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1.发明申请COMPOSITION FOR FORMING TRANSPARENT ELECTROCONDUCTIVE FILM, TRANSPARENT ELECTROCONDUCTIVE FILM, AND DISPLAY 审中-公开形成透明电极膜，透明电极膜和显示器的组合物公开(公告)号：US20100025638A1
公开(公告)日：2010-02-04
申请号：US12520660
申请日：2007-06-06
申请人： Masamichi Murota , Hirotoshi Umeda , Hiroshi Ikeda , Kunio Omura , Masato Murouchi , Kenji Hayashi , Daigou Mizoguchi , Masaaki Murakami
发明人： Masamichi Murota , Hirotoshi Umeda , Hiroshi Ikeda , Kunio Omura , Masato Murouchi , Kenji Hayashi , Daigou Mizoguchi , Masaaki Murakami
摘要： A composition includes a binder component and a conductive powder and a high-refractive-index powder both dispersed in the binder component, wherein the conductive powder includes 0.1 to 30 mass % of a tin hydroxide powder and 70 to 99.9 mass % of other conductive powder. The composition enables to form a transparent conductive film having excellent scratch resistance, excellent antistatic properties, an extremely high visible light transmittance and a controllable refractive index. Also described is the transparent conductive film. Further described is a display having the transparent conductive film on the display surface.
摘要翻译： 组合物包括分散在粘合剂组分中的粘合剂组分和导电粉末和高折射率粉末，其中导电粉末包含0.1至30质量％的氢氧化锡粉末和70至99.9质量％的其它导电粉末 。 该组合物能够形成具有优异的耐擦伤性，优异的抗静电性，极高的可见光透射率和可控的折射率的透明导电膜。 还描述了透明导电膜。 进一步描述了在显示表面上具有透明导电膜的显示器。
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2.发明申请公开(公告)号：US20100232024A1
公开(公告)日：2010-09-16
申请号：US12304005
申请日：2007-06-06
申请人： Masamichi Murota , Hiroshi Ikeda , Kunio Omura , Masato Murouchi , Kenji Hayashi , Daigou Mizoguchi , Masaaki Murakami
发明人： Masamichi Murota , Hiroshi Ikeda , Kunio Omura , Masato Murouchi , Kenji Hayashi , Daigou Mizoguchi , Masaaki Murakami
摘要： Through employment of a binder component, tin hydroxide powder serving as a conductive powder, and a high-refractive index powder; through dispersal of tin hydroxide powder and light-transmission-ensuring microparticles in a binder component at a predetermined ratio; and through employment of a specific binder component and, as a conductive powder, tin hydroxide powder and a conductive powder other than tin hydroxide powder at a predetermined ratio, there can be provided a composition which can form a transparent conductive film that exhibits excellent antistatic effect, and has very high visible light transmittance and provides transmitted images with natural hue by virtue of no color absorption wherein, if desired, the film also exhibits excellent scratch resistance and high antiglare effect, or the refractive index of the film can be controlled; such a transparent conductive film, and a display having such a transparent conductive film on a screen thereof.
摘要翻译： 通过使用粘合剂成分，用作导电粉末的氢氧化锡粉末和高折射率粉末; 通过以预定比例将粘结剂组分中的氢氧化锡粉末和透光确保微粒分散在其中; 并且通过使用特定的粘合剂成分，作为导电粉末，以氢氧化锡粉末和除了氢氧化锡粉末以外的导电粉末以规定的比例，可以提供能够形成表现出优异的抗静电效果的透明导电膜的组合物 ，并且具有非常高的可见光透射率，并且由于没有颜色吸收而提供具有自然色调的透射图像，其中如果需要，该膜还表现出优异的耐刮擦性和高防眩光效果，或者可以控制该膜的折射率; 这种透明导电膜，以及在其屏幕上具有这种透明导电膜的显示器。
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3.发明授权Zirconium oxide dispersion, photo-curing composition containing zirconium oxide particle, and cured film 失效氧化锆分散体，含有氧化锆颗粒的光固化组合物和固化膜公开(公告)号：US08507574B2
公开(公告)日：2013-08-13
申请号：US12516652
申请日：2007-06-06
CPC分类号： C01G25/02 , B01F17/0007 , B82Y30/00 , C01P2002/50 , C01P2004/64 , C01P2006/60 , C09C1/00 , Y10T428/24893
摘要： The present invention provides a zirconium oxide dispersion which contains zirconium oxide particles, a metal complex, and a dispersion medium and which has excellent storage stability; a photo-curing composition containing zirconium oxide particles which contains zirconium oxide particles, a metal complex, an actinic energy ray-curing compound, a photopolymerization initiator, and a dispersion medium and which composition can form, on a surface of a substrate, a cured film having excellent transparency and high refractive index, and which composition does not corrode a metal-made apparatus employed in a dispersion process and a coating apparatus; and a cured film produced by applying onto a substrate the photo-curing composition containing zirconium oxide particles through coating or printing, followed by hardening.
摘要翻译： 本发明提供一种氧化锆分散体，其含有氧化锆粒子，金属络合物和分散介质，其保存稳定性优异; 包含氧化锆颗粒的氧化锆颗粒的光固化组合物，金属络合物，光化学能量射线固化化合物，光聚合引发剂和分散介质，并且组合物可以在基材的表面上形成固化的 具有优异的透明度和高折射率的膜，并且该组合物不会腐蚀在分散方法中使用的金属制造装置和涂布装置; 以及通过涂布或印刷将含有氧化锆颗粒的光固化组合物施加到基板上，随后硬化而制成的固化膜。
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4.发明申请Zirconium Oxide Dispersion, Photo-curing Composition Containing Zirconium Oxide Particle, and Cured Film 失效氧化锆分散体，含有氧化锆颗粒的光固化组合物和固化膜公开(公告)号：US20100068482A1
公开(公告)日：2010-03-18
申请号：US12516652
申请日：2007-06-06
CPC分类号： C01G25/02 , B01F17/0007 , B82Y30/00 , C01P2002/50 , C01P2004/64 , C01P2006/60 , C09C1/00 , Y10T428/24893
摘要： The present invention provides a zirconium oxide dispersion which contains zirconium oxide particles, a metal complex, and a dispersion medium and which has excellent storage stability; a photo-curing composition containing zirconium oxide particles which contains zirconium oxide particles, a metal complex, an actinic energy ray-curing compound, a photopolymerization initiator, and a dispersion medium and which composition can form, on a surface of a substrate, a cured film having excellent transparency and high refractive index, and which composition does not corrode a metal-made apparatus employed in a dispersion process and a coating apparatus; and a cured film produced by applying onto a substrate the photo-curing composition containing zirconium oxide particles through coating or printing, followed by hardening.
摘要翻译： 本发明提供一种氧化锆分散体，其含有氧化锆粒子，金属络合物和分散介质，其保存稳定性优异; 包含氧化锆颗粒的氧化锆颗粒的光固化组合物，金属络合物，光化学能量射线固化化合物，光聚合引发剂和分散介质，并且组合物可以在基材的表面上形成固化的 具有优异的透明度和高折射率的膜，并且该组合物不会腐蚀在分散方法中使用的金属制造装置和涂布装置; 以及通过涂布或印刷将含有氧化锆颗粒的光固化组合物施加到基板上，随后硬化而制成的固化膜。
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5.发明申请公开(公告)号：US20110037036A1
公开(公告)日：2011-02-17
申请号：US12933480
申请日：2009-03-18
IPC分类号： H01B1/12
摘要： Disclosed is composition providing high refractive index to form a transparent conductive film having excellent transparency and high refractive index, a transparent conductive film produced thereby, a display having the transparent conductive film, and a dispersion having high storage stability for use in preparation of the composition. LCDs employ an anti-reflection film produced from the composition containing a metal complex in a resin solution or a solvent and a high refractive index metal oxide and a conductive metal oxide dispersed therein. However, conventional dispersion has problems such as corroding an apparatus and a material employed in a dispersion step and poor storage stability. Disclosed is a dispersion which contains a high refractive index metal oxide having a refractive index of 1.8 or higher, a conductive metal oxide, an alkoxide-free metal complex, and a dispersion medium, and which has a water content of 3 mass % or less.
摘要翻译： 公开了提供高折射率的组合物，以形成具有优异的透明性和高折射率的透明导电膜，由此制备的透明导电膜，具有透明导电膜的显示器和用于制备组合物的具有高储存稳定性的分散体 。 LCD采用由树脂溶液或溶剂中含有金属络合物的组合物和分散在其中的高折射率金属氧化物和导电金属氧化物制成的抗反射膜。 然而，传统的分散体具有腐蚀装置和在分散步骤中使用的材料和存储稳定性差的问题。 公开了含有折射率为1.8以上的高折射率金属氧化物，导电性金属氧化物，不含醇盐的金属络合物和分散介质的分散液，其含水量为3质量％以下 。
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6.发明申请公开(公告)号：US20110039081A1
公开(公告)日：2011-02-17
申请号：US12988945
申请日：2009-04-20
申请人： Masato Murouchi , Kenji Hayashi , Kaoru Suzuki , Masaaki Murakami
发明人： Masato Murouchi , Kenji Hayashi , Kaoru Suzuki , Masaaki Murakami
CPC分类号： G02B1/10 , C08K3/22 , C08K5/0091 , G02B27/0006 , G02F1/133502 , Y10T428/24942
摘要： A transparent-film-forming composition contains at least one microparticle-form inorganic substance having a refractive index of 1.80 or higher and lower than 3.00 (ingredient A), at least one microparticle-form inorganic substance having a refractive index of 1.55 or higher and lower than 1.80 (ingredient B), and a binder having a refractive index lower than that of the ingredient B, and preferably, a dispersion stabilizer, and being capable of forming, on a surface of a transparent substrate, a transparent film having excellent transparency and free from interference-related disturbance. A transparent-film-layered product has a transparent substrate and, on a surface of the substrate, a transparent film formed from the composition, which layered product exhibits a difference in refractive index between the transparent substrate and the transparent film of 0.03 or smaller and excellent transparency, and providing minimized interference-related disturbance.
摘要翻译： 透明膜形成组合物含有折射率为1.80以上且低于3.00（成分A）的至少一种微粒形式的无机物质，至少一种折射率为1.55以上的微粒形式的无机物质，以及 低于1.80（成分B）和折射率低于成分B的粘合剂，优选分散稳定剂，并且能够在透明基材的表面上形成透明性优异的透明膜 并且没有干扰相关的干扰。 透明膜层积体具有透明基板，并且在基板的表面上形成由该组合物形成的透明膜，该层叠体的透明基板和透明膜之间的折射率差为0.03以下， 良好的透明度，并且提供最小的与干扰有关的干扰。
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7.发明授权公开(公告)号：US08182574B2
公开(公告)日：2012-05-22
申请号：US12730776
申请日：2010-03-24
申请人： Yoshiaki Takata , Hiroki Hirata , Jun-etsu Satoh , Yasuro Niidome , Sunao Yamada , Koji Nishioka , Hideya Kawasaki , Daigou Mizoguchi , Masanori Nagai , Masato Murouchi , Masaoki Ishihara
发明人： Yoshiaki Takata , Hiroki Hirata , Jun-etsu Satoh , Yasuro Niidome , Sunao Yamada , Koji Nishioka , Hideya Kawasaki , Daigou Mizoguchi , Masanori Nagai , Masato Murouchi , Masaoki Ishihara
IPC分类号： B22F9/24
CPC分类号： B22F9/24 , B22F1/0025 , B22F2999/00 , B82Y30/00 , C22C5/02 , C23C24/00 , C23C24/08 , Y10S977/899 , B22F1/0088 , B22F1/0085
摘要： The present invention provides metal fine particles which have selective wavelength absorption characteristics in a wavelength region from visible light to near infrared light, and have sharp absorption characteristics, and influences little the surrounding wavelength, and therefore, they yield tones having high chroma. The present invention provides metal fine particles wherein an aspect ratio is in a range from 1.1 to 8.0, a maximum absorption wavelength in plasmon absorption is in a range from 400 nm to 1,200 nm, and an absorption coefficient at a peak position of the maximum absorption wavelength is in a range from 6,000 to 20,000 L/mol·cm (measurement concentration: 1.6×10−4 mol/L, and solvent: water).
摘要翻译： 本发明提供在从可见光到近红外光的波长区域中具有选择性波长吸收特性的金属微粒，并且具有尖锐的吸收特性，并且影响周围波长很小，因此它们产生色度高的色调。 本发明提供金属细颗粒，其中纵横比在1.1至8.0的范围内，等离子体激元吸收中的最大吸收波长在400nm至1200nm的范围内，并且在最大吸收峰峰位置处的吸收系数 波长在6000〜20,000L / mol·cm（测定浓度：1.6×10 -4 mol / L，溶剂：水）的范围内。
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公开(公告)号：US07976609B2
公开(公告)日：2011-07-12
申请号：US12704364
申请日：2010-02-11
申请人： Yasuro Niidome , Sunao Yamada , Koji Nishioka , Hideya Kawasaki , Hiroki Hirata , Daigou Mizoguchi , Yoshiaki Takata , Jun-etsu Satoh , Masaoki Ishihara , Masanori Nagai , Masato Murouchi
发明人： Yasuro Niidome , Sunao Yamada , Koji Nishioka , Hideya Kawasaki , Hiroki Hirata , Daigou Mizoguchi , Yoshiaki Takata , Jun-etsu Satoh , Masaoki Ishihara , Masanori Nagai , Masato Murouchi
CPC分类号： B22F1/0025 , B22F9/24 , B22F2999/00 , B82Y30/00 , C30B7/00 , C30B7/14 , C30B29/605 , Y10S977/762 , Y10S977/896 , B22F2202/11
摘要： A method for manufacturing metal nanorods includes: a step of adding a reducing agent to a metallic salt solution; a step of radiating light into the metallic salt solution containing the reducing agent; and a step of leaving the light-radiated metallic salt solution containing the reducing agent stationary in a dark place so as to grow metal nanorods. Metal nanorods can be also grown by forming a mixed solution by fractionating the above light-radiated metallic salt solution and mixing the fractionated metallic salt solution into a non-radiated metallic salt solution containing the reducing agent, or mixing a non-radiated metallic salt solution and the reducing agent into the above light-radiated metallic salt solution; and leaving the mixed solution stationary in a dark place so as to grow metal nanorods.
摘要翻译： 金属纳米棒的制造方法包括：向金属盐溶液中添加还原剂的工序; 将光照射到含有还原剂的金属盐溶液中的步骤; 以及将含有还原剂的光照射的金属盐溶液静置在黑暗处，以便生长金属纳米棒的步骤。 金属纳米棒也可以通过将上述光照的金属盐溶液分级分离并将分级的金属盐溶液混合到含有还原剂的非辐射金属盐溶液中，或混合未辐射的金属盐溶液 并将还原剂加入上述光照金属盐溶液中; 并将混合溶液静置在黑暗的地方，以便生长金属纳米棒。
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9.发明授权Method for manufacturing metal fine particles, metal fine particles manufactured thereby, and composition, light absorbing material and applied products containing the same 有权制造金属微粒的方法，由此制造的金属微粒，以及组合物，光吸收材料和含有此的金属微粒公开(公告)号：US07527668B2
公开(公告)日：2009-05-05
申请号：US11571316
申请日：2005-07-06
IPC分类号： B22F9/24
CPC分类号： C09C1/62 , B22F1/0025 , B22F9/24 , B82Y30/00 , C01P2002/84 , C01P2004/16 , C01P2004/32 , C01P2004/54 , C01P2004/62 , C08K3/08 , C08K9/04 , C08K2201/016 , C09D7/62 , C09D7/67 , C09D7/68 , C09D11/037 , C30B7/14 , C30B29/02 , C30B29/60 , Y10T428/12014
摘要： This method for manufacturing metal fine particles includes using an aqueous solution containing an amine having a reducing capacity and an ammonium salt having substantially no reducing capacity so as to reduce metal ions with said amine in a presence of said ammonium salt, thereby manufacturing rod-shaped metal fine particles. This metal fine particles are manufactured by this method for manufacturing metal fine particles, and have a major axis of 400 nm or less, a minor axis of 15 nm or less, and an aspect ratio of more than 1.
摘要翻译： 该金属微粒的制造方法包括使用含有还原能力的胺水溶液和基本上没有还原能力的铵盐，以便在所述铵盐存在下用所述胺还原金属离子，由此制造棒状 金属微粒。 该金属微粒通过该金属微粒的制造方法制造，长轴为400nm以下，短轴为15nm以下，长径比大于1。
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10.发明授权Metallic fine particles, process for producing the same, composition containing the same, and use thereof 有权金属微粒，其制造方法，含有它们的组合物及其用途公开(公告)号：US07846976B2
公开(公告)日：2010-12-07
申请号：US11721108
申请日：2005-12-08
IPC分类号： C09K3/00
CPC分类号： A61K8/30 , A61Q1/02 , B22F1/0018 , B22F9/24 , B22F2998/00 , B82Y30/00 , C08K3/08 , C08K9/04 , C09D5/00 , C09D7/67 , C09D7/68 , C09D7/70 , C09D11/037 , H01B1/02 , Y10T428/298 , Y10T428/2991 , B22F1/0025
摘要： A process for producing metallic fine particles is provided by, the reduction of the metallic ions performed in two steps using two types of reducing agents which significantly differ in reducing ability thereof, in which a reducing agent in which the reduction ability is strong is used in the first reduction step, and a reducing agent in which the reduction ability is weak is used in the second reduction step, and the nano-sized metallic fine particles are produced. An aqueous metallic salt solution containing a surfactant is used and a two-step reduction is performed in the same vessel, in which as the reducing agent of the first reduction process, at least one selected from the group consisting of boron hydride, dimethylamine borane, hydrazine, and ascorbic acid is used, and as the reducing agent of the second reduction process, specific alkylamine or alkanolamine is used.
摘要翻译： 通过使用两种还原能力显着不同的还原剂的还原能力差的两种还原剂还原金属离子来进行金属离子的还原，其中使用还原能力强的还原剂 在第二还原工序中使用第一还原工序和还原能力弱的还原剂，制造纳米尺寸的金属微粒。 使用含有表面活性剂的金属盐水溶液，在同一容器中进行两步还原，其中作为第一还原方法的还原剂，选自硼氢化物，二甲胺硼烷， 肼和抗坏血酸，并且作为第二还原方法的还原剂，使用特定的烷基胺或链烷醇胺。
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