Polyethers obtainable by reacting alkylolated
bis-(4-hydroxyphenyl)-methanes with polyalkylene oxides, and their use
as oil demulsifiers
    10.
    发明授权
    Polyethers obtainable by reacting alkylolated bis-(4-hydroxyphenyl)-methanes with polyalkylene oxides, and their use as oil demulsifiers 失效
    通过羟烷基化的双 - (4-羟基苯基) - 甲烷与聚环氧烷反应获得的聚醚,以及它们作为油破乳剂的用途

    公开(公告)号:US4814394A

    公开(公告)日:1989-03-21

    申请号:US43591

    申请日:1987-04-28

    CPC分类号: C10G33/04 C08G65/34 C08G8/36

    摘要: Polyethers with are suitable as oil demulsifiers are obtainable by reacting(A) a polyalkylene oxide obtained from ethylene oxide and propylene oxide and containing in total from 5 to 200 alkylene oxide units with(B) an alkylolation product of a low molecular weight aldehyde and a bis-(4-hydroxyphenyl)-methane of the general formula II ##STR1## wherein R.sup.1 and R.sup.2 may be identical or different and are each hydrogen, low molecular weight alkyl, phenyl, carboxyl or low molecular weight alkoxycarbonyl, the molar reaction ratio of the compound of the formula II to the alkylolating aldehyde being from 1:1 to 1:4, at from 100.degree. to 180.degree. C. in the presence of an acidic catalyst with removal of the water of reaction, the weight ratio of A to B being from 5:1 to 1:3.

    摘要翻译: 适合作为油破乳剂的聚醚可通过使(A)由环氧乙烷和环氧丙烷获得的聚环氧烷烃和总共5至200个烯化氧单元与(B)低分子量醛的烷氧基化产物和 双(4-羟基苯基) - 甲烷,其中R 1和R 2可以相同或不同,各自为氢,低分子量烷基,苯基,羧基或低分子量烷氧基羰基,摩尔反应比例 在酸性催化剂存在下,式II化合物与烷醇化醛的比例为1:1至1:4,在100至180℃下,除去反应水,A与 B为5:1至1:3。