摘要:
The present invention relates to a method for preparing an oligomerization catalyst system and the method comprises preparing a catalyst composition by mixing a PNP-based ligand compound and a transition metal compound, and mixing and activating a co-catalyst and the catalyst composition at a temperature from −40 to 80° C. The oligomerization catalyst system prepared by the method may maintain the activity thereof during an oligomerization reaction at a high temperature, and the reaction temperature of oligomerization may be easily controlled. Various merits in processing may be obtained.
摘要:
Provided are a novel metallocene-supported catalyst and a method of preparing a polyolefin using the same. The metallocene-supported catalyst according to the present disclosure may be used in the preparation of polyolefins, it may have excellent activity and excellent reactivity with comonomers, and it may prepare olefinic polymers having a high molecular weight and a low molecular weight.
摘要:
The present invention relates to a 1-octene composition. The 1-octene composition according to the present invention is prepared by ethylene oligomerization and comprises a high content of 1-octene and monomers useful for copolymerization of 1-octene at the same time.
摘要:
The present invention relates to a 1-octene composition. The 1-octene composition according to the present invention is prepared by ethylene oligomerization and comprises a high content of 1-octene and monomers useful for copolymerization of 1-octene at the same time.
摘要:
The present invention relates to ethylene-1-hexene-1-butene terpolymer and a film including the same. The ethylene-1-hexene-1-butene terpolymer according to the present invention has an optimized range of density and melt index and includes 1-hexene and 1-butene as comonomers, and can provide a polymer showing excellent properties by regulating the content ratio of the comonomers in a certain range. Therefore, the film prepared by using the same can be usefully used because it has excellent stickiness, processibility, and falling dart impact strength which are especially suitable for stretch films.
摘要:
The present invention relates to a ligand compound, a catalyst system for oligomerization of olefins including the ligand compound and the organic chromium compound, and a method for oligomerizing olefins using the same. The catalyst system for olefin oligomerization according to the present invention invention exhibits high selectivity to 1-hexene or 1-octene while having excellent catalytic activity, thereby enabling more efficient production of alpha-olefins.
摘要:
The present specification relates to an olefin oligomerization method and specifically to an olefin oligomerization method comprising the step of subjecting an olefin to a multimerization reaction by controlling a reaction temperature such that the weight ratio of 1-hexene to 1-octene within a product comprising 1-hexene and 1-octene has a predetermined value, in the presence of an oligomerization catalyst system comprising a ligand compound, a transition metal compound, and a cocatalyst, wherein the predetermined value for the weight ratio of 1-hexene to 1-octene within the product is selected in a range of 1:0.5 to 1:7. By the method, 1-hexene and 1-octene can be produced in a desired ratio.
摘要:
The present invention relates to a preparation method of a highly active supported metallocene catalyst which can prepare a polyolefin of high bulk density. More specifically, the present invention provides a method of preparing the supported metallocene catalyst in which one or more metallocene catalysts are loaded on the silica carrier of which the inside is penetrated by more cocatalyst than the prior art and the outside is attached with a substantial amount of the cocatalyst. The catalyst according to the present invention can prepare a polyolefin polymer with improved bulk density and efficiency while maintaining its highly active catalytic characteristic.
摘要:
This disclosure relates to a ligand compound, a catalyst system for olefin oligomerization, and a method for olefin oligomerization using the same. The catalyst system for olefin oligomerization according to the present invention has excellent catalytic activity, and yet, exhibits high selectivity to 1-hexene and 1-octene, thus enabling efficient preparation of alpha-olefin.
摘要:
The present invention relates to a ligand compound, a catalyst system for olefin oligomerization, and a method for olefin oligomerization using the same. The present ligand compound is a compound having a certain new structure and enables provision of a catalyst system for olefin oligomerization that can oligomerize ethylene with higher catalytic activity.