公开(公告)号：US20130011331A1

公开(公告)日：2013-01-10

申请号：US13618526

申请日：2012-09-14

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizum ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizum ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： C01G53/04 ,  C01D1/02

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。

公开(公告)号：US08486564B2

公开(公告)日：2013-07-16

申请号：US13618526

申请日：2012-09-14

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： H01M4/13

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。

公开(公告)号：US20130302687A1

公开(公告)日：2013-11-14

申请号：US13941253

申请日：2013-07-12

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： H01M4/36 ,  H01M4/525

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

公开(公告)号：US20120282525A1

公开(公告)日：2012-11-08

申请号：US13513209

申请日：2010-10-07

申请人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

发明人： Hiroki Nagai ,  Masahiro Morita ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako ,  Hiroyuki Toya

IPC分类号： H01M4/525

CPC分类号： H01M4/366 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/16 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.

摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。

公开(公告)号：US20120270107A1

公开(公告)日：2012-10-25

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/131

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

摘要翻译： 本发明的目的是提供具有小粒径和均匀粒度分布的镍钴锰复合氢氧化物颗粒及其制造方法。 [解决方案]提供了通过结晶反应制造镍钴锰复合氢氧化物的方法。 该方法包括：通过将包含镍，钴和锰的金属化合物和铵离子给体的成核水溶液的pH控制在液体温度下测定的pH为12.0〜14.0，进行成核的成核步骤 以25℃为标准; 以及通过将含有在成核步骤中形成的核的颗粒生长用水溶液的pH控制为在液体温度25℃下测定的pH为10.5〜12.0的粒子生长工序。

公开(公告)号：US09954224B2

公开(公告)日：2018-04-24

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/505 ,  H01M4/525 ,  H01M4/131 ,  C01G53/00 ,  H01M10/052

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

公开(公告)号：US20140011090A1

公开(公告)日：2014-01-09

申请号：US13820110

申请日：2011-03-28

申请人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

发明人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

IPC分类号： C30B7/14 ,  H01M10/0525 ,  H01M4/525 ,  H01M4/04 ,  H01M4/36 ,  H01M4/505

CPC分类号： C30B7/14 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/34 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/40 ,  H01M4/0471 ,  H01M4/0497 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y10T428/2982

摘要： Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.

摘要翻译： 提供具有小而均匀的粒度的镍锰复合氢氧化物颗粒及其制造方法，其具有能够获得具有中空结构的正极活性物质的双重结构。 当通过反应结晶获得镍锰复合氢氧化物时，使用包含至少含有镍的金属化合物的成核水溶液，含有锰和铵离子供体的金属化合物，并控制在 25℃的标准溶液温度为10.5〜12.0，在氧浓度大于1体积％的氧化气氛中进行成核，然后通过将氧化气氛的气氛转换为混合 氧浓度为1体积％以下的氧气和惰性气体。

公开(公告)号：US10017875B2

公开(公告)日：2018-07-10

申请号：US13820110

申请日：2011-03-28

申请人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

发明人： Hiroyuki Toya ,  Kensaku Mori ,  Shin Imaizumi ,  Kenji Ikeuchi ,  Toshiyuki Osako

IPC分类号： H01M10/0525 ,  C30B7/14 ,  H01M4/505 ,  H01M4/525 ,  C01G53/00 ,  H01M4/04 ,  H01M4/36

CPC分类号： C30B7/14 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/34 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/40 ,  H01M4/0471 ,  H01M4/0497 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y10T428/2982

摘要： Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.

公开(公告)号：US20130078520A1

公开(公告)日：2013-03-28

申请号：US13520915

申请日：2011-08-26

申请人： Hiroyuki Toya ,  Kazuomi Ryoshi ,  Toshiyuki Osako

发明人： Hiroyuki Toya ,  Kazuomi Ryoshi ,  Toshiyuki Osako

IPC分类号： H01M4/52 ,  H01M4/525

CPC分类号： H01M4/485 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/88 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/362 ,  H01M4/483 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0427 ,  H01M10/052 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54

摘要： Provided are nickel manganese composite hydroxide particles that are a precursor for forming cathode active material comprising lithium nickel manganese composite oxide having hollow structure of particles having a small and uniform particle size for obtaining a non-aqueous electrolyte secondary battery having high capacity, high output and good cyclability.When obtaining the nickel manganese composite hydroxide particles from a crystallization reaction, an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel and a metallic compound that contains manganese, and does not include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 11.5 to 13.5, and after nucleation is performed, an aqueous solution for particle growth, which includes the nuclei that were formed in the nucleation step and does not substantially include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 9.5 to 11.5, and is less than the pH value in the nucleation step.

公开(公告)号：US07351271B2

公开(公告)日：2008-04-01

申请号：US11030384

申请日：2005-01-06

申请人： Toshiyuki Osako ,  Tetsufumi Komukai

发明人： Toshiyuki Osako ,  Tetsufumi Komukai

IPC分类号： C22C27/02

CPC分类号： H01G9/0525 ,  B22F9/18 ,  C01G33/00 ,  C01G35/00 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/80 ,  C22B5/04 ,  C22B5/18 ,  C22B34/24 ,  C22C1/045

摘要： A method of manufacturing niobium and/or tantalum powder consisting of: a first-stage reduction process of reducing niobium and/or tantalum oxides with alkali metals and/or alkaline-earth metals to obtain low-grade oxide powder represented by (NbTa) Ox, where x=0.06 to 0.35, a process of removing the oxide of alkali metals and/or alkaline-earth metals generated in the first-stage reduction process, and a second-stage reduction process of reducing the low-grade oxide powder obtained in the first-stage reduction process, with a melt solution of alkali metals and alkaline-earth metals to obtain niobium and/or tantalum powder.

摘要翻译： 一种制造铌和/或钽粉末的方法，包括：用碱金属和/或碱土金属还原铌和/或钽氧化物以获得由（NbTa）Ox表示的低级氧化物粉末的第一级还原方法 ，其中x = 0.06〜0.35，除去在第一阶段还原工序中产生的碱金属和/或碱土金属的氧化物的工序，以及第二阶段的还原工序， 第一阶段还原过程，用碱金属和碱土金属的熔融溶液来获得铌和/或钽粉末。