PROCESS FOR THE CATALYTIC CONVERSION OF HYDROCARBONS
    6.
    发明申请
    PROCESS FOR THE CATALYTIC CONVERSION OF HYDROCARBONS 有权
    烃类催化转化方法

    公开(公告)号:US20090264693A1

    公开(公告)日:2009-10-22

    申请号:US12439309

    申请日:2006-09-28

    IPC分类号: C07C4/06

    摘要: A process for the catalytic conversion of hydrocarbons, said process comprising the following steps: a feedstock of hydrocarbons is contacted with a hydrocarbon-converting catalyst to conduct a catalytic cracking reaction in a reactor, then the reaction products are taken from said reactor and fractionated to give light olefins, gasoline, diesel, heavy oil and other saturated hydrocarbons with low molecular weight, wherein said hydrocarbon-converting catalyst comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M. The process of the present invention has a higher ability to convert petroleum hydrocarbon in a higher yield for light olefins, particularly for propylene.

    摘要翻译: 一种用于烃的催化转化的方法,所述方法包括以下步骤:烃的原料与烃转化催化剂接触以在反应器中进行催化裂化反应,然后将反应产物从所述反应器中取出并分馏成 给出轻质烯烃,汽油,柴油,重油和其他具有低分子量的饱和烃,其中所述烃转化催化剂基于催化剂的总重量包含1-60重量%的沸石混合物,5-99重量% %的耐热无机氧化物和0-70重量%的粘土,其中所述沸石混合物基于所述沸石混合物的总重量包含1-75重量%的用磷和过渡金属M,25 -99重量%的具有MFI结构的沸石和0-74重量%的大孔沸石,其中表示用磷和过渡金属M改性的沸石β的无水化学式被表示 氧化物的质量百分比为(0-0.3)Na2O。(0.5-10)Al2O3。(1.3-10)P2O5。(0.7-15)MxOy。(64-97)SiO2,其中过渡金属M为 选自Fe,Co,Ni,Cu,Mn,Zn和Sn中的一种或多种; x表示过渡金属M的原子数,y表示满足过渡金属M的氧化态所需的数。本发明的方法具有较高的轻质烯烃转化石油烃的能力, 特别是对于丙烯。