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    Binding-agent composition, coating agent containing said binding agent, and the use thereof
    1.
    发明授权
    Binding-agent composition, coating agent containing said binding agent, and the use thereof 失效
    结合剂组合物，含有所述粘合剂的包衣剂及其用途

    公开(公告)号：US5430107A

    公开(公告)日：1995-07-04

    申请号：US235269

    申请日：1994-04-29

    申请人： Klaus Bederke ,  Hermann Kerber ,  Walter Schubert ,  Thomas Brock ,  Helmut Loffler

    发明人： Klaus Bederke ,  Hermann Kerber ,  Walter Schubert ,  Thomas Brock ,  Helmut Loffler

    IPC分类号： C08G18/42 ,  B05D7/26 ,  C08F8/32 ,  C08F265/04 ,  C08F283/02 ,  C08F283/06 ,  C08G18/48 ,  C08G18/52 ,  C08G18/63 ,  C08G63/46 ,  C08K5/00 ,  C08L67/06 ,  C09D151/00 ,  C09D167/00 ,  C09D167/06 ,  C09D175/00 ,  C09D175/04 ,  C09D179/02

    CPC分类号： C09D179/02 ,  C08F265/04 ,  C08F283/02 ,  C08F283/06 ,  C09D151/00 ,  C09D167/00

    摘要： A binding-agent composition for coating agents which can be cured at low temperature contains:A. 4-72% by weight of an acidic CH-compound, obtained by transesterification of an aliphatic .beta.-ketocarboxylic acid ester with one or several monomers and/or polymers containing hydroxyl groups and which contain at least two hydroxyl groups in the molecule,B. 4-72% by weight of an .alpha.,.beta.-unsaturated compound with at least two groups of the general formulaR.sub.1 R.sub.2 C.dbd.CR.sub.3 --CO--attached via the residue of a divalent or polyvalent alcohol, a diamine or polyamine or amino alcohol to at least one additional R.sub.1 R.sub.2 C.dbd.CR.sub.3 --CO--group, where R.sub.1, R.sub.2 and R.sub.3 independently of each other are a hydrogen atom or a straight or branched alkyl residue with 1 to 10 carbon atoms,C. 10-80% by weight of one or several polyamines with, by way of curing agents, at least two amine functions, which can be primary and/or secondary and can be blocked, in the molecule, andD. 0.01-5% by weight, relative to the sum of the weights of components A), B) and C), of a catalyst in the form of a Lewis or Bronstedt base, whereby the conjugated acids of the latter have a pKA-value of at least 10.

    摘要翻译： 用于在低温下固化的涂布剂的粘合剂组合物包含：A. 4-72重量％的酸性CH-化合物，其通过脂族β-酮羧酸酯与一种或几种单体的酯交换和/ 或含有羟基并且在分子中含有至少两个羟基的聚合物，B 4-72重量％的α，β-不饱和化合物，其具有至少两个通式R 1 R 2 C = CR 3 -CO-连接通过的基团 二价或多价醇，二胺或多胺或氨基醇的残基至少一个另外的R 1 R 2 C = CR 3 -CO-基团，其中R 1，R 2和R 3彼此独立地是氢原子或直链或支链烷基 具有1至10个碳原子，C 10-80重量％的一种或多种多胺，通过固化剂，在分子中可以是伯和/或仲和可以被阻断的至少两种胺官能团 ，和D 0.01-5重量％，相对于 组分A），B）和C）的重量，其为路易斯或布朗斯台德形式的催化剂，由此后者的共轭酸的pKA值至少为10。

    Binder composition and its use in surface coatings
    3.
    发明授权
    Binder composition and its use in surface coatings 失效
    粘合剂组合物及其在表面涂料中的应用

    公开(公告)号：US5426156A

    公开(公告)日：1995-06-20

    申请号：US341450

    申请日：1994-11-16

    申请人： Klaus Bederke ,  Hermann Kerber ,  Walter Schubert ,  Gerhard Bremer ,  Thomas Brock ,  Fritz Sadowski

    发明人： Klaus Bederke ,  Hermann Kerber ,  Walter Schubert ,  Gerhard Bremer ,  Thomas Brock ,  Fritz Sadowski

    IPC分类号： C09D4/00 ,  C08F8/32 ,  C08F290/12 ,  C08F299/00 ,  C09D4/06 ,  C09D133/04 ,  C09D161/20 ,  C08L79/02

    CPC分类号： C08F299/00 ,  C08F290/126 ,  C08F8/32 ,  C09D4/06 ,  C08F2800/20

    摘要： Previous two-component coatings with enamine components cured very slowly at low temperatures and led to yellowed products. A binder composition is prepared which cures rapidly at low temperatures and leads to non-yellowing products. It contains as CH-acid component a polymer with at least two enamine functions in the molecule, obtained byA) transesterification of a .beta.-keto-ester with hydroxyl-group-containing compounds or polymers which contain at least two hydroxyl groups in the molecule, with an OH value of at least 50 and a number-average molecular weight of 500 to 10,000, followed by reaction with ammonia or primary and/or secondary amines, andB) as .alpha.,.beta.-unsaturated component a compound with at least two groups of the general formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X; in which X signifies --CO-- which is bonded via the residue of a di- or polyhydric alcohol, a di- or polyamine or an aminoalcohol to a further R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X group, where R.sub.1, R.sub.2 and R.sub.3 signify hydrogen or an alkyl group, components A) and B) are present in the ratio 2:1 to 1:1.5 relative to their equivalent weights, the composition exists as a two-component system, and component A) contains a Lewis or Bronsted base as catalyst.

    摘要翻译： 以前的双组分涂料，烯胺组分在低温下非常缓慢地固化并导致黄色产品。 制备粘合剂组合物，其在低温下快速固化并导致非黄变产物。 它包含作为CH酸组分的分子中具有至少两个烯胺功能的聚合物，其通过以下方式获得：A）β-酮酯与含有羟基的化合物或在分子中含有至少两个羟基的聚合物的酯交换 OH值至少为50，数均分子量为500至10,000，随后与氨或伯胺和/或仲胺反应，B）作为α，β-不饱和组分，具有至少两个 通式为R1R2C = CR3-X的基团; 其中X表示-CO-，其通过二元或多元醇，二胺或多胺或氨基醇的残基与另外的R 1 R 2 C = CR 3 -X基团结合，其中R 1，R 2和R 3表示氢或烷基 组分A）和B）相对于其当量的比例为2:1至1:1.5，组合物以双组分体系存在，组分A）含有路易斯或布朗斯台德碱作为催化剂。

    Pigment dispersion and its use
    4.
    发明授权
    Pigment dispersion and its use 失效
    颜料分散及其用途

    公开(公告)号：US4839414A

    公开(公告)日：1989-06-13

    申请号：US86931

    申请日：1987-08-18

    申请人： Klaus Bederke ,  Thomas Brock ,  Hermann Kerber ,  Paul Rupieper

    发明人： Klaus Bederke ,  Thomas Brock ,  Hermann Kerber ,  Paul Rupieper

    IPC分类号： B01J13/00 ,  B01F17/00 ,  B01F17/52 ,  C08G18/62 ,  C09B67/46 ,  C09D17/00

    CPC分类号： B01F17/005 ,  C08G18/6266 ,  C09B67/009 ,  C09D17/00

    摘要： A pigment dispersion and its use for the preparation of coating compounds are described. The dispersion contains a pigment, solvent and pigment dispersing agent. The pigment dispersing agent is a copolymer containing OH groups, obtainable by the reaction of:(A) 80 to 95% by weight of a copolymer of:(a) 0.5 to 40% by weight of N,N-di-Cl to 4-alkylamino-C.sub.1 to .sub.8 -alkyl(meth)acrylamides and/or a mixture of N,N-di-C to 4-alkylamino-C.sub.1 to 8 -alkyl(meth)acrylates and N-substituted (meth)acrylamides and/or (meth)acrylamide in which the ratio of amino(meth)acrylates to amido(meth)acrylates should be in the range of from 1:2 to 2:1,(b) 10 to 40% by weight of hydroxy-C.sub.2-8 -alkyl (meth)acrylates and(c) 20 to 89.5% by weight of copolymerizable, .alpha., .beta.-olefinically unsaturated compounds with(B) 5 to 20% by weight of a polyisocyanate containing unmasked and optionally also masked isocyanate groups as well as biuret, urethane or isocyanurate groups.

    摘要翻译： 描述了颜料分散体及其制备涂料化合物的用途。 分散体含有颜料，溶剂和颜料分散剂。 颜料分散剂是含有OH基团的共聚物，可以通过以下反应获得：（A）80〜95重量％的共聚物，其中：（a）0.5〜40重量％的N，N-2-Cl〜4 - 烷基氨基-C 1-8烷基（甲基）丙烯酰胺和/或N，N-二-C至4-烷基氨基-C 1-8烷基（甲基）丙烯酸酯和N-取代的（甲基）丙烯酰胺和/或 （甲基）丙烯酸酯与酰氨基（甲基）丙烯酸酯的比率应在1:2至2:1的范围内的（甲基）丙烯酰胺，（b）10至40重量％的羟基-C 2- （甲基）丙烯酸烷基酯和（c）20至89.5重量％的可共聚的α，β-烯属不饱和化合物与（B）5至20重量％的含有未掩蔽和任选的掩蔽的异氰酸酯基团的多异氰酸酯以及 缩二脲，聚氨酯或异氰脲酸酯基。

    Coating agents and the use thereof in processes for the production of multi-layer coatings
    7.
    发明授权
    Coating agents and the use thereof in processes for the production of multi-layer coatings 失效
    涂层剂及其在多层涂料生产方法中的应用

    公开(公告)号：US5663233A

    公开(公告)日：1997-09-02

    申请号：US492291

    申请日：1995-06-19

    申请人： Klaus Bederke ,  Friedrich Herrmann ,  Hermann Kerber ,  Thomas Kutzner ,  Hans-Martin Schonrock

    发明人： Klaus Bederke ,  Friedrich Herrmann ,  Hermann Kerber ,  Thomas Kutzner ,  Hans-Martin Schonrock

    IPC分类号： C08G18/40 ,  C09D167/00 ,  C09D175/04 ,  C08L67/02 ,  C08L33/02 ,  C08L61/28 ,  C08L67/04

    CPC分类号： C09D167/00 ,  C08G18/4063 ,  C09D175/04

    摘要： A solvent based coating composition containing a binding agent, the binding agent comprising: (a) 10 to 80 wt.% of at least one hydroxyfunctional polyester formed by reacting a mixture comprising: (i) 10 to 40 mol.% of a 2,2-dialkylalkanediol with two primary OH groups; (ii) 10 to 30 mol.% of a polyol with at least one secondary OH group; (iii) 20 to 50 mol.% of an aliphatic or cycloaliphatic dicarboxylic acid with fewer than 16 C atoms or anhydrides thereof; (iv) 5 to 30 mol.% of a compound selected from the group consisting of dimeric fatty acids, dimeric diols, epsilon-caprolactone, and mixtures thereof; (v) 1 to 15 mol.% of a hydroxycarboxylic acid with at least one hydroxy group and at least one carboxyl group; and (b) 10 to 80 wt.% of a (meth)acrylic copolymer containing a hydroxyl group; and (c) 10 to 60 wt.% of a crosslinking agent; wherein the sum of the wt.% of components (a)-(c) is 100% of the binding agent.

    摘要翻译： 一种含有粘合剂的溶剂型涂料组合物，所述粘合剂包含：（a）10至80重量％的至少一种羟基官能聚酯，所述羟基官能聚酯是通过使混合物反应形成的，所述混合物包含：（i）10至40摩尔％ 具有两个伯OH基的2-二烷基二醇; （ii）10至30mol％具有至少一个仲OH基团的多元醇; （iii）20-50mol％具有少于16个C原子的脂族或脂环族二羧酸或其酸酐; （iv）5至30mol％的选自二聚脂肪酸，二聚二醇，ε-己内酯及其混合物的化合物; （v）1至15mol％具有至少一个羟基和至少一个羧基的羟基羧酸; 和（b）10〜80重量％的含有羟基的（甲基）丙烯酸共聚物; 和（c）10〜60重量％的交联剂; 其中组分（a） - （c）的重量％的总和为粘合剂的100％。

    Process for priming plastic substrates, coating compositions for this purpose, and the use thereof
    8.
    发明授权
    Process for priming plastic substrates, coating compositions for this purpose, and the use thereof 失效
    用于引发塑料基材，用于该目的的涂料组合物及其用途的方法

    公开(公告)号：US5399383A

    公开(公告)日：1995-03-21

    申请号：US197355

    申请日：1994-02-16

    申请人： Manfred Mass ,  Klaus Bederke ,  Hermann Kerber

    发明人： Manfred Mass ,  Klaus Bederke ,  Hermann Kerber

    IPC分类号： B05D7/02 ,  B05D7/24 ,  C08G18/62 ,  C08J7/04 ,  C08L63/00 ,  C09D133/14 ,  C09D133/26 ,  C09D163/00 ,  C09D167/00 ,  C09D175/04 ,  C09D175/06

    CPC分类号： C09D133/14 ,  C08G18/6266 ,  C08J7/04 ,  C09D133/26 ,  C08J2323/12 ,  C08L63/00

    摘要： A process for priming of plastic substrates without adverse effects on the mechanical stability by applying to a plastic substrate, particularly a polyolefin substrate, a coating composition which comprises from 10 to 35% by weight of binders having an OH number of from 40 to 150, prepared from (meth)acrylamides, hydroxyalkyl (meth) acrylates and copolymerisable, olefinically unsaturated compounds with subsequent modification by means of polyisocyanates, up to 20% by weight of further binders, from 30 to 70% by weight of organic solvents, from 15 to 45% by weight of pigments and/or fillers, from 0 to 15% by weight of additives and from 1 to 30% by weight of epoxide- or polyisocyanate-based crosslinking agents.

    摘要翻译： 用于通过施加到塑料基材，特别是聚烯烃基材上的塑料基材的引发而不对机械稳定性产生不利影响的方法，涂料组合物包含10至35重量％的OH值为40至150的粘合剂， 由（甲基）丙烯酰胺，（甲基）丙烯酸羟烷基酯和可共聚的烯属不饱和化合物制备，随后通过多异氰酸酯改性，最多20重量％的另外的粘合剂，30-70重量％的有机溶剂，从15至 45重量％的颜料和/或填料，0至15重量％的添加剂和1至30重量％的环氧化物或多异氰酸酯基交联剂。

    Binder, process for its preparation and its use in clear or pigmented coating agents
    9.
    发明授权
    Binder, process for its preparation and its use in clear or pigmented coating agents 失效
    BINDER，其制备方法及其在清除或掺杂涂料中的用途

    公开(公告)号：US5136004A

    公开(公告)日：1992-08-04

    申请号：US391541

    申请日：1990-11-13

    申请人： Klaus Bederke ,  Hermann Kerber ,  Manfred Krumme ,  Fritz Sadowski ,  Werner Stephan

    发明人： Klaus Bederke ,  Hermann Kerber ,  Manfred Krumme ,  Fritz Sadowski ,  Werner Stephan

    IPC分类号： C08F220/06 ,  C08F20/32 ,  C08F212/00 ,  C08F212/08 ,  C08F220/04 ,  C08F220/10 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C08G18/62 ,  C09D125/00 ,  C09D125/04 ,  C09D133/04 ,  C09D133/06 ,  C09D175/04

    CPC分类号： C08F220/32 ,  C08F212/08

    摘要： The invention concerns a binder suitable for clear or pigmented coating agents. Binders based on copolymers containing hydroxyl groups have hitherto a high solvent content. The solids content of the new binders is improved without affecting the viscosity; gloss, body, flow and processing properties of coatings containing the new binders are improved. The binders consist essentially of a copolymer containing hydroxyl groups, made from specific quantities of styrol, tertbutacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxypropyl methacrylate, butanediol-1, 4-monoacrylate, acrylic acid and glycidyl esters of .alpha.-alkylalkane monocarboxylic acids and/or .alpha.,.alpha.-dialkylalkane monocarboxylic acids.

    摘要翻译： PCT No.PCT / EP88 / 01097 Sec。 371日期1990年11月13日 102（e）1990年11月13日日期PCT提交1988年12月2日PCT公布。 第WO89 / 05314号公报 日期：1989年6月15日。本发明涉及适用于透明或着色涂层剂的粘合剂。 基于含有羟基的共聚物的粘合剂迄今为止具有高溶剂含量。 新粘合剂的固体含量得到改善而不影响粘度; 提高了含有新粘合剂的涂料的光泽度，体积，流动性和加工性能。 粘合剂基本上由含有羟基的共聚物组成，由特定量的苯乙烯，叔丁基丙烯酸酯，甲基丙烯酸异丁酯，甲基丙烯酸2-乙基己酯，甲基丙烯酸2-羟丙酯，丁二醇-1,4-单丙烯酸酯，丙烯酸和α-烷基烷基的缩水甘油酯 一元羧酸和/或α，α-二烷基烷烃一元羧酸。