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1.发明授权
公开(公告)号：US4304818A
公开(公告)日：1981-12-08
申请号：US103571
申请日：1979-12-14
申请人： Hideyo Hirata , Takeshi Hakamada , Misao Souma , Masao Matsui , Yoshiyuki Suda , Yoshiharu Karasawa , Toshikazu Narahara
发明人： Hideyo Hirata , Takeshi Hakamada , Misao Souma , Masao Matsui , Yoshiyuki Suda , Yoshiharu Karasawa , Toshikazu Narahara
CPC分类号： C08G73/06 , C08G18/003 , C08G59/4028 , C08G73/0638 , H01B3/302 , H01B3/303 , H01B3/40 , H02K3/30 , Y10T428/2936 , Y10T428/2964 , Y10T428/2969 , Y10T428/2971 , Y10T428/31511 , Y10T428/31533 , Y10T428/31547 , Y10T428/31551 , Y10T428/31562 , Y10T428/31601 , Y10T428/31721 , Y10T428/31725
摘要： An insulation system for winding of electric rotating machines having thermal resistance of class H or more and excellent adhesiveness between a conductor and an insulating layer and resistance to thermal stress can be produced by wrapping a plurality of layers of an insulating tape or sheet having thermal resistance of class H or more around a winding conductor, impregnating the thus treated winding conductor with a solventless varnish consisting essentially of 1 equivalent of an epoxy compound containing at least two vicinal epoxy groups, more than one equivalent of an organic polyisocyanate, and then heating the inpregnated winding conductor at a temperature above 60.degree. C. for a time sufficient to form and cure a resin containing as recurring units at least two isocyanurate rings directly bonded to one another through the residue of the polyisocyanate and two oxazolidone rings directly bonded to each other through the residue of the polyepoxide in the presence of 0.01-10% by weight of a catalyst which forms the isocyanurate rings and oxazolidone rings based on the total amount of the polyepoxide and polyisocyanate.
摘要翻译： 用于缠绕具有H级以上的耐热性和导体与绝缘层之间优异的粘合性和耐热应力的电动旋转机械的绝缘系统可以通过包裹多层绝缘带或具有热阻的片材来制造 在绕组导体周围的H级以上的等级浸渍在这样处理的绕组导体上，用无溶剂的清漆基本上由1当量的含有至少两个邻位环氧基，多于1当量的有机多异氰酸酯的环氧化合物组成，然后加热 浸渍的绕组导体在60℃以上的时间足以形成和固化含有作为重复单元的树脂的树脂，所述树脂通过多异氰酸酯的残基和彼此直接键合的两个直接键合的至少两个异氰脲酸酯环直接键合 在0.01-10重量％存在下通过聚环氧化物的残基 基于聚环氧化物和多异氰酸酯的总量形成异氰脲酸酯环和恶唑烷酮环的催化剂。
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公开(公告)号：US4128531A
公开(公告)日：1978-12-05
申请号：US843205
申请日：1977-10-18
CPC分类号： C08G18/791 , C08G18/003 , C08G18/69 , C08L63/00
摘要： A thermosetting resin composition comprising a polyfunctional epoxy compound such as diglycidyl ether of bisphenol A, a polyfunctional isocyanate such as diphenylmethane diisocyanate, a curing agent and polybutadiene type polymer having terminal hydroxyl groups can produce cured articles excellent in heat resistance and crack resistance.
摘要翻译： 包含双酚A的多官能环氧化合物如二苯基甲烷二异氰酸酯的多官能异氰酸酯，具有末端羟基的固化剂和聚丁二烯型聚合物的热固性树脂组合物可以产生耐热性和抗裂性优异的固化体。
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3.发明授权Thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate stabilized by incorporating an organic electron acceptor 失效可热固化的可聚合树脂组合物，其包含聚环氧化物和通过掺入有机电子受体而稳定的多异氰酸酯
公开(公告)号：US4129554A
公开(公告)日：1978-12-12
申请号：US797429
申请日：1977-05-16
CPC分类号： C08G18/00 , C08G18/003 , C08G18/089 , C08G18/09
摘要： A thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate which is normally catalyzed by a basic curing catalyst for forming oxazolidone rings and isocyanurate rings or uredione rings is remarkably stabilized at low temperatures by incorporating a small amount of an organic electron acceptor, such as, picric acid, quinone, chloranil, or cyanoacetate ester into the composition. Since the specific electron acceptors effectively inhibit the polymerization of the reactive components in the composition at low temperatures, a shelf life of the composition is remarkably prolonged.
摘要翻译： 包含聚环氧化物和多异氰酸酯的热固性可聚合树脂组合物通常通过用于形成恶唑烷酮环和异氰脲酸酯环和脲基环的碱性固化催化剂通常催化，在低温下通过引入少量有机电子受体（例如 ，苦味酸，醌，氯醌或氰基乙酸酯加入到组合物中。 由于特定的电子受体在低温下有效地抑制组合物中反应性组分的聚合，所以组合物的保质期显着延长。
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公开(公告)号：US4070416A
公开(公告)日：1978-01-24
申请号：US605324
申请日：1975-08-18
申请人： Toshikazu Narahara , Katuo Sugawara , Yoshiharu Karasawa , Hitoshi Yokono , Junji Mukai , Tadashi Muroi
发明人： Toshikazu Narahara , Katuo Sugawara , Yoshiharu Karasawa , Hitoshi Yokono , Junji Mukai , Tadashi Muroi
CPC分类号： C08G18/791 , C08G18/003 , C08G59/4028 , C08G69/06 , C08G2105/02
摘要： A novel thermosetting resin can be obtained by mixing 1 equivalent or more of a polyfunctional isocyanate per 1 equivalent of a polyfunctional epoxide and then carrying out a polymerization reaction of the mixture in the presence of the catalyst which forms isocyanurate rings and oxazolidone rings so as to enable the mixture to form 2 or more isocyanurate rings directly connected with oxazolidone rings through an isocyanate residues.The resulting thermosetting resin has excellent electrical, chemical and impact resistances and excellent self-extinguishing properties. Said resin is used as an electric insulating material.
摘要翻译： 可以通过将1当量或更多个多官能异氰酸酯/ 1当量多官能环氧化物混合，然后在形成异氰脲酸酯环和恶唑烷酮环的催化剂存在下进行混合物的聚合反应，得到新的热固性树脂，以便 使得混合物通过异氰酸酯残基形成与恶唑烷酮环直接连接的2个或更多个异氰脲酸酯环。
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5.发明授权
公开(公告)号：US4269894A
公开(公告)日：1981-05-26
申请号：US99850
申请日：1979-12-03
CPC分类号： H02K3/30 , H01B3/46 , H01B7/282 , H01B7/29 , Y10T428/2936
摘要： Electric windings comprising an electric conductor and a plurality of cured insulating layers wrapping around the conductor, said cured insulating layers being obtained by bonding two or more insulating materials with a binder solution containing a mixture of a condensation polymerization type silicone resin containing hydroxyl groups in the molecule and an addition polymerization type silicone resin to form a composite insulating material, wrapping the composite insulating material around the conductor, impregnating the wrapped composite insulating material with an impregnating varnish of an epoxy-isocyanate resin and curing the impregnated composite insulating material, have excellent water resistance in addition to excellent thermal resistance, and mechanical properties.
摘要翻译： 电绕组包括电导体和围绕导体缠绕的多个固化的绝缘层，所述固化的绝缘层通过将两种或更多种绝缘材料与含有羟基的缩聚聚硅氧烷树脂的混合物的粘合剂溶液粘合而获得 分子和加成聚合型有机硅树脂以形成复合绝缘材料，将复合绝缘材料缠绕在导体周围，用环氧 - 异氰酸酯树脂的浸渍清漆浸渍包裹的复合绝缘材料并固化浸渍的复合绝缘材料具有优异的 耐水性除了优异的耐热性和机械性能外。
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6.发明授权Prepreg from poly(p-hydroxystyrene), epoxy-modified polybutadiene and maleimide 失效聚（对羟基苯乙烯），环氧改性聚丁二烯和马来酰亚胺
公开(公告)号：US5080965A
公开(公告)日：1992-01-14
申请号：US487406
申请日：1990-03-26
申请人： Katuo Sugawara , Akio Takahashi , Junichi Katagiri , Akira Nagai , Masahiro Ono , Toshikazu Narahara
发明人： Katuo Sugawara , Akio Takahashi , Junichi Katagiri , Akira Nagai , Masahiro Ono , Toshikazu Narahara
IPC分类号： C08G59/34 , B32B27/04 , B32B27/38 , C08F279/02 , C08G59/00 , C08G59/32 , C08G59/40 , C08J5/24 , C08L25/00 , C08L25/18 , C08L63/00 , C08L63/08 , H05K1/03
CPC分类号： C08J5/24 , C08F279/02 , H05K1/0353 , C08J2351/00 , Y10T428/24917 , Y10T442/2475 , Y10T442/2721 , Y10T442/2902 , Y10T442/2951 , Y10T442/3528
摘要： The present invention provides a thermosetting resin composition comprising(a) a prepolymer of a poly-p-hydroxystyrene derivative represented by the general formula ##STR1## wherein A is a halogen group, R.sub.1 is an alkenyl or alkenoyl group of 2 to 4 carbon atoms, 4 carbon atoms, m denotes a number of 1 to 4 and n denotes a number of 1 to 100,(b) an epoxy-modified polybutadiene, and(c) an aromatic maleimide compound, and a prepreg and a laminated sheet which use said resin composition.
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7.发明授权Composition comprising poly(p-hydroxystrene) derivative, epoxy-modified polybutadiene and aromatic maleimide 失效组合物，其包含聚（对 - 羟基硬
体）衍生物，环氧改性聚丁二烯和芳族马来酰亚胺公开(公告)号：US4931507A
公开(公告)日：1990-06-05
申请号：US266406
申请日：1988-11-02
申请人： Katuo Sugawara , Akio Takahashi , Junichi Katagiri , Akira Nagai , Masahiro Ono , Toshikazu Narahara
发明人： Katuo Sugawara , Akio Takahashi , Junichi Katagiri , Akira Nagai , Masahiro Ono , Toshikazu Narahara
IPC分类号： C08G59/34 , B32B27/04 , B32B27/38 , C08F279/02 , C08G59/00 , C08G59/32 , C08G59/40 , C08J5/24 , C08L25/00 , C08L25/18 , C08L63/00 , C08L63/08 , H05K1/03
CPC分类号： C08J5/24 , C08F279/02 , H05K1/0353 , C08J2351/00 , Y10T428/24917 , Y10T442/2475 , Y10T442/2721 , Y10T442/2902 , Y10T442/2951 , Y10T442/3528
摘要： The present invention provides a thermosetting resin composition comprising(a) a prepolymer of a poly(p-hydroxystyrene) derivative represented by the general formula ##STR1## wherein A is a halogen group, R.sub.1 is an alkenyl or alkenoyl group of 2 to 4 carbon atoms, m denotes a number of 1 to 4 and n denotes a number of 1 to 100,(b) an epoxy-modified polybutadiene, and(c) an aromatic maleimide compound, and a prepreg and a laminated sheet which use said resin composition.
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公开(公告)号：US4886858A
公开(公告)日：1989-12-12
申请号：US15325
申请日：1987-02-17
申请人： Junichi Katagiri , Akira Nagai , Keiko Tawara , Akio Takahashi , Motoyo Wajima , Toshikazu Narahara , Ryo Hiraga
发明人： Junichi Katagiri , Akira Nagai , Keiko Tawara , Akio Takahashi , Motoyo Wajima , Toshikazu Narahara , Ryo Hiraga
IPC分类号： C08L25/04 , C08F8/00 , C08F12/22 , C08F290/12 , C08F299/00 , C08G59/34 , C08L63/08 , H05K1/03
CPC分类号： C08G59/027 , C08F290/124 , C08F299/00 , C08F8/00 , C08L63/08 , H05K1/034 , Y10S428/901 , Y10T428/24917 , Y10T428/31511 , Y10T428/31529 , Y10T428/31678 , Y10T428/31696 , Y10T442/674
摘要： A thermosetting resin composition comprising a special poly(p-hydroxystyrene) derivative resin and a radical polymerization initiator, and if necessary an epoxy modified polybutadiene, can provide prepregs and laminates having a low dielectric constant, a shorter signalling delay time, good heat resistance and flame retardancy and thus being suitable for producing multilayer printed circuit boards.
摘要翻译： 包含特殊聚（对 - 羟基苯乙烯）衍生物树脂和自由基聚合引发剂的热固性树脂组合物，并且如果需要，可以提供环氧改性聚丁二烯，可以提供具有低介电常数，较短的信号延迟时间，良好的耐热性和较短的信号延迟时间的预浸料和层压材料 阻燃性，因此适用于生产多层印刷电路板。
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公开(公告)号：US4607094A
公开(公告)日：1986-08-19
申请号：US697530
申请日：1985-02-01
申请人： Katuo Sugawara , Akio Takahashi , Masahiro Ono , Ritsuro Tada , Motoyo Wajima , Toshikazu Narahara , Akira Nagai
发明人： Katuo Sugawara , Akio Takahashi , Masahiro Ono , Ritsuro Tada , Motoyo Wajima , Toshikazu Narahara , Akira Nagai
CPC分类号： C08G73/0655
摘要： The thermosetting resin composition of the present invention is prepared by mixing an aromatic cyanamide compound with a cyclic ester compound and/or a cyclic amide compound. Although a solventless type composition is preferable, the present invention is not limited thereto. The cured product of the present invention can be prepared by heating and curing said thermosetting resin composition. The obtained cured product of the present invention usually contains melamine rings, isomelamine rings and linear polyester and/or a linear polyamide units.
摘要翻译： 本发明的热固性树脂组合物通过将芳族氨基氰化合物与环状酯化合物和/或环状酰胺化合物混合来制备。 虽然优选无溶剂型组合物，但本发明不限于此。 本发明的固化物可以通过加热固化所述热固性树脂组合物来制备。 得到的本发明的固化物通常含有三聚氰胺环，异质单胺环和线性聚酯和/或线性聚酰胺单元。
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10.发明授权Odorless or low-odor crosslinkable compound and resin composition containing the same 失效无气味或低气味的交联性化合物和含有它们的树脂组合物
公开(公告)号：US4369288A
公开(公告)日：1983-01-18
申请号：US273034
申请日：1981-06-12
申请人： Tohru Koyama , Toshikazu Narahara , Yuji Aimono
发明人： Tohru Koyama , Toshikazu Narahara , Yuji Aimono
CPC分类号： C08G10/04 , C08C19/30 , C08F299/022 , C08L69/00
摘要： A crosslinkable compound obtained by reacting an aromatic hydrocarbon-formaldehyde resin with an .alpha.,.beta.-unsaturated monocarboxylic acid or an ester thereof has no odor or very slight odor. Said crosslinkable compound can be radical polymerized at a low temperature to give a cured article having excellent electrical insulating properties. Said crosslinkable compound can also be used as one component of a resin composition containing an unsaturated polyester resin or a polybutadiene resin modified with acrylic or methacrylic acid to give an odorless or low-odor resin composition suitable for producing reinforced plastics, paints and varnishes, adhesives, electrical parts, etc.
摘要翻译： 通过芳族烃 - 甲醛树脂与α，β-不饱和一元羧酸或其酯的反应得到的可交联化合物没有气味或非常轻微的气味。 所述交联性化合物可以在低温下自由基聚合，得到电绝缘性优异的固化物。 所述可交联化合物也可以用作含有不饱和聚酯树脂或用丙烯酸或甲基丙烯酸改性的聚丁二烯树脂的树脂组合物的一种组分，以产生适用于生产增强塑料，油漆和清漆的无味或低气味树脂组合物，粘合剂 ，电器配件等
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