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1.发明授权Process for the photographic production of relief images using selected titanocenes 失效使用选定的钛碳酸摄影制作浮雕图像的方法
公开(公告)号：US5034307A
公开(公告)日：1991-07-23
申请号：US570497
申请日：1990-08-21
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the metal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
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公开(公告)号：US4970136A
公开(公告)日：1990-11-13
申请号：US361194
申请日：1989-06-05
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the matal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
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公开(公告)号：US4857654A
公开(公告)日：1989-08-15
申请号：US77261
申请日：1987-07-24
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the metal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
摘要翻译： 具有例如其中一个或两个碳环或杂环芳环与钛键合的对 - 环戊二烯基配位体的二十碳烯，芳环在相对于金属碳的两个邻位中的至少一个中被氟取代 并且被至少一个游离的或醚化的或酯化的聚氧亚烷基取代，适合作为用于烯属不饱和基材的光聚合的光引发剂。
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公开(公告)号：US5106722A
公开(公告)日：1992-04-21
申请号：US567048
申请日：1990-08-14
IPC分类号： G03F7/028 , C07D207/32 , C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F7/08 , C07F7/28 , C07F17/00 , C08F2/50 , C08F4/76 , C09D4/00 , C09D11/10 , G03F7/029
CPC分类号： C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F17/00 , C07F7/0814 , C08F2/50 , G03F7/029 , Y10S430/121 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl groups, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as a further substituent, unsubstituted or substituted 1-pyrryl, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
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公开(公告)号：US5008302A
公开(公告)日：1991-04-16
申请号：US273522
申请日：1988-11-21
IPC分类号： G03F7/028 , C07D207/32 , C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F7/08 , C07F7/28 , C07F17/00 , C08F2/50 , C08F4/76 , C09D4/00 , C09D11/10 , G03F7/029
CPC分类号： C07D207/325 , C07D207/333 , C07D207/335 , C07D405/04 , C07F17/00 , C07F7/0814 , C08F2/50 , G03F7/029 , Y10S430/121 , Y10S430/148
摘要： Titanocenes containing two 5-membered cyclodienyl groups, for example cyclopentadienyl, and one or two 6-membered carbocyclic or 5- or 6-membered heterocyclic aromatic rings which are substituted by a fluorine atom in at least one of the two ortho-positions to the titanium-carbon bond and contain, as a further substituent, unsubstituted or substituted 1-pyrryl, are suitable as photoinitiators for radiation-induced polymerization of ethylenically unsaturated compounds.
摘要翻译： 含有两个5元环二烯基的二茂钛，例如环戊二烯基，以及一个或两个6元碳环或5元或6元杂环芳环，它们被两个邻位中的至少一个中的氟原子取代 作为另外的取代基，含有未取代的或取代的1-吡咯基，作为光引发剂适用于烯键式不饱和化合物的辐射诱导聚合。
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公开(公告)号：US06174854B1
公开(公告)日：2001-01-16
申请号：US08361257
申请日：1994-12-21
申请人： Urs Hofer , Werner Kaufmann , Manfred Rembold
发明人： Urs Hofer , Werner Kaufmann , Manfred Rembold
IPC分类号： C11D328
CPC分类号： D06M13/352 , C11D1/62 , C11D3/0015 , C11D3/42 , D06M13/358
摘要： There is provided a stable, concentrated fabric rinse composition comprising 0.1 to 20, preferably 1 to 10% by weight of a UV absorber selected from a hydroxyaryl-1,3,5-triazine, a sulphonated-1,3,5-triazine, an o-hydroxyphenylbenzotriazole or a 2-aryl-2H-benzotriazole, based on the total weight of the composition, and a fabric care ingredient, preferably a fabric softener, a stain release or stain repellant ingredient or a water-proofing agent, the remainder being substantially water. The fabric rinse composition is preferably a fabric softener composition comprising 5 to 25, preferably 10 to 20% by weight of a cationic fabric softening agent and 0.1 to 20, preferably 1 to 10% by weight of a UV absorber selected from a hydroxyaryl-1,3,5-triazine, a sulphonated-1,3,5-triazine, an o-hydroxyphenylbenzotriazole or a 2-aryl-2H-benzotriazole, each based on the total weight of the composition, the remainder being substantially water. The present invention also provides method for the treatment of a textile article, comprising applying, to the previously washed article, the said fabric rinse composition, preferably the rinse cycle fabric softener composition, whereby the SPF value of articles so treated can be significantly increased.
摘要翻译： 提供了稳定的浓缩织物漂洗组合物，其包含0.1至20重量％，优选1至10重量％的选自羟基芳基-1,3,5-三嗪，磺化1,3,5-三嗪， 基于组合物的总重量的邻羟基苯基苯并三唑或2-芳基-2H-苯并三唑，以及织物护理成分，优选织物柔软剂，防污剂或防污剂成分或防水剂，其余 基本上是水。 织物漂洗组合物优选是织物柔软剂组合物，其包含5至25重量％，优选10至20重量％的阳离子织物软化剂和0.1至20重量％，优选1至10重量％的选自羟基芳基-1 ，3,5-三嗪，磺化-1,3,5-三嗪，邻羟基苯基苯并三唑或2-芳基-2H-苯并三唑，各自基于组合物的总重量，其余基本上为水。 本发明还提供了一种用于处理纺织品的方法，其包括向先前洗涤的制品施加所述织物漂洗组合物，优选漂洗循环织物柔软剂组合物，由此可以显着提高如此处理的制品的SPF值。
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公开(公告)号：US5942564A
公开(公告)日：1999-08-24
申请号：US783184
申请日：1997-01-15
申请人： Jurgen Kaschig , Dieter Reinehr , Manfred Rembold
发明人： Jurgen Kaschig , Dieter Reinehr , Manfred Rembold
IPC分类号： C07D251/24 , C08K5/3477 , C08K5/3492 , C08L101/00 , C09D7/12 , D06M13/02 , D06M13/152 , D06M13/224 , D06M13/236 , D06M13/244 , D06M13/248 , D06M13/252 , D06M13/282 , D06M13/288 , D06M13/322 , D06M13/325 , D06M13/35 , D06M13/352 , D06M13/355 , D06M13/358 , D06M13/402 , D06M13/415 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/32 , C08K5/34
CPC分类号： C09D7/1241 , C07D251/24 , C08K5/3492 , C08K5/34926
摘要： The invention relates to o-hydroxyphenyl-s-triazines of formula ##STR1## wherein at least one of Y and Z are C.sub.1 -C.sub.18 alkoxyThe compounds are suitable for use as UV stabilisers for the photochemical and thermal stabilisation of polyester fibre materials and as stabilisers for organic ploymers.
摘要翻译： 本发明涉及下式的邻羟基苯基-s-三嗪，其中Y和Z中的至少一个是C 1 -C 18烷氧基该化合物适合用作UV稳定剂，用于聚酯纤维材料的光化学和热稳定化以及作为有机物的稳定剂 工匠
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公开(公告)号：US5856380A
公开(公告)日：1999-01-05
申请号：US656268
申请日：1996-06-14
申请人： Michael Bauer , Manfred Rembold
发明人： Michael Bauer , Manfred Rembold
IPC分类号： C08J7/18 , B05D7/24 , C08F30/02 , C08G79/02 , C08L101/00 , D06M10/00 , D06M10/02 , D06M10/08 , D06M13/02 , D06M13/244 , D06M13/282 , D06M14/20 , D06M14/26 , C08J3/28 , B32B9/04
摘要： A process is described for flame-proofing organic polymeric materials by means of a low temperature plasma treatment in the presence of at least one volatile, low-molecular compound. The process comprises subjecting a volatile compound, selected from a halogen-free phosphorus compound, to the low temperature plasma, such that a homogeneous polymeric structure forms on the organic material. A very wide range of organic materials can be effectively flame-proofed with the process of this invention without adversely affecting their other properties such as mechanical properties or photochemical stability.
摘要翻译： PCT No.PCT / EP94 / 04029 Sec。 371日期1996年6月14日第 102（e）1996年6月14日PCT 1994年12月3日PCT PCT。 公开号WO95 / 16715 日期1995年6月22日描述了在至少一种挥发性低分子化合物的存在下，通过低温等离子体处理来阻止有机聚合物材料的方法。 该方法包括使选自无卤素磷化合物的挥发性化合物经受低温等离子体，从而在有机材料上形成均匀的聚合物结构。 通过本发明的方法可以有效地阻燃非常宽范围的有机材料，而不会不利地影响其它性能如机械性能或光化学稳定性。
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公开(公告)号：US5591850A
公开(公告)日：1997-01-07
申请号：US340952
申请日：1994-11-17
申请人： Jean-Luc Birbaum , J urgen Kaschig , Dieter Reinehr , Manfred Rembold , Andr e Schmitter , Helmut Luther , Bernd Herzog , Dietmar H uglin
发明人： Jean-Luc Birbaum , J urgen Kaschig , Dieter Reinehr , Manfred Rembold , Andr e Schmitter , Helmut Luther , Bernd Herzog , Dietmar H uglin
IPC分类号： C07D251/02 , A61K8/00 , A61K8/42 , A61K8/49 , A61K8/85 , A61Q17/04 , C07D251/12 , C07D251/24 , C08K5/3492 , C08L67/00 , C09K3/00 , D06P1/642 , D06P3/52 , C07D251/00
CPC分类号： C08K5/3492 , A61K8/4966 , A61Q17/04 , C07D251/24 , D06P1/6426
摘要： o-Hydroxyphenyl-s-triazines are described which contain at least two alkoxyphenyl substituents. They have the formula (1).The compounds according to the invention are suitable as stabilizers for textile fiber materials, in particular polyester fiber materials, and for organic polymers. Furthermore, they are suitable for use as sunscreens in cosmetic preparations.
摘要翻译： 描述了含有至少两个烷氧基苯基取代基的邻羟基苯基-s-三嗪。 他们有公式（1）。 根据本发明的化合物适用于纺织纤维材料，特别是聚酯纤维材料和有机聚合物的稳定剂。 此外，它们适合用作化妆品制剂中的防晒剂。
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公开(公告)号：US06398982B1
公开(公告)日：2002-06-04
申请号：US09716553
申请日：2000-11-20
申请人： Urs Hofer , Werner Kaufmann , Manfred Rembold
发明人： Urs Hofer , Werner Kaufmann , Manfred Rembold
IPC分类号： C09K1106
CPC分类号： D06M13/352 , C11D1/62 , C11D3/0015 , C11D3/42 , D06M13/358
摘要： There is provided a stable, concentrated fabric rinse composition comprising 0.1 to 20, preferably 1 to 10% by weight of a UV absorber selected from a hydroxyaryl-1,3,5-triazine, a sulphonated-1,3,5-triazine, an o-hydroxyphenylbenzotriazole or a 2-aryl-2H-benzotriazole, based on the total weight of the composition, and a fabric care ingredient, preferably a fabric softener, a stain release or stain repellant ingredient or a water-proofing agent, the remainder being substantially water. The fabric rinse composition is preferably a fabric softener composition comprising 5 to 25, preferably 10 to 20% by weight of a cationic fabric softening agent and 0.1 to 20, preferably 1 to 10% by weight of a UV absorber selected from a hydroxyaryl-1,3,5-triazine, a sulphonated-1,3,5-triazine, an o-hydroxyphenylbenzotriazole or a 2-aryl-2H-benzotriazole, each based on the total weight of the composition, the remainder being substantially water. The present invention also provides method for the treatment of a textile article, comprising applying, to the previously washed article, the said fabric rinse composition, preferably the rinse cycle fabric softener composition, whereby the SPF value of articles so treated can be significantly increased.
摘要翻译： 提供了稳定的浓缩织物漂洗组合物，其包含0.1至20重量％，优选1至10重量％的选自羟基芳基-1,3,5-三嗪，磺化1,3,5-三嗪， 基于组合物的总重量的邻羟基苯基苯并三唑或2-芳基-2H-苯并三唑，以及织物护理成分，优选织物柔软剂，防污剂或防污剂成分或防水剂，其余 基本上是水。 织物漂洗组合物优选是织物柔软剂组合物，其包含5至25重量％，优选10至20重量％的阳离子织物软化剂和0.1至20重量％，优选1至10重量％的选自羟基芳基-1 ，3,5-三嗪，磺化-1,3,5-三嗪，邻羟基苯基苯并三唑或2-芳基-2H-苯并三唑，各自基于组合物的总重量，其余基本上为水。 本发明还提供了一种用于处理纺织品的方法，其包括向先前洗涤的制品施加所述织物漂洗组合物，优选漂洗循环织物柔软剂组合物，由此可以显着提高如此处理的制品的SPF值。
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