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1.发明授权Process for the photographic production of relief images using selected titanocenes 失效使用选定的钛碳酸摄影制作浮雕图像的方法
公开(公告)号：US5034307A
公开(公告)日：1991-07-23
申请号：US570497
申请日：1990-08-21
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the metal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
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公开(公告)号：US4970136A
公开(公告)日：1990-11-13
申请号：US361194
申请日：1989-06-05
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the matal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
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公开(公告)号：US4857654A
公开(公告)日：1989-08-15
申请号：US77261
申请日：1987-07-24
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the metal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
摘要翻译： 具有例如其中一个或两个碳环或杂环芳环与钛键合的对 - 环戊二烯基配位体的二十碳烯，芳环在相对于金属碳的两个邻位中的至少一个中被氟取代 并且被至少一个游离的或醚化的或酯化的聚氧亚烷基取代，适合作为用于烯属不饱和基材的光聚合的光引发剂。
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公开(公告)号：US5192642A
公开(公告)日：1993-03-09
申请号：US527988
申请日：1990-05-23
申请人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/124 , Y10S430/148 , Y10S526/943
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by an acyloxy group are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译： 其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代并且被酰氧基取代的芳族基团的式I化合物（I）的十六碳烯是合适的 作为烯属不饱和化合物的光聚合的光引发剂。
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公开(公告)号：US5026625A
公开(公告)日：1991-06-25
申请号：US273526
申请日：1988-11-21
IPC分类号： C07C211/52 , C07C217/08 , C07C233/12 , C07C233/15 , C07C233/59 , C07C233/66 , C07C233/88 , C07C233/91 , C07C235/06 , C07C255/24 , C07C255/30 , C07C255/45 , C07C271/06 , C07C311/21 , C07C335/16 , C07C381/06 , C07D205/08 , C07D207/40 , C07D207/404 , C07D207/408 , C07D207/448 , C07D209/48 , C07D209/76 , C07D307/14 , C07D521/00 , C07F7/10 , C07F7/28 , C07F17/00 , C08F2/50 , G03F7/029
CPC分类号： C07D207/404 , C07C211/52 , C07C217/08 , C07C233/15 , C07C233/66 , C07C233/88 , C07C311/21 , C07D205/08 , C07D207/408 , C07D209/48 , C07D209/76 , C07D307/14 , C07F17/00 , C07F7/10 , C08F2/50 , G03F7/029 , C07C2101/14 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl gropus, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as further substituents, a substituted amino radical, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
摘要翻译： 含有两个5元环二烯gropus，例如环戊二烯基，和一个或两个六元碳环或5元或它们被氟原子在两个邻位的至少一种取代的6元杂环芳环二茂钛 钛 - 碳键并含有作为其它取代基的取代的氨基，适用作用于烯属不饱和化合物的辐射诱导聚合的光引发剂。
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公开(公告)号：US5306600A
公开(公告)日：1994-04-26
申请号：US975042
申请日：1992-11-12
申请人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/124 , Y10S430/148 , Y10S526/943
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by an acyloxy group are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译： 其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代并且被酰氧基取代的芳族基团的式I化合物（I）的十六碳烯是合适的 作为烯属不饱和化合物的光聚合的光引发剂。
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公开(公告)号：US5068371A
公开(公告)日：1991-11-26
申请号：US527989
申请日：1990-05-23
申请人： Eginhard Steiner , Harry Beyeler , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Rinaldo Husler
IPC分类号： C07D207/33 , C07F7/28 , C07F17/00 , C08F2/50 , C08J7/04 , C09D4/00 , C09D5/00 , C09D11/10 , G03F7/029 , G03G5/00
CPC分类号： C08F2/50 , C07F17/00 , G03F7/029 , Y10S430/12 , Y10S430/121 , Y10S430/122 , Y10S430/123
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by a pyrrylalkyl group, amidoalkyl group or imidoalkyl group, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译： 其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代的芳族基团，另外被吡咯烷基，酰氨基烷基或 亚氨基烷基适合用作光引发剂，用于烯属不饱和化合物的光聚合。
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公开(公告)号：US5008302A
公开(公告)日：1991-04-16
申请号：US273522
申请日：1988-11-21
IPC分类号： G03F7/028 , C07D207/32 , C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F7/08 , C07F7/28 , C07F17/00 , C08F2/50 , C08F4/76 , C09D4/00 , C09D11/10 , G03F7/029
CPC分类号： C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F17/00 , C07F7/0814 , C08F2/50 , G03F7/029 , Y10S430/121 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl groups, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as a further substituent, unsubstituted or substituted 1-pyrryl, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
摘要翻译： 含有两个5元环二烯基的二茂钛，例如环戊二烯基，以及一个或两个6元碳环或5元或6元杂环芳环，它们被两个邻位中的至少一个中的氟原子取代 作为另外的取代基，含有未取代的或取代的1-吡咯基，作为光引发剂适用于烯键式不饱和化合物的辐射诱导聚合。
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公开(公告)号：US5106722A
公开(公告)日：1992-04-21
申请号：US567048
申请日：1990-08-14
IPC分类号： G03F7/028 , C07D207/32 , C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F7/08 , C07F7/28 , C07F17/00 , C08F2/50 , C08F4/76 , C09D4/00 , C09D11/10 , G03F7/029
CPC分类号： C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F17/00 , C07F7/0814 , C08F2/50 , G03F7/029 , Y10S430/121 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl groups, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as a further substituent, unsubstituted or substituted 1-pyrryl, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
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公开(公告)号：US4033942A
公开(公告)日：1977-07-05
申请号：US680640
申请日：1976-04-27
申请人： Fabio Beffa , Gerhard Back , Eginhard Steiner
发明人： Fabio Beffa , Gerhard Back , Eginhard Steiner
IPC分类号： C09B45/04 , C09B45/00 , C09B45/48 , C09B55/00 , C09B56/02 , D06P1/10 , D06P1/13 , C09B45/26 , C09B45/06
CPC分类号： C09B45/00 , C09B55/001 , D06P1/10 , D06P1/13
摘要： 1:2 Chromium complex dyes of an azo compound of the formula ##STR1## and an azomethine compound of the formula ##STR2## COMPLEXED TO A CHROMIUM ATOM, WHEREIN A is an ortho-phenylene or -- naphthylene diazo component radical; B is an ortho-phenylene or -- naphthylene coupling component radical; X is --O-- or --CO--O--; X' is --O--, --NH--, --N(lower alkyl)--, --N(aralkyl)-- or --N(aryl)--; R is an aliphatic radical; the benzene ring "a" is unsubstituted or substituted by a fused benzene ring, halo, nitro alkyl or alkoxy; the molecule containing 0-5 water solubilizing groups and optionally a group of the formula --N=N--Ar--N=N--Ar' and/or -N=N--Ar" wherein Ar, Ar' and Ar" represent an aromatic or carbocyclic radical.
摘要翻译： 1：2下式的偶氮化合物的铬络合物染料和与铬酸盐复合的式“IMAGE”的偶氮甲碱化合物，其中A是邻 - 亚苯基或 - 亚萘基重氮组分基团; B是邻 - 亚苯基或亚萘基偶合成分基; X是-O-或-CO-O-; X'是-O - ， - NH - ， - N（低级烷基） - ， - N（芳烷基） - 或-N（芳基） - 。 R是脂族基团; 苯环“a”未被取代或被稠合的苯环，卤素，硝基烷基或烷氧基取代; 含有0-5个水溶性基团和任选的式-N = N-Ar-N = N-Ar'和/或-N = N-Ar“的分子，其中Ar，Ar'和Ar”表示 芳族或碳环基。
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