Post ECP multi-step anneal/H2 treatment to reduce film impurity
    1.
    发明授权
    Post ECP multi-step anneal/H2 treatment to reduce film impurity 有权
    后期ECP多步退火/ H2处理以降低膜杂质

    公开(公告)号:US07432192B2

    公开(公告)日:2008-10-07

    申请号:US11347946

    申请日:2006-02-06

    IPC分类号: H01L21/4763

    CPC分类号: H01L21/76877 H01L21/2885

    摘要: A method of forming a copper interconnect in a dual damascene scheme is described. After a diffusion barrier layer and seed layer are sequentially formed on the sidewalls and bottoms of a trench and via in a dielectric layer, a first copper layer is deposited by a first ECP process at a 10 mA/cm2 current density to fill the via and part of the trench. A first anneal step is performed to remove carbon impurities and optionally includes a H2 plasma treatment. A second ECP process with a first deposition step at a 40 mA/cm2 current density and second deposition step at a 60 mA/cm2 current density is used to deposit a second copper layer that overfills the trench. After a second anneal step, a CMP process planarizes the copper layers. Fewer copper defects, reduced S, Cl, and C impurities, and improved Rc performance are achieved by this method.

    摘要翻译: 描述了在双镶嵌方案中形成铜互连的方法。 在扩散阻挡层和种子层依次形成在电介质层中的沟槽和通孔的侧壁和底部上之后,通过第一ECP工艺以10mA / cm 2 / >电流密度以填充通孔和部分沟槽。 进行第一退火步骤以除去碳杂质,并且任选地包括H 2 O 3等离子体处理。 使用在40mA / cm 2电流密度下的第一沉积步骤和以60mA / cm 2电流密度进行第二沉积步骤的第二个ECP工艺来沉积 第二铜层超过沟槽。 在第二退火步骤之后,CMP工艺使铜层平坦化。 通过该方法可以实现更少的铜缺陷,降低的S,Cl和C杂质,以及Rc性能的提高。

    Post ECP multi-step anneal/H2 treatment to reduce film impurity
    2.
    发明授权
    Post ECP multi-step anneal/H2 treatment to reduce film impurity 失效
    后期ECP多步退火/ H2处理以降低膜杂质

    公开(公告)号:US07030016B2

    公开(公告)日:2006-04-18

    申请号:US10812729

    申请日:2004-03-30

    IPC分类号: H01L21/44

    CPC分类号: H01L21/76877 H01L21/2885

    摘要: A method of forming a copper interconnect in a dual damascene scheme is described. After a diffusion barrier layer and seed layer are sequentially formed on the sidewalls and bottoms of a trench and via in a dielectric layer, a first copper layer is deposited by a first ECP process at a 10 mA/cm2 current density to fill the via and part of the trench. A first anneal step is performed to remove carbon impurities and optionally includes a H2 plasma treatment. A second ECP process with a first deposition step at a 40 mA/cm2 current density and second deposition step at a 60 mA/cm2 current density is used to deposit a second copper layer-that overfills the trench. After a second anneal step, a CMP process planarizes the copper layers. Fewer copper defects, reduced S, Cl, and C impurities, and improved Rc performance are achieved by this method.

    摘要翻译: 描述了在双镶嵌方案中形成铜互连的方法。 在扩散阻挡层和种子层依次形成在电介质层中的沟槽和通孔的侧壁和底部上之后,通过第一ECP工艺以10mA / cm 2 / >电流密度以填充通孔和部分沟槽。 进行第一退火步骤以除去碳杂质,并且任选地包括H 2 O 3等离子体处理。 使用在40mA / cm 2电流密度下的第一沉积步骤和以60mA / cm 2电流密度进行第二沉积步骤的第二个ECP工艺来沉积 第二铜层 - 过度填充沟槽。 在第二退火步骤之后,CMP工艺使铜层平坦化。 通过该方法可以实现更少的铜缺陷,降低的S,Cl和C杂质,以及Rc性能的提高。

    Post ECP multi-step anneal/H2 treatment to reduce film impurity
    3.
    发明申请
    Post ECP multi-step anneal/H2 treatment to reduce film impurity 失效
    后期ECP多步退火/ H2处理以降低膜杂质

    公开(公告)号:US20050227479A1

    公开(公告)日:2005-10-13

    申请号:US10812729

    申请日:2004-03-30

    IPC分类号: H01L21/311 H01L21/768

    CPC分类号: H01L21/76877 H01L21/2885

    摘要: A method of forming a copper interconnect in a dual damascene scheme is described. After a diffusion barrier layer and seed layer are sequentially formed on the sidewalls and bottoms of a trench and via in a dielectric layer, a first copper layer is deposited by a first ECP process at a 10 mA/cm2 current density to fill the via and part of the trench. A first anneal step is performed to remove carbon impurities and optionally includes a H2 plasma treatment. A second ECP process with a first deposition step at a 40 mA/cm2 current density and second deposition step at a 60 mA/cm2 current density is used to deposit a second copper layer-that overfills the trench. After a second anneal step, a CMP process planarizes the copper layers. Fewer copper defects, reduced S, Cl, and C impurities, and improved Rc performance are achieved by this method.

    摘要翻译: 描述了在双镶嵌方案中形成铜互连的方法。 在扩散阻挡层和种子层依次形成在电介质层中的沟槽和通孔的侧壁和底部上之后,通过第一ECP工艺以10mA / cm 2 / >电流密度以填充通孔和部分沟槽。 进行第一退火步骤以除去碳杂质,并且任选地包括H 2 O 3等离子体处理。 使用在40mA / cm 2电流密度下的第一沉积步骤和以60mA / cm 2电流密度进行第二沉积步骤的第二个ECP工艺来沉积 第二铜层 - 过度填充沟槽。 在第二退火步骤之后,CMP工艺使铜层平坦化。 通过该方法可以实现更少的铜缺陷,降低的S,Cl和C杂质,以及Rc性能的提高。

    Post ECP multi-step anneal/H2 treatment to reduce film impurity
    4.
    发明申请
    Post ECP multi-step anneal/H2 treatment to reduce film impurity 有权
    后期ECP多步退火/ H2处理以降低膜杂质

    公开(公告)号:US20060216930A1

    公开(公告)日:2006-09-28

    申请号:US11347946

    申请日:2006-02-06

    IPC分类号: H01L21/4763

    CPC分类号: H01L21/76877 H01L21/2885

    摘要: A method of forming a copper interconnect in a dual damascene scheme is described. After a diffusion barrier layer and seed layer are sequentially formed on the sidewalls and bottoms of a trench and via in a dielectric layer, a first copper layer is deposited by a first ECP process at a 10 mA/cm2 current density to fill the via and part of the trench. A first anneal step is performed to remove carbon impurities and optionally includes a H2 plasma treatment. A second ECP process with a first deposition step at a 40 mA/cm2 current density and second deposition step at a 60 mA/cm2 current density is used to deposit a second copper layer that overfills the trench. After a second anneal step, a CMP process planarizes the copper layers. Fewer copper defects, reduced S, Cl, and C impurities, and improved Rc performance are achieved by this method.

    摘要翻译: 描述了在双镶嵌方案中形成铜互连的方法。 在扩散阻挡层和种子层依次形成在电介质层中的沟槽和通孔的侧壁和底部上之后,通过第一ECP工艺以10mA / cm 2 / >电流密度以填充通孔和部分沟槽。 进行第一退火步骤以除去碳杂质,并且任选地包括H 2 O 3等离子体处理。 使用在40mA / cm 2电流密度下的第一沉积步骤和以60mA / cm 2电流密度进行第二沉积步骤的第二个ECP工艺来沉积 第二铜层超过沟槽。 在第二退火步骤之后,CMP工艺使铜层平坦化。 通过该方法可以实现更少的铜缺陷,降低的S,Cl和C杂质,以及Rc性能的提高。

    Method for preventing voids in metal interconnects
    8.
    发明授权
    Method for preventing voids in metal interconnects 有权
    防止金属互连中空隙的方法

    公开(公告)号:US07122471B2

    公开(公告)日:2006-10-17

    申请号:US10835315

    申请日:2004-04-28

    摘要: A novel method for preventing the formation of voids in metal interconnects fabricated on a wafer, particularly during a thermal anneal process, is disclosed. The method includes fabricating metal interconnects between metal lines on a wafer. During a thermal anneal process carried out to reduce electrical resistance of the interconnects, the wafer is positioned in spaced-apart relationship to a wafer heater. This spacing configuration facilitates enhanced stabilility and uniformity in heating of the wafer by reducing the presence of particles on and providing a uniform flow of heated air or gas against and the wafer backside. This eliminates or at least substantially reduces the formation of voids in the interconnects during the anneal process.

    摘要翻译: 公开了一种用于防止在晶片上制造的金属互连中空隙形成的新方法,特别是在热退火工艺期间。 该方法包括在晶片上的金属线之间制造金属互连。 在进行用于降低互连的电阻的热退火工艺期间,晶片以与晶片加热器隔开的关系定位。 这种间隔结构通过减少加热的空气或气体抵靠和晶片背面的颗粒的存在而提高晶片加热的稳定性和均匀性。 这在退火过程中消除或至少基本上减少了互连件中空隙的形成。

    Method and apparatus for stabilizing plating film impurities
    10.
    发明授权
    Method and apparatus for stabilizing plating film impurities 有权
    用于稳定镀膜杂质的方法和装置

    公开(公告)号:US07481910B2

    公开(公告)日:2009-01-27

    申请号:US10880675

    申请日:2004-06-30

    IPC分类号: C25D17/00 B01D29/56

    摘要: A method of stabilizing plating film impurities in an electrochemical plating bath solution is disclosed. The method includes providing an electrochemical plating machine in which an electrochemical plating process is carried out. A by-product bath solution is formed by continually removing a pre-filtered bath solution from the machine and removing an additive from the pre-filtered bath solution. A clean bath solution is formed by removing an additive by-product from the by-product bath solution. An additive bath solution is formed by adding a fresh additive to the clean bath solution. The additive bath solution is added to the electrochemical plating machine. An apparatus for stabilizing film impurities in an electrochemical plating bath solution is also disclosed.

    摘要翻译: 公开了一种在电化学镀浴溶液中稳定镀膜杂质的方法。 该方法包括提供其中进行电化学电镀处理的电化学电镀机。 通过从机器中连续除去预过滤的浴液并从预过滤的浴液中除去添加剂形成副产物浴溶液。 通过从副产物浴溶液中除去添加剂副产物形成清洁浴溶液。 通过向清洁浴溶液中加入新鲜添加剂形成添加浴溶液。 将添加浴溶液加入到电化学电镀机中。 还公开了一种用于稳定电化学镀浴溶液中的膜杂质的装置。