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    Method for Curing Radically Curable Compounds in a Protective Atmosphere and Device for Carrying Out Said Method
    1.
    发明申请
    Method for Curing Radically Curable Compounds in a Protective Atmosphere and Device for Carrying Out Said Method 审中-公开
    用于固化保护性气氛中的可自由基固化的化合物的方法和用于进行所述方法的装置

    公开(公告)号：US20080003372A1

    公开(公告)日：2008-01-03

    申请号：US11569213

    申请日：2005-05-24

    申请人： Martin Kamps ,  Fatmir Raka ,  Hubert Baumgart ,  Berthold Austrup

    发明人： Martin Kamps ,  Fatmir Raka ,  Hubert Baumgart ,  Berthold Austrup

    IPC分类号： B05D1/18 ,  B05C3/02

    CPC分类号： F26B21/14 ,  B05D3/0466 ,  B05D3/0486 ,  B05D3/067 ,  F26B3/28

    摘要： A method of curing free-radically curable compositions under an inert gas atmosphere, where the curing, which proceeds in accordance with a free-radical mechanism, is initiated, or initiated and maintained, in the free-radically curable compositions by radiation and the lateral escape of the inert gas atmosphere is prevented, which involves (1) immersing the free-radically curable compositions in an inert gas atmosphere below a depth from which the inert gas atmosphere constantly exhibits its lowest oxygen concentration, and (2) irradiating the free-radically curable compositions below this depth in the inert gas atmosphere, at least one of the radiation sources being arranged beneath the inert gas/air interface, and then (3) emersing the resultant cured compositions again from the inert gas atmosphere, and apparatus (1) according to FIG. 1 for its implementation.

    摘要翻译： 一种在惰性气体气氛下固化可自由基固化的组合物的方法，其中根据自由基机理进行的固化通过辐射和侧向起始或启动并保持在可自由基固化的组合物中 防止惰性气体气体的逸出，其包括（1）将自由基可固化组合物浸入惰性气体气氛中低于惰性气体气氛持续显示其最低氧浓度的深度，以及（2） 在惰性气体气氛中低于该深度的可自由基固化的组合物，至少一个辐射源设置在惰性气体/空气界面的下方，然后（3）再次从惰性气体气氛中排出所得的固化组合物，以及装置（1 ）。 1执行。

    METHOD FOR PRODUCING MOLDED PARTS, ESPECIALLY FOR USE IN AUTOMOBILE MANUFACTURE, AND CORRESPONDING APPROPRIATE FILMS COMPRISING A COATING
    3.
    发明申请
    METHOD FOR PRODUCING MOLDED PARTS, ESPECIALLY FOR USE IN AUTOMOBILE MANUFACTURE, AND CORRESPONDING APPROPRIATE FILMS COMPRISING A COATING 有权
    生产模具的方法，特别适用于汽车制造，以及对应包装涂料的适当膜

    公开(公告)号：US20090061215A1

    公开(公告)日：2009-03-05

    申请号：US11718566

    申请日：2005-10-17

    申请人： Hubert Baumgart ,  Horst Hintze-Bruning ,  Fatmir Raka ,  Gabriele Dlugosch ,  Frank Dietsche ,  Nick Gruber ,  Erich Beck ,  Reinhold Schwalm ,  Klaus Menzel ,  Yvonne Heischkel ,  Berthold Austrup

    发明人： Hubert Baumgart ,  Horst Hintze-Bruning ,  Fatmir Raka ,  Gabriele Dlugosch ,  Frank Dietsche ,  Nick Gruber ,  Erich Beck ,  Reinhold Schwalm ,  Klaus Menzel ,  Yvonne Heischkel ,  Berthold Austrup

    IPC分类号： B32B27/40

    CPC分类号： B29C37/0032 ,  B29C2037/0042 ,  C08G18/3212 ,  C08G18/672 ,  C08G18/722 ,  C09D175/16 ,  Y10T428/265

    摘要： A process for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements in an amount such that 1. a coating (MT) produced from the mixture (M) of component (KK) with additives, but as yet not crosslinked to completion, has a ratio of storage modulus G(MT)′ to loss modulus G(MT)″ of from 5 to 200, G(MT)′ and G(MT)″ having been determined at 20° C. by means of rheological oscillation measurements, and 2. a coating (ME) produced from the mixture (M) of component (KK) with additives and crosslinked to completion has a storage modulus E(ME)″ of from 1.0*107.0 to 8.0*107.0 Pa, E(ME)′ having been measured in the rubber-elastic range by dynamic mechanical thermal analysis.

    摘要翻译： 一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的着色涂料组合物（P）和可自由交联的涂料组合物（K）被施加到干燥但仍然 由涂料组合物（K）制备未完全交联的涂料（KT），涂覆的支撑片材成型并用液体聚合物材料注射回模塑或泡沫背衬，并且涂层（KT） - 如果尚未采用 地方治愈或后固化; 所述可交联涂料组合物（K）包含可自由基交联的组分（KK），其含有形成氢键的结构元素，其量使得1.由组分（KK）的混合物（M）与添加剂 ，但尚未交联完成，具有5至200，G（MT）'和G（MT）“的储能模量G（MT）'与损耗模量G（MT）”的比率已被确定 在20℃下，通过流变振动测量，和2.由组分（KK）与添加剂的混合物（M）产生并交联至完成的涂层（ME）具有的储能模量E（ME） 通过动态机械热分析在橡胶弹性范围内测量的1.0 * 107.0至8.0 * 107.0 Pa，E（ME）'。

    REFINISH SHEETS AND THEIR USE
    7.
    发明申请
    REFINISH SHEETS AND THEIR USE 有权
    精品及其使用

    公开(公告)号：US20090011189A1

    公开(公告)日：2009-01-08

    申请号：US12092411

    申请日：2006-11-09

    申请人： Hubert Baumgart ,  Berthold Austrup ,  Bostjan Muhic

    发明人： Hubert Baumgart ,  Berthold Austrup ,  Bostjan Muhic

    IPC分类号： B32B38/10 ,  B32B5/00 ,  B32B27/32 ,  B32B9/00 ,  B32B27/36 ,  B32B27/40 ,  B32B33/00 ,  B32B5/16

    CPC分类号： B05D1/286 ,  B05D5/005 ,  Y10T428/24355 ,  Y10T428/25 ,  Y10T428/28 ,  Y10T428/2848 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： Disclosed herein is a refinish sheet produced by (1) coating one side of a temporary carrier sheet (A) with at least one aqueous coating material (B) comprising at least one free-radically crosslinkable binder (B1) having a glass transition temperature of −70 to +50° C., an olefinically unsaturated double bond content of 2 to 10 eq/kg, and an acid group content of 0.05 to 15 eq/kg to produce at least one resultant layer (B); and (2) drying but not curing, or only part-curing, the at least one resultant layer (B) to produce at least one dried, uncured or part-cured layer (B). Also disclosed is a method of repairing a surface of a coated substrate using the refinish sheet.

    摘要翻译： 本文公开了一种修补片，其通过（1）用至少一种水性涂料（B）涂覆临时载体片（A）的一侧而制备的，所述水性涂料包含至少一种可自由基交联的粘合剂（B1），所述粘合剂的玻璃化转变温度为 -70〜+ 50℃，烯属不饱和双键含量为2〜10eq / kg，酸基含量为0.05〜15eq / kg，生成至少一个所得层（B）。 和（2）干燥但不固化或仅部分固化所述至少一个所得层（B）以产生至少一个干燥，未固化或部分固化的层（B）。 还公开了使用修补片来修复涂布的基材的表面的方法。

    Powder Slurries Which can be Thermally Hardened with Actinic Radiation and Method for the Production and Use Thereof
    8.
    发明申请
    Powder Slurries Which can be Thermally Hardened with Actinic Radiation and Method for the Production and Use Thereof 审中-公开
    可以用光化辐射热固化的粉末浆料及其生产和使用方法

    公开(公告)号：US20080255308A1

    公开(公告)日：2008-10-16

    申请号：US10595209

    申请日：2004-10-12

    申请人： Berthold Austrup ,  Hubert Baumgart ,  Guido Wilke

    发明人： Berthold Austrup ,  Hubert Baumgart ,  Guido Wilke

    IPC分类号： C08L75/04

    CPC分类号： C09D175/16 ,  C08G18/6229 ,  C08G18/6254 ,  C08G18/671 ,  C08G18/807 ,  C08G18/8096 ,  C08G18/8116 ,  C08G18/8175 ,  C08G18/62

    摘要： Powder slurries curable thermally and with actinic radiation and comprising solid and/or highly viscous particles dimensionally stable under storage and application conditions, including at least one binder free of carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and at least one ion-forming group; at least one blocked and/or part-blocked polyisocyanate; and at least one olefinically unsaturated constituent which is free of isocyanate-reactive functional groups and contains on average per molecule at least one isocyanate group blocked with pyrazole or with at least one substituted pyrazole and at least two carbon-carbon double bonds which can be activated with actinic radiation, prepared by reacting at least one polyisocyanate with pyrazole and/or with at least one substituted pyrazole and also with at least one compound containing an isocyanate-reactive functional group and at least two carbon-carbon double bonds activatable with actinic radiation, processes for preparing them, and their use.

    摘要翻译： 粉末浆料可热固化并具有光化辐射，并且在储存和使用条件下包括固体和/或高粘度颗粒尺寸稳定，包括至少一种不含可活化光化辐射的碳 - 碳双键的粘合剂，其包含至少一种（甲基）丙烯酸酯 每个分子平均含有至少一个异氰酸酯反应性官能团和至少一个离子形成基团的共聚物; 至少一种封端和/或部分封端的多异氰酸酯; 和至少一种不含异氰酸酯反应性官能团的烯属不饱和组分，平均每分子含有至少一个被吡唑或至少一个取代的吡唑封端的异氰酸酯基团和至少两个可被活化的碳 - 碳双键 通过使至少一种多异氰酸酯与吡唑和/或与至少一种取代的吡唑反应制备，并且还含有至少一种含有异氰酸酯反应性官能团的化合物和至少两种可用光化辐射活化的碳 - 碳双键， 制备它们的过程及其用途。

    Repair film and use thereof
    10.
    发明授权
    Repair film and use thereof 有权
    修复胶片及其使用

    公开(公告)号：US08337649B2

    公开(公告)日：2012-12-25

    申请号：US12092411

    申请日：2006-11-09

    申请人： Hubert Baumgart ,  Berthold Austrup ,  Bostjan Muhic

    发明人： Hubert Baumgart ,  Berthold Austrup ,  Bostjan Muhic

    IPC分类号： B32B38/10 ,  B32B5/00 ,  B32B27/32 ,  B32B9/00 ,  B32B27/36 ,  B32B27/40 ,  B32B33/00 ,  B32B5/16

    CPC分类号： B05D1/286 ,  B05D5/005 ,  Y10T428/24355 ,  Y10T428/25 ,  Y10T428/28 ,  Y10T428/2848 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： Disclosed herein is a refinish sheet produced by (1) coating one side of a temporary carrier sheet (A) with at least one aqueous coating material (B) comprising at least one free-radically crosslinkable binder (B1) having a glass transition temperature of −70 to +50° C., an olefinically unsaturated double bond content of 2 to 10 eq/kg, and an acid group content of 0.05 to 15 eq/kg to produce at least one resultant layer (B); and (2) drying but not curing, or only part-curing, the at least one resultant layer (B) to produce at least one dried, uncured or part-cured layer (B). Also disclosed is a method of repairing a surface of a coated substrate using the refinish sheet.

    摘要翻译： 本文公开了一种修补片，其通过（1）用至少一种水性涂料（B）涂覆临时载体片（A）的一侧而制备的，所述水性涂料包含至少一种可自由基交联的粘合剂（B1），所述粘合剂的玻璃化转变温度为 -70〜+ 50℃，烯属不饱和双键含量为2〜10eq / kg，酸基含量为0.05〜15eq / kg，生成至少一个所得层（B）。 和（2）干燥但不固化或仅部分固化所述至少一个所得层（B）以产生至少一个干燥，未固化或部分固化的层（B）。 还公开了使用修补片来修复涂布的基材的表面的方法。