公开(公告)号：US4985479A

公开(公告)日：1991-01-15

申请号：US329764

申请日：1989-03-28

申请人： Hideo Nagasaki ,  Shinichi Yachigo ,  Takeshi Takata ,  Hiroki Yamamoto ,  Yukoh Takahashi

发明人： Hideo Nagasaki ,  Shinichi Yachigo ,  Takeshi Takata ,  Hiroki Yamamoto ,  Yukoh Takahashi

IPC分类号： C08K5/134 ,  C08K5/3435 ,  C08K5/3492 ,  C08K5/526 ,  C08K5/527 ,  C08K5/5393

CPC分类号： C08K5/527 ,  C08K5/1345 ,  C08K5/3435 ,  C08K5/34926 ,  C08K5/526 ,  C08K5/5393

摘要： A stabilized polyolefin composition having improved weathering resistance is provided, whereby the following four components are incorporated into a polyolefin:(A) a hindered piperidine compound having a molecular weight of more than 750, such as poly-{[6-morpholino-1,3,5-triazine-2,4-diyl][2,2,6,6-tetramethyl-4-piperidyl)imino]hexamethylene[2,2,6,6-tetramethyl-4-piperidyl)imino]},(B) a hindered piperidine compound having a molecular weight of less than 500, such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate,(C) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate, and(D) a phosphorus-containing compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite.

摘要翻译： 提供了具有改善的耐候性的稳定的聚烯烃组合物，由此将以下四种组分引入聚烯烃中：（A）分子量大于750的受阻哌啶化合物，例如聚{{6-吗啉代-1， 亚氨基]亚己基[2,2,6,6-四甲基-4-哌啶基]亚氨基]}， （B）分子量小于500的受阻哌啶化合物，例如双（2,2,6,6-四甲基-4-哌啶基）癸二酸酯，（C）苯甲酸酯化合物如2,4-二 - 3,5-二叔丁基-4-羟基苯甲酸叔丁基苯酯和（D）含磷化合物如双（2,4-二叔丁基苯基）季戊四醇二亚磷酸酯。

公开(公告)号：US4812494A

公开(公告)日：1989-03-14

申请号：US128874

申请日：1987-12-04

申请人： Hideo Nagasaki ,  Shinichi Yachigo ,  Tamaki Ishii ,  Masakatsu Yoshimura ,  Yukoh Takahashi ,  Hiroki Yamamoto

发明人： Hideo Nagasaki ,  Shinichi Yachigo ,  Tamaki Ishii ,  Masakatsu Yoshimura ,  Yukoh Takahashi ,  Hiroki Yamamoto

IPC分类号： C08K5/34 ,  C08K5/17 ,  C08K5/3435 ,  C08K5/3475 ,  C08K5/3477 ,  C08L25/00 ,  C08L25/04 ,  C08L55/00 ,  C08L55/02

CPC分类号： C08K5/3435 ,  C08K5/3475

摘要： A styrene polymer is stabilized by incorporating into said styrene polymer(A) a hindered piperidine compound represented by the formula ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms,R.sub.2 is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, andR.sub.3 and R.sub.4 are each independently an alkyl group having 1 to 4 carbon atoms; and(B) a benzotriazole compound selected from the group consisting of 2-(2-hydroxy-5-methylphenyl)benzotriazole and 2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole.

摘要翻译： 苯乙烯聚合物通过将所述苯乙烯聚合物（A）中的受阻哌啶化合物（其中R 1为氢原子或具有1至3个碳原子的烷基，R 2为氢原子或烷基） 具有1至12个碳原子的基团，并且R 3和R 4各自独立地为具有1至4个碳原子的烷基; 和（B）选自2-（2-羟基-5-甲基苯基）苯并三唑和2-（2-羟基-3-叔丁基-5-甲基苯基）-5-氯苯并三唑的苯并三唑化合物。

公开(公告)号：US5300568A

公开(公告)日：1994-04-05

申请号：US667408

申请日：1991-04-08

申请人： Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto ,  Shinichi Yachigo ,  Hideo Nagasaki ,  Naoki Inui

发明人： Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto ,  Shinichi Yachigo ,  Hideo Nagasaki ,  Naoki Inui

IPC分类号： C08K5/32 ,  C08K5/34 ,  C08L21/00 ,  C08L23/00 ,  C08L23/04 ,  C08L25/00 ,  C08L51/06 ,  C08L71/12 ,  C08L53/00

CPC分类号： C08L23/04 ,  C08K5/32 ,  C08K5/34 ,  C08L71/12 ,  Y10S525/905

摘要： A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5% by weight of at least one polyolefin-resin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95% by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.1 are chain aliphatic groups, the nitrogen atoms may further bond each other to form a ring through X and R.sup.1 ; R.sup.2 and R.sup.3 are independently a hydrogen atom or an alkyl group of 1-12 carbon atoms and R.sup.2 and R.sup.3 may bond to form a ring).

摘要翻译： PCT No.PCT / JP90 / 00759 Sec。 371日期：1991年4月8日 102（e）日期1991年4月8日PCT Filed 1990年6月11日PCT公布。 WO91 / 19762 PCT出版物 日本1991年12月26日。一种热塑性树脂组合物，其包含100重量份的组合物，其包含95-5重量％的至少一种选自乙烯或（α-）α-烯烃或共聚物的均聚物的聚烯烃树脂（A） 和由多官能化合物（E）和/或不饱和单体（L）改性的这些均聚物或共聚物和5-95重量％的至少一种选自聚苯醚，改性聚苯醚的聚苯醚树脂（B） 与上述（E）和/或（L）和包含聚亚苯基或改性聚苯醚和芳族乙烯基聚合物树脂（M）的组合物和0.001-10重量份下式（I）的二硝基二胺（D） ）。 （*化学结构*）（I）（其中X表示可以含有卤素或氧原子的二价链脂肪族基团，环状脂肪族基团或芳香族基团，R 1表示氢原子，链状脂肪族基团，环状 脂族基团或芳香族基团，当X和R 1均为链状脂族基团时，氮原子可以进一步通过X和R 1彼此键合形成环; R2和R3独立地为氢原子或1- 12个碳原子，R2和R3可以键合形成环）。

公开(公告)号：US5109055A

公开(公告)日：1992-04-28

申请号：US548560

申请日：1990-07-05

申请人： Hideo Nagasaki ,  Naoki Inui ,  Shinichi Yachigo

发明人： Hideo Nagasaki ,  Naoki Inui ,  Shinichi Yachigo

IPC分类号： C08K5/08 ,  C08K5/32 ,  C08K5/3415

CPC分类号： C08K5/32 ,  C08K5/08 ,  C08K5/3415

摘要： A rubber composition comprising a base rubber, carbon black and a dinitrodiamine compound represented by the formula [I], ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen or an aliphatic, alicyclic or aromatic group, provided that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, provided that R.sup.2 and R.sup.3 may conjointly form a ring,is improved in its scorching without deterioration in its dynamic properties by incorporating thereto the following components (A) or (B):(A) N-(cyclohexylthio)phthalimide and a bismaleimide compound, or(B) 2,3,5,6-tetrachloro-1,4-benzoquinone.

公开(公告)号：US5362785A

公开(公告)日：1994-11-08

申请号：US886094

申请日：1992-05-21

申请人： Naoki Inui ,  Hideo Nagasaki ,  Shinichi Yachigo

发明人： Naoki Inui ,  Hideo Nagasaki ,  Shinichi Yachigo

IPC分类号： B60C1/00 ,  C08K3/04 ,  C08K5/17 ,  C08K5/32 ,  C08K5/36 ,  C08K5/375 ,  C08K13/02 ,  C08L9/06 ,  C08L21/00 ,  C08L81/02 ,  C08K5/16

CPC分类号： C08K5/32 ,  C08K5/375 ,  C08L9/06 ,  C08L7/00 ,  C08L9/00

摘要： A styrene/butadiene copolymer rubber to be used for automobile tires is lowered in its rolling resistance by blending it with carbon black and the following components (A) and (B):(A) a dinitrodiamine compound represented by the following formula (I): ##STR1## wherein X is a divalent organic group such as an alkylene, R.sup.1 is hydrogen or an organic group such as an alkyl, provided that two nitrogen atoms linking through X may further link through R.sup.1, and R.sup.2 and R.sup.3 are each hydrogen or an alkyl, provided that R.sup.2 and R.sup.3 may conjointly form a ring; and(B) a sulfide compound selected from dibenzothiazyl disulfide, tetralkylthiuram disulfide, and alkyl- or hydroxy-substituted phenol sulfide resin. The dinitrodiamine compound (A) and the sulfide compound (B) are added simultaneously to the rubber together with the carbon black in a first kneading step of a high temperature.

摘要翻译： 用于汽车轮胎的苯乙烯/丁二烯共聚物橡胶的滚动阻力通过与炭黑和以下组分（A）和（B）混合而降低：（A）由下式（I）表示的二硝基二胺化合物 （I）其中X是二价有机基团如亚烷基，R 1是氢或有机基团如烷基，条件是通过X连接的两个氮原子可以进一步连接通过R 1，而R 2和R 3是 每个氢或烷基，条件是R2和R3可以一起形成环; 和（B）选自二苯并噻唑二硫化物，四烷基秋兰姆二硫化物和烷基或羟基取代的苯酚硫化物树脂的硫化物化合物。 在高温的第一捏合步骤中，将二硝基二胺化合物（A）和硫化物（B）与炭黑同时加入到橡胶中。

公开(公告)号：US5428091A

公开(公告)日：1995-06-27

申请号：US171622

申请日：1993-12-22

申请人： Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto ,  Shinichi Yachigo ,  Hideo Nagasaki ,  Naoki Inui

发明人： Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto ,  Shinichi Yachigo ,  Hideo Nagasaki ,  Naoki Inui

IPC分类号： C08K5/32 ,  C08K5/34 ,  C08L21/00 ,  C08L23/00 ,  C08L23/04 ,  C08L25/00 ,  C08L51/06 ,  C08L71/12 ,  C08L53/00

CPC分类号： C08L23/04 ,  C08K5/32 ,  C08K5/34 ,  C08L71/12 ,  Y10S525/905

摘要： A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5 % by weight of at least one polyolefinresin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95 % by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.1 are chain aliphatic groups, the nitrogen atoms may further bond each other to form a ring through X and R.sup.1 ; R.sup.2 and R.sup.3 are independently a hydrogen atom or an alkyl group of 1-12 carbon atoms and R.sup.2 and R.sup.3 may bond to form a ring).

摘要翻译： 一种热塑性树脂组合物，其包含100重量份的组合物，其包含95-5重量％的至少一种选自乙烯或α-烯烃的均聚物或其共聚物的聚烯烃树脂（A），以及这些均聚物或共聚物，其被多官能化合物 （E）和/或不饱和单体（L）和5-95重量％的至少一种选自聚苯醚的聚苯醚树脂（B），具有上述（E）和/或（L）的改性聚苯醚 ）和包含聚亚苯基或改性聚苯醚和芳族乙烯基聚合物树脂（M）的组合物和0.001-10重量份下式（I）的二硝基二胺（D）。 （I）（其中X表示二价链脂肪族基团，环状脂肪族基团或可以含有卤素或氧原子的芳香族基团，R 1表示氢原子，链状脂肪族基团，环状脂肪族基团或 芳族基团，当X和R 1都是链状脂肪族基团时，氮原子可以进一步通过X和R 1彼此键合形成环; R2和R3独立地是氢原子或1-12个碳原子的烷基 并且R 2和R 3可以键合形成环）。

公开(公告)号：US5180764A

公开(公告)日：1993-01-19

申请号：US681363

申请日：1991-04-08

申请人： Hideo Nagasaki ,  Naoki Inui ,  Shinichi Yachigo ,  Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto

发明人： Hideo Nagasaki ,  Naoki Inui ,  Shinichi Yachigo ,  Hiroomi Abe ,  Takeshi Fujii ,  Masashi Yamamoto

IPC分类号： C08K5/32

CPC分类号： C08K5/32

摘要： A thermoplastic resin is stabilized by incorporating therein a dinitrodiamine compound represented by the formula of ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen or an aliphatic, alicyclic or aromatic group, provided that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, provided that R.sup.2 and R.sup.3 may conjointly form a ring. The composition thus blended is improved in thermal processing stability. Further, a modified polyolefin resin is improved in mechanical properties, particularly in impact strength, by the incorporation of the dinitrodiamine compound.

公开(公告)号：US5369143A

公开(公告)日：1994-11-29

申请号：US113769

申请日：1993-08-31

申请人： Isao Kurimoto ,  Naoki Inui ,  Kohji Yamatsuta ,  Hitoshi Murotani ,  Hideo Nagasaki ,  Shinichi Yachigo

发明人： Isao Kurimoto ,  Naoki Inui ,  Kohji Yamatsuta ,  Hitoshi Murotani ,  Hideo Nagasaki ,  Shinichi Yachigo

IPC分类号： C08J5/08 ,  C03C25/10 ,  D01F11/14 ,  D06M13/02 ,  D06M13/322 ,  D06M13/392 ,  D06M101/00 ,  D06M101/40 ,  C08K9/00

CPC分类号： D01F11/14

摘要： Inorganic fiber such as carbon fiber is modified by a surface treatment with a dinitrodiamine compound represented by the formula of ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen, an aliphatic group, an alicyclic group or an aromatic group, with the proviso that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, with the proviso that R.sup.2 and R.sup.3 may conjointly form a ring. The inorganic fiber thus modified is useful for reinforcement of resins.

摘要翻译： 无机纤维如碳纤维通过用下式表示的二硝基二胺化合物进行表面处理：其中X是二价脂族，脂环族或芳族基团，其可以在基团中含有卤素或氧，R 1是氢， 脂族基团，脂环族基团或芳族基团，条件是当X和R 1均为脂族基团时，与X连接的两个氮原子可以进一步连接R1，R2和R3彼此独立地为氢或烷基 1至12个碳原子，条件是R2和R3可以一起形成环。 这样改性的无机纤维可用于增强树脂。

公开(公告)号：US5362794A

公开(公告)日：1994-11-08

申请号：US89521

申请日：1993-07-21

申请人： Naoki Inui ,  Kazuaki Yamamoto ,  Hideo Nagasaki ,  Manji Sasaki ,  Shinichi Yachigo

发明人： Naoki Inui ,  Kazuaki Yamamoto ,  Hideo Nagasaki ,  Manji Sasaki ,  Shinichi Yachigo

IPC分类号： C08J3/24 ,  B60C1/00 ,  C08K3/00 ,  C08K3/04 ,  C08K3/06 ,  C08K5/16 ,  C08K5/23 ,  C08K5/45 ,  C08K5/47 ,  C08L9/06 ,  C08K3/02

CPC分类号： C08K5/23 ,  B60C1/0016 ,  C08K3/04 ,  C08K5/47 ,  Y10S152/905

摘要： A rubber composition comprising the following components:(A) a rubber component comprising at least 50% by weight of a styrene/butadiene copolymer rubber;(B) an azodicarboxylic ester compound represented by the formula ##STR1## wherein X is an alkyl of 3 to 8 carbon atoms, an unsubstituted or substituted phenyl, or an unsubstituted or substituted benzyl;(C) carbon black having a nitrogen absorption specific surface area of 100 to 250 m.sup.2 /g and a dibutyl phthalate absorption number of 110 to 170 ml/100 g;(D) sulfur; and(E) a benzothiazole vulcanization accelerator.This rubber composition shows a high loss factor (tan .delta.) in a low temperature range, and a low loss factor in a high temperature range which when applied to the production of automobile tires, achieves improved braking power on wet, snow covered or frozen road surfaces. Lowered rolling resistance during driving without loss in the strength characteristics of the composition are also exhibited.

摘要翻译： 一种橡胶组合物，其包含以下组分：（A）包含至少50重量％的苯乙烯/丁二烯共聚物橡胶的橡胶组分; （B）由式（I）表示的偶氮二羧酸酯化合物，其中X为3-8个碳原子的烷基，未取代或取代的苯基，或未取代或取代的苄基; （C）氮吸收比表面积为100〜250m 2 / g的碳黑，邻苯二甲酸二丁酯吸收值为110〜170ml / 100g; （D）硫; 和（E）苯并噻唑硫化促进剂。 该橡胶组合物在低温范围内显示出高的损耗因子（tanδ），并且在应用于汽车轮胎的生产时在高温范围内的低损耗因子在湿润，积雪或冷冻道路上实现了改善的制动力 表面。 还表现出在驾驶中降低的滚动阻力，而不损失组合物的强度特性。

公开(公告)号：US5191003A

公开(公告)日：1993-03-02

申请号：US741617

申请日：1991-08-07

申请人： Naoki Inui ,  Chinehito Ebina ,  Miyuki Oikawa ,  Hideo Nagasaki ,  Shinichi Yachigo ,  Manji Sasaki

发明人： Naoki Inui ,  Chinehito Ebina ,  Miyuki Oikawa ,  Hideo Nagasaki ,  Shinichi Yachigo ,  Manji Sasaki

IPC分类号： C08K5/20 ,  C08K9/08

CPC分类号： C08K9/08 ,  C08K5/20

摘要： A rubber composition comprising a rubber, a filler and a diamide compound represented by the formula: ##STR1## wherein X is hydrogen, alkyl of 1 to 18 carbon atoms, alkoxy of 1 to 18 carbon atoms, alkanoyl of 2 to 19 total carbon atoms, amino, nitro, cyano, hydroxy, carboxy or halogen, and n is an integer of 2 to 12. This rubber composition is increased in its loss factor and is useful for tires and rubber vibration isolators. For example, the resulting tires prepared from the rubber composition are improved in their gripping performance.

摘要翻译： 一种橡胶组合物，其包含由下式表示的橡胶，填料和二酰胺化合物：其中X为氢，1至18个碳原子的烷基，1至18个碳原子的烷氧基，2至19个总碳原子的烷酰基 ，氨基，硝基，氰基，羟基，羧基或卤素，n为2〜12的整数。该橡胶组合物的损失因子增加，可用于轮胎和橡胶隔振器。 例如，由橡胶组合物制备的所得轮胎的抓持性能得到改善。