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    Fuel compositions containing propoxylate
    7.
    发明授权
    Fuel compositions containing propoxylate 有权
    含丙氧基化物的燃料组合物

    公开(公告)号：US07250065B1

    公开(公告)日：2007-07-31

    申请号：US09720257

    申请日：1999-07-08

    申请人： Wolfgang Günther ,  Knut Oppenländer ,  Harald Schwahn ,  Irene Trötsch-Schaller

    发明人： Wolfgang Günther ,  Knut Oppenländer ,  Harald Schwahn ,  Irene Trötsch-Schaller

    IPC分类号： C10L1/18 ,  C10L1/22

    CPC分类号： C10L1/1985 ,  C10L1/146 ,  C10L1/2383 ,  C10L10/04 ,  C10L10/06

    摘要： Fuel compositions for internal combustion engines, comprising a principle amount of a liquid hydrocarbon fuel and an amount, which has a cleaning effect, of at least one propoxylate additive of the formula I where n is an integer from 10 to 20 and R1 is straight-chain or branched C8-C18-alkyl or C8-C18-alkenyl, if required in combination with at least one detergent additive, e.g. a polyalkylamine additive of the formula II R2—NH2   (II) where R2 is a straight-chain or branched polyalkyl radical having a number average molecular weight of from about 500 to about 5000, and fuel additive compositions which contain propoxylates of the formula I and, if required, further additives, such as the aforementioned polyalkylamines of the formula II, as intake valve cleaners.

    摘要翻译： 用于内燃机的燃料组合物，其包含液体烃燃料的主要量和具有清洁作用的量的至少一种式I的丙氧基化物添加剂，其中n是10至20的整数，R“ 1是直链或支链C 8 -C 18 - 烷基或C 8 -C 18 - 如果需要与至少一种洗涤剂添加剂组合，例如， 式II的多烷基胺添加剂<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 -NH 2（II ）其中R 2是数均分子量为从 约500至约5000，以及含有式I的丙氧基化物和如果需要的其它添加剂，例如上述式II的多烷基胺的进料阀清洁剂的燃料添加剂组合物。

    Method of preparing aldehydes by hydroformylation with a rhodium catalyst and recovery of the rhodium catalyst by extraction
    8.
    发明授权
    Method of preparing aldehydes by hydroformylation with a rhodium catalyst and recovery of the rhodium catalyst by extraction 失效
    通过用铑催化剂加氢甲酰化制备醛的方法，并通过萃取回收铑催化剂

    公开(公告)号：US06225507B1

    公开(公告)日：2001-05-01

    申请号：US09117662

    申请日：1998-08-04

    申请人： Bernhard Giessler ,  Heinz-Josef Kneuper ,  Michael Röper ,  Rocco Paciello ,  Knut Oppenländer ,  Wolfgang Günther

    发明人： Bernhard Giessler ,  Heinz-Josef Kneuper ,  Michael Röper ,  Rocco Paciello ,  Knut Oppenländer ,  Wolfgang Günther

    IPC分类号： C07C4550

    CPC分类号： B01J31/20 ,  B01J31/1658 ,  B01J31/4046 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  C07F9/3817 ,  C08G73/0206 ,  Y02P20/584 ,  C07C47/02

    摘要： A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms, comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of form 50 to 1000 bar and at a temperature of from 50° to 180° C. by means of a rhodium catalyst dissolved in a homogenous reaction medium and a catalyst recovery stage comprising extraction of the rhodium catalyst with an aqueous solution of chelating agent, isolation of alcohols and/or aldehyde from the extracted hydroformylation product steam, precarbonylation of the aqueous rhodium-containing extract in the presence of carbon monoxide, synthesis gas as, or a gas mixture containing carbon monoxide under a pressure of from 50 to 1000 bar and at a temperature of from 50° to 180° C., separation of the effluent of the precarbonylation stage into an organic phase containing the major portion of the rhodium and an aqueous phase containing the chelating agent and recycling of the organic phase to the hydroformylation stage, where the rhodium catalyst is extracted from the effluent of the hydroformylation stage using an aqueous solution of a sulfonic acid group-free, water-soluble polymer capable of chelating rhodium.

    摘要翻译： 一种通过加氢甲酰化含有多于3个碳原子的烯烃制备醛或醛和醇的方法，包括加氢甲酰化阶段，其中烯烃在50至1000巴的压力和50℃的温度下加氢甲酰化 通过溶解在均匀的反应介质中的铑催化剂和催化剂回收阶段，包括用螯合剂的水溶液萃取铑催化剂，从提取的加氢甲酰化产物蒸汽中分离出醇和/或醛， 在50至1000巴的压力和50至180℃的温度下，在一氧化碳，合成气或含有一氧化碳的气体混合物存在下，含铑水溶液提取物的预羰基化，分离 的预羰化阶段的流出物进入含有主要部分铑的有机相和含有螯合剂的水相 并将有机相再循环到加氢甲酰化阶段，其中使用不含磺酸基团的能够螯合铑的水溶性聚合物的水溶液从加氢甲酰化阶段的流出物中提取铑催化剂。