公开(公告)号：US5817892A

公开(公告)日：1998-10-06

申请号：US915594

申请日：1997-08-21

申请人： Hiroyuki Tamura ,  Hideo Tahara ,  Yoshinori Mitsuda ,  Yasuyuki Hattori

发明人： Hiroyuki Tamura ,  Hideo Tahara ,  Yoshinori Mitsuda ,  Yasuyuki Hattori

IPC分类号： B01J23/10 ,  B01J23/12 ,  C07B61/00 ,  C07C27/02 ,  C07C29/149 ,  C07C33/02 ,  C07C29/136

CPC分类号： C07C29/149 ,  B01J23/10 ,  B01J23/12

摘要： A process for producing an unsaturated alcohol wherein the catalytic activity and the capability of maintaining double bond are sustained for a long time and side-reactions are suppressed. An unsaturated alcohol is obtained by hydrogenating an alkyl or alkenyl ester of an unsaturated fatty acid or a triglyceride having a long-chain aliphatic unsaturated hydrocarbon group in the presence of a catalytic composition which is a composite metal oxide consisting of (a) zinc oxide and (b) oxide(s) of at least one metal selected from the group consisting of the elements of the group 3A in the periodic table and having a weight ratio of (a)/(b) of from 1/0.01 to 1/1.2.

摘要翻译： 制造不饱和醇的方法，其中催化活性和维持双键的能力长时间地持续并且副反应被抑制。 通过在由（a）氧化锌和（a）组成的复合金属氧化物的催化剂组合物存在下氢化不饱和脂肪酸或具有长链脂肪族不饱和烃基的甘油三酯的烷基或链烯基酯获得不饱和醇， （b）选自元素周期表中第3A族元素中的至少一种金属的氧化物，其重量比（a）/（b）为1 / 0.01-1 / 1.2 。

公开(公告)号：US5250713A

公开(公告)日：1993-10-05

申请号：US849187

申请日：1992-03-11

申请人： Hiroyuki Tamura ,  Yasuyuki Hattori ,  Kunizo Hashiba ,  Osamu Tabata ,  Kiyoshi Tsukada ,  Noriaki Fukuoka

发明人： Hiroyuki Tamura ,  Yasuyuki Hattori ,  Kunizo Hashiba ,  Osamu Tabata ,  Kiyoshi Tsukada ,  Noriaki Fukuoka

IPC分类号： C07C29/149 ,  C11B3/02 ,  C07C51/36

CPC分类号： C11B3/02 ,  C07C29/149

摘要： A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm.sup.2 in the absolute pressure at a temperature of from 100.degree. to 350.degree. C. in the presence of a catalyst of the following formula (I):Cu.multidot.X.sub.x .multidot.Y.sub.y .multidot.O.sub.z (I)wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

摘要翻译： 公开了一种生产脱硫脂肪和油或脂肪酸酯的方法，其包括在氢气或氢气和惰性气体气氛下以0.1-500kg / cm 2的压力下在脂肪和油或脂肪酸酯中的处理 在下式（I）的催化剂存在下，在100℃至350℃的温度下的绝对压力：其中所有符号在本公开中定义的CuxXxxYyxOz（I）。 还公开了使用脱硫脂肪和油或脂肪酸酯制备醇的方法。 根据本发明的醇的制造方法，可以有效且高效地制造纯度高，品质好的醇。

公开(公告)号：US5120885A

公开(公告)日：1992-06-09

申请号：US757053

申请日：1991-09-09

申请人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Hiroyuki Tamura ,  Akira Yamamuro ,  Kunizo Hashiba ,  Osamu Tabata

发明人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Hiroyuki Tamura ,  Akira Yamamuro ,  Kunizo Hashiba ,  Osamu Tabata

IPC分类号： C07C29/149

CPC分类号： C07C29/149

摘要： A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50.degree. to 200.degree. C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

摘要翻译： 公开了一种制备醇的方法，其包括在用于酯还原的催化剂的存在下用氢气催化降低脂肪和油或脂肪酸酯，其中起始油首先在50℃至200℃的温度下在氢气 气体或氢气和惰性气体的混合气体，在镍催化剂的存在下得到不大于0.6ppm的硫含量，酸值（KOH mg / g）不大于2.通过使用如此纯化的 起始油，用于酯还原的催化剂表现出延长的持续时间。

公开(公告)号：US5254705A

公开(公告)日：1993-10-19

申请号：US890109

申请日：1992-05-29

申请人： Yasuyuki Hattori ,  Hiroyuki Tamura ,  Hidetoshi Kadowaki ,  Kiyoshi Tsukada

发明人： Yasuyuki Hattori ,  Hiroyuki Tamura ,  Hidetoshi Kadowaki ,  Kiyoshi Tsukada

IPC分类号： B01J23/755 ,  C07C27/26 ,  C07C29/149 ,  C07C67/60 ,  C07C69/587 ,  C11B3/02 ,  C07C51/36

CPC分类号： C07C29/149 ,  C11B3/02

摘要： A process for producing desulfurized fats and oils or fatty acid esters, which are highly suitable as a starting material for producing alcohols via hydrogenation, at a high yield is disclosed. Desulfurized fats and oils or fatty acid esters are obtained by contacting fats and oils or fatty acid esters with a catalyst represented by the following formula (I) under a hydrogen atmosphere or a mixture of hydrogen with an inert gas:Ni.Cu.sub.x O.sub.y (I)wherein x represents an atomic ratio of Cu determined by referring Ni as 1 and a value of from 0.02 to 8; and y is an atomic ratio of oxygen satisfying the valence requirements of Ni and Cu. A process for producing alcohols using the desulfurized fats and oils or fatty acid esters is also disclosed. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

摘要翻译： 公开了一种生产脱硫脂肪或油脂或脂肪酸酯的方法，其高度适合作为通过氢化生产醇的起始原料。 通过在氢气氛下或氢气与惰性气体的混合物中将脂肪和油或脂肪酸酯与下式（I）表示的催化剂接触来获得脱硫脂肪和油或脂肪酸酯：Ni.CuxOy（I） 其中x表示通过将Ni指定为1而测定的Cu的原子比和0.02至8的值的原子比; y是满足Ni和Cu的化合价要求的氧的原子比。 还公开了使用脱硫脂肪和油或脂肪酸酯制备醇的方法。 还公开了使用脱硫脂肪和油或脂肪酸酯制备醇的方法。 根据本发明的醇的制造方法，可以有效且高效地制造纯度高，品质好的醇。

公开(公告)号：US08412573B2

公开(公告)日：2013-04-02

申请号：US13185237

申请日：2011-07-18

申请人： Takuji Maekawa ,  Yasuyuki Hattori ,  Masaki Takemura ,  Takahisa Hakoishi ,  Takashi Hosoda ,  Akira Yaegashi ,  Hiroshi Sugaya

发明人： Takuji Maekawa ,  Yasuyuki Hattori ,  Masaki Takemura ,  Takahisa Hakoishi ,  Takashi Hosoda ,  Akira Yaegashi ,  Hiroshi Sugaya

IPC分类号： G06Q40/00

CPC分类号： G06Q30/02 ,  G06Q30/0207 ,  G06Q30/0241 ,  G06Q30/0242 ,  G06Q30/0268

摘要： A method for distributing advertisement data to display terminal devices from a distribution server via a relay server. The relay server receives status notifications of the display terminal devices and transmits a tenor of receipt of the status notifications to the display terminal devices. The distribution server receiving status notifications and transmits the tenor of receipt of the status notifications to the relay server. The distribution server determines whether the reproduction schedule of the advertisement data has been changed and transmits a notification on a change. If the distribution server receives a request for acquisition of the as-changed reproduction schedule, the distribution server sends the as-changed reproduction schedule to the relay server. If the relay server determines that the reproduction schedule acquired from the distribution server has been changed, the relay server transmits the notification on the change of the reproduction schedule.

摘要翻译： 一种用于经由中继服务器从分发服务器向广播终端设备分发广告数据的方法。 中继服务器接收显示终端装置的状态通知，并将显示终端装置的状态通知的接收发送。 分发服务器接收状态通知，并向中继服务器发送状态通知的接收时间。 分发服务器确定广告数据的再现时间表是否已经改变，并且发送关于变化的通知。 如果分发服务器接收到用于获取改变的再现调度的请求，则分发服务器将改变的再现调度发送到中继服务器。 如果中继服务器确定从分发服务器获取的再现调度已经改变，则中继服务器发送关于再现时间表的改变的通知。

公开(公告)号：US20110282720A1

公开(公告)日：2011-11-17

申请号：US13185237

申请日：2011-07-18

申请人： Takuji Maekawa ,  Yasuyuki Hattori ,  Masaki Takemura ,  Takahisa Hakoishi ,  Takashi Hosoda ,  Akira Yaegashi ,  Hiroshi Sugaya

发明人： Takuji Maekawa ,  Yasuyuki Hattori ,  Masaki Takemura ,  Takahisa Hakoishi ,  Takashi Hosoda ,  Akira Yaegashi ,  Hiroshi Sugaya

IPC分类号： G06Q30/00

CPC分类号： G06Q30/02 ,  G06Q30/0207 ,  G06Q30/0241 ,  G06Q30/0242 ,  G06Q30/0268

摘要： A method for distributing advertisement data to display terminal devices from a distribution server via a relay server. The relay server receives status notifications of the display terminal devices and transmits a tenor of receipt of the status notifications to the display terminal devices. The distribution server receiving status notifications and transmits the tenor of receipt of the status notifications to the relay server. The distribution server determines whether the reproduction schedule of the advertisement data has been changed and transmits a notification on a change. If the distribution server receives a request for acquisition of the as-changed reproduction schedule, the distribution server sends the as-changed reproduction schedule to the relay server. If the relay server determines that the reproduction schedule acquired from the distribution server has been changed, the relay server transmits the notification on the change of the reproduction schedule.

摘要翻译： 一种用于经由中继服务器从分发服务器向广播终端设备分发广告数据的方法。 中继服务器接收显示终端装置的状态通知，并将显示终端装置的状态通知的接收发送。 分发服务器接收状态通知，并向中继服务器发送状态通知的接收时间。 分发服务器确定广告数据的再现时间表是否已经改变，并且发送关于变化的通知。 如果分发服务器接收到用于获取改变的再现调度的请求，则分发服务器将改变的再现调度发送到中继服务器。 如果中继服务器确定从分发服务器获取的再现调度已经改变，则中继服务器发送关于再现时间表的改变的通知。

公开(公告)号：US06383970B1

公开(公告)日：2002-05-07

申请号：US09597536

申请日：2000-06-19

申请人： Taku Mimura ,  Jun Kaita ,  Noriaki Fukuoka ,  Yasuyuki Hattori

发明人： Taku Mimura ,  Jun Kaita ,  Noriaki Fukuoka ,  Yasuyuki Hattori

IPC分类号： B01J3100

CPC分类号： C07C67/08 ,  B01J27/16 ,  B01J31/0261 ,  B01J2231/40 ,  B01J2231/49 ,  C07C67/03 ,  C07C69/52 ,  C07C69/24

摘要： The present invention provides a solid acid catalyst developing high activity and exhibiting high durability in various organic reactions. That is, the present invention provides a solid acid catalyst having the structure (A) in which a hydrogen atom is eliminated from at least one of OH groups contained in an inorganic phosphorus acid, the structure (B) in which a hydrogen atom is eliminated from at least one of OH groups contained in an organic phosphorus acid represented by the formula (1) or (2) and at least one metal atom (C) selected from aluminum, gallium and iron and a method for producing an ester, a ketal or an acetal by using the solid acid catalyst; wherein each of —R1 and —R2 is selected from —R, —OR, —OH and —H in which at least one of —R1 and —R2 is —R or —OR, given that —R is an organic group having 1-22 carbon atoms.

摘要翻译： 本发明提供一种在各种有机反应中显示出高活性和显示高耐久性的固体酸催化剂。 也就是说，本发明提供具有结构（A）的固体酸催化剂，其中从无机磷酸中所含的OH基中的至少一个除去氢原子，其中消除氢原子的结构（B） 由式（1）或（2）表示的有机磷酸中的至少一个OH基和选自铝，镓和铁中的至少一种金属原子（C）和酯的制备方法，缩酮 或通过使用固体酸催化剂的缩醛;其中-R1和-R2各自选自-R，-OR，-OH和-H，其中-R1和-R2中的至少一个是-R或-OR， 假定-R是具有1-22个碳原子的有机基团。

公开(公告)号：US5852388A

公开(公告)日：1998-12-22

申请号：US901258

申请日：1997-07-28

申请人： Shinya Nakai ,  Masashi Katsumata ,  Yasuyuki Hattori ,  Kenta Nagai ,  Yoshiaki Fukumitsu ,  Takehiko Ishizuka

发明人： Shinya Nakai ,  Masashi Katsumata ,  Yasuyuki Hattori ,  Kenta Nagai ,  Yoshiaki Fukumitsu ,  Takehiko Ishizuka

IPC分类号： H03B1/00 ,  H03B5/12 ,  H03B5/18

CPC分类号： H03B5/1847 ,  H03B5/1203 ,  H03B5/1231 ,  H03B5/124 ,  H03B5/1243 ,  H03B5/1256 ,  H03B5/1293 ,  H03B2200/0024 ,  H03B2200/004 ,  H03B2201/011 ,  H03B2201/012 ,  H03B2201/0208 ,  H03B2201/03

摘要： A voltage controlled oscillator including a resonator which generates an oscillation signal, a frequency of which is in response to a control signal, and an amplifier which amplifies the oscillation signal. Also included is a frequency adjusting mechanism, as well as a voltage control sensitivity mechanism. In one example, the resonator includes an input terminal to which the control signal is applied, a variable capacitance diode and a main inductor. The oscillation frequency adjusting mechanism includes a first variable capacitor, arranged in parallel with the main inductor of the resonator. In addition, the voltage control sensitivity adjusting mechanism includes a second variable capacitor arranged between the input terminal and the amplifying mechanism, and also arranged between a hot terminal of the variable capacitance diode and a hot terminal of the main inductor.

摘要翻译： 一种压控振荡器，包括产生其频率响应于控制信号的振荡信号的谐振器和放大振荡信号的放大器。 还包括频率调节机构以及电压控制灵敏度机构。 在一个示例中，谐振器包括施加控制信号的输入端子，可变电容二极管和主电感器。 振荡频率调节机构包括与谐振器的主电感并联布置的第一可变电容器。 此外，电压控制灵敏度调节机构包括布置在输入端子和放大机构之间的第二可变电容器，并且还布置在可变电容二极管的热端子和主电感器的热端子之间。

公开(公告)号：US5763353A

公开(公告)日：1998-06-09

申请号：US789540

申请日：1997-01-27

申请人： Yasuo Kadono ,  Yasuyuki Hattori ,  Masamitsu Horio ,  Fumihiko Nakamura

发明人： Yasuo Kadono ,  Yasuyuki Hattori ,  Masamitsu Horio ,  Fumihiko Nakamura

IPC分类号： B01J23/00 ,  B01J23/745 ,  B01J23/80 ,  C07C29/149 ,  B01J23/72

CPC分类号： B01J23/005 ,  B01J23/745 ,  B01J23/80 ,  C07C29/149

摘要： The present invention provides a hydrogenation catalyst precursor which does not bring about a problem of environmental pollution involved in copper-chromium catalysts and has a high activity, a high durability and a high selectivity as compared with those of conventional copper-iron-aluminum catalysts, a hydrogenation catalyst obtained by reducing the same, and a production process for alcohols using the above hydrogenation catalyst. The hydrogenation catalyst precursor described above comprises copper, iron and aluminum and containing as a principal component a compound oxide of copper, iron and aluminum in which an atomic ratio Cu:Fe:Al is 1:(0.02 to 0.4):(1.0 to 4.0) and which has a copper-aluminum spinel structure.

摘要翻译： 本发明提供一种不与铜铬催化剂相关的环境污染问题的氢化催化剂前体，与常规铜 - 铁 - 铝催化剂相比具有高活性，高耐久性和高选择性， 通过还原得到的氢化催化剂和使用上述氢化催化剂的醇的制备方法。 上述氢化催化剂前体包括铜，铁和铝，并以铜，铁和铝的复合氧化物为主要成分，其中原子比Cu：Fe：Al为1：（0.02〜0.4）：1.0〜4.0 ），其具有铜 - 铝尖晶石结构。

公开(公告)号：US5658843A

公开(公告)日：1997-08-19

申请号：US448580

申请日：1995-06-06

申请人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Taku Mimura ,  Osamu Tabata ,  Futoshi Nishigaki

发明人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Taku Mimura ,  Osamu Tabata ,  Futoshi Nishigaki

IPC分类号： B01J23/72 ,  B01J23/60 ,  B01J23/70 ,  B01J23/745 ,  B01J23/80 ,  B01J23/86 ,  B01J37/00 ,  B01J37/16 ,  B01J37/18 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125

CPC分类号： B01J37/18 ,  B01J23/60 ,  B01J23/72 ,  B01J23/80 ,  B01J23/868 ,  B01J37/16 ,  C07C29/149 ,  B01J23/745 ,  B01J37/0009

摘要： A method for preparing a copper-containing hydrogenation reaction catalyst includes the step of reducing a formed precursor of a copper-containing hydrogenation reaction catalyst with hydrogen gas or a mixture of hydrogen and inert gas by liquid phase reduction in a stream of a solvent. The reductive activation is carried out by the two steps of performing the first stage of liquid phase reduction by which the catalyst precursor is activated in the temperature range of from 20.degree. to 140.degree. C. so that at least 10% by weight of the copper oxide contained in the catalyst precursor can be reduced by the time when the temperature passes 140.degree. C., and then performing the second stage of liquid phase reduction by which the catalyst precursor is further activated in the temperature range of from 140.degree. to 250.degree. C. The catalyst thus obtained has markedly improved catalytic activity and selectivity. An alcohol of high quality can be obtained at a high productivity using the catalyst in a fixed bed continuous reaction system.

摘要翻译： PCT No.PCT / JP94 / 00077 Sec。 371日期：1995年6月6日 102（e）日期1995年6月6日PCT 1994年1月20日PCT PCT。 公开号WO95 / 19844 日期：1995年7月27日制备含铜氢化反应催化剂的方法包括以下步骤：用氢气或氢气和惰性气体的混合物在流中通过液相还原将还原形成的含铜氢化反应催化剂的前体 的溶剂。 还原活化通过进行第二阶段的液相还原的两个步骤进行，催化剂前体在20℃至140℃的温度范围内被活化，因此至少10重量％的铜 包含在催化剂前体中的氧化物可以在温度达到140℃时降低，然后进行第二阶段的液相还原，催化剂前体在140°至250°的温度范围内进一步活化 因此得到的催化剂显着地改善了催化活性和选择性。 使用固定床连续反应体系中的催化剂可以以高生产率获得高质量的醇。