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    Surfactants to create dispersions in fluorinated liquids
    1.
    发明授权
    Surfactants to create dispersions in fluorinated liquids 失效
    在氟化液体中产生分散体的表面活性剂

    公开(公告)号：US5844034A

    公开(公告)日：1998-12-01

    申请号：US847192

    申请日：1997-05-01

    申请人： Mark W. Grenfell ,  Richard M. Flynn ,  Patricia M. Savu

    发明人： Mark W. Grenfell ,  Richard M. Flynn ,  Patricia M. Savu

    IPC分类号： C11D7/50 ,  C08J3/09 ,  C08K5/095 ,  C08K5/20 ,  C08K5/435 ,  C09D127/12 ,  C09D133/02 ,  C09D139/06 ,  C11D7/60 ,  C08K5/02 ,  C08K5/05 ,  C08K5/06 ,  C08L27/12

    CPC分类号： C08J3/09 ,  C08K5/095 ,  C08K5/20 ,  C08K5/435 ,  C08J2327/12

    摘要： This invention provides a fluoropolymer dispersion useful for coating applications. The dispersion is a homogeneous and non-ozone depleting dispersion comprising a lubricious fluoropolymer, an inert perfluorinated liquid, a polar solvent, and an effective amount of a surface active agent selected from the group consisting of a. perfluoroaliphatic amidoalkanols; b. polymerized products formed from the reaction of a mixture comprising a hydrophilic monomer and a monomer of the general formula: ##STR1## wherein p and q are integers between 1 and 4 inclusive, x and y are integers between 0 and 4 inclusive, m is 1 or 2, n is an integer between 3 and 10 inclusive, X' is either a methyl group or a single hydrogen atom, g is 0 or 1, and Q is a sulfonamido constituent group according to the formula: ##STR2## wherein R.sup.1 is a hydrogen or a lower alkyl group having from 1 to 6 carbon atoms and wherein the hydrophilic monomer is present in an amount constituting inclusively between five and twenty-five weight percent of the reactant mixture when the polar solvent employed is a polar organic solvent and wherein the hydrophilic monomer is present in an amount constituting inclusively between one and twenty-five weight percent of the reactant mixture when the polar solvent employed is water; and c. Perfluorinated ether acids according to the general formula: ##STR3## wherein z is between 1 and 10 inclusive, s is between 0 to 4, t is between 0 to 4, v between 0 to 5, w is 0 or 1, and Y is either F or CF.sub.3.

    摘要翻译： 本发明提供了一种可用于涂料应用的含氟聚合物分散体。 分散体是均匀的和非消耗臭氧的分散体，其包含润滑的含氟聚合物，惰性全氟化液体，极性溶剂和有效量的选自a的表面活性剂。 全氟脂族酰氨基链烷醇; b。 由包含亲水单体和单体的混合物反应形成的由以下通式表示的聚合产物：其中p和q是包括1和4的整数，x和y是0和4之间的整数，其中m是1 或2，n为3〜10的整数，X'为甲基或单个氢原子，g为0或1，Q为根据下式的亚磺酰氨基成分基团：其中R1为 氢或具有1至6个碳原子的低级烷基，并且当所用的极性溶剂是极性有机溶剂时，所述亲水性单体以占所述反应物混合物的5至25重量％的量包含在其中的量存在，并且其中 当所使用的极性溶剂是水时，亲水性单体以包含在反应物混合物的一种和25重量％之间的量存在; 和c。 全氟化醚酸，其通式如下：其中z在1和10之间，其中s在0至4之间，t在0至4之间，v在0至5之间，w为0或1，Y为 F或CF3。

    Surfactants to create fluoropolymer dispersions in fluorinated liquids
    2.
    发明授权
    Surfactants to create fluoropolymer dispersions in fluorinated liquids 失效
    在氟化液体中形成氟聚合物分散体的表面活性剂

    公开(公告)号：US5660888A

    公开(公告)日：1997-08-26

    申请号：US646154

    申请日：1996-05-07

    申请人： Mark W. Grenfell ,  Richard M. Flynn ,  Patricia M. Savu

    发明人： Mark W. Grenfell ,  Richard M. Flynn ,  Patricia M. Savu

    IPC分类号： C11D7/50 ,  C08J3/09 ,  C08K5/095 ,  C08K5/20 ,  C08K5/435 ,  C09D127/12 ,  C09D133/02 ,  C09D139/06 ,  C11D7/60 ,  B05D5/00

    CPC分类号： C08J3/09 ,  C08K5/095 ,  C08K5/20 ,  C08K5/435 ,  C08J2327/12

    摘要： This invention provides a fluoropolymer dispersion useful for coating applications, The dispersion is a homogeneous and non-ozone depleting dispersion comprising a lubricious fluoropolymer, an inert perfluorinated liquid, a polar solvent, and an effective amount of a surface active agent selected from the group consisting of:a. perfluoroaliphatic amidoalkanols;b. polymerized products formed from the reaction of a mixture comprising a hydrophilic monomer and a monomer of the general formula: ##STR1## wherein p and q are integers between 1 and 4 inclusive, x and y are integers between 0 and 4 inclusive, m is 1 or 2, n is an integer between 3 and 10 inclusive, X' is either a methyl group or a single hydrogen atom, g is 0 or 1, and Q is a sulfonamido constituent group according to the formula: ##STR2## wherein R.sup.1 is a hydrogen or a lower alkyl group having from 1 to 6 carbon atoms and wherein the hydrophilic monomer is present in an amount constituting inclusively between five and twenty-five weight percent of the reactant mixture when the polar solvent employed is a polar organic solvent and wherein the hydrophilic monomer is present in an amount constituting inclusively between one and twenty-five weight percent of the reactant mixture when the polar solvent employed is water; andc. Perfluorinated ether acids according to the general formula: ##STR3## wherein z is between 1 and 10 inclusive, s is between 0 to 4, t is between 0 to 4, v between 0 to 5, w is 0 or 1, and Y is either F or CF.sub.3.

    摘要翻译： 本发明提供了一种可用于涂料应用的含氟聚合物分散体。该分散体是均匀的和非消耗臭氧的分散体，其包含润滑含氟聚合物，惰性全氟化液体，极性溶剂和有效量的表面活性剂，所述表面活性剂选自 的：a。 全氟脂族酰氨基链烷醇; b。 由包含亲水单体和单体的混合物反应形成的由以下通式表示的聚合产物：其中p和q是包括1和4的整数，x和y是0和4之间的整数，其中m是1 或2，n为3〜10的整数，X'为甲基或单个氢原子，g为0或1，Q为根据下式的亚磺酰氨基成分基团：其中R1为 氢或具有1至6个碳原子的低级烷基，并且当所用的极性溶剂是极性有机溶剂时，所述亲水性单体以占所述反应物混合物的5至25重量％的量包含在其中的量存在，并且其中 当所使用的极性溶剂是水时，亲水性单体以包含在反应物混合物的一种和25重量％之间的量存在; 和c。 全氟化醚酸，其通式如下：其中z在1和10之间，其中s在0至4之间，t在0至4之间，v在0至5之间，w为0或1，Y为 F或CF3。

    Surfactants to create fluoropolymer dispersions in fluorinated liquids
    3.
    发明授权
    Surfactants to create fluoropolymer dispersions in fluorinated liquids 失效
    在氟化液体中形成氟聚合物分散体的表面活性剂

    公开(公告)号：US5532310A

    公开(公告)日：1996-07-02

    申请号：US430556

    申请日：1995-04-28

    申请人： Mark W. Grenfell ,  Richard M. Flynn ,  Patricia M. Savu

    发明人： Mark W. Grenfell ,  Richard M. Flynn ,  Patricia M. Savu

    IPC分类号： C11D7/50 ,  C08J3/09 ,  C08K5/095 ,  C08K5/20 ,  C08K5/435 ,  C09D127/12 ,  C09D133/02 ,  C09D139/06 ,  C11D7/60 ,  C08K5/02 ,  C08K5/16 ,  C08L27/12 ,  C08L27/18

    CPC分类号： C08J3/09 ,  C08K5/095 ,  C08K5/20 ,  C08K5/435 ,  C08J2327/12

    摘要： This invention provides a fluoropolymer dispersion useful for coating applications. The dispersion is a homogeneous and non-ozone depleting dispersion comprising a lubricious fluoropolymer, an inert perfluorinated liquid, a polar solvent, and an effective amount of a surface active agent selected from the group consisting of:a. perfluoroaliphatic amidoalkanols;b. polymerized products formed from the reaction of a mixture comprising a hydrophilic monomer and a monomer of the general formula: ##STR1## wherein p and q are integers between 1 and 4 inclusive, x and y are integers between 0 and 4 inclusive, m is 1 or 2, n is an integer between 3 and 10 inclusive, X' is either a methyl group or a single hydrogen atom, g is 0 or 1, and Q is a sulfonamido constituent group according to the formula: ##STR2## wherein R.sup.1 is a hydrogen or a lower alkyl group having from 1 to 6 carbon atoms and wherein the hydrophilic monomer is present in an amount constituting inclusively between five and twenty-five weight percent of the reactant mixture when the polar solvent employed is a polar organic solvent and wherein the hydrophilic monomer is present in an amount constituting inclusively between one and twenty-five weight percent of the reactant mixture when the polar solvent employed is water; andc. Perfluorinated ether acids according to the general formula: ##STR3## wherein z is between 1 and 10 inclusive, s is between 0 to 4, t is between 0 to 4, v between 0 to 5, w is 0 or 1, and Y is either F or CF.sub.3.

    摘要翻译： 本发明提供了一种可用于涂料应用的含氟聚合物分散体。 分散体是均匀和非消耗臭氧的分散体，其包含润滑的含氟聚合物，惰性全氟化液体，极性溶剂和有效量的选自以下的a的表面活性剂：a。 全氟脂族酰氨基链烷醇; b。 由包含亲水单体和单体的混合物反应形成的由以下通式表示的聚合产物：其中p和q是包括1和4的整数，x和y是0和4之间的整数，其中m是1 或2，n为3〜10的整数，X'为甲基或单个氢原子，g为0或1，Q为根据下式的亚磺酰氨基成分基团：其中R1为 氢或具有1至6个碳原子的低级烷基，并且当所用的极性溶剂是极性有机溶剂时，所述亲水性单体以占所述反应物混合物的5至25重量％的量包含在其中的量存在，并且其中 当所使用的极性溶剂是水时，亲水性单体以包含在反应物混合物的一种和25重量％之间的量存在; 和c。 全氟化醚酸，其通式如下：其中z在1和10之间，其中s在0至4之间，t在0至4之间，v在0至5之间，w为0或1，Y为 F或CF3。

    Perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluorides and derivatives thereof
    8.
    发明授权
    Perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluorides and derivatives thereof 失效
    全氟（脂环族亚甲氧基亚烷基）羰基氟化物及其衍生物

    公开(公告)号：US5354901A

    公开(公告)日：1994-10-11

    申请号：US12249

    申请日：1993-02-01

    申请人： Richard M. Flynn ,  Patricia M. Savu

    发明人： Richard M. Flynn ,  Patricia M. Savu

    IPC分类号： C07C43/12 ,  B01F17/42 ,  C07C41/00 ,  C07C43/11 ,  C07C43/13 ,  C07C51/00 ,  C07C59/135 ,  C07C67/00 ,  C07C69/63 ,  C07C213/00 ,  C07C231/00 ,  C07C235/06 ,  C07C241/00 ,  C07C253/00 ,  C07C255/13 ,  C07C255/16 ,  C07C265/04 ,  C07C301/00 ,  C07C309/65 ,  C07D211/38 ,  C07D265/30 ,  C07F7/12 ,  C07C61/08

    CPC分类号： C07D265/30 ,  C07C255/16 ,  C07C43/11 ,  C07C43/137 ,  C07C59/135 ,  C08G65/007 ,  C07C2101/14 ,  Y10S516/914 ,  Y10S516/916 ,  Y10S516/919

    摘要： Perfluoro(cycloaliphatic methyleneoxyalkylene) compositions are provided. These compositions comprise perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds having (a) a perfluorocycloaliphatic moiety which can have up to two perfluoroalkyl substituents and a perfluoroalkylene substituent, and (b) a perfluoromethyleneoxyalkylene carbonyl fluoride radical, the methylene group of the radical being bonded to a ring carbon atom or the perfluoroalkylene substituent of the moiety and the alkylene group of the perfluoromethyleneoxyalkylene carbonyl fluoride being a perfluoro(methyl)methylene group, a perfluoroisopropyleneoxy(methyl)methylene group, or a poly(perfluoroisopropyleneoxy)perfluoro(methyl)methylene group having up to about 10 perfluoroisopropyleneoxy units. Also provided are functional derivatives of the perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds and nonfunctional derivatives of the perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds.

    摘要翻译： 提供全氟（脂环族亚甲氧基亚烷基）组合物。 这些组合物包含全氟（脂环族亚甲氧基亚烷基）碳酰氟化合物，其具有（a）可具有至多两个全氟烷基取代基和全氟亚烷基取代基的全氟环脂族部分，和（b）全氟亚甲基氧亚烷基碳酰氟基团，该基团的亚甲基键合至 全氟亚甲基氧亚烷基碳酰氟部分的全氟亚烷基取代基和全氟亚烷基氧亚烷基碳酰氟的亚烷基是全氟（甲基）亚甲基，全氟异丙烯氧基（甲基）亚甲基或聚（全氟异丙烯氧基）全氟（甲基）亚甲基，其具有 最多约10个全氟异丙烯单元。 还提供全氟（脂环族亚甲氧基亚烷基）碳酰氟化合物和全氟（脂环族亚甲氧基亚烷基）羰基氟化物的非官能衍生物的功能衍生物。

    Perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluorides and derivatives thereof
    9.
    发明授权
    Perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluorides and derivatives thereof 失效
    全氟（脂环族亚甲氧基亚烷基）羰基氟化物及其衍生物

    公开(公告)号：US5210282A

    公开(公告)日：1993-05-11

    申请号：US906504

    申请日：1992-06-30

    申请人： Richard M. Flynn ,  Patricia M. Savu

    发明人： Richard M. Flynn ,  Patricia M. Savu

    IPC分类号： C07C43/11 ,  C07C43/13 ,  C07C59/135 ,  C07C255/16 ,  C07D265/30

    CPC分类号： C07D265/30 ,  C07C255/16 ,  C07C43/11 ,  C07C43/137 ,  C07C59/135 ,  C08G65/007 ,  C07C2101/14

    摘要： Perfluoro(cycloaliphatic methyleneoxyalkylene) compositions are provided. These compositions comprise perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds having (a) a perfluorocycloaliphatic moiety which can have up to two perfluoroalkyl substituents and a perfluoroalkylene substituent, and (b) a perfluoromethyleneoxyalkylene carbonyl fluoride radical, the methylene group of the radical being bonded to a ring carbon atom or the perfluoroalkylene substituent of the moiety and the alkylene group of the perfluoromethyleneoxyalkylene carbonyl fluoride being a perfluoro(methyl)methylene group, a perfluoroisopropyleneoxy(methyl)methylene group, or a poly(perfluoroisopropyleneoxy)perfluoro(methyl)methylene group having up to about 10 perfluoroisopropyleneoxy units. Also provided are functional derivatives of the perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds and nonfunctional derivatives of the perfluoro(cycloaliphatic methyleneoxyalkylene) carbonyl fluoride compounds.

    摘要翻译： 提供全氟（脂环族亚甲氧基亚烷基）组合物。 这些组合物包含全氟（脂环族亚甲氧基亚烷基）碳酰氟化合物，其具有（a）可具有至多两个全氟烷基取代基和全氟亚烷基取代基的全氟环脂族部分，和（b）全氟亚甲基氧亚烷基碳酰氟基团，该基团的亚甲基键合至 全氟亚甲基氧亚烷基碳酰氟部分的全氟亚烷基取代基和全氟亚烷基氧亚烷基碳酰氟的亚烷基是全氟（甲基）亚甲基，全氟异丙烯氧基（甲基）亚甲基或聚（全氟异丙烯氧基）全氟（甲基）亚甲基，其具有 最多约10个全氟异丙烯单元。 还提供全氟（脂环族亚甲氧基亚烷基）碳酰氟化合物和全氟（脂环族亚甲氧基亚烷基）羰基氟化物的非官能衍生物的功能衍生物。