公开(公告)号：US20140080697A1

公开(公告)日：2014-03-20

申请号：US13929078

申请日：2013-06-27

申请人： Jun Long ,  Yuxia Zhu ,  Yibin Luo ,  Jinghui Deng ,  Jinyu Zheng ,  Fei Ren ,  Xue Yang ,  Ying Ouyang

发明人： Jun Long ,  Yuxia Zhu ,  Yibin Luo ,  Jinghui Deng ,  Jinyu Zheng ,  Fei Ren ,  Xue Yang ,  Ying Ouyang

IPC分类号： B01J29/80

CPC分类号： B01J29/80 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0045 ,  B01J37/10 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18

摘要： The present invention relates to a catalytic cracking catalyst and a preparation process thereof, the catalytic cracking catalyst has a cracking active component, an optional mesoporous aluminosilicate material, a clay and a binder, wherein said cracking active component comprises, substantially consists of or consists of: a rare earth-containing Y zeolite, an optional other Y zeolite, and an optional MFI-structured zeolite, said rare earth-containing Y zeolite has a rare earth content as rare earth oxide of 10-25 wt %, e.g. 11-23 wt %; a unit cell size of 2.440-2.472 nm, e.g. 2.450-2.470 nm; a crystallinity of 35-65%, e.g. 40-60%; a Si/Al atom ratio in the skeleton of 2.5-5.0; and a product of the ratio of the strength I1 of the peak at 2θ=11.8±0.1° to the strength I2 of the peak at 2θ=12.3±0.1° in the X-ray diffraction spectrogram of the zeolite and the weight percent of rare earth as rare earth oxide in the zeolite of higher than 48, e.g. higher than 55.

摘要翻译： 催化裂化催化剂及其制备方法本发明涉及催化裂化催化剂及其制备方法，催化裂化催化剂具有裂化活性组分，任选介孔硅铝酸盐材料，粘土和粘合剂，其中所述裂化活性组分基本上由 ：含稀土Y沸石，任选的其他Y沸石和任选的MFI结构沸石，所述稀土Y沸石具有稀土含量为10-25重量％的稀土氧化物，例如 11-23重量％ 单元电池尺寸为2.440-2.472nm，例如。 2.450-2.470nm; 结晶度为35-65％，例如。 40-60％; 骨架中Si / Al原子比为2.5-5.0; 和沸石的X射线衍射光谱图中峰的强度I1与峰的强度I1的比值= 11.8±0.1°与峰的强度I2的比值= 12.3±0.1°，重量百分比 的稀土作为稀土氧化物在沸石中高于48，例如 高于55。

公开(公告)号：US09630171B2

公开(公告)日：2017-04-25

申请号：US13929044

申请日：2013-06-27

申请人： Jun Long ,  Fei Ren ,  Yuxia Zhu ,  Yibin Luo ,  Jiasong Yan ,  Xue Yang ,  Huiping Tian ,  Li Zhuang ,  Beiyan Chen ,  Minggang Li ,  Ying Ouyang ,  Xiangtian Shu

发明人： Jun Long ,  Fei Ren ,  Yuxia Zhu ,  Yibin Luo ,  Jiasong Yan ,  Xue Yang ,  Huiping Tian ,  Li Zhuang ,  Beiyan Chen ,  Minggang Li ,  Ying Ouyang ,  Xiangtian Shu

IPC分类号： B01J29/06 ,  B01J29/80 ,  B01J29/08 ,  C01B39/02 ,  B01J37/30 ,  B01J37/28

CPC分类号： B01J29/80 ,  B01J29/088 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C01B39/026

摘要： The present invention discloses a catalytic cracking catalyst and a preparation process therefor. The catalytic cracking catalyst comprises a cracking active component, 10 wt %-70 wt % of a clay on the dry basis, and 10 wt %-40 wt % of an inorganic oxide binder (as oxide), relative to the weight of the catalytic cracking catalyst, wherein said cracking active component contains, relative to the weight of the catalytic cracking catalyst, 10 wt %-50 wt % of a modified Y-type zeolite on the dry basis and 0-40 wt % of other zeolite on the dry basis, wherein said modified Y-type zeolite is characterized by having a unit cell size of 2.420-2.440 nm; as percent by weight of the modified Y-type zeolite, a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%; and a specific hydroxy nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g.

公开(公告)号：US20140005032A1

公开(公告)日：2014-01-02

申请号：US13929044

申请日：2013-06-27

申请人： Jun LONG ,  Fei Ren ,  Yuxia Zhu ,  Yibin Luo ,  Jiasong Yan ,  Xue Yang ,  Huiping Tian ,  Li Zhuang ,  Beiyan Chen ,  Minggang Li ,  Ying Ouyang ,  Xiangtian Shu

发明人： Jun LONG ,  Fei Ren ,  Yuxia Zhu ,  Yibin Luo ,  Jiasong Yan ,  Xue Yang ,  Huiping Tian ,  Li Zhuang ,  Beiyan Chen ,  Minggang Li ,  Ying Ouyang ,  Xiangtian Shu

IPC分类号： B01J29/80

CPC分类号： B01J29/80 ,  B01J29/088 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  C01B39/026

摘要： The present invention discloses a catalytic cracking catalyst and a preparation process therefor. The catalytic cracking catalyst comprises a cracking active component, 10 wt %-70 wt % of a clay on the dry basis, and 10 wt %-40 wt % of an inorganic oxide binder (as oxide), relative to the weight of the catalytic cracking catalyst, wherein said cracking active component contains, relative to the weight of the catalytic cracking catalyst, 10 wt %-50 wt % of a modified Y-type zeolite on the dry basis and 0-40 wt % of other zeolite on the dry basis, wherein said modified Y-type zeolite is characterized by having a unit cell size of 2.420-2.440 nm; as percent by weight of the modified Y-type zeolite, a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%; and a specific hydroxy nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g.

摘要翻译： 本发明公开了一种催化裂化催化剂及其制备方法。 催化裂化催化剂包含相对于催化剂重量的裂化活性组分，10重量％-70重量％的干基粘土和10重量％-40重量％的无机氧化物粘合剂（作为氧化物） 裂化催化剂，其中所述裂化活性组分相对于催化裂化催化剂的重量含有10重量％-50重量％的基于干基的改性Y型沸石和0-40重量％干燥的其它沸石 其中所述改性的Y型沸石的特征在于具有2.420-2.440nm的晶胞尺寸; 改性Y型沸石的重量百分比，磷含量为0.05-6％，RE2O3含量为0.03-10％，氧化铝含量小于22％; 特异性羟基巢浓度小于0.35mmol / g且大于0.05mmol / g。

公开(公告)号：US08716163B2

公开(公告)日：2014-05-06

申请号：US12439315

申请日：2006-09-28

申请人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

发明人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

IPC分类号： B01J21/00 ,  B01J21/16 ,  B01J29/04 ,  B01J29/08 ,  B01J29/18

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1076 ,  B01J35/1095 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0234 ,  B01J2229/20 ,  B01J2229/42 ,  C04B35/18 ,  C04B2235/3201 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/447 ,  C10G2400/20

摘要： A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M.

摘要翻译： 一种烃转化催化剂，其基于催化剂的总重量包含1-60重量％的沸石混合物，5-99重量％的耐热无机氧化物和0-70重量％的粘土，其中所述沸石混合物 包括基于所述沸石混合物的总重量，1-75重量％的用磷和过渡金属M改性的沸石β，25-99重量％的具有MFI结构的沸石和0-74重量％的 大孔沸石，其中用磷改性的沸石β和过渡金属M的无水化学式以氧化物的质量百分比表示为（0-0.3）Na 2 O（0.5-10）Al 2 O 3（1.3-10） P2O5（0.7-15）MxOy（64-97）SiO2，其中过渡金属M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种; x表示过渡金属M的原子数，y表示满足过渡金属M的氧化态所需的数。

公开(公告)号：US20090325786A1

公开(公告)日：2009-12-31

申请号：US12439315

申请日：2006-09-28

申请人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

发明人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

IPC分类号： B01J29/04 ,  B01J21/16 ,  B01J29/40 ,  B01J29/072 ,  B01J29/08 ,  B01J29/18

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1076 ,  B01J35/1095 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0234 ,  B01J2229/20 ,  B01J2229/42 ,  C04B35/18 ,  C04B2235/3201 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/447 ,  C10G2400/20

摘要： A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M. The catalysts provided in the present invention have higher ability to convert petroleum hydrocarbons and higher yields for light olefins, particularly for propylene. The catalysts can be used for the selectively producing light olefins.

摘要翻译： 一种烃转化催化剂，其基于催化剂的总重量包含1-60重量％的沸石混合物，5-99重量％的耐热无机氧化物和0-70重量％的粘土，其中所述沸石混合物 包括基于所述沸石混合物的总重量，1-75重量％的用磷和过渡金属M改性的沸石β，25-99重量％的具有MFI结构的沸石和0-74重量％的 大孔沸石，其中用磷和过渡金属M改性的沸石β的无水化学式以氧化物的质量百分比表示为（0-0.3）Na 2 O（0.5-10）Al 2 O 3（1.3-10） P2O5（0.7-15）MxOy（64-97）SiO2，其中过渡金属M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种; x表示过渡金属M的原子数，y表示满足过渡金属M的氧化态所需的数。本发明提供的催化剂具有较高的转化石油烃的能力和较高的轻质烯烃产率，特别是 用于丙烯。 催化剂可用于选择性生产轻质烯烃。

公开(公告)号：US09611432B2

公开(公告)日：2017-04-04

申请号：US12822493

申请日：2010-06-24

申请人： Youhao Xu ,  Shouye Cui ,  Jun Long ,  Jianhong Gong ,  Zhijian Da ,  Jiushun Zhang ,  Yuxia Zhu ,  Yibin Luo ,  Jinlian Tang

发明人： Youhao Xu ,  Shouye Cui ,  Jun Long ,  Jianhong Gong ,  Zhijian Da ,  Jiushun Zhang ,  Yuxia Zhu ,  Yibin Luo ,  Jinlian Tang

IPC分类号： C10G11/18 ,  B01J29/06 ,  C10G11/05 ,  B01J29/08 ,  B01J35/00 ,  B01J37/04 ,  B01J37/10

CPC分类号： C10G11/05 ,  B01J29/06 ,  B01J29/084 ,  B01J29/088 ,  B01J29/90 ,  B01J35/002 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/10 ,  B01J38/30 ,  B01J2229/16 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  C10G11/18

摘要： The present invention provides a catalytic cracking catalyst, processing method and use thereof. When the catalyst is added into a commercial catalytic cracking unit, it has an initial activity of not higher than 80, preferably not higher than 75, more preferably not higher than 70, a self-balancing time of 0.1-50 h, and an equilibrium activity of 35-60. Said method enables the activity and selectivity of the catalyst in the catalytic cracking unit to be more homogeneous and notably improves the selectivity of the catalytic cracking catalyst, so as to obviously reduce the dry gas and coke yields, to sufficiently use steam and to reduce the energy consumption of the FCC unit.

公开(公告)号：US20080261803A1

公开(公告)日：2008-10-23

申请号：US11915765

申请日：2006-05-31

申请人： Yibin Luo ,  Zhijian Da ,  Ying Ouyang ,  Li Zhuang ,  Jun Long ,  Xingtian Shu ,  Baoning Zong

发明人： Yibin Luo ,  Zhijian Da ,  Ying Ouyang ,  Li Zhuang ,  Jun Long ,  Xingtian Shu ,  Baoning Zong

IPC分类号： B01J21/04

CPC分类号： C01B39/10 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/85 ,  B01J2229/18 ,  C01B39/06 ,  C10G11/05

摘要： A modified zeolite beta having an anhydrous chemical formula, by weight % of the oxides, of (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(70-97)SiO2, wherein M is one or more transition metal(s) selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn, x is the number of the atoms of said transition metal M, and y is a number that meets with the requirement of the oxidation state of said transition metal M, is disclosed. The modified zeolite beta can be used as an active component of a cracking catalyst or additive for catalytic cracking of petroleum hydrocarbons.

摘要翻译： 具有无水化学式的改性沸石β，其重量百分比为（0-0.3）Na 2 O（0.5-10）Al 2 O 3， （1.3-10）P 5 （0.7-15）M＆lt; x＆lt; （70-97）SiO 2，其中M是一种或多种选自Fe，Co，Ni，Cu，Mn，Zn的过渡金属和 Sn，x是所述过渡金属M的原子数，y是满足所述过渡金属M的氧化态的要求的数。 改性沸石β可用作裂化催化剂或石油烃催化裂化添加剂的活性组分。

公开(公告)号：US07767611B2

公开(公告)日：2010-08-03

申请号：US11915765

申请日：2006-05-31

申请人： Yibin Luo ,  Zhijian Da ,  Ying Ouyang ,  Li Zhuang ,  Jun Long ,  Xingtian Shu ,  Baoning Zong

发明人： Yibin Luo ,  Zhijian Da ,  Ying Ouyang ,  Li Zhuang ,  Jun Long ,  Xingtian Shu ,  Baoning Zong

IPC分类号： B01J29/06 ,  B01J29/072

CPC分类号： C01B39/10 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/85 ,  B01J2229/18 ,  C01B39/06 ,  C10G11/05

摘要： A modified zeolite beta having an anhydrous chemical formula, by weight % of the oxides, of (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(70-97)SiO2, wherein M is one or more transition metal(s) selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn, x is the number of the atoms of said transition metal M, and y is a number that meets with the requirement of the oxidation state of said transition metal M, is disclosed. The modified zeolite beta can be used as an active component of a cracking catalyst or additive for catalytic cracking of petroleum hydrocarbons.

摘要翻译： （0-0.3）Na2O（0.5-10）Al2O3。（1.3-10）P2O5（0.7-15）MxOy（70-97）的氧化物的无水化学式的改性沸石β ）SiO 2，其中M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种过渡金属，x是所述过渡金属M的原子数，y是 公开了满足所述过渡金属M的氧化态的要求的数量。 改性沸石β可用作裂化催化剂或石油烃催化裂化添加剂的活性组分。

公开(公告)号：US07713904B2

公开(公告)日：2010-05-11

申请号：US10562965

申请日：2004-06-24

申请人： Baoning Zong ,  Jinyu Zheng ,  Wenhua Xie ,  Yong Xu ,  Xuhong Mu ,  Yibin Luo ,  Minggang Li ,  Xingtian Shu

发明人： Baoning Zong ,  Jinyu Zheng ,  Wenhua Xie ,  Yong Xu ,  Xuhong Mu ,  Yibin Luo ,  Minggang Li ,  Xingtian Shu

IPC分类号： B01J27/195 ,  B01J29/06

CPC分类号： B01J29/84 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J29/405 ,  B01J29/80 ,  B01J2229/42 ,  C10G45/12 ,  C10G47/20

摘要： This invention relates to a composition with desulfurization property, in which the desulfurization component is a kind of molecular sieves with incorporation of vanadium into the skeleton. The composition has high hydrothermal stability and the vanadium is hard to lose.

摘要翻译： 本发明涉及具有脱硫性质的组合物，其中脱硫组分是一种将钒掺入骨架中的分子筛。 该组合物具有很高的水热稳定性，钒难以失去。

公开(公告)号：US20070060468A1

公开(公告)日：2007-03-15

申请号：US10562965

申请日：2004-06-24

申请人： Baoning Zong ,  Jinyu Zheng ,  Wenhua Xie ,  Yong Xu ,  Xuhong Mu ,  Yibin Luo ,  Minggang Li ,  Xingtian Shu

发明人： Baoning Zong ,  Jinyu Zheng ,  Wenhua Xie ,  Yong Xu ,  Xuhong Mu ,  Yibin Luo ,  Minggang Li ,  Xingtian Shu

IPC分类号： B01J29/04

CPC分类号： B01J29/84 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J29/405 ,  B01J29/80 ,  B01J2229/42 ,  C10G45/12 ,  C10G47/20

摘要： This invention relates to a composition with desulfurization property, in which the desulfurization component is a kind of molecular sieves with incorporation of vanadium into the skeleton. The composition has high hydrothermal stability and the vanadium is hard to lose.

摘要翻译： 本发明涉及具有脱硫性质的组合物，其中脱硫组分是一种将钒掺入骨架中的分子筛。 该组合物具有很高的水热稳定性，钒难以失去。