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公开(公告)号：US4113656A
公开(公告)日：1978-09-12
申请号：US773427
申请日：1977-02-28
申请人： Kenneth L. Riley , Lloyd A. Pine
发明人： Kenneth L. Riley , Lloyd A. Pine
CPC分类号： B01J35/10 , B01J23/85 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1085 , C10G2300/107
摘要： A catalyst is provided which comprises a hydrogenation component composited with an alumina-containing support. The catalyst has a median pore radius ranging from about 70 to about 95 Angstroms and a specified pore size distribution. A preferred catalyst is cobalt-molybdenum on alumina. Also provided is a hydrotreating process utilizing said catalyst.
摘要翻译： 提供了一种催化剂，其包含与含氧化铝的载体复合的氢化组分。 该催化剂具有约70-约95埃的中值孔半径和规定的孔径分布。 优选的催化剂是氧化铝上的钴 - 钼。 还提供了利用所述催化剂的加氢处理方法。
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2.发明授权
公开(公告)号：US4069139A
公开(公告)日：1978-01-17
申请号：US644835
申请日：1975-12-29
申请人： Kenneth L. Riley , Lloyd A. Pine
发明人： Kenneth L. Riley , Lloyd A. Pine
CPC分类号： B01J35/10 , B01J23/85 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1085 , C10G2300/107
摘要： A catalyst is provided which comprises a hydrogenation component composited with an alumina-containing support. The catalyst has a median pore radius ranging from about 70 to about 95 Angstroms and a narrow specified pore size distribution in a range of 10 Angstroms above and 10 Angstroms below the median pore radius. A preferred catalyst is cobalt-molybdenum on alumina. Also provided is a hydrodesulfurization process utilizing said catalyst.
摘要翻译： 提供了一种催化剂，其包含与含氧化铝的载体复合的氢化组分。 催化剂的中值孔半径范围为约70至约95埃，窄的规定的孔径分布在10埃以上且低于中值孔径半径10埃的范围内。 优选的催化剂是氧化铝上的钴 - 钼。 还提供了利用所述催化剂的加氢脱硫方法。
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公开(公告)号：US4054644A
公开(公告)日：1977-10-18
申请号：US526675
申请日：1974-11-25
摘要： Hydrogen is produced by reacting carbon monoxide with steam at a temperature of at least 200.degree. F. in the presence of a supported catalyst containing: (1) at least one alkali metal compound derived from an acid having an ionization constant below 1 .times. 10.sup.-3, (2) a metallic hydrogenation- dehydrogenation material, and (3) a halogen moiety. The ratio of metal component to alkali metal compound, each calculated on the basis of the oxide thereof, ranges from 0.0001 to about 10 parts by weight per part by weight of the alkali metal compound. The halide constituent is present in amounts in excess of about 0.01 weight %, based on total catalyst. A preferred catalyst composition comprises potassium carbonate, a mixture of cobalt and molybdenum oxides and combined chlorine contained on an alumina support.
摘要翻译： 通过使一氧化碳与蒸汽在至少200°F的温度下，在负载型催化剂存在下反应生成氢气，所述载体催化剂含有：（1）至少一种衍生自电离常数低于1×10 -5的酸的碱金属化合物， 3，（2）金属氢化 - 脱氢材料，和（3）卤素部分。 基于其氧化物计算的金属组分与碱金属化合物的比率为每重量份碱金属化合物0.0001-约10重量份。 基于总催化剂，卤化物组分的存在量超过约0.01重量％。 优选的催化剂组合物包含碳酸钾，钴和钼氧化物的混合物以及氧化铝载体上所含的混合氯。
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公开(公告)号：US3974096A
公开(公告)日：1976-08-10
申请号：US526306
申请日：1974-11-22
摘要： Hydrogen is produced by reacting carbon monoxide with steam at a temperature of at least 200.degree.F. in the presence of a supported catalyst containing: (1) at least one alkali metal compound derived from an acid having an ionization constant below 1 .times. 10.sup..sup.-3, (2) a metallic hydrogenation-dehydrogenation material, and (3) a halogen moiety. The ratio of metal component to alkali metal compound, each calculated on the basis of the oxide thereof, ranges from 0.0001 to about 10 parts by weight per part by weight of the alkali metal compound. The halide constituent is present in amounts in excess of about 0.01 weight %, based on total catalyst. A preferred catalyst composition comprises potassium carbonate, a mixture of cobalt and molybdenum oxides and combined chlorine contained on an alumina support.
摘要翻译： 氢气是在负载型催化剂存在下，在至少200°F的温度下使一氧化碳与蒸汽反应生成的，所述催化剂包含：（1）至少一种衍生自电离常数低于1×10 5的酸的碱金属化合物， - > 3，（2）金属氢化 - 脱氢材料，和（3）卤素部分。 基于其氧化物计算的金属组分与碱金属化合物的比率为每重量份碱金属化合物0.0001-约10重量份。 基于总催化剂，卤化物组分的存在量超过约0.01重量％。 优选的催化剂组合物包含碳酸钾，钴和钼氧化物的混合物以及氧化铝载体上所含的混合氯。
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公开(公告)号：US4465780A
公开(公告)日：1984-08-14
申请号：US434201
申请日：1982-10-14
申请人： Lloyd A. Pine
发明人： Lloyd A. Pine
CPC分类号： C10G11/05 , B01J29/084
摘要： A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with an anion such as a dihydrogen phosphate anion or a dihydrogen phosphite anion and additionally with an ammonium salt other than a salt of an inorganic acid of phosphorus. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.
摘要翻译： 提供由粘土起始材料制成的含磷低碱金属含量沸石催化剂。 催化剂通过使部分阳离子交换的含煅烧沸石的催化剂与阴离子例如磷酸二氢根阴离子或二氢亚磷酸根阴离子并且另外与磷酸的无机酸盐以外的铵盐接触而获得。 还提供了利用含磷催化剂的烃催化裂化方法。
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公开(公告)号：US4348270A
公开(公告)日：1982-09-07
申请号：US246448
申请日：1981-03-23
IPC分类号： B01J23/745 , B01J27/04 , B01J37/02 , B01J37/08 , B01J37/16 , C10G1/08 , C10G49/12 , C10G1/06 , C10G11/02 , C10G45/04 , C10G47/12
CPC分类号： B01J27/04 , B01J23/745 , B01J37/0215 , B01J37/086 , B01J37/16 , C10G1/086 , C10G49/12
摘要： A catalyst is provided which comprises a composition comprising a catalytic metal component, carbon and hydrogen deposited on a low surface area aluminum alloy powder support prepared by atomizing the metal alloy. Hydrocarbon treating and conversion processes utilizing the catalyst are also provided. The catalyst is particularly suitable for slurry processes.
摘要翻译： 提供了一种催化剂，其包含一种组合物，其包含沉积在通过雾化金属合金制备的低表面积铝合金粉末载体上的催化金属成分，碳和氢。 还提供了利用催化剂的烃处理和转化方法。 催化剂特别适用于淤浆方法。
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公开(公告)号：US4149965A
公开(公告)日：1979-04-17
申请号：US919509
申请日：1978-06-27
申请人： Lloyd A. Pine , William E. Winter
发明人： Lloyd A. Pine , William E. Winter
CPC分类号： C10G49/24 , C10G2300/4031
摘要： A naphtha hydrorefining process is initiated by contacting an olefinic naphtha feed at hydrorefining conditions including a pressure below about 200 psig, with hydrogen and a catalyst that has been partially deactivated by treating a fresh or a regenerated catalyst with a substantially non-metals containing hydrocarbonaceous oil in the presence of hydrogen under conditions sufficient to decrease the hydrogenation activity of the catalyst.
摘要翻译： 通过使烯烃石脑油进料在包括低于约200psig的压力的加氢条件下与氢气和通过用基本上不含金属的含烃油处理新鲜或再生催化剂而部分失活的催化剂来引发石脑油加氢精制方法 在氢气存在下，足以降低催化剂的氢化活性的条件下进行。
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公开(公告)号：US3954670A
公开(公告)日：1976-05-04
申请号：US455236
申请日：1974-03-27
申请人： Lloyd A. Pine
发明人： Lloyd A. Pine
CPC分类号： B01J23/00 , B01J21/02 , B01J29/061 , C10G49/08
摘要： A catalyst support comprised of boria and alumina is prepared by the hydrolysis of a mixture of boron alkoxide and aluminum alkoxide. The boria-alumina composition prepared in accordance with the invention can be readily formed for use as a support for catalysts useful in a number of hydrocarbon conversion processes. For example, the boria-alumina may be used as a support for various combinations of zeolite, nickel oxide and molybdenum oxide to produce a catalyst particularly useful in the hydrocracking of petroleum feedstocks.
摘要翻译： 通过硼醇盐和烷氧基铝的混合物的水解制备由氧化硼和氧化铝组成的催化剂载体。 根据本发明制备的氧化硼 - 氧化铝组合物可以容易地形成用作用于多种烃转化方法的催化剂的载体。 例如，氧化硼 - 氧化铝可用作沸石，氧化镍和氧化钼的各种组合的载体，以产生特别可用于石油原料加氢裂化的催化剂。
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公开(公告)号：US4701431A
公开(公告)日：1987-10-20
申请号：US850274
申请日：1986-04-10
申请人： Lloyd A. Pine
发明人： Lloyd A. Pine
CPC分类号： B01J29/084 , B01J2229/16
摘要： A rare earth stabilized aluminum deficient zeolite having the structure of faujasite is provided. The zeolite is produced by contacting a Y-type zeolite with a dealuminating agent to remove aluminum from the crystal structure of the zeolite and ion exchanging the zeolite with a specified amount of rare earth metal cations to stabilize the aluminum deficient zeolite.
摘要翻译： 提供了具有八面沸石结构的稀土稳定的缺铝沸石。 沸石是通过使Y型沸石与脱铝剂接触以从沸石的晶体结构中除去铝，并将沸石与特定量的稀土金属阳离子交换沸石以稳定缺铝沸石而制备的。
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10.发明授权
公开(公告)号：US4504382A
公开(公告)日：1985-03-12
申请号：US596427
申请日：1984-04-03
申请人： Lloyd A. Pine
发明人： Lloyd A. Pine
CPC分类号： C10G11/05 , B01J29/084
摘要： A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with an anion such as a dihydrogen phosphate anion or a dihydrogen phosphite anion and additionally with an ammonium salt other than a salt of an inorganic acid of phosphorus. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.
摘要翻译： 提供由粘土起始材料制成的含磷低碱金属含量沸石催化剂。 催化剂通过使部分阳离子交换的含煅烧沸石的催化剂与阴离子例如磷酸二氢根阴离子或二氢亚磷酸根阴离子并且另外与磷酸的无机酸盐以外的铵盐接触而获得。 还提供了利用含磷催化剂的烃催化裂化方法。
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