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1.发明申请公开(公告)号：US20050089456A1
公开(公告)日：2005-04-28
申请号：US10900320
申请日：2004-07-28
申请人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
发明人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
CPC分类号： F01N11/002 , B01D53/9422 , B01D53/9495 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2027 , B01D2255/2047 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/91 , F01N3/0814 , F01N3/0842 , F01N3/0871 , F01N3/0878 , F01N13/009 , F01N2250/12 , F01N2430/06 , F01N2510/06 , F01N2570/04 , F01N2610/03 , F02D41/027 , F02D41/0275 , F02D41/1455 , F02D41/146 , F02D41/1462 , F02D41/1463 , F02D41/1465 , F02D2200/0806 , F02D2200/0814 , Y02A50/2324 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which exhaust gas containing NOx gas passes, and a catalyst disposed in the exhaust gas duct such that it contacts the exhaust gas. The catalyst chemically adsorbs NOx when a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, adsorbed NOx is catalytically reduced in the presence of a reducing agent when the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent.
摘要翻译： 一种用于内燃机的废气净化装置，包括与发动机连接的废气管道，通过该排气气体通过含有NO x气体的废气，以及设置在排气管道中的催化剂， 接触废气。 当排气中存在的化学计量的气态氧化剂大于废气中存在的用于还原NOx的气态还原剂的催化剂时，催化剂化学吸附NO x， 当还原剂的化学计量量不大于还原剂的化学计量时，在还原剂的存在下催化还原吸附的NO x。
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2.发明授权
公开(公告)号：US6161378A
公开(公告)日：2000-12-19
申请号：US202243
申请日：1998-12-10
申请人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
发明人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
CPC分类号： F01N11/002 , B01D53/9422 , B01D53/9495 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2027 , B01D2255/2047 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/91 , F01N3/0814 , F01N3/0842 , F01N3/0871 , F01N3/0878 , F01N13/009 , F01N2250/12 , F01N2430/06 , F01N2510/06 , F01N2570/04 , F01N2610/03 , F02D41/027 , F02D41/0275 , F02D41/1455 , F02D41/146 , F02D41/1462 , F02D41/1463 , F02D41/1465 , F02D2200/0806 , F02D2200/0814 , Y02A50/2324 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which exhaust gas containing NO.sub.x gas passes, and a catalyst disposed in the exhaust gas duct such that it contacts the exhaust gas. The catalyst chemically adsorbs NO.sub.x when a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NO.sub.x, adsorbed NO.sub.x is catalytically reduced in the presence of a reducing agent when the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent.
摘要翻译： PCT No.PCT / JP97 / 01955 Sec。 371 1998年12月10日第 102（e）1998年12月10日日期PCT 1997年6月9日PCT公布。 出版物WO97 / 47864 日本公报1997年12月18日在内燃机中使用的排气净化装置具备：与发动机连接的排气管道，通过该排气通过含有NOx的废气，以及设置在排气管道内的催化剂，使其与排气接触 加油站。 当废气中存在的化学计量的气态氧化剂大于用于还原NOx的排气中存在的气态还原剂的化学计量时，催化剂化学吸附NOx，在还原剂的存在下，吸附的NOx被催化还原， 氧化剂的化学计量量不大于还原剂的化学计量量。
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3.发明申请公开(公告)号：US20070204595A1
公开(公告)日：2007-09-06
申请号：US11746313
申请日：2007-05-09
申请人： Hiroshi HANAOKA , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
发明人： Hiroshi HANAOKA , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
IPC分类号： F01N3/00
CPC分类号： F01N11/002 , B01D53/9422 , B01D53/9495 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2027 , B01D2255/2047 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/91 , F01N3/0814 , F01N3/0842 , F01N3/0871 , F01N3/0878 , F01N13/009 , F01N2250/12 , F01N2430/06 , F01N2510/06 , F01N2570/04 , F01N2610/03 , F02D41/027 , F02D41/0275 , F02D41/1455 , F02D41/146 , F02D41/1462 , F02D41/1463 , F02D41/1465 , F02D2200/0806 , F02D2200/0814 , Y02A50/2324 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which exhaust gas containing NOx gas passes, and a catalyst disposed in the exhaust gas duct such that it contacts the exhaust gas. The catalyst chemically adsorbs NOx when a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, adsorbed NOx is catalytically reduced in the presence of a reducing agent when the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent.
摘要翻译： 一种用于内燃机的废气净化装置，包括与发动机连接的废气管道，通过该排气气体通过含有NO x气体的废气，以及设置在排气管道中的催化剂， 接触废气。 当排气中存在的化学计量的气态氧化剂大于废气中存在的用于还原NOx的气态还原剂的催化剂时，催化剂化学吸附NO x， 当还原剂的化学计量量不大于还原剂的化学计量时，在还原剂的存在下催化还原吸附的NO x。
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4.发明授权公开(公告)号：US06397582B1
公开(公告)日：2002-06-04
申请号：US09620650
申请日：2000-07-20
申请人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
发明人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
IPC分类号： F01N300
CPC分类号： F01N11/002 , B01D53/9422 , B01D53/9495 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2027 , B01D2255/2047 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/91 , F01N3/0814 , F01N3/0842 , F01N3/0871 , F01N3/0878 , F01N13/009 , F01N2250/12 , F01N2430/06 , F01N2510/06 , F01N2570/04 , F01N2610/03 , F02D41/027 , F02D41/0275 , F02D41/1455 , F02D41/146 , F02D41/1462 , F02D41/1463 , F02D41/1465 , F02D2200/0806 , F02D2200/0814 , Y02A50/2324 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which the exhaust gas containing NOx gas passes and a catalyst so disposed in the exhaust gas duct that it contacts with the exhaust gas. The catalyst chemically adsorbs NOx under the condition that a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, while NOx being adsorbed is catalytically reduced in the presence of the reducing agent under the condition that the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent. Thereby, NOx the lean burn exhaust gas in the engine can be effectively made harmlessly.
摘要翻译： 在内燃机中使用的废气净化装置具备：与发动机连接的排气管道，通过该排气气体使含有NOx的废气通过，排气管与排气相接触的催化剂。 催化剂在排气中存在的化学计量的气态氧化剂大于存在于用于还原NOx的排气中的气态还原剂的化学计量量的条件下化学吸附NOx，而在存在下催化还原NOx 的还原剂在氧化剂的化学计量不大于还原剂的化学计量量的条件下进行。 因此，能够有效地使发动机中的贫燃废气的NOx成为无害化。
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5.发明授权公开(公告)号：US07093432B2
公开(公告)日：2006-08-22
申请号：US10119075
申请日：2002-04-10
申请人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
发明人： Hiroshi Hanaoka , Osamu Kuroda , Ryouta Doi , Hidehiro Iizuka , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Kojiro Okude , Norihiro Shinotsuka , Toshio Manaka
IPC分类号： F01N3/10
CPC分类号： F01N11/002 , B01D53/9422 , B01D53/9495 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2022 , B01D2255/2027 , B01D2255/2047 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/91 , F01N3/0814 , F01N3/0842 , F01N3/0871 , F01N3/0878 , F01N13/009 , F01N2250/12 , F01N2430/06 , F01N2510/06 , F01N2570/04 , F01N2610/03 , F02D41/027 , F02D41/0275 , F02D41/1455 , F02D41/146 , F02D41/1462 , F02D41/1463 , F02D41/1465 , F02D2200/0806 , F02D2200/0814 , Y02A50/2324 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas purification apparatus for use in an internal combustion engine comprises an exhaust gas duct connected to the engine through which the exhaust gas containing NOx gas passes and a catalyst so disposed in the exhaust gas duct that it contacts with the exhaust gas.The catalyst chemically adsorbs NOx under the condition that a stoichiometric amount of a gaseous oxidizing agent present in the exhaust gas is larger than that of a gaseous reducing agent present in the exhaust gas for reducing NOx, while NOx being adsorbed is catalytically reduced in the presence of the reducing agent under the condition that the stoichiometric amount of the oxidizing agent is not larger that of the reducing agent.Thereby, NOx, the lean burn exhaust gas in the engine can be effectively made harmlessly.
摘要翻译： 在内燃机中使用的废气净化装置具备：与发动机连接的排气管道，通过该排气气体使含有NOx的废气通过，排气管与排气相接触的催化剂。 催化剂在排气中存在的化学计量的气态氧化剂大于存在于用于还原NOx的排气中的气态还原剂的化学计量量的条件下化学吸附NOx，而在存在下催化还原NOx 的还原剂在氧化剂的化学计量不大于还原剂的化学计量量的条件下进行。 由此，能够有效地使发动机中的稀燃废气成为无害化的NOx。
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公开(公告)号：US06272848B1
公开(公告)日：2001-08-14
申请号：US09116708
申请日：1998-07-17
申请人： Kojiro Okude , Hidehiro Iizuka , Osamu Kuroda , Ryouta Doi , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Norihiro Shinotsuka
发明人： Kojiro Okude , Hidehiro Iizuka , Osamu Kuroda , Ryouta Doi , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Toshifumi Hiratsuka , Norihiro Shinotsuka
IPC分类号： F01N300
CPC分类号： F01N3/085 , B01D53/9495 , F01N3/0842 , F01N2570/04 , F02D41/0285 , F02D2041/288
摘要： An apparatus and method of highly efficiently purifying nitrogen oxides are provided. An NOx chemisorption reduction catalyst chemically absorbs NOx under a condition that an exhaust gas of an internal combustion engine is an oxidizing atmosphere and deoxidizes adsorbed NOx under a reducing atmosphere. An SOx absorbent absorbs SOx contained in the exhaust gas of the oxidizing atmosphere, and deoxidizes and release SOx absorbed in the reducing atmospheric exhaust gas. The catalyst and absorbent are arranged in the exhaust path to purify the exhaust gas while preventing or suppressing SOx-poisoning of the NOx chemisorption reduction catalyst.
摘要翻译： 提供了高效净化氮氧化物的装置和方法。 NOx化学吸附还原催化剂在内燃机的排气是氧化气氛并在还原气氛下脱氧吸附的NOx的条件下，化学吸收NOx。 SO x吸收剂吸收氧化气氛的废气中所含的SOx，并且还原和释放在还原气氛废气中吸收的SO x。 催化剂和吸收剂布置在排气路径中以净化废气，同时防止或抑制NOx化学吸附还原催化剂的SOx中毒。
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7.发明授权
公开(公告)号：US5968870A
公开(公告)日：1999-10-19
申请号：US958673
申请日：1997-10-27
申请人： Hidehiro Iizuka , Ryouta Doi , Hiroshi Hanaoka , Toshio Ogawa , Osamu Kuroda , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Norihiro Shinotsuka
发明人： Hidehiro Iizuka , Ryouta Doi , Hiroshi Hanaoka , Toshio Ogawa , Osamu Kuroda , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Norihiro Shinotsuka
CPC分类号： B01D53/9422 , B01J23/58 , B01J23/63 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/202 , B01D2255/2047 , B01D2255/2063 , B01D2255/2065 , B01D2255/20707
摘要： A catalyst being formed of a porous supporter supporting alkali metals, Ti and a noble metal, or further supporting at least one of rare earth metal and magnesium, being disposed in a flow passage of an internal combustion engine, and being used to purify NOx contained in the exhaust gas. The above catalyst has NOx resistance to exhaust gas burnt with a rich condition and with a lean condition and a high resistivity to poisoning by SOx.
摘要翻译： 催化剂由支撑碱金属，Ti和贵金属的多孔支撑体形成，或进一步支撑稀土金属和镁中的至少一种，设置在内燃机的流路中，用于净化所含的NOx 在废气中。 上述催化剂对具有丰富的条件并且具有稀薄条件和高SOx中毒性的高电阻燃烧的废气具有耐NOx性。
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公开(公告)号：US06596247B1
公开(公告)日：2003-07-22
申请号：US09348272
申请日：1999-07-07
申请人： Hidehiro Iizuka , Ryouta Doi , Hiroshi Hanaoka , Toshio Ogawa , Osamu Kuroda , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Norihiro Shinotsuka
发明人： Hidehiro Iizuka , Ryouta Doi , Hiroshi Hanaoka , Toshio Ogawa , Osamu Kuroda , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Norihiro Shinotsuka
IPC分类号： B01D5356
CPC分类号： B01D53/9422 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/202 , B01D2255/2047 , B01D2255/2063 , B01D2255/2065 , B01D2255/20707 , B01J23/58 , B01J23/63
摘要： A catalyst being formed of a porous supporter supporting alkali metals, Ti and noble metal, or further supporting at least one of rare earth metal and magnesium, being disposed in a flow passage of the internal combustion engine, and being used to purify NOx contained in the exaust gas. The above catalyst has excellent NOx resistance not only to the exaust gas burnt with the stoichiometric air-to-fuel ratio or rich condition, but to the exhaust gas burnt with the lean condition, and furthermore has a high resistivity to poisoning of SOx slightly contained in the fuel.
摘要翻译： 催化剂由支撑碱金属，Ti和贵金属的多孔支撑体形成，或进一步支撑稀土金属和镁中的至少一种，设置在内燃机的流路中，用于净化含有 大气。 上述催化剂不仅具有优良的耐NOx燃烧性能，而且具有化学计量空燃比或浓度较高的燃烧气体，而且对贫燃料燃烧的废气具有优异的耐NOx性，而且还具有高电阻率， 在燃料中。
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9.发明授权
公开(公告)号：US5972828A
公开(公告)日：1999-10-26
申请号：US943151
申请日：1997-10-03
申请人： Ryouta Doi , Hidehiro Iizuka , Hiroshi Hanaoka , Toshio Ogawa , Osamu Kuroda , Hisao Yamashita , Yuichi Kitahara , Toshifumi Hiratsuka
发明人： Ryouta Doi , Hidehiro Iizuka , Hiroshi Hanaoka , Toshio Ogawa , Osamu Kuroda , Hisao Yamashita , Yuichi Kitahara , Toshifumi Hiratsuka
CPC分类号： B01D53/945 , B01J23/63 , Y02T10/22
摘要： In order to remove nitrogen oxide in an exhaust gas released from a lean burn engine, a catalyst: supporting an rare earth metal, an alkali earth metal, titanium, a noble metal, and magnesium on the surface of a porous carrier made of inorganic oxides is provided. In order to manufacture the catalyst, the rare earth metal is supported onto the surface of the carrier first, subsequently the alkali earth metal other than magnesium and titanium are supported, the noble metal is supported, and magnesium is supported finally onto the surface of the carrier.The catalyst of the present invention is scarcely poisoned by SOx in the exhaust gas released from the lean burn engine, and has a heat resistivity durable against high speed driving.
摘要翻译： 为了除去从稀燃发动机排出的废气中的氮氧化物，在由无机氧化物制成的多孔质载体的表面上含有稀土金属，碱土金属，钛，贵金属和镁的催化剂 被提供。 为了制造催化剂，首先将稀土金属负载在载体的表面上，随后负载除了镁和钛之外的碱土金属，负载贵金属，最后将镁负载在 载体 本发明的催化剂在从稀燃发动机排出的排气中几乎不被SOx中毒，具有耐高速行驶耐热性的耐热性。
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公开(公告)号：US6045764A
公开(公告)日：2000-04-04
申请号：US638811
申请日：1996-04-29
申请人： Hidehiro Iizuka , Osamu Kuroda , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Takeshi Atago , Hiroatsu Tokuda , Takao Ishikawa , Hiroshi Hanaoka , Hiroshi Tobita , Shinichi Ichikawa , Toshifumi Hiratsuka
发明人： Hidehiro Iizuka , Osamu Kuroda , Toshio Ogawa , Hisao Yamashita , Shigeru Azuhata , Yuichi Kitahara , Takeshi Atago , Hiroatsu Tokuda , Takao Ishikawa , Hiroshi Hanaoka , Hiroshi Tobita , Shinichi Ichikawa , Toshifumi Hiratsuka
CPC分类号： B01J37/0244 , B01D53/9418 , B01J23/63 , B01J35/0006 , B01D2251/208 , B01D2255/1021 , B01D2255/204 , B01D2255/2063 , B01D2255/2065 , B01D2255/908 , Y02T10/24
摘要： An exhaust gas purifying catalyst is provided for purifying NOx contained in an exhaust gas from an internal combustion engine of a vehicle operated at a high air fuel ratio due to excessive oxygen, using unburnt HC or CO in the exhaust gas as a reducing agent. The catalyst comprises platinum, strontium and a rare earth metal, as active components, each supported on a support of inorganic oxide. The active components of the catalyst include platinum of 0.01-3.7 by wt ratio, strontium of 0.01-55 by wt ratio and a rare earth metal of 0.01-36 wt ratio, per the inorganic oxide of 100 by wt ratio.
摘要翻译： 提供一种废气净化催化剂，用于净化来自由于过量的氧气而以高空燃比操作的车辆的内燃机中的废气中的NOx，使用废气中的未燃HC或CO作为还原剂。 催化剂包括铂，锶和稀土金属作为活性组分，各自负载在无机氧化物的载体上。 催化剂的活性组分包括0.01-3.7重量％的铂，0.01-55重量％的锶，0.01-36重量％的稀土金属，相对于100重量％的无机氧化物。
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