 62 to 400 and being selected from the group consisting of aliphatic diols, cycloaliphatic diols, and mixtures thereof, and optionally,c) additional diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof,wherein said component c), when added, is added either simultaneously with component b) or separately from component b), the quantities of components a)i), a)ii), and c) being such that the molar ratio of diisocyanate to macrodiol is from 1.5:1 to 22:1, and the reaction of components a) and b) and optionally component c) is conducted at temperatures of from 90.degree. to 230.degree. C., with the proviso that the reaction conditions are maintained until said polyurethane has a melt viscosity of at least 2500 mPa.s at 120.degree. C.

    摘要翻译: 本发明涉及生物相容的纯聚氨酯。 这些纯聚氨酯包括以下物质的反应产物:a)含有NCO基团的预加合物,其包含i)选自脂族二异氰酸酯,脂环族二异氰酸酯及其混合物的二异氰酸酯的反应产物,ii)具有 分子量为500至10,000,其中所述组分i)和ii)在90-150℃的温度下反应; 其中b)分子量为62至400的扩链剂,并且选自脂族二醇,脂环族二醇及其混合物,以及任选地,c)另外的二异氰酸酯,其选自脂族二异氰酸酯,脂环族脂族 二异氰酸酯及其混合物,其中所述组分c)在加入时与组分b)同时加入或与组分b)分开加入,组分a)i),a)ii)和c)的数量使得 二异氰酸酯与大分子二醇的摩尔比为1.5:1至22:1,组分a)和b)和任选组分c)的反应在90℃至230℃的温度下进行,条件是 维持反应条件,直到所述聚氨酯在120℃下的熔体粘度为至少2500mPa.s。

    Cycloaliphatic thermoplastic polyurethane elastomers
    3.
    发明授权
    Cycloaliphatic thermoplastic polyurethane elastomers 失效
    环脂族热塑性聚氨酯弹性体

    公开(公告)号:US5942593A

    公开(公告)日:1999-08-24

    申请号:US805840

    申请日:1997-03-03

    摘要: A process for the preparation of a polyurethane-urea elastomer having a mole ratio of NCO groups to all active hydrogen atoms in the range of 0.9 to 1.2 is disclosed. The process comprise reacting (A), (B) and (C.2) for form an NCO-containing prepolymer and then reacting said prepolymer with (C.1) and (D). Accordingly (A) is 5-isocyanato-1-(isocyanatomethyl)-1,1,3-trimethylcyclohexane or bis-(4-isocyanatocyclohexyl)-methane,(B) is polytetrahydrofuran or hexanediol polycarbonate and (C.2) is a chain extender. (C.1) is 5-amino-3-amino-methyl-1,3,3-trimethylcyclohexane or bis-(4-aminocyclohexyl)-methane and (D) is a molecular weight regulator. The elastomer thus produced is particularly suitable for the preparation of moldings, films, flexible tubing (for medical purposes) and catheters.

    摘要翻译: 公开了一种制备具有NCO基摩尔数与所有活性氢原子在0.9至1.2范围内的聚氨酯 - 脲弹性体的方法。 该方法包括使(A),(B)和(C.2)反应形成含NCO的预聚物,然后使所述预聚物与(C.1)和(D)反应。 因此(A)是5-异氰酸基-1-(异氰酸根合甲基)-1,1,3-三甲基环己烷或双 - (4-异氰酸根合环己基) - 甲烷,(B)是聚四氢呋喃或己二醇聚碳酸酯,(C.2) 延长剂 (C.1)是5-氨基-3-氨基 - 甲基-1,3,3-三甲基环己烷或双 - (4-氨基环己基) - 甲烷,(D)是分子量调节剂。 如此制备的弹性体特别适用于制备模制品,薄膜,柔性管(用于医疗用途)和导管。

    Thermoplastic comprising metal identification platelets
    4.
    发明授权
    Thermoplastic comprising metal identification platelets 有权
    热塑性塑料包括金属鉴定血小板

    公开(公告)号:US09334385B2

    公开(公告)日:2016-05-10

    申请号:US12677700

    申请日:2008-09-02

    摘要: The invention relates to a transparent thermoplastic material, containing 0.0001 to 2 wt. % of substantially flat metal identification platelets with a largest length elongation of less than 200 μm and a thickness of 2-10 μm, a round or n-angled shape where n≧4, wherein the metal identification platelets do not have any recesses or have recesses that lie substantially in the center of the metal identification platelet, do not come closer than 20 μm to the circumferential outer edge of the metal identification platelet, and do not account for more than 30% of the surface area of the metal identification platelet. The invention also relates to the production thereof and the use for producing films for personalization of a card layer composite and data carriers in card form, especially smart cards, magnetic strip cards, identification cards and the like.

    摘要翻译: 本发明涉及一种透明热塑性材料,其含有0.0001至2重量% 具有小于200μm最大长度伸长率和2-10μm厚度的基本平坦的金属识别血小板的%,n≥4的圆形或n角形状,其中金属识别血小板没有任何凹陷或具有 基本上位于金属识别片的中心的凹部不会比金属识别片的周向外缘稍微超过20μm,并且不超过金属识别片的表面积的30%以上。 本发明还涉及其制造以及用于制造卡层复合材料和卡片形式的数据载体,特别是智能卡,磁条卡,识别卡等的个性化的膜的用途。

    Polycarbonate for making extruded films that are virtually free of surface defects
    7.
    发明授权
    Polycarbonate for making extruded films that are virtually free of surface defects 有权
    用于制造实际上没有表面缺陷的挤出薄膜的聚碳酸酯

    公开(公告)号:US08084570B2

    公开(公告)日:2011-12-27

    申请号:US11977586

    申请日:2007-10-25

    IPC分类号: C08G64/00

    摘要: Linear polycarbonate resin virtually free of surface defects that impair the suitability of the resin for demanding optical application is disclosed. Also disclosed is a process for the manufacture of the resin. The surface defects included in the resin are in the form of transparent fluorescing particles, the particle count of which portion that are 15 and 250 μm in size, is up to 1.8 counts/g, said count being determined by exciting the residue remaining after filtering a solution of said polycarbonate in methylene chloride through a Teflon filter of 5 μm pore size at a wavelength of 400-440 nm, 25× overall magnification and illumination time of 40 millisec. The polycarbonate is suitable for making films of improved optical properties.

    摘要翻译: 公开了实质上没有表面缺陷的线性聚碳酸酯树脂,其损害了用于要求光学应用的树脂的适用性。 还公开了用于制造树脂的方法。 包含在树脂中的表面缺陷是透明荧光颗粒的形式,其尺寸为15和250μm的部分的颗粒数量达到1.8个计数/ g,所述计数通过激发过滤后剩余的残余物来确定 所述聚碳酸酯在二氯甲烷中的溶液通过孔径为5μm的Teflon过滤器,波长为400-440nm,总体放大倍数为25×,照射时间为40毫秒。 聚碳酸酯适用于制备改善光学性能的薄膜。