公开(公告)号：US20120219825A1

公开(公告)日：2012-08-30

申请号：US13392864

申请日：2010-08-24

申请人： Hideyuki Minagi ,  Eiji Okamatsu

发明人： Hideyuki Minagi ,  Eiji Okamatsu

IPC分类号： B32B15/01

CPC分类号： C25D5/14 ,  C25D3/12 ,  C25D5/36 ,  C25D5/50 ,  C25D7/0614 ,  H01M2/0262 ,  H01M2/0275 ,  H01M2/0285 ,  H01M2/0287 ,  H01M2/0292 ,  Y02E60/12 ,  Y10S428/935 ,  Y10T428/12937 ,  Y10T428/12993

摘要： Provided is a Ni-plated steel sheet having excellent press formability. An Fe—Ni diffusion layer and a softened Ni layer formed on the Fe—Ni diffusion layer are formed on a surface of a steel sheet corresponding to an outer surface of a battery can, a semi-bright Ni plating layer is formed on the softened Ni layer, a Ni coating weight of the Fe—Ni diffusion layer and the softened Ni layer formed on the Fe—Ni diffusion layer is set smaller than a Ni coating weight of the semi-bright Ni plating layer, and average roughness Ra of the semi-bright Ni plating layer measured by a traceable roughness gauge is 1.0 μm or more and 2.0 μm or less, and a maximum height Ry of the semi-bright Ni plating layer measured by the traceable roughness gauge is 5 μm or more and 20 μm or less. Further, in the above-mentioned Ni-plated steel sheet, the Ni coating weight of the Fe—Ni diffusion layer and the softened Ni layer formed on the Fe—Ni diffusion layer is 5 to 8 g/m2, and the Ni coating weight of the semi-bright Ni plating layer is 8 g/m2 or more. Further, surface roughness Ra′ of a surface of the semi-bright Ni plating layer in an area of 2.5 μm×2.5 μm which is obtained by an atomic force microscope falls within a range from 5 to 22 nm.

摘要翻译： 本发明提供一种压制成型性优异的镀镍钢板。 在与电池壳体的外表面相对应的钢板的表面上形成有在Fe-Ni扩散层上形成的Fe-Ni扩散层和软化Ni层，在软化后形成半亮度Ni镀层 Ni层，Fe-Ni扩散层的Ni镀层重量和Fe-Ni扩散层上形成的软化Ni层的比例设定为小于半亮度Ni镀层的Ni涂层重量，平均粗糙度Ra 通过可追溯粗糙度计测量的半亮度Ni镀层为1.0μm以上且2.0μm以下，通过可追溯粗糙度计测定的半亮度Ni镀层的最大高度Ry为5μm以上且20μm 或更少。 此外，在上述镀镍钢板中，Fe-Ni扩散层的Ni涂层重量和Fe-Ni扩散层上形成的软化Ni层的重量为5〜8g / m 2，Ni涂层重量 的半光亮镀Ni层为8g / m 2以上。 此外，通过原子力显微镜得到的半亮度Ni镀层的表面的2.5μm×2.5μm的表面的表面粗糙度Ra'在5〜22nm的范围内。

公开(公告)号：US20130209867A1

公开(公告)日：2013-08-15

申请号：US13521036

申请日：2010-12-28

申请人： Hideyuki Minagi ,  Eiji Okamatsu

发明人： Hideyuki Minagi ,  Eiji Okamatsu

IPC分类号： H01M2/02

CPC分类号： H01M2/0257 ,  C25D3/12 ,  C25D5/14 ,  C25D5/36 ,  C25D5/50 ,  C25D7/00 ,  H01M2/0285 ,  H01M2/0287 ,  H01M2/0292

摘要： Provided is a Ni-plated steel sheet being excellent in press formability and suppression of wear of a mold and capable of maintaining alkali battery characteristic even after a lapse of time. In a Ni-plated steel sheet for a battery can having excellent press formability, an Fe—Ni diffusion layer and a Ni layer formed on the Fe—Ni diffusion layer are formed on a surface of a steel sheet corresponding to an outer surface of the battery can, a semi-bright Ni plating layer is formed on the Ni layer, a Ni coating weight of the Fe—Ni diffusion layer and the Ni layer formed on the Fe—Ni diffusion layer is set equal to or smaller than a Ni coating weight of the semi-bright Ni plating layer, the Ni coating weight of the semi-bright Ni plating layer is 2.25 g/m2 or more, surface roughness Ra1 of a surface of the semi-bright Ni plating layer in an area of 2.5 μm×2.5 μm which is measured by an atomic force microscope falls within a range from 3 to 11 nm, and surface roughness Ra2 measured by a traceable roughness gauge is 0.3 μm or more and 2.0 μm or less with respect to the surface roughness Ra of the semi-bright Ni plating layer.

摘要翻译： 本发明提供一种压模成型性优异，抑制模具磨损，并且即使经过时间也能够保持碱性电池特性的镀镍钢板。 在具有优异的压制成形性的电镀罐用镀镍钢板中，在与Fe-Ni扩散层的外表面相对应的钢板的表面上形成Fe-Ni扩散层和形成在Fe-Ni扩散层上的Ni层 电池罐，在Ni层上形成半亮Ni镀层，将Fe-Ni扩散层的Ni镀层重量和形成在Fe-Ni扩散层上的Ni层设定为等于或小于Ni涂层 半亮度Ni镀层的重量，半亮度Ni镀层的Ni涂层重量为2.25g / m 2以上，半亮度Ni镀层的面积为2.5μm的表面的表面粗糙度Ra1 通过原子力显微镜测定的×2.5μm，在3〜11nm的范围内，通过可追溯粗糙度计测定的表面粗糙度Ra2相对于表面粗糙度Ra为0.3μm以上且2.0μm以下 半光亮镀镍层。

公开(公告)号：US08795846B2

公开(公告)日：2014-08-05

申请号：US13392864

申请日：2010-08-24

申请人： Hideyuki Minagi ,  Eiji Okamatsu

发明人： Hideyuki Minagi ,  Eiji Okamatsu

IPC分类号： C25D5/50 ,  C25D5/14 ,  H01M2/02 ,  C25D5/36 ,  C25D3/12 ,  C25D7/06

CPC分类号： C25D5/14 ,  C25D3/12 ,  C25D5/36 ,  C25D5/50 ,  C25D7/0614 ,  H01M2/0262 ,  H01M2/0275 ,  H01M2/0285 ,  H01M2/0287 ,  H01M2/0292 ,  Y02E60/12 ,  Y10S428/935 ,  Y10T428/12937 ,  Y10T428/12993

摘要： Provided is a Ni-plated steel sheet having excellent press formability. An Fe—Ni diffusion layer and a softened Ni layer formed on the Fe—Ni diffusion layer are formed on a surface of a steel sheet corresponding to an outer surface of a battery can, a semi-bright Ni plating layer is formed on the softened Ni layer, a Ni coating weight of the Fe—Ni diffusion layer and the softened Ni layer formed on the Fe—Ni diffusion layer is set smaller than a Ni coating weight of the semi-bright Ni plating layer, and average roughness Ra of the semi-bright Ni plating layer measured by a traceable roughness gauge is 1.0 μm or more and 2.0 μm or less, and a maximum height Ry of the semi-bright Ni plating layer measured by the traceable roughness gauge is 5 μm or more and 20 μm or less.

摘要翻译： 本发明提供一种压制成型性优异的镀镍钢板。 在与电池壳体的外表面相对应的钢板的表面上形成有在Fe-Ni扩散层上形成的Fe-Ni扩散层和软化Ni层，在软化后形成半亮度Ni镀层 Ni层，Fe-Ni扩散层的Ni镀层重量和Fe-Ni扩散层上形成的软化Ni层的比例设定为小于半亮度Ni镀层的Ni涂层重量，平均粗糙度Ra 通过可追溯粗糙度计测量的半亮度Ni镀层为1.0μm以上且2.0μm以下，通过可追溯粗糙度计测定的半亮度Ni镀层的最大高度Ry为5μm以上且20μm 或更少。

公开(公告)号：US08734961B2

公开(公告)日：2014-05-27

申请号：US13377258

申请日：2010-05-31

申请人： Shinichi Takematsu ,  Eiji Okamatsu ,  Hideyuki Minagi

发明人： Shinichi Takematsu ,  Eiji Okamatsu ,  Hideyuki Minagi

IPC分类号： C25D5/50 ,  H01M2/02 ,  B21B1/22 ,  B21D51/26 ,  C25D5/16 ,  C25D3/12 ,  C25D7/00

CPC分类号： B21B1/227 ,  B21D51/26 ,  C25D3/12 ,  C25D5/16 ,  C25D5/48 ,  C25D5/50 ,  C25D7/00 ,  H01M2/02 ,  H01M2/0292 ,  Y10T29/49108 ,  Y10T29/49982 ,  Y10T428/12937 ,  Y10T428/12993

摘要： A Ni-plated steel sheet is provided in which the occurrence of scratches at the time of forming a battery can is suppressed. Also provided is a method which includes a step where a surface of a steel sheet is plated with Ni in a Ni adhesion amount of 0.3-2 μm, a step where the Ni-plated steel sheet is heated to 600-800° C. to form an Fe−Ni diffusion layer as an outermost surface layer, and a step where the steel sheet is rolled by temper rolling so as to adjust the Fe−Ni diffusion layer so that the steel sheet has the surface roughness Ra of 0.9-2.0 μm and the surface roughness Ry of 4.0-15 μm. A Ni-plated steel sheet which includes an Fe−Ni diffusion layer as an outermost surface layer and in which the diffusion layer has the surface roughness Ra of 0.9-2.0 μm and the surface roughness Ry of 4.0-15 μm and the diffusion layer has such an Fe/Ni ratio that the Fe accounts for 20-50% in Auger analysis is subjected to drawing using a water-soluble liquid which contains water-soluble emersion as a press lubricant.

摘要翻译： 提供了一种镀镍钢板，其中抑制了形成电池壳时的划痕的发生。 还提供了一种方法，其包括以0.3-2μm的Ni附着量将钢板的表面镀Ni的步骤，将镀Ni钢板加热至600-800℃至 形成作为最外表面层的Fe-Ni扩散层，并且通过回火轧制轧制钢板以调整Fe-Ni扩散层以使钢板的表面粗糙度Ra为0.9-2.0μm的步骤 表面粗糙度Ry为4.0〜15μm。 一种镀镍钢板，其包括Fe-Ni扩散层作为最外表面层，其中扩散层的表面粗糙度Ra为0.9-2.0μm，表面粗糙度Ry为4.0-15μm，扩散层具有 在俄歇分析中Fe占20-50％的Fe / Ni比例使用含有水溶性浸出物的水溶性液体作为压力润滑剂进行拉伸。

公开(公告)号：US20120171518A1

公开(公告)日：2012-07-05

申请号：US13377258

申请日：2010-05-31

申请人： Shinichi Takematsu ,  Eiji Okamatsu ,  Hideyuki Minagi

发明人： Shinichi Takematsu ,  Eiji Okamatsu ,  Hideyuki Minagi

IPC分类号： B32B15/01 ,  C23C10/20 ,  C23C10/60 ,  H01M2/02

CPC分类号： B21B1/227 ,  B21D51/26 ,  C25D3/12 ,  C25D5/16 ,  C25D5/48 ,  C25D5/50 ,  C25D7/00 ,  H01M2/02 ,  H01M2/0292 ,  Y10T29/49108 ,  Y10T29/49982 ,  Y10T428/12937 ,  Y10T428/12993

摘要： A Ni-plated steel sheet is provided in which thee occurrence of scratches at the time of forming a battery can is suppressed. Also provided is a method which includes a step where a surface of a steel sheet is plated with Ni in a Ni adhesion amount of 0.3-2 μm, a step where the Ni-plated steel sheet is heated to 600-800° C. to form an Fe−Ni diffusion layer as an outermost surface layer, and a step where the steel sheet is rolled by temper rolling so as to adjust the Fe−Ni diffusion layer so that the steel sheet has the surface roughness Ra of 0.9-2.0 μm and the surface roughness Ry of 4.0-15 μm. A Ni-plated steel sheet which includes an Fe−Ni diffusion layer as an outermost surface layer and in which the diffusion layer has the surface roughness Ra of 0.9-2.0 μm and the surface roughness Ry of 4.0-15 μm and the diffusion layer has such an Fe/Ni ratio that the Fe accounts for 20-50% in Auger analysis is subjected to drawing using a water-soluble liquid which contains water-soluble emersion as a press lubricant.

摘要翻译： 提供了一种镀镍钢板，其中抑制了在形成电池罐时发生划痕。 还提供了一种方法，其包括以0.3-2μm的Ni附着量将钢板的表面镀Ni的步骤，将镀Ni钢板加热至600-800℃至 形成作为最外表面层的Fe-Ni扩散层，以及通过调质轧制钢板以调整Fe-Ni扩散层以使钢板的表面粗糙度Ra为0.9-2.0μm的步骤 表面粗糙度Ry为4.0〜15μm。 一种镀镍钢板，其包括Fe-Ni扩散层作为最外表面层，其中扩散层的表面粗糙度Ra为0.9-2.0μm，表面粗糙度Ry为4.0-15μm，扩散层具有 在俄歇分析中Fe占20-50％的Fe / Ni比例使用含有水溶性浸出物的水溶性液体作为压力润滑剂进行拉伸。

公开(公告)号：US20080292957A1

公开(公告)日：2008-11-27

申请号：US10568089

申请日：2004-05-14

申请人： Tatsuo Tomomori ,  Yoshitaka Honda ,  Eiji Yamane ,  Eiji Okamatsu ,  Hitoshi Ohmura

发明人： Tatsuo Tomomori ,  Yoshitaka Honda ,  Eiji Yamane ,  Eiji Okamatsu ,  Hitoshi Ohmura

IPC分类号： H01M2/02

CPC分类号： H01M2/0285 ,  C23C18/32 ,  C23C18/34 ,  C23C18/36 ,  C23C28/02 ,  C23C28/021 ,  C23C28/023 ,  C23C28/028 ,  C23C30/00 ,  C25D3/562 ,  C25D5/14 ,  C25D5/50 ,  C25D7/00 ,  H01M2/0202 ,  H01M2/0225 ,  H01M2/024 ,  H01M2/0272 ,  H01M2/0275 ,  H01M2/0287 ,  H01M6/08 ,  H01M10/24 ,  H01M10/30 ,  H01M10/345

摘要： A bakery case-use surface-treated steel sheet excellent in battery performance, a battery case and a battery using it. The battery case is obtained by forming, on the Surface corresponding to a battery case of a inner surface of a steel sheet to be plated a surface-treated steel sheet having a nickel-plated layer as a lower layer and a nickel-phosphorus alloy plated layer or a nickel-cobalt-phosphorus alloy plated layer as an upper layer by a deep drawing method, a DI (drawing and ironing) method or a DTR (drawing thin and redraw) method.

摘要翻译： 电池性能优异的面包店使用表面处理钢板，电池盒和使用它的电池。 电池壳体通过在与镀覆有钢板的内表面的电池壳体的表面上形成有镀镍层作为下层的表面处理钢板和镀镍 - 磷合金而获得 层或通过深冲压法，DI（拉伸和熨烫）法或DTR（拉伸薄和重画）法作为上层的镍钴合金镀层。