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    Fischer-tropsch process and reactor assembly
    5.
    发明授权
    Fischer-tropsch process and reactor assembly 有权
    费 - 托法和反应器组装

    公开(公告)号：US07855234B2

    公开(公告)日：2010-12-21

    申请号：US11988970

    申请日：2006-07-14

    申请人： Arend Hoek ,  Hans Michiel Huisman

    发明人： Arend Hoek ,  Hans Michiel Huisman

    IPC分类号： C07C27/00

    CPC分类号： C10G2/32 ,  B01J8/0278 ,  B01J8/065 ,  B01J8/067 ,  B01J8/22 ,  B01J2219/00038 ,  B01J2219/00202 ,  B01J2219/00211 ,  B01J2219/00231 ,  B01J2219/00238 ,  C10G2/34 ,  C10G2400/02 ,  C10G2400/06 ,  C10G2400/08 ,  C10G2400/10 ,  C10G2400/18

    摘要： A method of accommodating a reduction in production capacity of one or more reactors in a multi-reactor assembly adapted for the production of hydrocarbon products from syngas, the syngas being provided by a syngas manufacturing facility and provided to an entry stream system providing syngas to each of the reactors, and having an exit stream system taking at least hydrocarbon products from the reactors, wherein the method comprises the steps of: redistributing the syngas from the one or more said reactors to one or more other reactors, and increasing the temperature in the said one or more other reactors to at least partially take over the reduction in production capacity of the one or more reactors.

    摘要翻译： 一种在适合从合成气生产碳氢化合物产品的多反应器组合中容纳一个或多个反应器的生产能力降低的方法，合成气由合成气制造设施提供并提供给进入流系统，其将合成气提供给每个 的反应器，并且具有至少从反应器中取出烃产物的出口流系统，其中所述方法包括以下步骤：将来自所述一个或多个所述反应器的合成气重新分配到一个或多个其它反应器，并且增加所述反应器中的温度 所述一个或多个其它反应器至少部分地承担一个或多个反应器的生产能力的降低。

    Integrated process and reactor arrangement for hydrocarbon synthesis
    6.
    发明授权
    Integrated process and reactor arrangement for hydrocarbon synthesis 有权
    烃合成的综合工艺和反应堆装置

    公开(公告)号：US08497310B2

    公开(公告)日：2013-07-30

    申请号：US12643706

    申请日：2009-12-21

    申请人： Arend Hoek ,  Hans Michiel Huisman

    发明人： Arend Hoek ,  Hans Michiel Huisman

    IPC分类号： C07C27/00

    CPC分类号： B01J8/0278 ,  B01J8/065 ,  B01J8/22 ,  B01J23/75 ,  B01J23/8472 ,  B01J23/8892 ,  B01J2208/00548 ,  B01J2219/00038 ,  C10G2/332 ,  C10G2/341 ,  C10G2/342

    摘要： The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor. It further relates to a reactor arrangement suitable for operating the process according to the invention for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas comprising at least two parallel operating reactors, each containing a catalyst, wherein the reactors are connected to a common header for the distribution of synthesis gas to the reactors, and wherein the common header comprises a distribution means for selectively controlling the amount of synthesis gas fed to each reactor.

    摘要翻译： 本发明涉及在生产周期（即，在再生之间或在新鲜负载的催化剂的启动与第一次再生之间）中生产通常为气态的，通常为液体的和任选的常规固体烃的方法，其通过多次合成气的催化转化 反应器装置包括至少两个并联的操作反应器，其包含能够将合成气转化为烃的催化剂，每个反应器具有不同的相对反应速率，其中合成气以与该反应器中的相对反应速率成正比的进料速率分配给每个反应器 相应的反应器。 本发明还涉及一种适用于操作根据本发明的方法的反应器装置，用于在生产循环期间通过催化转化包含至少两个平行操作反应器的催化转化来生产通常为气态的，通常为固体的烃，每个反应器含有催化剂 ，其中所述反应器连接到用于将合成气分配到所述反应器的公共集管，并且其中所述公共集管包括用于选择性地控制供给到每个反应器的合成气量的分配装置。

    Shaped catalyst particles for hydrocarbon synthesis
    7.
    发明授权
    Shaped catalyst particles for hydrocarbon synthesis 失效
    用于烃合成的成型催化剂颗粒

    公开(公告)号：US07563745B2

    公开(公告)日：2009-07-21

    申请号：US10517098

    申请日：2003-06-06

    申请人： Arend Hoek ,  Hans Michiel Huisman ,  Carolus Matthias Anna Maria Mesters

    发明人： Arend Hoek ,  Hans Michiel Huisman ,  Carolus Matthias Anna Maria Mesters

    IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J29/00 ,  B01J37/00 ,  C01B3/38 ,  C07C1/02 ,  C01B3/26 ,  C10G47/00 ,  C10G47/02 ,  C10G47/04 ,  C10G11/00 ,  C10G35/06

    CPC分类号： C10G2/332 ,  B01J23/75 ,  B01J23/8892 ,  B01J35/026 ,  B01J37/0009 ,  C10G2/33 ,  C10G49/00

    摘要： The invention relates to a shaped catalyst or catalyst precursor containing a catalytically active component or a precursor therefore, the component selected from elements of Group VIII of the Periodic Table of the Elements, supported on a carrier, which catalyst or catalyst precursor is an elongated shaped particle having three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles while three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions.The invention further relates to a process to prepare the catalyst or catalyst precursor from a shapeable dough, to the die-plate used for the preparation of an extruded catalyst or catalyst precursor, to the use of the catalysts, as well as to hydrocarbons prepared by using the catalyst.The invention further relates to a process to obtain fuels and optionally base oils, by hydrogenation, hydroisomerisation and/or hydrocracking of the hydrocarbons prepared by using the catalyst.

    摘要翻译： 本发明涉及含有催化活性组分或前体的成型催化剂或催化剂前体，所述催化剂或催化剂前体包含负载在载体上的选自元素周期表第Ⅷ族元素的组分，该催化剂或催化剂前体是细长形状 具有从中心位置延伸并连接到中心位置的三个突起的颗粒，其中中心位置沿着颗粒的纵向轴线对准，颗粒的横截面占据由围绕中心圆的六个圆的外边缘包围的空间 ，六个圆中的每一个接触两个相邻的圆，而三个交替的圆与中心圆相等，并且可以附接到中心圆，减去三个剩余外圆所占据的空间并且包括六个间隙区。 本发明还涉及一种从可成型面团制备催化剂或催化剂前体的方法，用于制备挤出的催化剂或催化剂前体的模板，使用催化剂以及由 使用催化剂。 本发明还涉及通过使用催化剂制备的烃的氢化，加氢异构化和/或加氢裂化来获得燃料和任选的基础油的方法。

    Fischer-tropsch process and reactor assembly
    8.
    发明申请
    Fischer-tropsch process and reactor assembly 有权
    费 - 托法和反应器组装

    公开(公告)号：US20090124711A1

    公开(公告)日：2009-05-14

    申请号：US11988970

    申请日：2006-07-14

    申请人： Arend Hoek ,  Hans Michiel Huisman

    发明人： Arend Hoek ,  Hans Michiel Huisman

    IPC分类号： C10G2/00 ,  B01J19/00

    CPC分类号： C10G2/32 ,  B01J8/0278 ,  B01J8/065 ,  B01J8/067 ,  B01J8/22 ,  B01J2219/00038 ,  B01J2219/00202 ,  B01J2219/00211 ,  B01J2219/00231 ,  B01J2219/00238 ,  C10G2/34 ,  C10G2400/02 ,  C10G2400/06 ,  C10G2400/08 ,  C10G2400/10 ,  C10G2400/18

    摘要： A method of accommodating a reduction in production capacity of one or more reactors in a multi-reactor assembly adapted for the production of hydrocarbon products from syngas, the syngas being provided by a syngas manufacturing facility and provided to an entry stream system providing syngas to each of the reactors, and having an exit stream system taking at least hydrocarbon products from the reactors, wherein the method comprises the steps of: redistributing the syngas from the one or more said reactors to one or more other reactors, and increasing the temperature in the said one or more other reactors to at least partially take over the reduction in production capacity of the one or more reactors.

    摘要翻译： 一种在适合从合成气生产碳氢化合物产品的多反应器组合中容纳一个或多个反应器的生产能力降低的方法，合成气由合成气制造设施提供并提供给进入流系统，其将合成气提供给每个 的反应器，并且具有至少从反应器中取出烃产物的出口流系统，其中所述方法包括以下步骤：将来自所述一个或多个所述反应器的合成气重新分配到一个或多个其它反应器，并且增加所述反应器中的温度 所述一个或多个其它反应器至少部分地承担一个或多个反应器的生产能力的降低。

    INTEGRATED PROCESS AND REACTOR ARRANGEMENT FOR HYDROCARBON SYNTHESIS
    9.
    发明申请
    INTEGRATED PROCESS AND REACTOR ARRANGEMENT FOR HYDROCARBON SYNTHESIS 有权
    油气合成的综合工艺和反应器装置

    公开(公告)号：US20100160461A1

    公开(公告)日：2010-06-24

    申请号：US12643706

    申请日：2009-12-21

    申请人： Arend HOEK ,  Hans Michiel Huisman

    发明人： Arend HOEK ,  Hans Michiel Huisman

    IPC分类号： C07C27/06 ,  B01J19/00

    CPC分类号： B01J8/0278 ,  B01J8/065 ,  B01J8/22 ,  B01J23/75 ,  B01J23/8472 ,  B01J23/8892 ,  B01J2208/00548 ,  B01J2219/00038 ,  C10G2/332 ,  C10G2/341 ,  C10G2/342

    摘要： The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor. It further relates to a reactor arrangement suitable for operating the process according to the invention for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas comprising at least two parallel operating reactors, each containing a catalyst, wherein the reactors are connected to a common header for the distribution of synthesis gas to the reactors, and wherein the common header comprises a distribution means for selectively controlling the amount of synthesis gas fed to each reactor.

    摘要翻译： 本发明涉及在生产周期（即，在再生之间或在新鲜负载的催化剂的启动与第一次再生之间）中生产通常为气态的，通常为液体的和任选的常规固体烃的方法，其通过多次合成气的催化转化 反应器装置包括至少两个并联的操作反应器，其包含能够将合成气转化为烃的催化剂，每个反应器具有不同的相对反应速率，其中合成气以与该反应器中的相对反应速率成正比的进料速率分配给每个反应器 相应的反应器。 本发明还涉及一种适用于操作根据本发明的方法的反应器装置，用于在生产循环期间通过催化转化包含至少两个平行操作反应器的催化转化来生产通常为气态的，通常为固体的烃，每个反应器含有催化剂 ，其中所述反应器连接到用于将合成气分配到所述反应器的公共集管，并且其中所述公共集管包括用于选择性地控制供给到每个反应器的合成气量的分配装置。

    Process for the production of liquid hydrocarbons
    10.
    发明授权
    Process for the production of liquid hydrocarbons 失效
    液体烃的生产工艺

    公开(公告)号：US06942839B2

    公开(公告)日：2005-09-13

    申请号：US10931490

    申请日：2004-09-01

    申请人： Hans Michiel Huisman ,  Koen Willem De Leeuw

    发明人： Hans Michiel Huisman ,  Koen Willem De Leeuw

    IPC分类号： C01B3/38 ,  C07C1/04 ,  C10G2/00 ,  B01J10/00 ,  B01J8/04

    CPC分类号： C10G2/30 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/045 ,  C01B2203/0485 ,  C01B2203/062 ,  C01B2203/065 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1023 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/127 ,  C07C1/0485 ,  C07C2521/06 ,  C07C2523/75

    摘要： A process for producing normally liquid hydrocarbon products from a hydrocarbonaceous feedstock, especially from normally gaseous hydrocarbon feed, having the following steps: (a) partial oxidation of the normally gaseous hydrocarbon feed at elevated pressure using air or oxygen enriched air as oxidant, to obtain a syngas mixture having hydrogen, carbon monoxide and nitrogen; (b) converting hydrogen and carbon monoxide obtained in step (a) into a normally liquid hydrocarbon product and a normally gaseous hydrocarbon product; (c) separating from the reaction mixture obtained in step (b) an off-gas mixture having nitrogen, normally gaseous hydrocarbon product, and unconverted hydrogen, carbon monoxide and normally gaseous hydrocarbon feed, insofar as such unconverted components are present; (d) combusting at least a part of the off-gas mixture in a steam raising apparatus, producing steam of an elevated pressure; and (e) expanding the steam produced in step (d) for compressing the air or oxygen enriched air and/or the normally gaseous hydrocarbon feed used in step (a); and a plant having equipment in a line-up suitable for carrying out the process.

    摘要翻译： 一种从含烃原料，特别是通常气态烃进料生产常规烃类产物的方法，具有以下步骤：（a）使用空气或富氧空气作为氧化剂，在升高的压力下将常规气态烃进料部分氧化，以获得 具有氢气，一氧化碳和氮气的合成气混合物; （b）将步骤（a）中获得的氢气和一氧化碳转化为通常为液体的烃产物和通常为气态烃产物; （c）与步骤（b）中获得的反应混合物分离出具有氮气，通常为气态烃产物和未转化氢气，一氧化碳和通常为气态烃进料的废气混合物，只要存在这种未转化的组分; （d）在蒸汽提升装置中燃烧至少一部分废气混合物，产生高压蒸汽; 和（e）扩大在步骤（d）中产生的用于压缩步骤（a）中使用的空气或富氧空气和/或常规气态烃进料的蒸汽; 以及具有适合于执行该过程的阵列中的设备的设备。