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    Oil-free elastomeric poly(aryloxyphosphazene) copolymers
    2.
    发明授权
    Oil-free elastomeric poly(aryloxyphosphazene) copolymers 失效
    无油弹性聚（芳氧基磷腈）共聚物

    公开(公告)号：US4179555A

    公开(公告)日：1979-12-18

    申请号：US919888

    申请日：1978-06-28

    申请人： Tai C. Cheng ,  John W. Fieldhouse ,  Arthur E. Oberster ,  Daniel F. Graves

    发明人： Tai C. Cheng ,  John W. Fieldhouse ,  Arthur E. Oberster ,  Daniel F. Graves

    IPC分类号： C08G79/00 ,  C08G79/02 ,  C08G79/04 ,  C08J9/10 ,  C08L85/00 ,  C08L85/02 ,  C09D185/00 ,  H01B3/30

    CPC分类号： C08J9/10 ,  C08G79/025 ,  C08L85/02 ,  H01B3/30 ,  C08J2385/02 ,  Y10T428/294

    摘要： Poly(aryloxyphosphazene) copolymers are prepared having randomly repeating units represented by the formula: ##STR1## wherein R and R.sup.1 may be the same or different and are selected from the group consisting of monovalent aryl radicals and substituted aryl radicals having the structure: ##STR2## wherein X is a substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, amino and halogen substituted on any sterically permissible position on the phenyl group; and wherein the amount of Cl present in the form of P--C1 bonds is from about 0.4 percent to about 10 percent by weight based upon the total weight of copolymer.The copolymers may contain minor proportions of randomly distributed units in addition to the repeating units described above, these additional units containing reactive sites enabling the properties of the copolymers to be modified by crosslinking and/or curing.The copolymers are elastomeric even in the absence of low molecular weight polyphosphazene oils. The copolymers are curable by a variety of curing agents such as sulfur and peroxides, and can also be cured by radiation and ultraviolet light. The copolymers may be utilized in various applications such as foams and coatings, and are particularly suited for use in wire coating formulations.

    摘要翻译： 制备具有由下式表示的无规重复单元的聚（芳氧基磷腈）共聚物：其中R和R 1可以相同或不同，并且选自具有以下结构的一价芳基和取代的芳基：其中X是选自烷基，烷氧基，芳基，芳氧基，氨基和在苯基上的任何空间上允许的位置上取代的卤素的取代基; 并且其中以P-C1键形式存在的Cl的量为基于共聚物总重量的约0.4重量％至约10重量％。 除了上述重复单元之外，共聚物可以含有少量的随机分布的单元，这些含有能够通过交联和/或固化来改性共聚物性质的反应性位点的这些附加单元。 即使在不存在低分子量聚磷腈油的情况下，共聚物也是弹性体。 共聚物可通过各种固化剂如硫和过氧化物固化，并且还可以通过辐射和紫外光固化。 共聚物可以用于各种应用中，例如泡沫和涂料，并且特别适用于丝线涂布配方。

    Chemical modification of poly(bis-aryloxyphosphazene) with amines
    3.
    发明授权
    Chemical modification of poly(bis-aryloxyphosphazene) with amines 失效
    聚（双 - 芳氧基磷腈）与胺的化学改性

    公开(公告)号：US4130547A

    公开(公告)日：1978-12-19

    申请号：US844018

    申请日：1977-10-20

    申请人： John W. Fieldhouse

    发明人： John W. Fieldhouse

    IPC分类号： C08L85/00 ,  C08G79/00 ,  C08G79/02 ,  C08L85/02 ,  C08G79/04

    CPC分类号： C08G79/025

    摘要： Improvement of the polyaryloxy and polyalkylaryloxy-phosphazenes such as those described in U.S. Pat. No. 3,853,794 is achieved by treating such polyphosphazenes with organic amines, preferably in solution. The polyphosphazenes are chemically modified as a result of such treatment and are converted from tough fibrous materials to relatively soft readily processed products.

    摘要翻译： （PG，1）改进了聚芳氧基和聚烷氧基 - 磷腈，如美国专利No. 通过用有机胺处理这种聚磷腈，优选在溶液中来实现3,853,794。 作为这种处理的结果，聚磷腈被化学改性，并且由韧性纤维材料转变成相对柔软的容易加工的产品。

    Contact adhesive and adhesive system for EPDM elastomers
    4.
    发明授权
    Contact adhesive and adhesive system for EPDM elastomers 失效
    接触EPDM弹性体的粘合剂和粘合剂系统

    公开(公告)号：US4657958A

    公开(公告)日：1987-04-14

    申请号：US827456

    申请日：1986-02-11

    申请人： John W. Fieldhouse ,  Mark L. Stayer

    发明人： John W. Fieldhouse ,  Mark L. Stayer

    IPC分类号： C09J123/32 ,  C08K5/01 ,  C08K3/36 ,  C08K5/17 ,  C08K5/05

    CPC分类号： C09J123/32

    摘要： Adhesive compositions for bonding EPDM elastomers comprise (a) a neutralized sulfonated EPDM elastomeric terpolymer; (b) an organic hydrocarbon solvent; (c) an ionic plasticizer or mixture of ionic plasticiziers; (d) a phenolic hydrocarbon resin or mixture of phenolic hydrocarbon resins and (e) a material selected from mineral oils, petroleum oils, polybutenes, polyisobutylenes and ethylene/propylene copolymers. Such adhesive compositions are particularly suitable for bonding sheets of black EPDM, especially sheets of cured black EPDM, elastomeric membranes together and may also be utilized to bond sheets of cured black EPDM to other uncured elastomers and to non-elastomeric substrates as well.The adhesive compositions to proper selection of the component (e) material and the addition of a color pigment or dye thereto may also be used to bond colored EPDM elastomers such as white, blue, yellow, green, etc.An adhesive composition for bonding sheets of EPDM elastomeric roofing membrane in cases where the membrane is to be anchored to the roof surface by mechanical systems will further contain a hydrophobic silica.

    摘要翻译： 用于粘合EPDM弹性体的粘合剂组合物包含（a）中和的磺化EPDM弹性体三元共聚物; （b）有机烃溶剂; （c）离子增塑剂或离子塑化剂的混合物; （d）酚醛树脂或酚醛树脂的混合物和（e）选自矿物油，石油，聚丁烯，聚异丁烯和乙烯/丙烯共聚物的材料。 这种粘合剂组合物特别适合于将黑色EPDM的片材，特别是固化的黑色EPDM片材，弹性体膜粘合在一起，并且还可以用于将固化的黑色EPDM的片材与其它未固化的弹性体和非弹性体基材结合。 用于适当选择组分（e）材料和向其中添加着色颜料或染料的粘合剂组合物也可以用于粘合着色的EPDM弹性体如白色，蓝色，黄色，绿色等。用于粘合片材的粘合剂组合物 在通过机械系统将膜锚定到屋顶表面的情况下，EPDM弹性体屋顶膜将进一步含有疏水性二氧化硅。

    Adhesive tape compositions and method for covering roofs
    8.
    发明授权
    Adhesive tape compositions and method for covering roofs 失效
    胶带组合物和覆盖屋顶的方法

    公开(公告)号：US5859114A

    公开(公告)日：1999-01-12

    申请号：US626710

    申请日：1996-04-01

    申请人： James A. Davis ,  John W. Fieldhouse

    发明人： James A. Davis ,  John W. Fieldhouse

    IPC分类号： C09J7/00 ,  C09J7/02 ,  C09J121/00 ,  C09J123/16 ,  E04D5/14 ,  C08L51/04

    CPC分类号： C09J123/16 ,  E04D5/142 ,  E04D5/148

    摘要： An adhesive tape composition includes a polymer blend comprising at least one ethylene-propylene-diene terpolymer and at least one fully saturated adhesive-enhancing polymer miscible with said at least one ethylene-propylene-diene terpolymer. The tape adhesive composition further includes at least one tackifying additive compatible with said polymer blend and a sulfur and organic accelerator cure package for said polymer blend, the adhesive composition being devoid of butyl rubber which is found in most other adhesive tape compositions. This composition is seen as providing excellent long-term heat aging, weathering resistance, and low temperature properties as compared to adhesive tape compositions containing butyl rubber. Moreover, the adhesive tape composition provides more surface tack, better "quick-grab", and higher green strength as compared to adhesive tape compositions containing 100 percent EPDM rubber. A method is also provided for covering roofs which includes the step of employing the adhesive tape composition.

    摘要翻译： 胶带组合物包括包含至少一种乙烯 - 丙烯 - 二烯三元共聚物和至少一种与所述至少一种乙烯 - 丙烯 - 二烯三元共聚物可混合的完全饱和粘合剂增强聚合物的聚合物共混物。 胶带粘合剂组合物还包括与所述聚合物共混物相容的至少一种增粘添加剂和用于所述聚合物共混物的硫和有机促进剂固化包，所述粘合剂组合物没有在大多数其它粘合带组合物中存在的丁基橡胶。 与含有丁基橡胶的胶带组合物相比，该组合物被认为是提供优异的长期热老化，耐候性和低温性能。 此外，与含有100％EPDM橡胶的胶带组合物相比，胶带组合物提供更多的表面粘着性，更好的“快速抓取”和更高的生坯强度。 还提供了一种用于覆盖屋顶的方法，其包括使用胶带组合物的步骤。

    Surface treatment for tack reduction of elastomer surfaces
    9.
    发明授权
    Surface treatment for tack reduction of elastomer surfaces 失效
    表面处理用于弹性体表面的降粘

    公开(公告)号：US4521479A

    公开(公告)日：1985-06-04

    申请号：US498380

    申请日：1983-05-26

    申请人： Ralph A. Maglio ,  John W. Fieldhouse

    发明人： Ralph A. Maglio ,  John W. Fieldhouse

    IPC分类号： C08J7/04 ,  C08L23/16 ,  B32B23/04 ,  B32B25/04

    CPC分类号： C08J7/047 ,  C08L23/16 ,  C08J2323/16 ,  C08J2401/00 ,  C08L2312/00 ,  Y10T428/253 ,  Y10T428/3188

    摘要： A method for reducing the surface tack of EPDM and related elastomers is provided. The method involves coating the surfaces of the elastomer with particulate cellulose. Sheets of cellulose coated elastomer can be subjected to rolling up and curing operations without encountering surface sticking problems. In addition, the cellulose coated surfaces of the elastomer can be bonded together for the purpose of forming splices or seams without the necessity for first removing the cellulose coating.

    摘要翻译： 提供了降低EPDM和相关弹性体的表面粘性的方法。 该方法包括用颗粒状纤维素涂覆弹性体的表面。 纤维素涂层弹性体的片材可以进行卷起和固化操作，而不会遇到表面粘附问题。 此外，弹性体的纤维素涂覆表面可以结合在一起，以形成接头或接缝，而不需要首先除去纤维素涂层。

    Process for the production of phosphazene polymers
    10.
    发明授权
    Process for the production of phosphazene polymers 失效
    磷腈聚合物的制备方法

    公开(公告)号：US4129529A

    公开(公告)日：1978-12-12

    申请号：US824004

    申请日：1977-08-12

    申请人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    发明人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    IPC分类号： C08G79/02 ,  C08G73/00

    CPC分类号： C08G79/025

    摘要： The production of phosphazene polymers represented by the general formula ##STR1## WHEREIN N IS AN INTEGER FROM 7 TO UPWARDS OF 50,000 WHEREIN ONE OR MORE KINDS OF OR or OR' groups is attached to the phosphorus atoms in a substantially linear chain of alternating P and N atoms, the groups when more than one group is present being randomly distributed along the PN backbone, is enhanced by employing a single solvent for both each of the reactants (polydihalophosphazene and either aryloxide and/or alkoxide) and for the product (phosphazene polymer). By this expedient, the formation of the desired product is achieved in a homogeneous system rather than in a heterogeneous system as in the prior art where different solvents were employed for each of the reactants and for the reaction products.

    摘要翻译： {PG，1}由通式{r1 {tc，1 {rb {ab，44 {m，1 {sb，21 {us，5 {ob，4 {mr，1P {M， 1 {AB，2 OR {MR，1 {AB，6 OR {40 {MR，1 {AD，44 N {AB，44 {SB，21 {US，5 {CB，4 {S，6 { {HD {{{{{{{{{{N {N} N = 1，从7到UPWARDS为50,000，其中一种或多种OR或OR {40 {0组连接在交替的P和N的基本线性链中的磷原子 原子，当存在多于一个基团时的基团通过使用单一溶剂用于每种反应物（聚二卤代膦和芳氧化物和/或醇盐）和对于产物（磷腈聚合物）而增强， 。 通过这种方法，所需产物的形成在均匀系统中而不是在异构体系中实现，如在现有技术中，其中对于每种反应物和反应产物使用不同的溶剂。