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1.发明授权Silver halide elements containing solubilized antifoggants and low fogging tabular silver halide grains 失效含有溶解的防灰雾剂和低雾化的片状卤化银颗粒的卤化银元素公开(公告)号：US06518007B1
公开(公告)日：2003-02-11
申请号：US10014704
申请日：2001-12-11
IPC分类号： G03C134
CPC分类号： G03C1/346 , G03C1/0051 , G03C1/04 , G03C7/3022 , G03C7/39236 , G03C2001/03511 , G03C2200/44
摘要： This invention relates to a multicolor silver halide photographic element comprising a support and at least one high bromide silver halide emulsion layer comprising low fogging tabular silver halide grains, said element further comprising an antifoggant represented by the following Structure I: R1—SO2—C(R2)R3—(CO)m—(L)n—SG I wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.
摘要翻译： 本发明涉及一种多色卤化银照相元件，其包含支持体和至少一种包含低雾化片状卤化银颗粒的高溴化卤化银乳剂层，所述元件还包含由以下结构I表示的防灰雾剂：其中R1是脂族或 环状基，R2和R3独立地为氢或溴，只要其中至少一个为溴，L为二价连接基团，m和n分别为0或1，SG为pKa为8的增溶基团 或更少。
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2.发明授权公开(公告)号：US06893809B2
公开(公告)日：2005-05-17
申请号：US10244569
申请日：2002-09-16
CPC分类号： G03C7/30541 , G03C1/0051 , G03C1/04 , G03C7/3022 , G03C7/3029 , G03C7/3041 , G03C7/30594 , G03C7/333 , G03C2007/3032 , G03C2007/3034 , G03C2200/38 , G03C2200/53 , Y10S430/156
摘要： This invention relates to a negative silver halide photographic element comprising a support and a silver halide imaging layer containing a light sensitive silver halide imaging emulsion, said silver halide imaging layer further comprising a separately precipitated non-imaging intentionally fogged fine grain emulsion and an electron transfer agent releasing compound represented by formula (I): CAR1-(L)n-ETA (I) wherein: CAR1 is a carrier moiety which is capable of releasing -(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable electron transfer agent, and (optionally) a development accelerator releasing compound represented by the formula (II): CAR2—(SAM)-NX1—NX2X3 (II) wherein: CAR2 is a carrier moiety which is capable of releasing —(SAM)-NX1—NX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and —NX1—NX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl, or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.
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公开(公告)号：US06756188B2
公开(公告)日：2004-06-29
申请号：US10244270
申请日：2002-09-16
申请人： John E. Keevert , Stephen P. Singer , Kenneth J. Reed , Kenneth J. Lushington , Mary C. Brick , James A. Friday
发明人： John E. Keevert , Stephen P. Singer , Kenneth J. Reed , Kenneth J. Lushington , Mary C. Brick , James A. Friday
IPC分类号： G03C746
CPC分类号： G03C7/30594 , G03C1/0051 , G03C1/04 , G03C7/3022 , G03C7/3029 , G03C7/30541 , G03C2007/3034 , Y10S430/156
摘要： This invention relates to a photographic element comprising a support and at least two silver halide emulsion layers further comprising, an electron transfer agent releasing compound represented by the formula (I): CAR1—(L)n—ETA (I) wherein: CAR1 is a carrier moiety which is capable of releasing —(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable 1-aryl-3-pyrazolidinone electron transfer agent having a calculated log partition coefficient (c log P) greater than or equal to 2.40 and the total sum of the Hammett sigma(para) values of the substituents on the 1-aryl ring is 0.51 or less, the ETA being bonded to L or CAR1 through either the nitrogen atom in the 2-position or the oxygen attached to the 3-position of the pyrazolidinone ring; and a development accelerator releasing compound represented by the formula (II): CAR2—(SAM)—NX1—NX2X3 (II) wherein: CAR2 is a carrier moiety which is capable of releasing —(SAM)—NX1—NX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and —NX1—NX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.
摘要翻译： 本发明涉及一种照相元件，其中包含支持体和至少两个卤化银乳剂层，还包含由式（I）表示的电子转移剂释放化合物：其中：CAR 1是能够释放的载体部分 - （L）n-ETA与氧化显影剂反应; L为二价连接基团，n为0,1或2; 和ETA是具有大于或等于2.40的计算对数分配系数（c log P）的可释放的1-芳基-3-吡唑烷酮电子转移剂，并且1-位的取代基的哈米特σ（对）值的总和， 芳基环为0.51以下，ETA通过2位的氮原子或与吡唑烷酮环的3位相连的氧键连接至L或CAR 1;以及由吡唑烷酮环的3位表示的显影促进剂释放化合物 式（II）：其中：CAR 2是能够与氧化显影剂反应释放 - （SAM）-NX 1 -XX 2 X 3的载体部分; SAM是银 与载体部分连接的可吸收部分，与氧化显影剂反应释放; 和-X 1 -NX 2 X 3是其中X 1，X 2和X 3独立地为氢或选自烷基，芳基，羰基或磺酰基的取代基的肼基团 条件是X 1，X 2和X 3中的至少一个是氢。
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公开(公告)号：US10435639B2
公开(公告)日：2019-10-08
申请号：US13140648
申请日：2008-12-17
申请人： Albert Gary Difrancesco , Thomas D. Allston , Richard K. Hailstone , Andreas Langner , Kenneth J. Reed
发明人： Albert Gary Difrancesco , Thomas D. Allston , Richard K. Hailstone , Andreas Langner , Kenneth J. Reed
IPC分类号： C10L1/12 , B01J23/00 , C10M103/06 , C10M177/00 , B01J37/03 , B01J23/10 , B01J23/83 , B01J35/00 , B82Y30/00
摘要： A process for making cerium dioxide nanoparticles containing at least one transition metal (M) utilizes a suspension of cerium hydroxide nanoparticles prepared by mechanical shearing of an aqueous mixture containing an oxidant in an amount effective to enable oxidation of cerous ion to ceric ion, thereby forming a product stream that contains transition metal-containing cerium dioxide nanoparticles, Ce1-xMxO2, wherein “x” has a value from about 0.3 to about 0.8. The nanoparticles thus obtained have a cubic fluorite structure, a mean hydrodynamic diameter in the range of about 1 nm to about 10 nm, and a geometric diameter of less than about 4 nm. The transition metal-containing crystalline cerium dioxide nanoparticles can be used to prepare a dispersion of the particles in a nonpolar medium.
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5.发明授权
公开(公告)号：US5604086A
公开(公告)日：1997-02-18
申请号：US620773
申请日：1996-03-22
申请人： Kenneth J. Reed , Jeffrey C. Hansen
发明人： Kenneth J. Reed , Jeffrey C. Hansen
CPC分类号： G03C1/0051
摘要： A photographic emulsion is disclosed comprised of a dispersing medium and radiation-sensitive silver halide grains with greater than 50 percent of total grain projected area being accounted for by grains containing a host portion of a face centered cubic rock salt crystal lattice structure and a first epitaxial phase containing greater than 90 mole percent iodide. The host portion is tabular, being bounded by an exterior having first and second parallel major faces joined by a peripheral edge. The first epitaxial phase accounts for less than 60 percent of total silver, and the first epitaxial phase is restricted to a portion of the exterior of the host portion that includes at least 15 percent of the major faces.
摘要翻译： 公开了一种照相乳剂，其包括分散介质和具有大于总颗粒投影面积的50％的辐射敏感卤化银颗粒，其由含有面心立方岩盐晶格结构的主体部分和第一外延 相含有大于90摩尔％的碘化物。 主体部分是片状的，由具有由周边边缘连接的第一和第二平行主面的外部限定。 第一外延相占总银的小于60％，第一外延相限于主体部分外部的至少包含15％主面的部分。
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公开(公告)号：US4286008A
公开(公告)日：1981-08-25
申请号：US926077
申请日：1978-07-19
申请人： Kenneth J. Reed , Alan L. Lythgoe
发明人： Kenneth J. Reed , Alan L. Lythgoe
IPC分类号： B44C1/16 , B41M3/12 , B41M5/00 , B44C1/165 , B44C1/17 , C08F2/46 , C09D11/00 , G03F7/09 , B32B3/00 , B32B27/14
CPC分类号： B41M3/12 , Y10S428/913 , Y10S428/914 , Y10T428/24802 , Y10T428/24901 , Y10T428/264 , Y10T428/265
摘要： A dry release transfer is disclosed in which the design layer is formed by printing one or more inks onto a carrier sheet, at least one of the inks being a photopolymerizable composition, and subjecting the design layer to ultra-violet radiation or an electron beam discharge in order to polymerize the photopolymerizable ink. By suitable selection of polymerizable components of the ink so that the photopolymerized ink has a high Young's modulus, a stress-resisting design layer is produced which will release readily from the carrier on mechanically stressing the carrier, e.g. by rubbing lightly with a ball-point pen.
摘要翻译： 公开了一种干式脱模转印，其中通过将一种或多种油墨印刷在载体片材上形成设计层，至少一种油墨是可光聚合的组合物，并使设计层经受紫外线辐射或电子束放电 以使聚合可光聚合的油墨。 通过适当选择油墨的可聚合组分使得光聚合油墨具有高的杨氏模量，产生耐应力设计层，其在机械应力载体上容易地从载体上释放，例如， 用圆珠笔轻轻摩擦。
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公开(公告)号：US10279393B2
公开(公告)日：2019-05-07
申请号：US15652189
申请日：2017-07-17
申请人： Kenneth J. Reed
发明人： Kenneth J. Reed
IPC分类号： B22F1/02 , B22F9/24 , B22F1/00 , B82Y30/00 , C01G3/00 , B01J13/00 , B01J35/00 , C30B7/00 , B01J37/16 , B01J23/72
摘要： The present process provides a method for synthesizing oxide-free copper nanometal dispersion in a free and reduced state using a solution phase synthesis process. A solution of an organic reducing agent containing at least two proximal nitrogen atoms is reacted with a separate solution containing a copper salt reformulated into a charge transfer complex. The reaction products are stabilized with Lewis bases and Lewis acids and optionally can be concentrated by removing a portion of the volatile low molecular weight solvent by either the use of a partial vacuum or by chemical extraction into another phase.
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公开(公告)号：US08679344B2
公开(公告)日：2014-03-25
申请号：US12549776
申请日：2009-08-28
CPC分类号： B01J23/10 , B01D61/243 , B01D61/425 , B01D2315/16 , B01J13/003 , B01J13/0034 , B01J13/0047 , B01J35/0013 , C08K3/22 , C09D1/00 , C09D7/61 , C09D7/67 , C09K3/1463 , C10L1/10 , C10L1/1233 , C10L1/125 , C10L1/1608 , C10L1/1616 , C10L1/1824 , C10L1/1852 , C10L1/1881 , C10L1/19
摘要： A process for replacing the continuous phase of a nanoparticle dispersion with a less polar phase, includes filtering the dispersion through a semi-permeable membrane filter to remove the continuous phase, and introducing a less polar phase.
摘要翻译： 用极性较小的相代替纳米颗粒分散体的连续相的方法包括通过半透膜过滤器过滤分散体以除去连续相，并引入极性较小的相。
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公开(公告)号：US07896185B2
公开(公告)日：2011-03-01
申请号：US11682454
申请日：2007-03-06
CPC分类号： B65D43/0258 , B65D2543/00092 , B65D2543/00296 , B65D2543/00509 , B65D2543/00537 , B65D2543/00555 , B65D2543/00648 , B65D2543/00685 , B65D2543/0074 , B65D2543/00796 , B65D2543/0099
摘要： A molded plastic container, such as a five gallon pail, that includes a lid and main body that are selectively attachable to each other without a resilient gasket. The main body of the plastic container includes a flexible sealing finger formed along the top rim of the main body. The flexible sealing finger is received within a sealing chamber formed as part of the rim. The sealing chamber is defined by a gland seal such that when the lid is attached to the main body, both the flexible finger and the gland seal can deflect to create multiple sealing points between the flexible sealing finger and the sealing chamber. A latch ring is formed on the outer surface of the main body and engages a locking tab formed on the lid to hold the flexible finger in the sealing chamber.
摘要翻译： 一种模制塑料容器，例如五加仑桶，其包括可以选择性地相互连接而没有弹性垫圈的盖和主体。 塑料容器的主体包括沿着主体的顶部边缘形成的柔性密封指状物。 柔性密封指被容纳在形成为边缘的一部分的密封室内。 密封室由密封密封件限定，使得当盖子附接到主体时，柔性指状物和压盖密封件都可以偏转以在柔性密封指状物和密封腔室之间产生多个密封点。 在主体的外表面上形成一个锁环，并与形成在盖子上的锁定接片接合，以将柔性指状物保持在密封室中。
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10.发明授权
公开(公告)号：US4314020A
公开(公告)日：1982-02-02
申请号：US175224
申请日：1980-08-04
CPC分类号： G03C8/52
摘要： Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer. The outermost timing layer contains photographic addenda, such as development inhibitors, for substantially terminating development of the silver halide emulsion. The timing layer next to the neutralizing layer has a much longer breakdown time so that it is permeated by the alkaline processing composition only after silver halide development has been substantially terminated.
摘要翻译： 摄影组合件，元件，接收元件和覆盖片包括两个定时层和中和层的组合。 最外层的定时层含有摄影附加物，如开发抑制剂，用于基本上终止卤化银乳剂的开发。 中和层旁边的定时层具有更长的击穿时间，使得仅在卤化银显影基本上终止后才被碱处理组合物渗透。
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