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公开(公告)号：US5324699A
公开(公告)日：1994-06-28
申请号：US900517
申请日：1992-06-17
CPC分类号： B01J27/12 , B01J27/16 , C07C2/62 , C07C2527/1213 , C07C2527/173
摘要： The present invention relates to a novel alkylation catalyst complex and to alkylation processes employing such a catalyst complex. More specifically, the invention relates to a novel catalyst complex comprising a BF.sub.3 :H.sub.3 PO.sub.4 adduct, and at least one polar hydrocarbon formed in situ. The catalyst complex may optionally include water as well as an added solubilizing agent. The invention further includes a pretreatment method for enhancing the isoparaffin selectivity of a catalyst complex containing a BF.sub.3 :H.sub.3 PO.sub.4 adduct.
摘要翻译： 本发明涉及一种新的烷基化催化剂络合物和使用这种催化剂络合物的烷基化方法。 更具体地说，本发明涉及包含BF 3 :H 3 PO 4加合物和至少一种在原位形成的极性烃的新型催化剂络合物。 催化剂络合物可以任选地包括水以及添加的增溶剂。 本发明还包括用于提高含有BF 3 :H 3 PO 4加合物的催化剂络合物的异构烷烃选择性的预处理方法。
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公开(公告)号：US5245101A
公开(公告)日：1993-09-14
申请号：US608856
申请日：1990-11-05
IPC分类号： C07C2/62
CPC分类号： C07C2/62 , C07C2527/1213 , C07C2527/173
摘要： The invention provides a catalyst complex for promoting alkylation of an isoparaffin with an olefin, said catalyst complex comprising the reaction product of BF.sub.3 and at least one selected from the group consisting of H.sub.3 PO.sub.4 and H.sub.2 O; and, additionally, excess BF.sub.3 in concentration of from about 10 ppm (weight) to about 5 percent by weight of the total isoparaffin and olefin feed.The invention further provides a process for the alkylation of an isoparaffin with an olefin by contacting a mixture of isoparaffin and olefin with the catalyst complex of the invention, decanting the hydrocarbon product from the catalyst complex, and deacidifying the hydrocarbon product.
摘要翻译： 本发明提供了一种用于促进异链烷烃与烯烃烷基化的催化剂配合物，所述催化剂配合物包含BF 3的反应产物和选自H 3 PO 4和H 2 O的至少一种; 另外还含有过量的BF 3，其浓度为总异链烷烃和烯烃进料的约10ppm（重量）至约5％重量。 本发明还提供了一种通过使异链烷烃和烯烃的混合物与本发明的催化剂络合物接触，从催化剂络合物中倾析烃产物，并使烃产物脱酸来使烯烃与烷烃烷基化的方法。
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3.发明授权Process for preparing long chain alkyl aromatic compounds employing Lewis acid-promoted zeolite catalysts 失效使用路易斯酸促进的沸石催化剂制备长链烷基芳族化合物的方法
公开(公告)号：US5030785A
公开(公告)日：1991-07-09
申请号：US470012
申请日：1990-01-25
申请人： Albin Huss, Jr. , Quang N. Le , Samuel A. Tabak , Stephen S. Wong
发明人： Albin Huss, Jr. , Quang N. Le , Samuel A. Tabak , Stephen S. Wong
CPC分类号： B01J29/04 , C07C2/12 , C07C2/66 , C07C2529/70
摘要： Aromatic hydrocarbons are alkylated with relatively long chain alkylating agents, e.g., C.sub.6 + olefins, in the presence of, as catalyst, certain Lewis acid-promoted zeolites to provide long chain aromatic products which are useful, inter alia, as lubricating oil stocks.
摘要翻译： 在作为催化剂存在某些路易斯酸促进的沸石的情况下，用相对较长链烷基化试剂例如C 6 +烯烃烷基化芳烃，以提供长链芳族产物，其特别可用作润滑油原料。
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4.发明授权Process for preparing long chain alkyl aromatic compounds employing Lewis acid-promoted amorphous inorganic oxide 失效制备长链酸性芳族化合物的方法，使用LEWIS酸促进的无定形无机氧化物
公开(公告)号：US5107048A
公开(公告)日：1992-04-21
申请号：US470017
申请日：1990-01-25
申请人： Albin Huss, Jr. , Quang N. Le , Samuel A. Tabak , Stephen S. Wong
发明人： Albin Huss, Jr. , Quang N. Le , Samuel A. Tabak , Stephen S. Wong
IPC分类号： C07C2/68
CPC分类号： C07C2/68 , C07C2521/08 , C07C2527/10 , C07C2527/1213 , C07C2527/133
摘要： Aromatic hydrocarbons are alkylated with relatively long chain alkylating agents, e.g., C.sub.8 + olefins, at mole ratio of aromatic to alkylating agent of not greater than about 5 in the presence of, as catalyst, a Lewis acid-promoted amorphous, porous inorganic oxide such as silica to provide long chain alkyl aromatic products which are useful, inter alia, as lubricating oil stocks.
摘要翻译： 使用相对较长链烷基化剂（例如C 8+烯烃）将芳族烃烷基化，在作为催化剂的路易斯酸促进的无定形多孔无机氧化物如芳族化合物与烷基化剂的摩尔比不大于约5的情况下， 二氧化硅以提供长链烷基芳族化合物，其特别可用作润滑油原料。
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5.发明授权
公开(公告)号：US5012033A
公开(公告)日：1991-04-30
申请号：US470016
申请日：1990-01-25
CPC分类号： B01J29/04 , C07C2/12 , C07C2/60 , C07C2527/1213 , C07C2529/06 , C07C2529/70
摘要： Isoparaffin-olefin alkylation is carried out in the presence of a Lewis acid-promoted catalyst, said catalyst comprising a synthetic porous crystalline material characterized in its calcined form by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译： 异链烷烃烯烃烷基化在路易斯酸促进催化剂存在下进行，所述催化剂包括合成多孔结晶材料，其特征在于其煅烧形式的X射线衍射图包括12.36 +/- 0.4的面间d-间距， 11.03 +/- 0.2,8.33 +/- 0.14，6.18 +/- 0.12，6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US4956518A
公开(公告)日：1990-09-11
申请号：US377993
申请日：1989-07-11
申请人： Jonathan E. Child , Tai-Sheng Chou , Albin Huss, Jr. , Clinton R. Kennedy , Francis P. Ragonese , Samuel A. Tabak
发明人： Jonathan E. Child , Tai-Sheng Chou , Albin Huss, Jr. , Clinton R. Kennedy , Francis P. Ragonese , Samuel A. Tabak
IPC分类号： B01D3/00 , B01J20060101 , B01J27/08 , B01J27/12 , B60P1/00 , C07C2/60 , C07C9/14 , C07C9/22 , C10G20060101
CPC分类号： C10G29/205 , B01J27/08 , B01J27/12 , C07C2/60 , B01J21/08 , C07C2521/04 , C07C2521/08 , C07C2527/10 , C07C2527/1213 , C07C2527/126 , C07C2527/133
摘要： An improved continuous process for alkylation of isoparaffins with olefins to yield a product which includes a large proportion of highly branced paraffins for making gasoline having improved octane is taught. The improved process comprises contacting isoparaffins and olefins with a composite catalyst comprising a Lewis acid and a non-zeolitic inorganic oxide in the presence of a controlled amount of water. The process results in reduced catalyst aging and obviates environmental problems associated with prior art processes.
摘要翻译： 教导了改进的用烯烃烷基化异链烷烃的连续方法，以产生包含大量高度分支的链烷烃的产物，用于制备具有改进的辛烷值的汽油。 改进的方法包括在受控量的水的存在下使异链烷烃和烯烃与包含路易斯酸和非沸石无机氧化物的复合催化剂接触。 该方法导致催化剂老化减少并且消除与现有技术方法相关的环境问题。
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7.发明申请APPARATUS AND PROCESS FOR PRODUCING GASOLINE, OLEFINS AND AROMATICS FROM OXYGENATES 审中-公开从氧化剂生产汽油，油脂和芳烃的装置和方法公开(公告)号：US20160102032A1
公开(公告)日：2016-04-14
申请号：US14872340
申请日：2015-10-01
申请人： Bing Du , Samuel A. Tabak , Mitch L. Hindman , Eric B. Shen , David L. Johnson , Mohsen N. Harandi , Clay R. Sutton , Lu Han , Michael F. Raterman , Zhongcheng Wang , Samia Ilias , Brett Loveless , Stephen J. McCarthy
发明人： Bing Du , Samuel A. Tabak , Mitch L. Hindman , Eric B. Shen , David L. Johnson , Mohsen N. Harandi , Clay R. Sutton , Lu Han , Michael F. Raterman , Zhongcheng Wang , Samia Ilias , Brett Loveless , Stephen J. McCarthy
CPC分类号： C07C1/20 , B01J8/0055 , B01J8/1836 , B01J8/24 , B01J8/26 , B01J8/34 , B01J2208/00256 , B01J2208/00274 , B01J2208/0084 , B01J2208/00893 , C07C2/56 , C07C2/864 , C07C2/865 , C07C2521/16 , C07C2529/40 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10G2400/28 , C10G2400/30 , C10L1/06 , Y02P30/20 , Y02P30/42
摘要： Apparatuses and processes for converting an oxygenate feedstock, such as methanol and/or dimethyl ether, in a fluidized bed containing a catalyst to hydrocarbons, such as gasoline boiling components, olefins and aromatics are provided herein.
摘要翻译： 本文提供了将含有催化剂的流化床中的含氧化合物原料如甲醇和/或二甲醚转化成烃的装置和方法，例如汽油沸点组分，烯烃和芳烃。
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8.发明申请APPARATUS AND PROCESS FOR PRODUCING GASOLINE, OLEFINS AND AROMATICS FROM OXYGENATES 有权从氧化剂生产汽油，油脂和芳烃的装置和方法公开(公告)号：US20160102031A1
公开(公告)日：2016-04-14
申请号：US14872323
申请日：2015-10-01
申请人： Bing Du , Samuel A. Tabak , Mitch L. Hindman , Eric B. Shen , David L. Johnson , Mohsen N. Harandi , Clay R. Sutton , Lu Han , Michael F. Raterman , Zhongcheng Wang , Rohit Vijay , Stephen J. McCarthy
发明人： Bing Du , Samuel A. Tabak , Mitch L. Hindman , Eric B. Shen , David L. Johnson , Mohsen N. Harandi , Clay R. Sutton , Lu Han , Michael F. Raterman , Zhongcheng Wang , Rohit Vijay , Stephen J. McCarthy
CPC分类号： C07C1/20 , B01J8/0055 , B01J8/1836 , B01J8/24 , B01J8/26 , B01J8/34 , B01J2208/00256 , B01J2208/00274 , B01J2208/0084 , B01J2208/00893 , C07C2/56 , C07C2/864 , C07C2/865 , C07C2521/16 , C07C2529/40 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10G2400/28 , C10G2400/30 , C10L1/06 , Y02P30/20 , Y02P30/42
摘要： Apparatuses and processes for converting an oxygenate feedstock, such as methanol and dimethyl ether, in a fluidized bed containing a catalyst to hydrocarbons, such as gasoline boiling components, olefins and aromatics are provided herein.
摘要翻译： 本文提供了将含有催化剂的流化床中的含氧化合物原料如甲醇和二甲醚转化成烃的装置和方法，例如汽油沸点组分，烯烃和芳烃。
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9.发明授权Process for upgrading olefinic gasoline by etherification wherein asymmetrical dialkyl ethers are produced 失效通过非对称二烷基醚生产过氧化物来提高烯烃汽油的方法
公开(公告)号：US5078751A
公开(公告)日：1992-01-07
申请号：US505094
申请日：1990-04-04
CPC分类号： C10L1/023
摘要： A process is disclosed for upgrading C.sub.5 -C.sub.8 olefin-containing gasoline to a high octane motor gasoline blending component.C.sub.3 -C.sub.4 olefins are hydrated to alcohols and then selectively removed from the aqueous hydration reactor effluent stream via liquid extraction with the gasoline feedstream. The alcohol enriched gasoline extract stream is then etherified and unreacted alcohols are extracted to yield a high octane gasoline blending component free of metal-bearing additives.
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10.发明授权Multistage system for conversion of lower olefins with reactor quenching means 失效用反应器淬火方法转化低级烯烃的多级体系
公开(公告)号：US4942021A
公开(公告)日：1990-07-17
申请号：US137224
申请日：1987-12-23
摘要： A continuous multistage catalytic conversion system for upgrading lower olefins comprisingfirst adaibatic catalytic bed reactor means containing an acidic zeolite solid catalyst;means for feeding light olefinic gas directly to the first reactor without addition of separate diluent or recycle streams;means for operating the first reactor under olefin partial conversion conditions at elevated temperature to control adiabatic temperature increase;interstage quench means for injecting a liquid coolant directly into first stage effluent for reducing the temperature thereof and protecting downstream catalyst;second catalytic bed reactor means for receiving cooled first stage effluent with injected liquid coolant and further converting the olefins over a metallic zeolite catalyst having a metal ethene oligomerization component;means for cooling and recovering heavier liquid hydrocarbon product from the second reactor effluent; andmeans for recovering liquid coolant from the second effluent for recycle to the interstage quench means.
摘要翻译： 一种用于升级低级烯烃的连续多级催化转化系统，包括含有酸性沸石固体催化剂的第一辅助催化床反应器装置; 用于将轻质烯属气体直接供给到第一反应器而不加入单独的稀释剂或再循环流的装置; 用于在高温下在烯烃部分转化条件下操作第一反应器的装置，以控制绝热温度升高; 级间骤冷装置，用于将液体冷却剂直接注入第一级流出物中以降低其温度并保护下游催化剂; 第二催化床反应器装置，用于接收具有注入的液体冷却剂的冷却的第一级流出物，并进一步转化具有金属乙烯低聚组分的金属沸石催化剂的烯烃; 用于从第二反应器流出物冷却和回收较重液体烃产物的装置; 以及用于从第二流出物回收液体冷却剂以再循环到级间骤冷装置的装置。
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