公开(公告)号：US08716163B2

公开(公告)日：2014-05-06

申请号：US12439315

申请日：2006-09-28

申请人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

发明人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

IPC分类号： B01J21/00 ,  B01J21/16 ,  B01J29/04 ,  B01J29/08 ,  B01J29/18

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1076 ,  B01J35/1095 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0234 ,  B01J2229/20 ,  B01J2229/42 ,  C04B35/18 ,  C04B2235/3201 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/447 ,  C10G2400/20

摘要： A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M.

摘要翻译： 一种烃转化催化剂，其基于催化剂的总重量包含1-60重量％的沸石混合物，5-99重量％的耐热无机氧化物和0-70重量％的粘土，其中所述沸石混合物 包括基于所述沸石混合物的总重量，1-75重量％的用磷和过渡金属M改性的沸石β，25-99重量％的具有MFI结构的沸石和0-74重量％的 大孔沸石，其中用磷改性的沸石β和过渡金属M的无水化学式以氧化物的质量百分比表示为（0-0.3）Na 2 O（0.5-10）Al 2 O 3（1.3-10） P2O5（0.7-15）MxOy（64-97）SiO2，其中过渡金属M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种; x表示过渡金属M的原子数，y表示满足过渡金属M的氧化态所需的数。

公开(公告)号：US20090325786A1

公开(公告)日：2009-12-31

申请号：US12439315

申请日：2006-09-28

申请人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

发明人： Yujian Liu ,  Huiping Tian ,  Xingtian Shu ,  Jun Long ,  Yibin Luo ,  Chaogang Xie ,  Zhenyu Chen ,  Liuzhou Zhao ,  Yuxia Zhu ,  Youbao Lu

IPC分类号： B01J29/04 ,  B01J21/16 ,  B01J29/40 ,  B01J29/072 ,  B01J29/08 ,  B01J29/18

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1076 ,  B01J35/1095 ,  B01J37/0045 ,  B01J37/0219 ,  B01J37/0234 ,  B01J2229/20 ,  B01J2229/42 ,  C04B35/18 ,  C04B2235/3201 ,  C04B2235/3262 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/447 ,  C10G2400/20

摘要： A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M. The catalysts provided in the present invention have higher ability to convert petroleum hydrocarbons and higher yields for light olefins, particularly for propylene. The catalysts can be used for the selectively producing light olefins.

摘要翻译： 一种烃转化催化剂，其基于催化剂的总重量包含1-60重量％的沸石混合物，5-99重量％的耐热无机氧化物和0-70重量％的粘土，其中所述沸石混合物 包括基于所述沸石混合物的总重量，1-75重量％的用磷和过渡金属M改性的沸石β，25-99重量％的具有MFI结构的沸石和0-74重量％的 大孔沸石，其中用磷和过渡金属M改性的沸石β的无水化学式以氧化物的质量百分比表示为（0-0.3）Na 2 O（0.5-10）Al 2 O 3（1.3-10） P2O5（0.7-15）MxOy（64-97）SiO2，其中过渡金属M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种; x表示过渡金属M的原子数，y表示满足过渡金属M的氧化态所需的数。本发明提供的催化剂具有较高的转化石油烃的能力和较高的轻质烯烃产率，特别是 用于丙烯。 催化剂可用于选择性生产轻质烯烃。

公开(公告)号：US09486795B2

公开(公告)日：2016-11-08

申请号：US12666711

申请日：2008-06-27

申请人： Jun Long ,  Yujian Liu ,  Huiping Tian ,  Liuzhou Zhao ,  Yuxia Zhu ,  Zhenyu Chen ,  Yun Xu ,  Jing Fan

发明人： Jun Long ,  Yujian Liu ,  Huiping Tian ,  Liuzhou Zhao ,  Yuxia Zhu ,  Zhenyu Chen ,  Yun Xu ,  Jing Fan

IPC分类号： C10G11/05 ,  B01J35/10 ,  B01J29/06 ,  B01J29/40 ,  B01J29/80 ,  B01J29/08 ,  B01J29/70

CPC分类号： B01J35/10 ,  B01J29/06 ,  B01J29/084 ,  B01J29/40 ,  B01J29/405 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/80 ,  B01J35/108 ,  B01J2229/42 ,  C10G11/05

摘要： A catalyst for catalytically cracking hydrocarbon oils contains a substrate comprising alumina and a molecular sieve, characterized in that the pore distribution of said catalyst is 5-70% of the

摘要翻译： 用于催化裂化烃油的催化剂含有包含氧化铝和分子筛的底物，其特征在于所述催化剂的孔分布为<2nm孔的5-70％，2-4nm孔的5-70％ 4-6nm孔中的0-10％，6-20nm孔的20-80％，20-100nm孔中的0-40％，基于孔径不大的孔的孔体积 超过100nm。 本发明的催化剂具有大的BET孔体积，高重量油裂解能力和耐焦化能力。

公开(公告)号：US20100270210A1

公开(公告)日：2010-10-28

申请号：US12666711

申请日：2008-06-27

申请人： Jun Long ,  Yujian Liu ,  Huiping Tian ,  Liuzhou Zhao ,  Yuxia Zhu ,  Zhenyu Chen ,  Yun Xu ,  Jing Fan

发明人： Jun Long ,  Yujian Liu ,  Huiping Tian ,  Liuzhou Zhao ,  Yuxia Zhu ,  Zhenyu Chen ,  Yun Xu ,  Jing Fan

IPC分类号： B01J29/06 ,  C10G11/05

CPC分类号： B01J35/10 ,  B01J29/06 ,  B01J29/084 ,  B01J29/40 ,  B01J29/405 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/80 ,  B01J35/108 ,  B01J2229/42 ,  C10G11/05

摘要： A catalyst for catalytically cracking hydrocarbon oils contains a substrate comprising alumina and a molecular sieve, characterized in that the pore distribution of said catalyst is 5-70% of the

摘要翻译： 用于催化裂化烃油的催化剂含有包含氧化铝和分子筛的底物，其特征在于所述催化剂的孔分布为<2nm孔的5-70％，2-4nm孔的5-70％ 4-6nm孔中的0-10％，6-20nm孔的20-80％，20-100nm孔中的0-40％，基于孔径不大的孔的孔体积 超过100nm。 本发明的催化剂具有大的BET孔体积，高重量油裂解能力和耐焦化能力。

公开(公告)号：US07923399B2

公开(公告)日：2011-04-12

申请号：US11547209

申请日：2005-03-31

申请人： Jun Long ,  Zhijian Da ,  Huiping Tian ,  Zhenyu Chen ,  Weilin Zhang ,  Xingtian Shu ,  Jiushun Zhang ,  Yuxia Zhu ,  Yujian Liu

发明人： Jun Long ,  Zhijian Da ,  Huiping Tian ,  Zhenyu Chen ,  Weilin Zhang ,  Xingtian Shu ,  Jiushun Zhang ,  Yuxia Zhu ,  Yujian Liu

IPC分类号： B01J29/42

CPC分类号： B01J29/42 ,  B01J29/084 ,  B01J29/40 ,  B01J29/405 ,  B01J29/48 ,  B01J29/80 ,  B01J2229/42 ,  C10G11/05 ,  C10G2300/807 ,  C10G2400/20

摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2  I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2  II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

摘要翻译： 用于转化烃的催化剂包括基于催化剂的重量，1-60重量％的沸石，0.1-10重量％的助催化组分，5-98重量％的耐热无机氧化物，和 以氧化物换算0-70重量％的粘土。 沸石是含有MFI结构的含沸石的磷光体和过渡金属或沸石与大孔沸石的混合物，其基于混合物的重量，包含所述MFI结构的75-100重量％ 含沸石的磷光体和过渡金属和0-25重量％的大孔沸石。 就氧化物的质量而言，含有荧光粉和过渡金属的MFI结构的沸石具有以下无水化学式：（0-0.3）Na2O（0.3-5.5）Al2O3（1.0-10）P2O5。 （0.7-15）M1xOy（0.01-5）M2mOn（0-10）RE2O3（70-97）SiO2 I或（0-0.3）Na2O（0.3-5）Al2O3（1.0-10）P2O5（ 0.7-15）MpOq。（0-10）RE2O3。（70-98）SiO2 II助催化剂组分是选自碱金属，ⅣB族金属，Ⅷ族非贵金属的一种或多种 ，元素周期表中的稀土金属。 该催化剂具有较高的转化石油烃的能力和较高的丙烯，乙烯和轻质芳族化合物的产率。

公开(公告)号：US20070293714A1

公开(公告)日：2007-12-20

申请号：US11547209

申请日：2005-03-31

申请人： Jun Long ,  Zhijian Da ,  Huiping Tian ,  Zhenyu Chen ,  Weilin Zhang ,  Xingtian Shu ,  Jiushun Zhang ,  Yuxia Zhu ,  Yujian Liu

发明人： Jun Long ,  Zhijian Da ,  Huiping Tian ,  Zhenyu Chen ,  Weilin Zhang ,  Xingtian Shu ,  Jiushun Zhang ,  Yuxia Zhu ,  Yujian Liu

IPC分类号： B01J29/42 ,  C10G11/05

CPC分类号： B01J29/42 ,  B01J29/084 ,  B01J29/40 ,  B01J29/405 ,  B01J29/48 ,  B01J29/80 ,  B01J2229/42 ,  C10G11/05 ,  C10G2300/807 ,  C10G2400/20

摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2  I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2  II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

公开(公告)号：US09163182B2

公开(公告)日：2015-10-20

申请号：US12027123

申请日：2008-02-06

申请人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

发明人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

IPC分类号： C10G51/02 ,  C10G11/14 ,  C10G11/05 ,  C10G11/16 ,  C10G11/18

CPC分类号： C10G11/14 ,  C10G11/05 ,  C10G11/16 ,  C10G11/182 ,  C10G2300/205 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/701 ,  C10G2400/04

摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.

摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

公开(公告)号：US20080289997A1

公开(公告)日：2008-11-27

申请号：US12027123

申请日：2008-02-06

申请人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

发明人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

IPC分类号： C10G11/00

CPC分类号： C10G11/14 ,  C10G11/05 ,  C10G11/16 ,  C10G11/182 ,  C10G2300/205 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/701 ,  C10G2400/04

摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.

摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

公开(公告)号：US07347930B2

公开(公告)日：2008-03-25

申请号：US10964644

申请日：2004-10-15

申请人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

发明人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

IPC分类号： C10G11/00 ,  C10G29/04

CPC分类号： C10G11/14 ,  C10G11/05 ,  C10G11/16 ,  C10G11/182 ,  C10G2300/205 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/701 ,  C10G2400/04

摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.

摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

公开(公告)号：US07485595B2

公开(公告)日：2009-02-03

申请号：US10855386

申请日：2004-05-28

申请人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

发明人： Jun Long ,  Yuxia Zhu ,  Huiping Tian ,  Yujian Liu ,  Zhenyu Chen ,  Yaoqing Guo ,  Zhijian Da ,  Jiushun Zhang ,  Mingyuan He

IPC分类号： B01J29/04 ,  B01J29/87 ,  B01J29/06 ,  B01J21/00 ,  B01J29/00 ,  B01J29/08 ,  B01J21/16 ,  B01J23/00 ,  B01J23/32 ,  B01J23/02 ,  B01J23/06 ,  B01J23/70

CPC分类号： B01J29/088 ,  B01J29/061 ,  B01J29/146 ,  B01J29/166 ,  B01J37/0045 ,  B01J37/16 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05

摘要： A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.

摘要翻译： 一种分子筛催化剂，用于裂解烃，包括分子筛，耐火无机氧化物，粘土和金属组分，其中所述分子筛的量为1至90重量％，耐火无机氧化物为2至80重量％ ，粘土为2〜80重量％，金属成分为0.1〜30重量％，以所述金属的最高化合价的氧化物计，基于催化剂的总量计，其中， 所述金属组分基本上以还原状态存在，并且是选自IIIA族金属（铝以外）中的一种或多种金属，以及IVA，VA，IB，IIB，VB，VIB和VIIB族的金属，以及 周期表第Ⅷ族的非贵金属。 该催化剂具有较高的裂解活性和较高的硫还原活性。