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1.发明授权
公开(公告)号：US4914070A
公开(公告)日：1990-04-03
申请号：US254149
申请日：1988-10-06
IPC分类号： B01D53/86 , B01D53/94 , B01J27/224 , C01B31/36 , C10G49/02
CPC分类号： B01D53/945 , B01J27/224 , C01B31/36 , C10G49/02 , C01P2002/54 , C01P2006/12 , C01P2006/60 , Y02C20/20 , Y02T10/22
摘要： The invention is directed to a process for the production of fine grains of silicon carbide which are formed by an agglomerate of submicronic grains having a specific surface area that is at least 100 m.sup.2 .multidot.g.sup.-1, which are intended in particular to serve as a carrier for catalysts for petrochemistry, and for catalytic reactions at elevated temperature which can attain 1000.degree. C., the process comprising reacting vapors of silicon monoxide SiO on carbon, being characterized by: generating vapors of SiO in a first reaction zone by heating a mixture SiO.sub.2 +Si at a temperature of between 1100.degree. and 1400.degree. C., under a pressure of between 0.1 and 1.5 hPa; and, in a second reaction zone, contacting the SiO vapors with reactive carbon in the divided state with a specific surface area that is at least equal to 200 m.sup.2 .multidot.g.sup.-1 at a temperature of between 1100.degree. and 1400.degree. C. Preferably, the reactive carbon is doped by an addition of from 1 to 10% by weight of a metallic element selected from uranium, cerium, titanium, zirconium, hafnium and lanthanides.
摘要翻译： 本发明涉及一种用于生产碳化硅微细颗粒的方法，该方法由具有至少100m 2×g -1的比表面积的亚微米颗粒的聚集体形成，特别是用作载体 用于石油化学的催化剂，以及在可以达到1000℃的升高的温度下进行催化反应，该方法包括使一氧化碳SiO的蒸汽反应在碳上，其特征在于：通过加热混合物SiO 2 +产生第一反应区中的SiO的蒸汽， Si在1100至1400℃的温度下，在0.1至1.5hPa的压力下; 并且在第二反应区中，使分解状态的SiO蒸气与至少等于200m 2×g-1的比表面积在1100〜1400℃的温度下接触。优选地，反应性 通过加入1至10重量％的选自铀，铈，钛，锆，铪和镧系元素的金属元素来掺杂碳。
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公开(公告)号：US08163171B2
公开(公告)日：2012-04-24
申请号：US11311005
申请日：2005-12-19
申请人： Thomas Andrew Gribschaw , Sylvain Hantzer , Stephen John McCarthy , Steven E. Silverberg , Vijay Swarup
发明人： Thomas Andrew Gribschaw , Sylvain Hantzer , Stephen John McCarthy , Steven E. Silverberg , Vijay Swarup
CPC分类号： B01J29/043 , B01J2229/20 , B01J2229/42 , C10G45/54 , C10G65/08 , C10G2300/1051 , C10G2300/1055 , C10G2300/1096 , C10G2300/301 , C10G2300/4018 , C10G2400/02 , C10G2400/06
摘要： The invention relates to hydrocarbon fluids having high purity with respect to at least one of sulfur species, nitrogen species, oxygenated species, and unsaturated species, particularly hydrocarbon fluids low in aromatics, a method of making said hydrocarbon fluids, a catalyst for use in said method, an apparatus whereby said method may be practiced, and uses of said fluids.
摘要翻译： 本发明涉及相对于硫物种，氮物质，氧化物质和不饱和物质，特别是芳族化合物中的烃类流体中的至少一种，具有高纯度的烃流体，制备所述烃流体的方法，用于所述 方法，可以实施所述方法的装置以及所述流体的使用。
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3.发明申请Process for improving basestock low temeperature performance using a combination catalyst system 审中-公开使用组合催化剂体系提高基础油低温性能的方法公开(公告)号：US20060142142A1
公开(公告)日：2006-06-29
申请号：US10532143
申请日：2002-11-12
申请人： William Murphy , Ian Cody , Robert Wittenbrink , Stuart Soled , Gary McVicker , Sylvain Hantzer , Sandra Linek
发明人： William Murphy , Ian Cody , Robert Wittenbrink , Stuart Soled , Gary McVicker , Sylvain Hantzer , Sandra Linek
IPC分类号： B01J29/04
CPC分类号： B01J29/064 , B01J21/12 , B01J23/42 , B01J23/44 , B01J29/068 , B01J29/44 , B01J29/7484 , B01J35/0006 , C10G2400/10
摘要： Waxy feeds are converted to a basestock using a unitized mixed powdered pellet catalyst comprising a metal hydrogenation component on a support having a frist dewaxing component and a second isomerization component, wherein the first component is selected from 10 and 12 ring molecular sieves and mixtures thereof and the second component is an amorphous inorganic oxide. The first and second components are present in a ratio sufficient to promote wax isomerization and naphthene distractions without substantial decrease in VI.
摘要翻译： 将蜡状饲料转化为基础油料，使用包含金属氢化组分的单体化混合粉末颗粒催化剂在具有四分体脱蜡组分和第二异构化组分的载体上，其中第一组分选自10和12个环分子筛及其混合物， 第二组分是无定形无机氧化物。 第一和第二组分以足以促进蜡异构化和环烷烃分散而不显着降低VI的比例存在。
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公开(公告)号：US20060138023A1
公开(公告)日：2006-06-29
申请号：US10532142
申请日：2002-11-12
申请人： William Murphy , Gary McVicker , Sylvain Hantzer , Ian Cody , Stuart Soled , Sandra Linek , Joseph Baumgartner
发明人： William Murphy , Gary McVicker , Sylvain Hantzer , Ian Cody , Stuart Soled , Sandra Linek , Joseph Baumgartner
IPC分类号： C10G73/38
CPC分类号： B01J29/7484 , B01J23/40 , B01J29/068 , B01J29/44 , B01J29/80 , B01J35/0006 , B01J35/0066 , C10G45/64 , C10G2400/10
摘要： A method for hydroisomerizing a waxy feed to favor one of VI or yield is described. The method uses a unitized pellet powder catalyst comprising a metal hydrogeneration component, a first catalytic component selected from 8, 10 and 12 ring moleular sieves and mixtures thereof, and a second amorphous isomerization component which is an amorphous inorganic oxide. Importantly, the ratio of feed and second components are present in a predetermined ratio to provide a preselected acidity favoring one of VI or yield resulting from the hydroisomerization.
摘要翻译： 描述了用于使蜡质进料加氢异构化以有利于VI中的一种或产率的方法。 该方法使用包含金属加氢成分，选自8,10和12个环状筛子及其混合物的第一催化剂组分和作为无定形无机氧化物的第二无定形异构化组分的组合颗粒粉末催化剂。 重要的是，进料和第二组分的比例以预定的比例存在，以提供有利于VI中的一种的预选酸度或由加氢异构化产生的收率。
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5.发明授权公开(公告)号：US06221240B1
公开(公告)日：2001-04-24
申请号：US09326827
申请日：1999-06-07
申请人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
发明人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
IPC分类号： C10G4500
CPC分类号： C10G25/003 , C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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公开(公告)号：US10016747B2
公开(公告)日：2018-07-10
申请号：US14887492
申请日：2015-10-20
CPC分类号： B01J29/703 , B01J29/74 , C10G45/62 , C10G45/64 , C10G65/043 , C10G65/12 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10M101/02
摘要： Methods are provided for using a dewaxing catalyst formed using at least two structure directing agents for production of a lubricant base stock. For example, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic production of lubricant base stocks. Additionally or alternately, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can provide improved aromatic saturation during processing of a feed for lubricant base stock production.
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公开(公告)号：US20160121315A1
公开(公告)日：2016-05-05
申请号：US14887492
申请日：2015-10-20
IPC分类号： B01J29/70 , C10G65/04 , C10G65/12 , C10M101/02 , C10G45/64
CPC分类号： B01J29/703 , B01J29/74 , C10G45/64 , C10G65/043 , C10G65/12 , C10M101/02
摘要： Methods are provided for using a dewaxing catalyst formed using at least two structure directing agents for production of a lubricant base stock. For example, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic production of lubricant base stocks. Additionally or alternately, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can provide improved aromatic saturation during processing of a feed for lubricant base stock production.
摘要翻译： 提供了使用至少两种用于生产润滑剂基础原料的结构导向剂形成的脱蜡催化剂的方法。 例如，使用多个引导剂（和/或使用这种晶体制备的配制的催化剂）形成的ZSM-48晶体可以具有增加的活性和/或可以在催化生产润滑剂基础油料时提供改善的产率。 另外或替代地，使用多个引导剂（和/或使用这种晶体制备的配制的催化剂）形成的ZSM-48晶体可以在用于润滑剂原料生产的进料的加工期间提供改善的芳族饱和度。
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公开(公告)号：US08366908B2
公开(公告)日：2013-02-05
申请号：US12655120
申请日：2009-12-23
申请人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
发明人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译： 提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。 在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。
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9.发明授权公开(公告)号：US07220350B2
公开(公告)日：2007-05-22
申请号：US10678690
申请日：2003-10-03
申请人： Ian A. Cody , William J. Murphy , Sylvain Hantzer
发明人： Ian A. Cody , William J. Murphy , Sylvain Hantzer
CPC分类号： B01J29/7461 , B01J29/068 , B01J37/10 , B01J37/12 , B01J2229/12 , B01J2229/34 , C10G45/02 , C10G45/58 , C10G45/60 , C10G45/62 , C10G45/64 , C10G65/043
摘要： A waxy hydrocarbon feed is catalytically treated with a dewaxing catalyst that has been selectively activated. The selective activation of the catalyst involves treating the catalyst with at least one oxygenate. The selectively activated catalyst can then be used to dewax waxy hydrocarbon to improve yield and product quality of the isomerate product.
摘要翻译： 用选择性活化的脱蜡催化剂对蜡状烃进料进行催化处理。 催化剂的选择性活化涉及用至少一种含氧化合物处理催化剂。 然后选择性活化的催化剂可用于脱蜡蜡质烃以提高异构产物的产率和产品质量。
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10.发明申请公开(公告)号：US20060070916A1
公开(公告)日：2006-04-06
申请号：US11205641
申请日：2005-08-17
CPC分类号： B01J29/0325 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C10G45/46 , C10G45/52 , C10G45/54 , C10G2400/10
摘要： An improved aromatics saturation process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof, a mesoporous support, and a binder.
摘要翻译： 改进的芳族化合物饱和方法，其用于使用含有选自VIII族贵金属及其混合物，中孔载体和粘合剂的氢化 - 脱氢组分的催化剂的润滑油沸程进料流。
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