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1.
公开(公告)号:US08344197B2
公开(公告)日:2013-01-01
申请号:US12894778
申请日:2010-09-30
申请人: James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
发明人: James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
IPC分类号: C07C2/66
CPC分类号: C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要: In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译: 在制备对二甲苯的方法中,将甲醇预热至第一温度,将包含甲苯和/或苯的芳族原料预热至第二温度,并将预热的甲醇和芳族原料以第一个甲醇 与芳烃原料摩尔比。 预热的芳族原料在催化剂存在下在反应器中在烷基化条件下与预热的甲醇接触,使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。 在反应期间,在反应器内测量温度并与预定的最佳温度进行比较。 然后以降低反应器中测量的和预定的最佳温度之间的任何差异的方式调节甲醇与芳族原料的摩尔比。
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2.
公开(公告)号:US20110092755A1
公开(公告)日:2011-04-21
申请号:US12894778
申请日:2010-09-30
申请人: James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
发明人: James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
IPC分类号: C07C15/08
CPC分类号: C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要: In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译: 在制备对二甲苯的方法中,将甲醇预热至第一温度,将包含甲苯和/或苯的芳族原料预热至第二温度,并将预热的甲醇和芳族原料以第一个甲醇 与芳烃原料摩尔比。 预热的芳族原料在催化剂存在下在反应器中在烷基化条件下与预热的甲醇接触,使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。 在反应期间,在反应器内测量温度并与预定的最佳温度进行比较。 然后以降低反应器中测量的和预定的最佳温度之间的任何差异的方式调节甲醇与芳族原料的摩尔比。
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公开(公告)号:US20130253245A1
公开(公告)日:2013-09-26
申请号:US13618211
申请日:2012-09-14
IPC分类号: C07C2/86
CPC分类号: C07C2/865 , C07C2/864 , Y02P20/582 , C07C15/08
摘要: The invention relates to the production of paraxylene by an alkylation process that also produces oxygenates. The process is controlled to utilize recycle to minimize said oxygenates.
摘要翻译: 本发明涉及通过也产生含氧化合物的烷基化方法生产对二甲苯。 控制该过程以利用再循环以使所述含氧化合物最小化。
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公开(公告)号:US09006506B2
公开(公告)日:2015-04-14
申请号:US13618211
申请日:2012-09-14
IPC分类号: C07C2/86
CPC分类号: C07C2/865 , C07C2/864 , Y02P20/582 , C07C15/08
摘要: The invention relates to the production of paraxylene by an alkylation process that also produces oxygenates. The process is controlled to utilize recycle to minimize said oxygenates.
摘要翻译: 本发明涉及通过也产生含氧化合物的烷基化方法生产对二甲苯。 控制该过程以利用再循环以使所述含氧化合物最小化。
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公开(公告)号:US20130217940A1
公开(公告)日:2013-08-22
申请号:US13483836
申请日:2012-05-30
申请人: Xiaobo Zheng , John Di-Yi Ou , Mark P. Hagemeister
发明人: Xiaobo Zheng , John Di-Yi Ou , Mark P. Hagemeister
IPC分类号: C07C2/86
CPC分类号: C07C2/864 , B01J29/40 , B01J29/65 , B01J29/70 , B01J29/703 , B01J29/7034 , B01J29/7042 , B01J29/7046 , B01J29/90 , B01J38/30 , B01J2229/123 , B01J2229/20 , B01J2229/36 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2521/16 , C07C2523/02 , C07C2523/10 , C07C2527/16 , C07C2529/40 , C07C2529/65 , C07C2529/83 , C07C2529/85 , Y02P20/52 , Y02P20/584 , C07C15/08
摘要: The present inventors have surprisingly discovered that paraxylene selectivity is found to increase as the amount of coke on catalyst increases. In embodiments the paraxylene selectivity and productivity is maximized by controlling the amount of coke on the catalyst while maintaining xylene yield at an acceptable value. The control of coke may be achieved by one or a combination of the following techniques: increasing catalyst on-oil time, decreasing catalyst residence time in the regenerator, reducing the air or oxygen supply to the regenerator, and decreasing catalyst circulation rate, or a combination thereof.
摘要翻译: 本发明人惊奇地发现,当催化剂上的焦炭量增加时,发现对二甲苯选择性增加。 在实施方案中,通过控制催化剂上的焦炭的量,同时将二甲苯收率保持在可接受的值来最大化对二甲苯选择性和生产率。 焦炭的控制可以通过以下技术的一种或组合来实现:增加催化剂油中时间,减少再生器中的催化剂停留时间,减少再生器中的空气或氧气供应,以及降低催化剂循环速率,或 的组合。
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公开(公告)号:US09295962B2
公开(公告)日:2016-03-29
申请号:US13487651
申请日:2012-06-04
CPC分类号: B01J8/18 , B01J8/1827 , B01J2219/00006 , C07C2/864 , C07C5/2729 , C07C7/12 , C07C7/14 , C07C7/1485 , C07C2523/04 , C07C2529/40 , C07C2529/65 , C07C15/08
摘要: The invention is a process for producing paraxylene, benzene and/or toluene is alkylated with methanol in the presence of a catalyst under conditions effective to convert said benzene and/or toluene to xylene and produce a product stream containing water, xylene and one or more phenolic impurities. The said product stream is separated into a water-rich stream and a xylene-rich stream containing one or more phenolic impurities and at least a portion of the xylene-rich stream is contacted with an aqueous solution of a base under conditions to remove at least some of the phenolic impurities from the xylene-rich stream portion.
摘要翻译: 本发明是在有效将所述苯和/或甲苯转化为二甲苯的条件下,在催化剂存在下用甲醇烷基化的对二甲苯,苯和/或甲苯的方法,并产生含有水,二甲苯和一种或多种 酚类杂质。 将所述产物流分离成富含水的物流和含有一种或多种酚类杂质的富含二甲苯的物流,并且至少部分富含二甲苯的物流与碱的水溶液接触,至少除去 一些来自富含二甲苯的料流部分的酚类杂质。
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公开(公告)号:US20120316375A1
公开(公告)日:2012-12-13
申请号:US13487651
申请日:2012-06-04
CPC分类号: B01J8/18 , B01J8/1827 , B01J2219/00006 , C07C2/864 , C07C5/2729 , C07C7/12 , C07C7/14 , C07C7/1485 , C07C2523/04 , C07C2529/40 , C07C2529/65 , C07C15/08
摘要: The invention is a process for producing paraxylene, benzene and/or toluene is alkylated with methanol in the presence of a catalyst under conditions effective to convert said benzene and/or toluene to xylene and produce a product stream containing water, xylene and one or more phenolic impurities. The said product stream is separated into a water-rich stream and a xylene-rich stream containing one or more phenolic impurities and at least a portion of the xylene-rich stream is contacted with an aqueous solution of a base under conditions to remove at least some of the phenolic impurities from the xylene-rich stream portion.
摘要翻译: 本发明是在有效将所述苯和/或甲苯转化为二甲苯的条件下,在催化剂存在下用甲醇烷基化的对二甲苯,苯和/或甲苯的方法,并产生含有水,二甲苯和一种或多种 酚类杂质。 将所述产物流分离成富含水的物流和含有一种或多种酚类杂质的富含二甲苯的物流,并且至少部分富含二甲苯的物流与碱的水溶液接触,以至少除去 一些来自富含二甲苯的料流部分的酚类杂质。
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公开(公告)号:US08859835B2
公开(公告)日:2014-10-14
申请号:US13218520
申请日:2011-08-26
申请人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
发明人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
IPC分类号: C07C15/00
CPC分类号: C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要: In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400° C.
摘要翻译: 在含焦炭金属催化剂的再生方法中,焦化催化剂在再生区与含有二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。
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公开(公告)号:US20120083637A1
公开(公告)日:2012-04-05
申请号:US13218520
申请日:2011-08-26
申请人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
发明人: Kenneth R. Clem , Larry L. Iaccino , Mobae Afeworki , Juan D. Henao , Neeraj Sangar , Xiaobo Zheng , Lorenzo C. DeCaul
CPC分类号: C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要: In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400° C.
摘要翻译: 在含焦炭金属催化剂的再生方法中,焦化催化剂在再生区与含有二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。
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公开(公告)号:US09181147B2
公开(公告)日:2015-11-10
申请号:US13465733
申请日:2012-05-07
申请人: Larry L. Iaccino , S. Mark Davis , John D. Y. Ou , Xiaobo Zheng
发明人: Larry L. Iaccino , S. Mark Davis , John D. Y. Ou , Xiaobo Zheng
CPC分类号: C07C2/864 , C10G9/005 , C10G9/36 , C10G11/00 , C10G29/205 , C10G35/00 , C10G57/005 , C10G2300/1092 , C10G2300/1096 , C10G2400/30 , C07C15/08
摘要: In a hydrocarbon upgrading process, a hydrocarbon feed is treated in at least one of a steam cracker, catalytic cracker, coker, hydrocracker, and reformer under suitable conditions to produce a first stream comprising olefinic and aromatic hydrocarbons. A second stream composed mainly of C4+ olefinic and aromatic hydrocarbons is recovered from the first stream and is fed together with a methylating agent to a reaction zone containing a catalyst under reaction conditions including a temperature of about 450° C. to about 700° C., such that aromatics components in the second stream undergo dealkylation, transalkylation and/or methylation and aliphatic components undergo cracking and aromatization to produce a third stream having an increased xylene content compared with said second stream and a C3− olefin by-product. The C3− olefin by-product is recovered and para-xylene is removed from at least part of said third stream.
摘要翻译: 在烃改质方法中,在合适条件下,在蒸汽裂化器,催化裂化器,焦化器,加氢裂化器和重整器中的至少一种中处理烃进料以产生包含烯烃和芳族烃的第一流。 从第一流回收主要由C4 +烯烃和芳烃组成的第二料流,并在包括约450℃至约700℃的温度的反应条件下与甲基化剂一起加入含有催化剂的反应区。 使得第二流中的芳烃组分经历脱烷基化,烷基转移和/或甲基化,并且脂族组分经历裂化和芳构化以产生与所述第二料流和C3-烯烃副产物相比具有增加的二甲苯含量的第三料流。 回收C3-烯烃副产物,并从至少部分所述第三料流中除去对二甲苯。
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