摘要:
A method for preventing settlement of aquatic fouling organisms on surface of an aquatic structure without environmental hazard is provided. The method is based upon absolutely novel concept to prevent the settlement by means of thick slime layer, i.e. bio-jelly, deposited on said surface. The present invention also provides a bio-jelly producing agent and a bio-jelly producing paint both useful for the present method. Further, the present invention provides a novel low toxic antifouling agent.
摘要:
An antifouling paint containing as an active component, in an amount of 5 to 100% by weight of the non-volatile of the paint, an alkylphenoxy group containing organo-silicon compound selected from an organo-silane, a bis-silyl compound and a polysiloxane, the alkyl being a straight or branched C.sub.7 to C.sub.12 alkyl of the formula: C.sub.x H.sub.2x+1 (in which x is 7 to 12) or a 1-methyl-1-phenylethyl group.The novel antifouling paint of the invention can afford a long-lasting, strong antifouling effect when used as a marine paint.
摘要:
A bioactive substance control-releasing resinous composition comprising a resin having main chain and side chains, at least one side chain bearing at the end portion thereof an organic acid moiety having a biological activity, through a metal ester bonding. The resin is hydrolyzed in an ionic atmosphere at a controlled rate to generate a bioactive substance as well as metal ions and is useful in various fields and especially as a resinous vehicle for a coating composition.
摘要:
The present invention relates to a hydrolyzable resin composition based on the resin having at least one side chain bearing a particular metal containing terminal group. The invention also concerns an antifouling coating composition containing said hydrolyzable resin composition as a vehicle.
摘要:
A hydrolyzable resin composition consisting essentially of a resin selected from the group consisting of an acrylic resin, a polyester resin and an epoxy resin and an organic solvent in which the resin is soluble, wherein said resin has at least one side chain bearing at least one terminal group of the formula: ##STR1## wherein X represents ##STR2## M is a metal selected from zinc, copper and tellurium; x is an integer of 1 to 2; R represents an organic acid residue selected from ##STR3## and R.sub.1 is a monovalent organic residue, and the metal content of said resin is 0.3 to 20% by weight of the resin.The subject composition provides superior antifouling coating compositions.
摘要:
The invention relates to a novel hydrolyzable silicone resin composition comprising a polysiloxane having at least one polyvalent metal ester group represented by either one of the following formulae:(--COO--) (.sub.m --M--(R.sub.2).sub.n--R.sub.1 --COO--).sub.m --M--(R.sub.2).sub.n ##STR1## in which R.sub.2 is a hydroxyl group, an alkoxyl group, an alkyl group, a halogen or oxygen atom; R.sub.1 is a bivalent organic residue; p and q each is 0 or an integer of 1 to 8; m is an integer of 2 or more; n is 0 or an integer of 1 or more, providing that the sum of m and n is equal to the valence number of metal M; and M is a bivalent to tetravalent metal selected from the group consisting of Ti, Al, Mg, Zn, Pb, Zr, Cu, Ni, Co and Sn, its preparation and coating composition containing the same, which is useful in an antifouling paint.
摘要:
The present invention provides a method of forming a composite coating film which makes it possible to attain both appearance and workability in a high-humidity environment. The method of forming a composite coating film according to the present invention comprises applying a water-based base coat composition on a substrate, and then a clear coat thereon, wherein said water-based base coat composition comprises a pigment and a resin emulsion obtained by emulsion polymerization of an &agr;, &bgr;-ethylenically unsaturated monomer mixture, said &agr;,&bgr;-ethylenically unsaturated monomer mixture having an acid value of 3 to 50 mg KOH/g and containing at least 65% by weight of a (meth)acrylic ester whose ester moiety contains 1 or 2 carbon atoms.
摘要:
A polymerizable vinyl monomer represented by the formula: ##STR1## wherein R represents a hydrogen atom or methyl group and n is a real number of 3 to 100, and preparation thereof. The vinyl monomer is useful for the preparation of vinyl resin which is highly reactive in crosslinking with a hardener and capable of resulting in a coating of resilient, tough and flexible nature.
摘要:
A curable resin composition containing (a) a homo- or copolymer of an organohydrogenpolysiloxane macromonomer, (b) an alkenyl group-containing polymer, and (c) a hydrosilylation catalyst is disclosed. The organohydrogenpolysiloxane macromonomer may be incorporated into a single polymer entity together with an alkenyl group-containing monomer unit to produce a self-crosslinkable copolymer.
摘要:
A curing type resin composition used as a molding material, a paint binder, etc. comprises a curing agent and a copolymer composed of a silicone compound and an .alpha., .beta.-unsaturated vinyl monomer. The silicone compound is selected from the group consisting of silicone compounds having the following general structural formulas (1) and (2) respectively, and the curing agent has at least two functional groups, individual molecules of which react with a functional group in the groups Y of the silicone compound. ##STR1## wherein: X is selected from the group consisting of a 3-acryloxypropyl group and a 3-methacryloxypropyl group;Y is selected from the group consisting of a 3-glycidoxypropyl group; a 2-(3',4'-epoxycyclohexyl)ethyl group; a 3-hydroxypropyl group; a 3-(2'-hydroxyethoxy)propyl group; and a 3-(4'-(3',3'-dihydroxymethyl)butoxy)propyl group,R is selected from the group consisting of a phenyl group and an alkyl group having 1 to 6 carbon atoms; anda, b, and c are numbers in the following ranges:1.ltoreq.a.ltoreq.200.5.ltoreq.b.ltoreq.21.ltoreq.c.ltoreq.10.
摘要翻译:用作成型材料的固化型树脂组合物,涂料粘合剂等包括固化剂和由硅氧烷化合物和α,β-不饱和乙烯基单体组成的共聚物。 硅氧烷化合物分别选自具有以下一般结构式(1)和(2)的硅氧烷化合物,并且固化剂具有至少两个官能团,其各自的分子与基团中的官能团反应 Y的硅氧烷化合物。 (1)(2)其中:X选自3-丙烯酰氧基丙基和3-甲基丙烯酰氧基丙基; Y选自3-缩水甘油氧基丙基; 2-(3',4'-环氧环己基)乙基; 3-羟基丙基; 3-(2'-羟基乙氧基)丙基; 和3-(4' - (3',3'-二羟甲基)丁氧基)丙基,R选自苯基和具有1至6个碳原子的烷基; 和a,b和c是以下范围的数字:1 = a = 20 0.5 = b = 2 1 = c = 10。