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公开(公告)号:US07838708B2
公开(公告)日:2010-11-23
申请号:US12692831
申请日:2010-01-25
申请人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
发明人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
CPC分类号: C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要: Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译: 将烷烃,烯烃和芳族化合物转化为烯烃,醇,醚和醛的先前公开的方法和装置的改进包括:安全性改进,替代原料的使用,工艺简化,改进卤化步骤,改性步骤, 固体氧化物反应的改进,固体氧化物再生的改进,分离改进,维护,启动,停机和施工材料。
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公开(公告)号:US20100121119A1
公开(公告)日:2010-05-13
申请号:US12692831
申请日:2010-01-25
申请人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
发明人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
IPC分类号: C07C17/013
CPC分类号: C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要: Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译: 将烷烃,烯烃和芳族化合物转化为烯烃,醇,醚和醛的先前公开的方法和装置的改进包括:安全性改进,替代原料的使用,工艺简化,改进卤化步骤,改性步骤, 固体氧化物反应的改进,固体氧化物再生的改进,分离改进,维护,启动,停机和施工材料。
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公开(公告)号:US20110034741A1
公开(公告)日:2011-02-10
申请号:US12904030
申请日:2010-10-13
申请人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Rreed , Michael F. Doherty
发明人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Rreed , Michael F. Doherty
IPC分类号: C07C17/013
CPC分类号: C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要: Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译: 将烷烃,烯烃和芳族化合物转化为烯烃,醇,醚和醛的先前公开的方法和装置的改进包括:安全性改进,替代原料的使用,工艺简化,改进卤化步骤,改性步骤, 固体氧化物反应的改进,固体氧化物再生的改进,分离改进,维护,启动,停机和施工材料。
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公开(公告)号:US08415512B2
公开(公告)日:2013-04-09
申请号:US12904030
申请日:2010-10-13
申请人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Rreed , Michael F. Doherty
发明人: Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Rreed , Michael F. Doherty
CPC分类号: C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要: Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译: 将烷烃,烯烃和芳族化合物转化为烯烃,醇,醚和醛的先前公开的方法和装置的改进包括:安全性改进,替代原料的使用,工艺简化,改进卤化步骤,改善重复步骤, 固体氧化物反应的改进,固体氧化物再生的改进,分离改进,维护,启动,停机和施工材料。
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公开(公告)号:US06472572B1
公开(公告)日:2002-10-29
申请号:US09886078
申请日:2001-06-20
申请人: Xiao Ping Zhou , Ivan Marc Lorkovic , Galen D. Stucky , Peter C. Ford , Jeffrey H. Sherman , Philip Grosso
发明人: Xiao Ping Zhou , Ivan Marc Lorkovic , Galen D. Stucky , Peter C. Ford , Jeffrey H. Sherman , Philip Grosso
IPC分类号: C07C2700
CPC分类号: C07C29/124 , C07C17/10 , C07C41/01 , C07D301/26 , Y02P20/125 , C07C19/075 , C07C31/04 , C07C43/043
摘要: Methanol and/or dimethyl ether are manufactured from methane by mixing methane and bromine in a reactor to form methyl bromide and hydrogen bromide. The methyl bromide only or the methyl bromide and the hydrogen bromide are directed into contact with metal oxide to form methanol and/or dimethyl ether and a metal bromide. The metal bromide is oxidized to form original metal oxide catalyst and bromine, both of which are recycled.
摘要翻译: 甲烷和/或二甲醚由甲烷通过在反应器中混合甲烷和溴来形成甲基溴和溴化氢。 仅甲基溴或甲基溴和溴化氢与金属氧化物接触以形成甲醇和/或二甲醚和金属溴化物。 金属溴化物被氧化形成原始的金属氧化物催化剂和溴,这两种催化剂都被再循环。
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公开(公告)号:US06462243B1
公开(公告)日:2002-10-08
申请号:US09951570
申请日:2001-09-11
申请人: Xiao Ping Zhou , Ivan Marc Lorkovic , Galen D. Stucky , Peter C. Ford , Jeffrey H. Sherman , Philip Grosso
发明人: Xiao Ping Zhou , Ivan Marc Lorkovic , Galen D. Stucky , Peter C. Ford , Jeffrey H. Sherman , Philip Grosso
IPC分类号: C07C2700
CPC分类号: C07C29/124 , C07C17/10 , C07C41/01 , C07D301/26 , Y02P20/125 , C07C19/075 , C07C31/04 , C07C43/043
摘要: Alcohols and/or ethers are synthesized from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide is directed into contact with metal oxide to form alcohol and/or ether and a metal bromide. The metal bromide is oxidized to metal oxide and bromine, both of which are recycled.
摘要翻译: 通过在反应器中混合烷烃和溴以形成烷基溴和溴化氢从烷烃合成醇和/或醚。 使烷基溴与金属氧化物接触以形成醇和/或醚和金属溴化物。 金属溴化物被氧化成金属氧化物和溴,两者都被再循环。
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公开(公告)号:US06214176B1
公开(公告)日:2001-04-10
申请号:US09479114
申请日:2000-01-07
IPC分类号: C07C2900
CPC分类号: C07C29/48 , B01F2003/04858 , B01F2215/0431 , B01J8/009 , B01J10/007 , B01J12/007 , B01J19/123 , B01J19/127 , B01J19/2415 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J2219/00081 , B01J2219/00139 , B01J2219/00162 , B01J2219/00189 , B01J2219/0869 , B01J2219/0877 , B01J2219/0884 , B01J2219/0892 , C01B3/38 , C01B2203/0233 , C01B2203/1035 , C01B2203/1041 , C01B2203/1241 , C07C29/00 , C12C11/02 , Y02P20/52 , C07C31/04 , C07C31/08 , C07C31/10
摘要: In a method of and apparatus for manufacturing methanol and higher alcohols from natural gas a catalytic area is formed on the exterior of a gas permeable partition. Natural gas is maintained on the interior of the gas permeable partition at predetermined pressure. Relative movement between the gas permeable partition and the water forms sub-micron sized bubbles of natural gas. Electromagnetic radiation is directed onto the catalytic surface to form hydroxyl radicals from the water. Methyl, ethyl, and propyl ions from the natural gas combine with the hydroxyl ions to form methanol, ethanol, and propanol.
摘要翻译: 在从天然气制造甲醇和高级醇的方法和装置中,在透气性隔板的外部形成催化区域。 天然气以预定压力保持在透气隔板的内部。 透气隔板与水之间的相对运动形成亚微米级的天然气气泡。 电磁辐射被引导到催化表面上以从水中形成羟基自由基。 来自天然气的甲基,乙基和丙基离子与羟基离子结合形成甲醇,乙醇和丙醇。
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公开(公告)号:US07883568B2
公开(公告)日:2011-02-08
申请号:US11703277
申请日:2007-02-05
申请人: Sagar B. Gadewar , Peter K. Stoimenov , Philip Grosso , Eric W. McFarland , Ashley W. Breed , Michael J. Weiss , Michael D. Wyrsta
发明人: Sagar B. Gadewar , Peter K. Stoimenov , Philip Grosso , Eric W. McFarland , Ashley W. Breed , Michael J. Weiss , Michael D. Wyrsta
IPC分类号: B01D53/02
CPC分类号: B01D3/10 , B01D1/16 , B01D53/685 , B01D53/75 , B01D2251/60 , B01D2257/2022 , B01D2257/2025 , C01B7/0743 , C01B7/096 , C01B21/0433 , C01B21/045 , C01B2210/0009 , C01B2210/0015
摘要: A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.
摘要翻译: 提供了一种使用一种或多种物理分离从溴或氯中分离一种或多种轻质气体的方法,并与化学洗涤器接触以回收额外的卤素。 一方面,该方法包括(a)向蒸馏塔或闪蒸器提供含有一种或多种轻质气体的卤素进料; (b)操作蒸馏塔或闪蒸器以将进料分离成(i)含有主要量的卤素和不多于少量轻质气体的第一液体,和(ii)含有 主要量的轻质气体,不超过少量的卤素; 和(c)将蒸汽提供给化学洗涤器以从蒸气中回收卤素。
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公开(公告)号:US08415517B2
公开(公告)日:2013-04-09
申请号:US12504865
申请日:2009-07-17
申请人: Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman , Peter Stoimenov , Hongfei Lin , Shawn Huff , Shouli Sun
发明人: Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J. A. Komon , Jeffrey H. Sherman , Peter Stoimenov , Hongfei Lin , Shawn Huff , Shouli Sun
IPC分类号: C07C1/00
CPC分类号: B01J8/00 , B01J8/18 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C17/06 , C07C17/10 , C07C17/23 , C07C17/26 , Y02C20/30 , C07C19/075 , C07C25/02
摘要: A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
摘要翻译: 一种方法,包括:提供第一卤素流; 提供第一烷烃流; 使第一卤素流的至少一部分与至少一部分第一烷烃流在第一反应容器中反应以形成第一卤化流; 提供包含C2和高级烃的第二烷烃流; 提供第二卤素流; 以及使第二卤素流的至少一部分与第二烷烃物流的至少一部分在第二反应容器中反应以形成第二卤化物流。
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10.
公开(公告)号:US20100099929A1
公开(公告)日:2010-04-22
申请号:US12504865
申请日:2009-07-17
申请人: Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J.A. Komon , Jeffrey H. Sherman , Peter Stoimenov , Hongfei Lin , Shawn Huff , Shouli Sun
发明人: Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric W. McFarland , Zachary J.A. Komon , Jeffrey H. Sherman , Peter Stoimenov , Hongfei Lin , Shawn Huff , Shouli Sun
IPC分类号: C07C17/013 , C07C1/00
CPC分类号: B01J8/00 , B01J8/18 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C17/06 , C07C17/10 , C07C17/23 , C07C17/26 , Y02C20/30 , C07C19/075 , C07C25/02
摘要: A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
摘要翻译: 一种方法,包括:提供第一卤素流; 提供第一烷烃流; 使第一卤素流的至少一部分与至少一部分第一烷烃流在第一反应容器中反应以形成第一卤化流; 提供包含C2和高级烃的第二烷烃流; 提供第二卤素流; 以及使第二卤素流的至少一部分与第二烷烃物流的至少一部分在第二反应容器中反应以形成第二卤化物流。
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