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公开(公告)号：US09416227B2
公开(公告)日：2016-08-16
申请号：US14111135
申请日：2012-04-24
IPC分类号： C08G71/04
CPC分类号： C08G71/04 , Y10T428/2982
摘要： A problem is to provide polyhydroxyurethane microparticles, which have a narrow particle size distribution and are applicable to a wide range of use. Provided are polyhydroxyurethane microparticles which are spherical polymer microparticles having particle sizes of 0.1 μm to 300 μm. A polymer that makes up the polymer microparticles has in a structure thereof chemical structure units represented by the following formula (1) and/or chemical structure units represented by the following formula (2). In the chemical structure units (1) and (2), —O—CO— bonds have been derived from carbon dioxide.
摘要翻译： 问题在于提供具有窄的粒度分布并且适用于广泛使用的多羟基氨基甲酸酯微粒。 提供作为粒径为0.1μm〜300μm的球形聚合物微粒的聚羟基
氨基甲酸酯微粒。 构成聚合物微粒的聚合物具有由下式（1）表示的化学结构单元和/或下式（2）所示的化学结构单元的结构。 在化学结构单元（1）和（2）中，-O-CO-键源自二氧化碳。-
2.发明申请COATING COMPOSITION FOR FORMING GAS BARRIER LAYER, GAS BARRIER FILM, AND METHOD FOR PRODUCING GAS BARRIER FILM 有权用于形成气体阻隔层的涂料组合物，气体阻隔膜和用于生产气体阻隔膜的方法公开(公告)号：US20130323491A1
公开(公告)日：2013-12-05
申请号：US14000053
申请日：2012-02-22
IPC分类号： C09D175/12
CPC分类号： C09D175/12 , B29C47/0021 , B29C47/065 , B29C47/14 , C08G71/04 , C08J7/047 , C08J2375/04 , C08J2475/04 , C09D175/04 , C09D175/08 , Y10T428/1321 , Y10T428/1352 , Y10T428/263 , Y10T428/269 , Y10T428/31551
摘要： Provided are a coating composition for forming a gas barrier layer as configured such that a specific compound having two or more 5-membered cyclic carbonate groups and a compound having two or more amino groups are reactable at an equivalent ratio of functional groups of 0.8 to 1.25 to form the gas barrier layer with a polyhydroxyurethane resin as a principal component; a gas barrier film formed of a single layer or multiple layers, at least one of the layer or layers that forms or form the film is a layer that exhibits gas barrier properties, and the layer is formed of a polyhydroxyurethane resin having a specific chemical structure; and a production method of a film having gas barrier properties. Owing to the use of the specific polyhydroxyurethane resin, the coating composition, gas barrier film and production method readily enable to reduce moisture-dependent variations in gas barrier properties, to avoid the production of noxious fumes upon incineration disposal, to provide excellent processability, and to lower the pollutant load on the environment.
摘要翻译： 提供一种形成气体阻隔层的涂料组合物，其配置为使具有两个以上5元环状碳酸酯基团的具体化合物和具有两个以上氨基的化合物以0.8〜1.25的官能团的当量比可以反应 以聚羟基聚氨酯树脂为主要成分形成阻气层; 由单层或多层形成的阻气膜，形成或形成膜的层或层中的至少一层是具有阻气性的层，该层由具有特定化学结构的多羟基聚氨酯树脂形成 ; 以及具有阻气性的膜的制造方法。 由于使用特定的聚羟基聚氨酯树脂，涂料组合物，阻气膜和制备方法容易地减少阻气性的水分依赖性变化，以避免在焚烧处理时产生有害烟雾，提供优异的可加工性，以及 降低环境污染物负荷。
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3.发明授权Polysiloxane-modified polyhydroxy polyurethane resin, method for producing same, heat-sensitive recording material using the resin, imitation leather, thermoplastic polyolefin resin skin material, material for weather strip, and weather strip 有权聚硅氧烷改性的多羟基聚氨酯树脂，其制造方法，使用树脂的热敏记录材料，仿皮革，热塑性聚烯烃树脂表皮材料，耐候条纹材料和耐候条公开(公告)号：US08951933B2
公开(公告)日：2015-02-10
申请号：US13510576
申请日：2010-11-25
IPC分类号： B41M5/40 , B60R13/02 , C08G18/61 , C08L83/04 , C09D175/04 , D06N3/14 , B32B27/12 , B32B27/28 , B32B27/40 , B41M5/44
CPC分类号： C09D175/04 , B32B27/12 , B32B27/283 , B32B27/40 , B32B2307/21 , B32B2307/306 , B32B2307/584 , B32B2307/714 , B41M5/443 , B41M2205/30 , B60J10/15 , B60R13/02 , C08G18/61 , C08G71/04 , C08G2150/00 , C08L83/04 , C09D183/04 , D06N3/0036 , D06N3/128 , D06N3/14 , D06N3/146 , D06N2201/0227 , D06N2209/046 , D06N2209/105 , D06N2209/143 , D10B2321/121 , D10B2331/04 , Y10S428/904 , Y10T428/249921 , Y10T428/31551 , Y10T428/31573 , Y10T428/31587 , Y10T442/20
摘要： Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin characterized by being derived from a reaction between a 5-membered cyclic carbonate polysiloxane compound represented by the below-described formula (1) and an amine compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin. wherein A means
摘要翻译： 公开了一种聚硅氧烷改性的多羟基聚氨酯树脂及其制备方法，其特征在于衍生自下述式（1）表示的5元环状碳酸酯聚硅氧烷化合物与胺化合物的反应， 以及树脂组合物，热敏记录介质，仿皮革，热塑性聚烯烃树脂表皮材料，耐候条材料和耐候条，均使用树脂。 其中A表示
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4.发明授权Polysiloxane-modified polyhydroxy polyurethane resin, method for producing same, heat-sensitive recording material using the resin, imitation leather, thermoplastic polyolefin resin skin material, material for weather strip, and weather strip 有权聚硅氧烷改性的多羟基聚氨酯树脂，其制造方法，使用树脂的热敏记录材料，仿皮革，热塑性聚烯烃树脂表皮材料，耐候条纹材料和耐候条公开(公告)号：US08703648B2
公开(公告)日：2014-04-22
申请号：US13510583
申请日：2010-11-25
IPC分类号： B41M5/42
CPC分类号： C08G71/04 , B41M5/443 , B41M2205/02 , B41M2205/06 , B41M2205/36 , C08G18/8029 , C08G77/458 , C09D175/04 , D06N3/14 , D06N2209/046 , D06N2209/105 , D06N2209/108 , D06N2211/28 , Y10T428/249921 , Y10T428/31551 , Y10T428/31573 , Y10T428/31587 , Y10T442/20
摘要： Disclosed are a polysiloxane-modified polyhydroxy polyurethane resin derived from a reaction between a 5-membered cyclic carbonate compound and an amine-modified polysiloxane compound, and its production process; and a resin composition, thermal recording medium, imitation leather, thermoplastic polyolefin resin skin material, weather strip material, and weather strip, all of which make use of the resin.
摘要翻译： 公开了衍生自5元环状碳酸酯化合物和胺改性聚硅氧烷化合物之间的反应的聚硅氧烷改性的多羟基聚氨酯树脂及其制造方法; 以及树脂组合物，热敏记录介质，仿皮革，热塑性聚烯烃树脂表皮材料，耐候条材料和耐候条，均使用树脂。
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公开(公告)号：US10000609B2
公开(公告)日：2018-06-19
申请号：US13818552
申请日：2011-08-11
CPC分类号： C08G71/04 , C08G18/61 , C08G18/792 , C08G18/8025 , C08G18/8029 , C08G18/8074 , C08G18/8077 , C08J7/042 , C08J7/047 , C08J2323/02 , C08J2423/28 , C08J2475/04 , D06N3/128 , D06N3/14 , D06N2211/28 , Y10T428/249921 , Y10T428/31587 , Y10T442/20
摘要： Provided are a self-crosslinking polysiloxane-modified polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate polysiloxane compound represented by the following formula (1) and an amine compound and having polysiloxane segments and masked isocyanate groups in its structure: wherein A means and its production process. The present invention can provide a polyhydroxy polyurethane resin, the development of applications of which has not moved ahead in the prior art, as a novel self-crosslinking polyhydroxy polyurethane resin that enables to provide products excellent in lubricity, abrasion resistance, chemical resistance, non-tackiness, heat resistance and the like, is useful from the viewpoint of the reduction of warming gas, and is responsive to the environment.
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6.发明授权Coating composition for forming gas barrier layer, gas barrier film, and method for producing gas barrier film 有权用于形成气体阻隔层的涂料组合物，阻气膜和用于制备阻气膜的方法公开(公告)号：US09540537B2
公开(公告)日：2017-01-10
申请号：US14000053
申请日：2012-02-22
IPC分类号： B29C47/00 , B29C47/06 , B29C47/14 , C08G71/04 , C08J7/04 , C09D175/04 , C09D175/08 , C09D175/12
CPC分类号： C09D175/12 , B29C47/0021 , B29C47/065 , B29C47/14 , C08G71/04 , C08J7/047 , C08J2375/04 , C08J2475/04 , C09D175/04 , C09D175/08 , Y10T428/1321 , Y10T428/1352 , Y10T428/263 , Y10T428/269 , Y10T428/31551
摘要： Provided are a coating composition for forming a gas barrier layer as configured such that a specific compound having two or more 5-membered cyclic carbonate groups and a compound having two or more amino groups are reactable at an equivalent ratio of functional groups of 0.8 to 1.25 to form the gas barrier layer with a polyhydroxyurethane resin as a principal component; a gas barrier film formed of a single layer or multiple layers, at least one of the layer or layers that forms or form the film is a layer that exhibits gas barrier properties, and the layer is formed of a polyhydroxyurethane resin having a specific chemical structure; and a production method of a film having gas barrier properties. Owing to the use of the specific polyhydroxyurethane resin, the coating composition, gas barrier film and production method readily enable to reduce moisture-dependent variations in gas barrier properties, to avoid the production of noxious fumes upon incineration disposal, to provide excellent processability, and to lower the pollutant load on the environment.
摘要翻译： 提供一种形成气体阻隔层的涂料组合物，其配置为使具有两个以上5元环状碳酸酯基团的具体化合物和具有两个以上氨基的化合物以0.8〜1.25的官能团的当量比可以反应 以聚羟基聚氨酯树脂为主要成分形成阻气层; 由单层或多层形成的阻气膜，形成或形成膜的层或层中的至少一层是具有阻气性的层，该层由具有特定化学结构的多羟基聚氨酯树脂形成 ; 以及具有阻气性的膜的制造方法。 由于使用特定的聚羟基聚氨酯树脂，涂料组合物，阻气膜和制备方法容易地减少阻气性的水分依赖性变化，以避免在焚烧处理时产生有害烟雾，提供优异的可加工性，以及 降低环境污染物负荷。
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7.发明授权Five-membered cyclocarbonate polysiloxane compound and process for preparation of same 有权五元环碳酸酯聚硅氧烷化合物及其制备方法公开(公告)号：US08975420B2
公开(公告)日：2015-03-10
申请号：US13503936
申请日：2010-10-07
IPC分类号： C07D307/04 , C07D307/77
CPC分类号： C08G77/458 , C07F7/0838 , C08G77/14 , C08G77/38 , C09D183/10
摘要： A 5-membered cyclic carbonate polysiloxane compound is represented by the below-described formula (1), and is produced by a process that reacts an epoxy-modified polysiloxane compound with carbon dioxide. wherein A means in which R1 means an alkylene group which has from 1 to 12 carbon atoms and may be linked via an element of O, S or N and/or —(C2H4O)b—, R2 means a direct bond or an alkylene group having from 2 to 20 carbon atoms, R2 may be linked to an alicyclic group or aromatic group, b stands for a number of from 1 to 300, and a stands for a number of from 1 to 300.
摘要翻译： 5元环状碳酸酯聚硅氧烷化合物由下述式（1）表示，通过使环氧改性聚硅氧烷化合物与二氧化碳反应的方法制造。 其中A表示其中R1表示具有1至12个碳原子并可以通过O，S或N和/或 - （C 2 H 4 O）b - 的元素连接的亚烷基，R 2表示直接键或亚烷基 具有2至20个碳原子，R 2可以连接到脂环族基团或芳族基团，b代表1至300个数，a代表1至300个数。
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公开(公告)号：US10066048B2
公开(公告)日：2018-09-04
申请号：US13805970
申请日：2011-06-21
IPC分类号： C08G18/80 , B32B27/12 , B32B27/32 , B32B27/40 , C08G18/79 , C08G71/04 , C09D175/04 , D06N3/14
CPC分类号： C08G18/807 , B32B27/12 , B32B27/32 , B32B27/40 , C08G18/792 , C08G18/8022 , C08G18/8025 , C08G18/8029 , C08G18/8074 , C08G18/8077 , C08G71/04 , C09D175/04 , D06N3/14 , D06N2211/28 , Y10T428/249921 , Y10T428/31587 , Y10T442/20
摘要： Provided are a self-crosslinking polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate compound and an amine compound and having masked isocyanate groups in its structure; a process for producing the resin; an imitation leather composed of a base fabric and a resin composition composed of the resin as its principal component and impregnated in or laminated on the base fabric; as kin material made of a thermoplastic polyolefin resin, said skin material including a thermoplastic polyolefin resin sheet and a top coat layer formed directly or via a primer layer on the sheet, wherein the top coat layer has been formed with a resin composition composed of the resin as its principal component; and a weather strip material composed, as its principal components, of the resin and a specific diorganopolysiloxane and/or a silicone oil.
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9.发明授权Self-crosslinkable polysiloxane-modified polyhydroxy polyurethane resin, process for producing said resin, resin material comprising said resin, and artificial leather produced utilizing said resin 有权自交联聚硅氧烷改性的多羟基聚氨酯树脂，所述树脂的制造方法，包含所述树脂的树脂材料和利用所述树脂制造的人造革公开(公告)号：US09359719B2
公开(公告)日：2016-06-07
申请号：US14009464
申请日：2012-04-02
IPC分类号： C08G18/58 , C08G18/61 , C08G18/72 , C09D175/04 , D06N3/14 , C08L83/04 , C08G18/78 , C08G18/80 , C08G59/14 , C08G18/38
CPC分类号： D06N3/14 , C08G18/3893 , C08G18/58 , C08G18/61 , C08G18/7825 , C08G18/8022 , C08G18/8074 , C08G18/8077 , C08G59/1438 , C08L83/04 , C09D175/04 , D06N3/128 , D06N3/146 , D06N2209/06 , D06N2209/105 , D06N2209/143 , D06N2209/1685 , D06N2211/28 , Y10T442/20
摘要： A problem is to provide, in the field of polyhydroxy polyurethane resins the development of applications of which has not moved ahead by conventional technologies, a self-crosslinking polyhydroxy polyurethane resin, which enables to provide products, such as imitation leathers, excellent in abrasion resistance, chemical resistance, heat resistance and the like, and moreover, which is useful from the viewpoint of a reduction in greenhouse gas, contains carbon dioxide incorporated and fixed therein, and is responsive to environmental conservation. Provided are a self-crosslinking, polysiloxane-modified, polyhydroxy polyurethane resin having masked isocyanate groups in a structure of a polysiloxane-modified, polyhydroxy polyurethane resin derived from a reaction of a 5-membered cyclic carbonate compound and an amine-modified polysiloxane compound and having polysiloxane segments therein; a production process of the self-crosslinking resin; a resin material containing the self-crosslinking resin; and an imitation leather composed of a base fabric and a resin composition composed of the self-crosslinking resin as its principal component and impregnated in or laminated on the base fabric.
摘要翻译： 一个问题是提供在多羟基聚氨酯树脂领域，其应用的发展并没有超越传统技术，自交联多羟基聚氨酯树脂，其能够提供诸如仿皮革的产品，耐磨性优异 ，耐化学性，耐热性等，而且从减少温室气体的观点出发，含有二氧化碳，其中并入并固定二氧化碳，并且对环境保护有反应。 本发明提供一种自交联聚硅氧烷改性的多羟基聚氨酯树脂，其具有由5-元环状碳酸酯化合物与胺改性聚硅氧烷化合物的反应衍生的聚硅氧烷改性的多羟基聚氨酯树脂的结构中的具有掩蔽异氰酸酯基团 其中具有聚硅氧烷链段; 自交联树脂的生产工艺; 含有自交联树脂的树脂材料; 以及由基础织物和由自交联树脂作为其主要成分组成并浸渍或层压在基底织物上的树脂组合物的仿皮。
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公开(公告)号：US20140030526A1
公开(公告)日：2014-01-30
申请号：US14111135
申请日：2012-04-24
IPC分类号： C08G71/04
CPC分类号： C08G71/04 , Y10T428/2982
摘要： A problem is to provide polyhydroxyurethane microparticles, which have a narrow particle size distribution and are applicable to a wide range of use. Provided are polyhydroxyurethane microparticles which are spherical polymer microparticles having particle sizes of 0.1 μm to 300 μm. A polymer that makes up the polymer microparticles has in a structure thereof chemical structure units represented by the following formula (1) and/or chemical structure units represented by the following formula (2). In the chemical structure units (1) and (2), —O—CO— bonds have been derived from carbon dioxide.
摘要翻译： 问题在于提供具有窄的粒度分布并且适用于广泛使用的多羟基氨基甲酸酯微粒。 提供了粒径为0.1μm至300μm的球形聚合物微粒的聚羟基
氨基甲酸酯微粒。 构成聚合物微粒的聚合物具有由下式（1）表示的化学结构单元和/或下式（2）所示的化学结构单元的结构。 在化学结构单元（1）和（2）中，-O-CO-键源自二氧化碳。
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