公开(公告)号：US06221926B1

公开(公告)日：2001-04-24

申请号：US09319966

申请日：1999-06-14

申请人： Hidekazu Oohara ,  Hidehiro Yamaguchi ,  Kyoichi Nakamura

发明人： Hidekazu Oohara ,  Hidehiro Yamaguchi ,  Kyoichi Nakamura

IPC分类号： C08J918

CPC分类号： C08J9/18 ,  B29B9/10 ,  C08J2203/14 ,  C08J2325/04 ,  C08J2351/00

摘要： Foamable modified polystyrene resin particles (E) comprising a particle of a modified polystyrene resin (C) containing a blowing agent (D), wherein the modified polystyrene resin (C) comprises conjugated diene polymer rubber particles (B) dispersed uniformly throughout a polystyrene resin (A) and when the foamable modified polystyrene resin particle (E) is expanded, there is substantially no deformation of the rubber particles (B) before and after the expansion. A foamed article of a modified polystyrene resin which has a cell membrane of the modified polystyrene resin comprising a polystyrene resin and conjugated diene polymer rubber particles dispersed uniformly throughout the polystyrene resin and has a fusion rate of not less than 50%, wherein the rubber particles maintain substantially spherical form in the cell membrane. According to the present invention, the foamed article of the modified polystyrene resin having break resistance and fusion rate which are equal to those of a high impact polystyrene foamed article can be provided at low cost.

摘要翻译： 包含发泡剂（D）的改性聚苯乙烯树脂（C）的颗粒的可发泡改性聚苯乙烯树脂颗粒（E），其中改性聚苯乙烯树脂（C）包括均匀分散在聚苯乙烯树脂中的共轭二烯聚合物橡胶颗粒（B） （A），发泡性改性聚苯乙烯树脂粒子（E）膨胀时，膨胀前后橡胶粒子（B）基本上不变形。 改性聚苯乙烯树脂的泡沫制品，其具有改性聚苯乙烯树脂的细胞膜，其包含均匀分散在聚苯乙烯树脂中的聚苯乙烯树脂和共轭二烯聚合物橡胶颗粒，并且具有不低于50％的熔融率，其中橡胶颗粒 在细胞膜中保持基本上球形。 根据本发明，可以以低成本提供具有抗冲击性聚苯乙烯发泡体的耐破坏性和熔融率等同的改性聚苯乙烯树脂的发泡体。

公开(公告)号：US09175403B2

公开(公告)日：2015-11-03

申请号：US13394304

申请日：2009-09-11

申请人： Hidehiro Yamaguchi ,  Shigeki Yamamoto ,  Tomohiro Iko ,  Wei Li

发明人： Hidehiro Yamaguchi ,  Shigeki Yamamoto ,  Tomohiro Iko ,  Wei Li

IPC分类号： C08G18/02 ,  C23C28/00 ,  B32B7/12 ,  B32B15/08 ,  C08G18/08 ,  C08G18/12 ,  C08G18/32 ,  C08G18/42 ,  C08G18/66 ,  C08G18/73 ,  C08G18/75 ,  C09D5/08 ,  C09J175/04 ,  B05D5/10 ,  B05D7/14

CPC分类号： C23C28/00 ,  B05D5/10 ,  B05D7/14 ,  B32B7/12 ,  B32B15/08 ,  B32B2605/00 ,  C08G18/0809 ,  C08G18/0814 ,  C08G18/12 ,  C08G18/3275 ,  C08G18/4213 ,  C08G18/4222 ,  C08G18/4238 ,  C08G18/6655 ,  C08G18/73 ,  C08G18/755 ,  C08G18/757 ,  C08G18/758 ,  C08G2170/80 ,  C09D5/08 ,  C09J175/04 ,  C08G18/302

摘要： A composition for adhesion layer that is used for obtaining a multi-layered surface treatment steel sheet in which an adhesion layer is formed onto at least one surface of the steel sheet, and an upper layer and/or an intermediate layer which has a design and which contains a rust preventive pigment and/or a colored pigment is formed onto the adhesion layer; the composition including a cationic urethane resin and a silicon compound in an aqueous medium, and the ratio between the temperature at which the logarithmic decrement for the mixture of the cationic urethane resin and the silicon compound in the rigid-body pendulum type free damped vibration method shows the maximum value and the temperature at which the logarithmic decrement for the cationic urethane resin alone in the rigid-body pendulum type free damped vibration method shows the maximum value is in the range of 1.2 to 3.0.

摘要翻译： 一种用于获得其中在钢板的至少一个表面上形成粘合层的多层表面处理钢板的粘合层用组合物和上层和/或中间层，所述上层和/或中间层具有设计和 在粘合层上形成有防锈颜料和/或着色颜料; 在水性介质中包含阳离子聚氨酯树脂和硅化合物的组合物，以及刚体摆锤式自由振动法中阳离子聚氨酯树脂和硅化合物的混合物的对数递减的温度之比 表示在刚体摆式自由阻尼振动法中单独的阳离子聚氨酯树脂的对数减量的最大值和温度显示最大值在1.2至3.0的范围内。

公开(公告)号：US20150021192A1

公开(公告)日：2015-01-22

申请号：US14361143

申请日：2011-11-30

申请人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

发明人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

IPC分类号： C25D9/10 ,  C25D21/18 ,  C25D11/00

CPC分类号： C25D9/10 ,  C25D9/08 ,  C25D11/00 ,  C25D21/18

摘要： The purpose of the present invention is to provide a replenisher which is capable of supplying Zr ions to a metal surface treatment solution, while suppressing an increase in the HF concentration in the metal surface treatment solution, so that a chemical conversion coating film can be continuously formed on a steel sheet by electrolysis. A replenisher of the present invention is a replenisher which is used for the purpose of supplying zirconium ions to a metal surface treatment solution that contains zirconium ions and fluorine ions, and the replenisher contains (A) zirconium hydrofluoric acid or a salt thereof and/or (B) hydrofluoric acid or a salt thereof and (C) a fluorine-free zirconium compound. The total concentration (g/l) of zirconium ions derived from the components (A) and (C) is 20 or more, and the ratio of the total molar amount (MF) of the fluorine ions derived from the components (A) and (B) relative to the total molar amount (MZr) of the zirconium ions derived from the components (A) and (C), namely MF/MZr is 0.01 or more but less than 4.00.

摘要翻译： 本发明的目的是提供一种能够在抑制金属表面处理溶液中的HF浓度增加的同时向金属表面处理溶液供给Zr离子的补充剂，从而能够连续地进行化学转化覆膜 通过电解在钢板上形成。 本发明的补充剂是用于将锆离子供给到含有锆离子和氟离子的金属表面处理溶液中的补充剂，补充剂含有（A）氢氟酸锆或其盐和/或 （B）氢氟酸或其盐和（C）无氟锆化合物。 从（A）成分和（C）成分得到的锆离子的总浓度（g / l）为20以上，来自（A）成分的氟离子的总摩尔量（MF） （A）和（C）衍生的锆离子的总摩尔量（MZr），即MF / MZr为0.01以上且小于4.00。

公开(公告)号：US20140050939A1

公开(公告)日：2014-02-20

申请号：US14113502

申请日：2012-04-26

申请人： Atsushi Morishita ,  Taihei Kaneto ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Hidehiro Yamaguchi ,  Shinji Nomura

发明人： Atsushi Morishita ,  Taihei Kaneto ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Hidehiro Yamaguchi ,  Shinji Nomura

IPC分类号： C09D7/12

CPC分类号： C09D7/63 ,  C23C22/361 ,  C23C22/44 ,  C23C2222/20 ,  Y10T428/12569 ,  Y10T428/273 ,  Y10T428/31663

摘要： A surface-treated metal material of the present invention has a composite film on the surface of a metal material. The composite film includes an organic silicon compound (W) having cyclic siloxane bonds, at least one metal compound (X) selected from a group consisting of a titanium compound and a zirconium compound, a phosphate compound (Y) and a fluorine compound (Z). In each of the components of the composite film, the ratio of XS/WS is from 0.06 to 0.16, where WS is a solid mass of Si derived from the organic silicon compound (W) and XS is a solid mass of at least one metal component selected from a group consisting of Ti and Zr included in the metal compound (X); the ratio of YS/WS is from 0.15 to 0.31, where WS is the solid mass of Si and YS is a solid mass of P derived from the phosphate compound (Y); and the ratio of ZS/WS is from 0.08 to 0.50, where WS is the solid mass of Si and ZS is a solid mass of F derived from the fluorine compound (Z).

摘要翻译： 本发明的表面处理金属材料在金属材料的表面具有复合膜。 复合膜包括具有环状硅氧烷键的有机硅化合物（W），选自由钛化合物和锆化合物组成的组中的至少一种金属化合物（X），磷化合物（Y）和氟化合物（Z ）。 在复合膜的每个组分中，XS / WS的比例为0.06至0.16，其中WS是来自有机硅化合物（W）的Si的固体质量，XS是至少一种金属的固体质量 选自金属化合物（X）中所含的由Ti和Zr组成的组的组分; YS / WS的比例为0.15〜0.31，其中WS是Si的固体质量，YS是来自磷酸盐化合物（Y）的P的固体质量; 并且ZS / WS的比例为0.08〜0.50，其中WS为Si的固体质量，ZS为来自氟化合物（Z）的F的固体质量。

公开(公告)号：US07462582B2

公开(公告)日：2008-12-09

申请号：US10364732

申请日：2003-02-11

申请人： Shinobu Komiyama ,  Hidehiro Yamaguchi ,  Akihiro Seo

发明人： Shinobu Komiyama ,  Hidehiro Yamaguchi ,  Akihiro Seo

IPC分类号： C10M125/00 ,  C10M125/30 ,  C10M173/00

CPC分类号： C10M161/00 ,  C10M141/00 ,  C10M141/02 ,  C10M173/02 ,  C10M2201/08 ,  C10M2201/084 ,  C10M2201/087 ,  C10M2201/102 ,  C10M2201/103 ,  C10M2205/14 ,  C10M2205/16 ,  C10M2207/126 ,  C10M2207/40 ,  C10M2213/062 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2230/06 ,  C10N2240/402 ,  C10N2240/405 ,  C10N2240/406 ,  C10N2240/407 ,  C10N2240/408 ,  C10N2250/121

摘要： A waterborne composition for forming protective coatings to provide, by a simple method comprising coating and drying onto a metal surface, a coating that is uniform with little unevenness and that has an excellent galling resistance and workability that are at least as good as the corresponding properties afforded by conversion treatment methodologies, contains water-soluble inorganic salt and smectite-type clay mineral. The lubrication performance of the coating can also be improved when said composition additionally contains a lubricating component.

摘要翻译： 一种用于形成保护涂层的水性组合物，通过包括涂覆和干燥到金属表面上的简单方法提供均匀且几乎不均匀且具有优异的耐磨损性和可加工性的涂层，其至少与相应的性能一样好 由转化处理方法提供，含有水溶性无机盐和蒙脱石型粘土矿物。 当所述组合物另外含有润滑组分时，也可以改善涂层的润滑性能。

公开(公告)号：US09284657B2

公开(公告)日：2016-03-15

申请号：US14361143

申请日：2011-11-30

申请人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

发明人： Yuta Yoshida ,  Hiroki Sunada ,  Shigeki Yamamoto ,  Hidehiro Yamaguchi

IPC分类号： C25D9/10 ,  C25D11/00 ,  C25D9/08 ,  C25D21/18

CPC分类号： C25D9/10 ,  C25D9/08 ,  C25D11/00 ,  C25D21/18

摘要： A replenisher which is capable of supplying Zr ions to a metal surface treatment solution, while suppressing an increase in the HF concentration in the metal surface treatment solution, so that a chemical conversion coating film can be continuously formed on a steel sheet by electrolysis and contains (A) zirconium hydrofluoric acid or a salt thereof and/or (B) hydrofluoric acid or a salt thereof and (C) a fluorine-free zirconium compound. The total concentration (g/l) of zirconium ions derived from the components (A) and (C) is 20 or more, and the ratio of the total molar amount (MF) of the fluorine ions derived from the components (A) and (B) relative to the total molar amount (MZr) of the zirconium ions derived from the components (A) and (C), namely MF/MZr is 0.01 or more but less than 4.00.

摘要翻译： 能够在金属表面处理液中抑制金属表面处理液中的HF浓度上升的同时能够向金属表面处理液供给Zr离子的补充剂，能够通过电解在钢板上连续地形成化学转化膜， （A）氢氟酸锆或其盐和/或（B）氢氟酸或其盐和（C）无氟锆化合物。 从（A）成分和（C）成分得到的锆离子的总浓度（g / l）为20以上，来自（A）成分的氟离子的总摩尔量（MF） （A）和（C）衍生的锆离子的总摩尔量（MZr），即MF / MZr为0.01以上且小于4.00。

公开(公告)号：US20130197154A1

公开(公告)日：2013-08-01

申请号：US13824498

申请日：2011-09-16

申请人： Hidehiro Yamaguchi ,  Yuki Ishikawa ,  Yasuharu Nagai

发明人： Hidehiro Yamaguchi ,  Yuki Ishikawa ,  Yasuharu Nagai

IPC分类号： C08F116/06

CPC分类号： C08F116/06 ,  C04B35/4682 ,  C04B35/63416 ,  C04B35/6342 ,  C04B2235/5445 ,  C04B2235/6025 ,  C08F8/12 ,  C08F8/28 ,  C08F8/50 ,  C08F216/38 ,  C08K3/00 ,  C08F16/06

摘要： The present invention provides a modified polyvinyl alcohol enabling to produce polyvinyl acetal that is excellent in solubility in a solvent even with a low degree of polymerization while hardly causing reaction inhibition, coloring, and particle coarsening, and a method for producing the modified polyvinyl alcohol. The present invention also provides a modified polyvinyl acetal that is excellent in solubility in a solvent even with a low degree of polymerization, and has high elasticity, mechanical strength, and a film forming property. The present invention further provides a method for producing the modified polyvinyl acetal, a polyvinyl acetal film produced from the modified polyvinyl acetal, a method for producing the polyvinyl acetal film, a ceramic slurry composition, a method for producing the ceramic slurry composition, and a ceramic green sheet. The present invention is a modified polyvinyl alcohol including at least one functional group selected from the group consisting of hydroxyl, aldehyde, carboxyl, and lactone ring groups at a molecular end, and having a degree of saponification of 99.95 mol % or higher and a 1,2-glycol bond content of 1.4 mol % or lower.

摘要翻译： 本发明提供一种改性聚乙烯醇，其能够生产聚合物缩醛，即使在低聚合反应时溶剂性也优异，同时几乎不引起反应抑制，着色和颗粒粗化，以及改性聚乙烯醇的制备方法。 本发明还提供即使在低聚合度下溶剂性也优异的改性聚乙烯醇缩醛，具有高弹性，机械强度和成膜性。 本发明还提供一种改性聚乙烯醇缩醛的制造方法，由改性聚乙烯醇缩醛制造的聚乙烯醇缩醛膜，聚乙烯醇缩醛膜的制造方法，陶瓷浆料组合物，陶瓷浆料组合物的制造方法以及 陶瓷绿板。 本发明是一种改性聚乙烯醇，其在分子末端具有选自羟基，醛，羧基和内酯环基中的至少一种官能团，皂化度为99.95mol％以上，1 ，2-二醇键含量为1.4摩尔％以下。

公开(公告)号：US20090110921A1

公开(公告)日：2009-04-30

申请号：US11989096

申请日：2006-07-14

申请人： Taihei Kaneto ,  Atsushi Morishita ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Shinji Nomura ,  Hidehiro Yamaguchi

发明人： Taihei Kaneto ,  Atsushi Morishita ,  Yoshio Kimata ,  Akira Takahashi ,  Ikuo Kikuchi ,  Shinji Nomura ,  Hidehiro Yamaguchi

IPC分类号： B32B9/04

CPC分类号： C23C22/44 ,  C08G77/14 ,  C08G77/26 ,  C09D5/084 ,  C23C2222/20 ,  Y10T428/273 ,  Y10T428/31663

摘要： The present invention provides a metal material given a chrome-free surface treatment satisfying all of the requirements of corrosion resistance, heat resistance, fingermark resistance, conductivity, coatability, and blackening resistance at the time of working, which was difficult to achieve with conventional chromate-free technology. The chromate-free surface treated metal material of the present invention is comprised of a metal material on the surface of which is coated and dried an aqueous metal surface treatment agent comprising an organic silicon compound (W), obtained by blending a silane coupling agent (A) containing one amino group in its molecule and a silane coupling agent (B) containing one glycidyl group in its molecule in a solid weight ratio [(A)/(B)] of 0.5 to 1.7, at least one type of fluorocompound (X) selected from fluorotitanic acid or fluorozirconic acid, phosphoric acid (Y), and a vanadium compound (Z) so as to form a composite coating containing the different ingredients.

摘要翻译： 本发明提供了赋予无铬表面处理的金属材料，其满足了常规铬酸盐难以达到的耐蚀性，耐热性，防水印性，导电性，可涂布性和耐黑变性的所有要求 免费技术。 本发明的无铬酸盐表面处理金属材料由金属材料构成，其表面涂覆并干燥含有金属表面处理剂，其含有有机硅化合物（W），其通过将硅烷偶联剂（ A），其分子中含有一个氨基和其分子中含有一个缩水甘油基的硅烷偶联剂（B），其固体重量比[（A）/（B）]为0.5至1.7，至少一种氟化合物 X）选自氟钛酸或氟锆酸，磷酸（Y）和钒化合物（Z），以形成含有不同成分的复合涂层。

公开(公告)号：US20050119133A1

公开(公告)日：2005-06-02

申请号：US10508999

申请日：2003-03-24

申请人： Shinobu Komiyama ,  Masayuki Yoshida ,  Hidehiro Yamaguchi

发明人： Shinobu Komiyama ,  Masayuki Yoshida ,  Hidehiro Yamaguchi

IPC分类号： C10M169/04 ,  C10M173/02 ,  C10M173/00

CPC分类号： C10M169/04 ,  C10M173/02 ,  C10M2201/0623 ,  C10M2201/085 ,  C10M2201/0853 ,  C10M2207/12 ,  C10M2207/1203 ,  C10M2207/1253 ,  C10M2207/126 ,  C10N2210/02 ,  C10N2220/084 ,  C10N2230/06 ,  C10N2240/402 ,  C10N2240/405 ,  C10N2250/08 ,  C10M2207/125

摘要： Particles each of which consists of an inorganic polyvalent metal compound as a nucleus and a coating of a metallic soap of the polyvalent metal coating the nucleus (coated particles); products and preparation processes using the particles; a lubricating coating forming agent wherein particles each of which consists of a polyvalent metal salt of phosphoric acid as a nucleus and a coating of a metallic soap of the polyvalent metal coating the surface of the nucleus are suspended in an aqueous solution of a water soluble inorganic salt and/or a water soluble organic acid salt; and a lubricating coating. The coated particles are novel particles which can be used as an ingredient of coating-type lubricating coating; are excellent in seizure resistance; can inhibit wear of tools at the time of plastic working since the friction coefficient of the surface of the particles is low; and are slow to cause pollution of working oils. Lubricating coating obtained by applying the lubricating coating forming agent onto the surface of a metallic material gives excellent cold plastic working properties, namely lubricity and seizure resistance to the metallic material.

摘要翻译： 各自由作为核的无机多价金属化合物和包覆核（涂覆颗粒）的多价金属的金属皂的涂层组成的颗粒; 使用颗粒的产品和制备过程; 润滑涂层形成剂，其中由磷酸的多价金属盐作为核的颗粒和涂覆在核表面上的多价金属的金属皂的涂层悬浮在水溶性无机的水溶液中 盐和/或水溶性有机酸盐; 和润滑涂层。 涂层颗粒是可用作涂层型润滑涂层成分的新型颗粒; 抗癫痫发作优良; 由于颗粒表面的摩擦系数低，因此可以抑制塑料加工时工具的磨损; 造成工作油污染缓慢。 通过将润滑涂层形成剂涂覆在金属材料的表面上获得的润滑涂层具有优异的冷塑性加工性能，即对金属材料的润滑性和抗咬合性。

公开(公告)号：US08241744B2

公开(公告)日：2012-08-14

申请号：US12312429

申请日：2007-11-14

申请人： Ikuo Kikuchi ,  Kimitaka Hayashi ,  Yoshio Kimata ,  Atsushi Morishita ,  Taihei Kaneto ,  Shinji Nomura ,  Hidehiro Yamaguchi

发明人： Ikuo Kikuchi ,  Kimitaka Hayashi ,  Yoshio Kimata ,  Atsushi Morishita ,  Taihei Kaneto ,  Shinji Nomura ,  Hidehiro Yamaguchi

IPC分类号： B32B15/08 ,  B05D3/02 ,  C23C22/36 ,  C23C22/42 ,  C23C22/44

CPC分类号： C23C22/44 ,  C23C2222/20 ,  Y10T428/254 ,  Y10T428/273

摘要： This surface-treated metal material includes a composite film obtained by applying a metal surface treatment agent on a surface of a metal material and drying the metal surface treatment agent, the metal surface treatment agent containing: an organic silicon compound (W) obtained by combining a silane coupling agent (A) containing one amino group in a molecule and one glycidyl group in a molecule, at a solid content mass ratio [(A)/(B)] of 0.7 to 1.7; at least one kind of fluorine compound (X) selected from titanium hydrofluoric acid and zirconium hydrofluoric acid; a phosphoric acid (Y); a vanadium compound (Z); and at least one kind of lubricant (J).

摘要翻译： 该表面处理金属材料包括通过在金属材料的表面上施加金属表面处理剂并干燥金属表面处理剂而获得的复合膜，金属表面处理剂包含：通过组合获得的有机硅化合物（W） （A）/（B）]为0.7〜1.7的分子中含有一个氨基，分子内含有一个缩水甘油基的硅烷偶联剂（A） 选自氢氟酸钛和氢氟酸锆中的至少一种氟化合物（X）; 磷酸（Y）; 钒化合物（Z）; 和至少一种润滑剂（J）。