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公开(公告)号：US20100003501A1
公开(公告)日：2010-01-07
申请号：US12165765
申请日：2008-07-01
申请人： Lan H. Liu , Robert F. Kamrath , Encai Hao , Taun L. McKenzie , Marc D. Radcliffe , Richard J. Pokorny , Christopher B. Walker, JR. , Anthony M. Renstrom
发明人： Lan H. Liu , Robert F. Kamrath , Encai Hao , Taun L. McKenzie , Marc D. Radcliffe , Richard J. Pokorny , Christopher B. Walker, JR. , Anthony M. Renstrom
CPC分类号： G02B1/111 , B82Y20/00 , B82Y30/00 , G02F1/133502 , Y10T428/25 , Y10T428/254 , Y10T428/26 , Y10T428/265 , Y10T428/2995 , Y10T428/31855
摘要： Antireflective films comprising a flexible high refractive index layer that comprises at least 60 wt-% of inorganic nanoparticles, the nanoparticles having a refractive index of at least 1.60, dispersed in a crosslinked organic material. Also described are surface treated nanoparticles.
摘要翻译： 包含柔性高折射率层的抗反射膜，其包含分散在交联的有机材料中的至少60重量％的无机纳米颗粒，纳米颗粒具有至少1.60的折射率。 还描述了表面处理的纳米颗粒。
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公开(公告)号：US08343622B2
公开(公告)日：2013-01-01
申请号：US12165765
申请日：2008-07-01
申请人： Lan H. Liu , Robert F. Kamrath , Encai Hao , Taun L. McKenzie , Marc D. Radcliffe , Richard J. Pokorny , Christopher B. Walker, Jr. , Anthony M. Renstrom
发明人： Lan H. Liu , Robert F. Kamrath , Encai Hao , Taun L. McKenzie , Marc D. Radcliffe , Richard J. Pokorny , Christopher B. Walker, Jr. , Anthony M. Renstrom
CPC分类号： G02B1/111 , B82Y20/00 , B82Y30/00 , G02F1/133502 , Y10T428/25 , Y10T428/254 , Y10T428/26 , Y10T428/265 , Y10T428/2995 , Y10T428/31855
摘要： Antireflective films comprising a flexible high refractive index layer that comprises at least 60 wt-% of inorganic nanoparticles, the nanoparticles having a refractive index of at least 1.60, dispersed in a crosslinked organic material. Also described are surface treated nanoparticles.
摘要翻译： 包含柔性高折射率层的抗反射膜，其包含分散在交联的有机材料中的至少60重量％的无机纳米颗粒，纳米颗粒具有至少1.60的折射率。 还描述了表面处理的纳米颗粒。
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3.发明授权Self-assembling antireflective coating comprising surface modified high refractive index nanoparticles 有权包含表面改性的高折射率纳米颗粒的自组装抗反射涂层公开(公告)号：US08202573B2
公开(公告)日：2012-06-19
申请号：US12670124
申请日：2008-09-02
申请人： Richard J. Pokorny , Thomas P. Klun , Marc D. Radcliffe , Robert F. Kamrath , Christopher B. Walker, Jr.
发明人： Richard J. Pokorny , Thomas P. Klun , Marc D. Radcliffe , Robert F. Kamrath , Christopher B. Walker, Jr.
IPC分类号： C09D163/00 , C09D171/00 , C09D201/00 , B05D7/00 , B05D5/06
CPC分类号： G02B1/11 , B82Y20/00 , C08K3/22 , C08K9/06 , C09D5/006 , C09D7/62 , G02B2207/101 , Y10T428/24942
摘要： Presently described are self-assembling antireflective (“AR”) coating compositions comprising high refractive index surface modified nanoparticles. Also described are various articles such as protective films, optical displays, and windows, comprising such (e.g. dried and cured) AR coating.
摘要翻译： 目前描述的是包含高折射率表面改性纳米颗粒的自组装抗反射（“AR”）涂层组合物。 还描述了包括这种（例如干燥和固化的）AR涂层的各种制品，例如保护膜，光学显示器和窗户。
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4.发明申请SELF-ASSEMBLING ANTIREFLECTIVE COATING COMPRISING SURFACE MODIFIED HIGH REFRACTIVE INDEX NANOPARTICLES 有权包含表面改性高折射率纳米粒子的自组装抗反射涂层公开(公告)号：US20100189970A1
公开(公告)日：2010-07-29
申请号：US12670124
申请日：2008-09-02
申请人： Richard J. Pokorny , Thomas P. Klun , Marc D. Radcliffe , Robert F. Kamrath , Christopher B. Walker, JR.
发明人： Richard J. Pokorny , Thomas P. Klun , Marc D. Radcliffe , Robert F. Kamrath , Christopher B. Walker, JR.
CPC分类号： G02B1/11 , B82Y20/00 , C08K3/22 , C08K9/06 , C09D5/006 , C09D7/62 , G02B2207/101 , Y10T428/24942
摘要： Presently described are self-assembling antireflective (“AR”) coating compositions comprising high refractive index surface modified nanoparticles. Also described are various articles such as protective films, optical displays, and windows, comprising such (e.g. dried and cured) AR coating.
摘要翻译： 目前描述的是包含高折射率表面改性纳米颗粒的自组装抗反射（“AR”）涂层组合物。 还描述了包括这种（例如干燥和固化的）AR涂层的各种制品，例如保护膜，光学显示器和窗户。
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公开(公告)号：US20120135210A1
公开(公告)日：2012-05-31
申请号：US13365313
申请日：2012-02-03
申请人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one free-radically polymerizable fluoropolymer and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有包含包含至少一种可自由基聚合的含氟聚合物和表面改性的无机纳米颗粒的可聚合低折射率组合物的反应产物的表面层的抗反射膜。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US08137801B2
公开(公告)日：2012-03-20
申请号：US12304505
申请日：2007-06-06
申请人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/265 , Y10T428/269 , Y10T428/3154 , Y10T428/31935
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US20100232021A1
公开(公告)日：2010-09-16
申请号：US12304505
申请日：2007-06-06
申请人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, JR. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254 , Y10T428/256 , Y10T428/265 , Y10T428/269 , Y10T428/3154 , Y10T428/31935
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one fluorinated free-radically polymerizable material and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有表面层的抗反射膜，该表面层包含包含至少一种氟化可自由基聚合材料和表面改性无机纳米颗粒的可聚合低折射率组合物的反应产物。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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公开(公告)号：US08343624B2
公开(公告)日：2013-01-01
申请号：US13365313
申请日：2012-02-03
申请人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
发明人： Christopher B. Walker, Jr. , Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , William D. Coggio , Chuntao Cao , Mark J. Pellerite , Paul C. Kelley , Robert J. Fleming
CPC分类号： G02B1/111 , Y10T428/24942 , Y10T428/25 , Y10T428/254
摘要： Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one free-radically polymerizable fluoropolymer and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.
摘要翻译： 描述了具有包含包含至少一种可自由基聚合的含氟聚合物和表面改性的无机纳米颗粒的可聚合低折射率组合物的反应产物的表面层的抗反射膜。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。
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9.发明申请公开(公告)号：US20080274352A1
公开(公告)日：2008-11-06
申请号：US11744318
申请日：2007-05-04
申请人： Encai Hao , Mark J. Pellerite , Marc D. Radcliffe , Lan H. Liu , Jeffrey A. Peterson , Stephen A. Johnson
发明人： Encai Hao , Mark J. Pellerite , Marc D. Radcliffe , Lan H. Liu , Jeffrey A. Peterson , Stephen A. Johnson
CPC分类号： G02B1/16 , B32B5/16 , C08J7/04 , C08J2301/12 , C08J2367/02 , C08J2481/00 , G02B1/11 , G02B1/116 , H01J2211/446 , H01J2329/8685 , Y10T428/269
摘要： Optical films are described that comprise an antistatic primer disposed on the substrate and a high refractive index layer disposed on the primer. The primer comprises a sulfopolymer and at least one antistatic agent. The high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antistatic agent is preferably selected from conductive inorganic particles, conductive polymer, and mixtures thereof. Also describes are antistatic compositions and surface treated conductive inorganic oxide particles.
摘要翻译： 描述了包含设置在基板上的抗静电底漆和设置在底漆上的高折射率层的光学膜。 底漆包含磺基聚合物和至少一种抗静电剂。 高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗静电剂优选选自导电无机颗粒，导电聚合物及其混合物。 还描述了抗静电组合物和表面处理的导电无机氧化物颗粒。
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10.发明授权Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film 有权氟（甲基）丙烯酸酯聚合物组合物适用于低折射率层的抗反射膜公开(公告)号：US08231973B2
公开(公告)日：2012-07-31
申请号：US12303584
申请日：2007-05-04
申请人： Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , Suresh Iyer , Zai-Ming Qiu
发明人： Marc D. Radcliffe , Thomas P. Klun , Lan H. Liu , Richard J. Pokorny , Suresh Iyer , Zai-Ming Qiu
CPC分类号： G02B1/111 , B32B7/02 , B32B27/08 , B32B27/20 , B32B27/285 , B32B27/302 , B32B27/308 , B32B27/322 , B32B27/36 , B32B2264/102 , B32B2264/105 , B32B2307/418 , B32B2307/554 , B32B2457/00 , B32B2551/00 , B32B2551/08 , B32B2605/08 , B32B2605/18 , Y10T428/3154
摘要： Antireflective film articles and low refractive index coating compositions are described that comprises a fluorinated free-radically polymerizable polymeric (e.g. intermediate) material. The free-radically polymerizable fluorinated polymeric intermediate comprises the reaction product of i) at least one multi-functional free-radically polymerizable material having a fluorine content of at least 25 wt-%, and ii) optionally other multi-functional free-radically polymerizable material. The total amount of multi-functional materials is preferably at least about 25 wt-%.
摘要翻译： 描述了包含氟化可自由基聚合的聚合物（例如中间体）材料的抗反射膜制品和低折射率涂料组合物。 可自由基聚合的氟化聚合物中间体包含i）至少一种氟含量至少为25重量％的多官能可自由基聚合材料的反应产物，和ii）任选其它多官能可自由基聚合的 材料。 多功能材料的总量优选为至少约25重量％。
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