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    Process to produce polyalphaolefins
    3.
    发明授权
    Process to produce polyalphaolefins 有权
    生产聚α-烯烃的方法

    公开(公告)号：US08513478B2

    公开(公告)日：2013-08-20

    申请号：US11832287

    申请日：2007-08-01

    申请人： Margaret M. Wu ,  Mark P. Hagemeister ,  Norman Yang

    发明人： Margaret M. Wu ,  Mark P. Hagemeister ,  Norman Yang

    IPC分类号： C07C2/22

    CPC分类号： C08F10/00 ,  C08F110/14 ,  Y02P20/582 ,  C08F4/65912 ,  C08F4/65927 ,  C08F4/65908 ,  C08F2500/03 ,  C08F2500/17

    摘要： Liquid poly-alpha-olefins having a KV100 of 2 to 6000 cSt, 20 weight percent dimer or less and a viscosity index of 60 or more are obtained by contacting in a reaction zone, in the presence of from 0 to 60 psi hydrogen, C3 to C20 alpha-olefin monomers with a non-coordinating anion activator, a single bridged meso-metallocene transition metal compound having less than about 35 wt % racemic isomer, and a co-activator. The molar ratio of activator to meso-metallocene is from 10:1 to 0.1:1, and the alpha-olefin monomers in the feed components are present in at least 20 wt % or more based upon the weight of the meso-metallocene, non-coordinating anion activator, co-activator, monomers, and solvent or diluent. The productivity of the process is at least 50,000 g of total product per gram of transition metal compound and no more than 5% monomer is converted from olefin to alkane.

    摘要翻译： 通过在0至60psi的氢气，C3的存在下在反应区中接触，获得KV100为2至6000cSt，20重量％的二聚物或更低的粘度指数为60或更大的液体聚α-烯烃， 具有非配位阴离子活化剂的C 20α-烯烃单体，具有小于约35重量％外消旋异构体的单桥连内消旋金属茂过渡金属化合物和共活化剂。 活化剂与内消旋金属茂的摩尔比为10:1至0.1:1，并且进料组分中的α-烯烃单体以基于内消旋金属茂的重量计至少为20重量％或更多， 配位阴离子活化剂，共活化剂，单体和溶剂或稀释剂。 该方法的生产率为每克过渡金属化合物至少50,000g总产物，并且不超过5％的单体由烯烃转化为烷烃。

    Process To Produce Polyalphaolefins
    4.
    发明申请
    Process To Produce Polyalphaolefins 有权
    生产聚α-烯烃的方法

    公开(公告)号：US20090036725A1

    公开(公告)日：2009-02-05

    申请号：US11832287

    申请日：2007-08-01

    申请人： Margaret M. Wu ,  Mark P. Hagemeister ,  Norman Yang

    发明人： Margaret M. Wu ,  Mark P. Hagemeister ,  Norman Yang

    IPC分类号： C07C2/02

    CPC分类号： C08F10/00 ,  C08F110/14 ,  Y02P20/582 ,  C08F4/65912 ,  C08F4/65927 ,  C08F4/65908 ,  C08F2500/03 ,  C08F2500/17

    摘要： The present invention relates to processes to produce liquid poly-alpha-olefins comprising: a) contacting in a reaction zone, in the presence of from 0 to 60 psi hydrogen, one or more C3 to C20 alpha-olefin monomers with a non-coordinating anion activator, a single bridged meso-metallocene transition metal compound having less than about 35 wt % racemic isomer, and a co-activator selected from the group consisting of alkyl aluminum compounds and alkyl alumoxanes, provided that when the alkyl alumoxane is present it is present in a molar ratio of less than 0.1:1 of alkylalumoxane to meso-metallocene, and provided that when the alkyl aluminum compound is present it is present at a molar ratio of alkyl aluminum to meso-metallocene of from 2:1 to 10,000 to 1, where the molar ratio of activator to meso-metallocene is from 10:1 to 0.1:1, and provided that ethylene is not present at more than 30 volume % of the monomers entering the reaction zone, and provided that the alpha-olefin monomers in the feed components are present in at least 20 wt % or more based upon the weight of the meso-metallocene, non-coordinating anion activator, co-activator, monomers, and solvent or diluent, and where: i) the productivity of the process is at least 50,000 g of total product per gram of transition metal compound (where the total product is defined to be the total amount of product exiting the reactor, minus unreacted monomers and solvents); and ii) no more than 5% monomer is converted from olefin to alkane; and b) obtaining a liquid polyalphaolefin product having a pour point of less than 25° C., a KV100 of 2 to 6000 cSt, 20 weight percent dimer or less and a viscosity index of 60 or more.

    摘要翻译： 本发明涉及制备液体聚-α-烯烃的方法，包括：a）在0至60psi氢气存在下，在反应区中使一个或多个C 3至C 20α-烯烃单体与非配位的 阴离子活化剂，具有小于约35重量％外消旋异构体的单桥连的内消旋 - 金属茂过渡金属化合物，以及选自烷基铝化合物和烷基铝氧烷的共活化剂，条件是当烷基铝氧烷存在时，它是 以烷基铝氧烷与内消旋金属茂的摩尔比小于0.1:1存在，并且当烷基铝化合物存在时，其烷基铝与内消旋金属茂的摩尔比为2:1至10,000至 1，其中活化剂与内消旋金属茂的摩尔比为10:1至0.1:1，并且条件是进入反应区的单体的体积百分比不超过30体积％，并且条件是α-烯烃 单体i 基于内消旋金属茂，非配位阴离子活化剂，共活化剂，单体和溶剂或稀释剂的重量，进料组分以至少20重量％或更多的重量存在，其中：i） 每克过渡金属化合物的总产物至少为50,000g（其中总产物定义为离开反应器的产物的总量，减去未反应的单体和溶剂）; 和ii）不超过5％的单体从烯烃转化为烷烃; 和b）获得倾点小于25℃，KV100为2至6000cSt，20重量％二聚物或更低，粘度指数为60以上的液体聚α-烯烃产物。