摘要:
Block copolymers having a polyisobutylene segment and a polycycloaliphatic diene polymer segment are presented. Star block copolymers with 2 to 16 block copolymer arms, wherein each of the arms has a polyisobutylene segment and a polycycloaliphatic diene polymer segment, are presented. The star block copolymers are synthesized via the “core first” method.
摘要:
Block copolymers and star polymers having copolymer arms of PIB-PAN have been synthesized via living carbocationic polymerization and atom transfer radical polymerization in a methylene chloride/cyclohexanone solvent system.
摘要:
A composition of matter including a polyisobutylene segment and a polycycloolefin segment. The polyisobutylene segment and the polycycloolefin segment form a repeating unit multiblock copolymer. A method of forming a composition of matter that includes a polyisobutylene segment and a polycycloolefin segment.
摘要:
A multiply-crosslinked polyisobutylene-based polyurethane includes a plurality of multi-telechelic polyisobutylene-based segments and a plurality of urethane segments having a plurality of chain extender-based segments therein. Each end of one of the plurality of urethane segments is linked either to an end of one of the plurality of multi-telechelic polyisobutylene-based segments, or to an end of one of the plurality of chain extender-based segments. Also, one or more of the plurality of urethane segments are physically crosslinked to one or more other of the plurality of urethane segments. Notably, the plurality of multi-telechelic polyisobutylene-based segments constitute at least 70 weight percent of the polyisobutylene-based polyurethane and the plurality of urethane segments, including the plurality of chain extender-based segments therein, constitute up to 30 weight percent of the polyisobutylene-based polyurethane.
摘要:
In one or more embodiments, the present invention provides a method for forming allyl telechelic polyisobutylene polymers having well defined molecular weights and molecular weight distributions using living cationic polymerization under ideal temperature control using a mixture of polar and nonpolar refluxing solvents. The methods according to various embodiments of the present invention provide temperature control that approaches the ideal, i.e., the heat of polymerization is instantaneously absorbed by the medium and the temperature of the system remains unchanged. The heat generated during the exothermic polymerization of isobutylene is released as an increase in the rate of reflux, rather than the temperature, since the temperature is set by the boiling point of the system and does not change.
摘要:
A system and method to opportunistically capture and use measurements on a priori unknown radio signals, not intended for radio navigation or geolocation, to improve navigation/geolocation position estimation yield and accuracy.
摘要:
A system and method for determining a position of a wireless mobile device. The method comprising the steps of providing one base station in communication with the mobile device, providing a sensor spaced apart a known distance from the base station, and determining the range between the mobile device and the base station. The time of arrival of a signal transmitted from the mobile device is measured at the sensor and a set of coordinates is calculated for the mobile device relative to the sensor as a function of the known distance from the sensor to the base station, the range between the mobile device and the base station, an estimate of base station transmission timing relative to a time source, and the time of arrival. One of the set of coordinates may then be chosen to thereby determine a position of the mobile device relative to the sensor.
摘要:
The present invention generally relates to implantable devices for producing insulin in diabetic animals. Some embodiments include amphiphilic biomembranes for use in biological applications (e.g., as an alternative and/or supplemental insulin source). Some embodiments also include live insulin-producing cells contained within one or more amphiphilic membranes so as to prevent or diminish an immuno-response and/or rejection by the host.
摘要:
The present invention relates to the production of amphiphilic copolymer networks, or co-networks, and to methods for preparing amphiphilic co-networks. Furthermore, the present invention relates to products and/or films made from the amphiphilic co-networks produced in accordance with the synthesis methods of the present invention. In one embodiment, the present invention is related to crosslinkable and/or polymerizable compositions that can be utilized to form amphiphilic co-networks, where such compositions are block copolymer compositions that are formed from the combination of at least one hydrophilic segment, at least one hydrophobic segment, and at least one crosslinkable and/or polymerizable segment. In yet another embodiment, the present invention relates to amphiphilic co-networks that are optically clear and highly oxyphilic.