公开(公告)号：US20100179353A1

公开(公告)日：2010-07-15

申请号：US12377831

申请日：2007-08-14

申请人： Masataka Nakanishi ,  Katsuhiko Oshimi ,  Takao Sunaga

发明人： Masataka Nakanishi ,  Katsuhiko Oshimi ,  Takao Sunaga

IPC分类号： C07C43/03

CPC分类号： C08G59/063

摘要： This invention provides a modified liquid epoxy resin having a low viscosity and a high performance, which is obtained by reacting a mixture of a bisphenol and a phenol aralkyl resin with an epiholohydrin. The bisphenol is preferable to be bisphenol F and is further preferable to have a bifunctional form purity as detected by gel permeation chromatography at UV 254 nm of not less than 95% by area in view of the fluidity. Moreover, the mixture of bisphenol and the phenol aralkyl resin is preferable to have a ratio of the phenol aralkyl resin of 10-70% by mass.

摘要翻译： 本发明提供一种具有低粘度和高性能的改性液体环氧树脂，其通过使双酚和苯酚芳烷基树脂的混合物与外露醇反应而获得。 考虑到流动性，双酚优选为双酚F，并且进一步优选具有通过凝胶渗透色谱法在UV 254nm下检测不超过95％面积的双官能形式纯度。 此外，双酚和苯酚芳烷基树脂的混合物的苯酚芳烷基树脂的比例优选为10-70质量％。

公开(公告)号：US20090054587A1

公开(公告)日：2009-02-26

申请号：US11908526

申请日：2006-03-14

申请人： Katsuhiko Oshimi ,  Yasumasa Akatsuka ,  Masataka Nakanishi ,  Takao Sunaga

发明人： Katsuhiko Oshimi ,  Yasumasa Akatsuka ,  Masataka Nakanishi ,  Takao Sunaga

IPC分类号： C08G59/00 ,  C08G65/32 ,  C08G65/38

CPC分类号： C08G59/245 ,  C09D163/00 ,  Y10T428/31511

摘要： An object of the present invention is to provide an epoxy resin exhibiting superior heat resistance, dielectric properties, water resistance, and workability, a resin composition containing the epoxy resin, and a prepreg and a laminated plate. The epoxy resin of the invention is expressed by the following formula. (In the formula, R represents a hydrocarbon group having a carbon number of 1 to 4. m Represents an integer of 1 to 4 and when m is 2 to 4, R's may be the same or different. n Represents a positive number of 1 to 6 on average.) The epoxy resin composition of the invention contains the epoxy resin of the invention and a curing agent.

摘要翻译： 本发明的目的是提供一种表现出优异的耐热性，介电性能，耐水性和可加工性的环氧树脂，含有环氧树脂的树脂组合物，以及预浸料和层压板。 本发明的环氧树脂由下式表示。 （式中，R表示碳原子数为1〜4的烃基。m表示1〜4的整数，m为2〜4时，R可以相同或不同，n表示正数1 平均为6）。本发明的环氧树脂组合物含有本发明的环氧树脂和固化剂。

公开(公告)号：US08981160B2

公开(公告)日：2015-03-17

申请号：US12377831

申请日：2007-08-14

申请人： Masataka Nakanishi ,  Katsuhiko Oshimi ,  Takao Sunaga

发明人： Masataka Nakanishi ,  Katsuhiko Oshimi ,  Takao Sunaga

IPC分类号： C07C43/03 ,  C08G59/06

CPC分类号： C08G59/063

摘要： This invention provides a modified liquid epoxy resin having a low viscosity and a high performance, which is obtained by reacting a mixture of a bisphenol and a phenol aralkyl resin with an epiholohydrin. The bisphenol is preferable to be bisphenol F and is further preferable to have a bifunctional form purity as detected by gel permeation chromatography at UV 254 nm of not less than 95% by area in view of the fluidity. Moreover, the mixture of bisphenol and the phenol aralkyl resin is preferable to have a ratio of the phenol aralkyl resin of 10-70% by mass.

摘要翻译： 本发明提供一种具有低粘度和高性能的改性液体环氧树脂，其通过使双酚和苯酚芳烷基树脂的混合物与外露醇反应而获得。 考虑到流动性，双酚优选为双酚F，并且进一步优选具有通过凝胶渗透色谱法在UV 254nm下检测不超过95％面积的双官能形式纯度。 此外，双酚和苯酚芳烷基树脂的混合物的苯酚芳烷基树脂的比例优选为10-70质量％。

公开(公告)号：US07968672B2

公开(公告)日：2011-06-28

申请号：US12085287

申请日：2006-11-29

申请人： Katsuhiko Oshimi ,  Shigeru Moteki ,  Takao Sunaga ,  Masataka Nakanishi ,  Sumio Ichimura

发明人： Katsuhiko Oshimi ,  Shigeru Moteki ,  Takao Sunaga ,  Masataka Nakanishi ,  Sumio Ichimura

IPC分类号： C08G65/38 ,  C08G59/00

CPC分类号： C08L61/06 ,  C08G8/10 ,  C08G59/063 ,  C08G59/688

摘要： A phenol aralkyl type phenolic resin represented by the general formula (1), wherein the total content of the compounds represented by formulae (2) to (4) is 58 to 92% as determined by GPC and the contents of the compounds represented by formulae (2) to (4) as determined by HPLC satisfy the following relationship: 0.60≦(2a+b)/(2a+2b+2c)≦0.90 wherein a is the content of the compound of formula (2); b is the content of the compound of formula (3); and c is the content of the compound of formula (4).

摘要翻译： 由通式（1）表示的苯酚芳烷基型酚醛树脂，其中由式（2）〜（4）表示的化合物的总含量为58〜92％，通过GPC测定，由式 通过HPLC测定的（2）〜（4）满足以下关系：0.60＆nlE;（2a + b）/（2a + 2b + 2c）＆nlE; 0.90其中a为式（2）化合物的含量; b是式（3）化合物的含量; 和c是式（4）化合物的含量。

公开(公告)号：US20090286929A1

公开(公告)日：2009-11-19

申请号：US12085287

申请日：2006-11-29

申请人： Katsuhiko Oshimi ,  Shigeru Moteki ,  Takao Sunaga ,  Masataka Nakanishi ,  Sumio Ichimura

发明人： Katsuhiko Oshimi ,  Shigeru Moteki ,  Takao Sunaga ,  Masataka Nakanishi ,  Sumio Ichimura

IPC分类号： C08L71/12 ,  C08G65/38 ,  C08G59/06

CPC分类号： C08L61/06 ,  C08G8/10 ,  C08G59/063 ,  C08G59/688

摘要： A phenol aralkyl type phenolic resin represented by the general formula (1), wherein the total content of the compounds represented by formulae (2) to (4) is 58 to 92% as determined by GPC and the contents of the compounds represented by formulae (2) to (4) as determined by HPLC satisfy the following relationship: 0.60≦(2a+b)/(2a+2b+2c)≦0.90 wherein a is the content of the compound of formula (2); b is the content of the compound of formula (3); and c is the content of the compound of formula (4).

摘要翻译： 由通式（1）表示的苯酚芳烷基型酚醛树脂，其中由式（2）〜（4）表示的化合物的总含量为58〜92％，通过GPC测定，由式 通过HPLC测定的（2）至（4）满足以下关系：0.60a + b）/（2a + 2b + 2c）<= 0.90其中a为式（2）化合物的含量; b是式（3）化合物的含量; 和c是式（4）化合物的含量。

公开(公告)号：US20080200636A1

公开(公告)日：2008-08-21

申请号：US11884174

申请日：2006-02-20

申请人： Masataka Nakanishi ,  Yasumasa Akatsuka ,  Katsuhiko Oshimi ,  Takao Sunaga

发明人： Masataka Nakanishi ,  Yasumasa Akatsuka ,  Katsuhiko Oshimi ,  Takao Sunaga

IPC分类号： C08G65/38

CPC分类号： C08G59/3218 ,  C08L63/00

摘要： It is an object of the present invention, with respect to a phenol aralkyl type epoxy resin, to suppress any crystal precipitation, improve the quality manageability and operation efficiency at composition production and enhance the properties, including heat resistance, thereof. It is also intended to provide a resin composition that even when stored in the form of a varnish for a prolonged period of time, is resistant to crystal precipitation, excelling in storage stability and operation efficiency, and that gives a hardening product of low dielectric constant and low dielectric tangent excelling in heat resistance, water resistance and flame retardance.There is provided an epoxy resin characterized by comprising a phenol aralkyl type epoxy resin in which a content (an area % measured by gel permeation chromatography) of a bifunctional compound is 20% or less, and provided a resin composition obtained therefrom.

摘要翻译： 本发明的目的是关于苯酚芳烷基型环氧树脂，以抑制任何晶体沉淀，提高组合物生产中的质量管理性和操作效率，并提高其耐热性的性能。 另外，为了提供一种树脂组合物，即使长时间地以清漆的形式存储，也能够耐结晶析出，保存稳定性和操作效率优异，并且能够得到低介电常数的硬化物 低介电切线耐热性，耐水性和阻燃性优异。 提供一种环氧树脂，其特征在于包含其中通过双官能化合物的含量（通过凝胶渗透色谱法测量的面积％）为20％以下的苯酚芳烷基型环氧树脂，并提供由其获得的树脂组合物。

公开(公告)号：US20120296011A1

公开(公告)日：2012-11-22

申请号：US13575661

申请日：2011-01-28

申请人： Kouichi Kawai ,  Katsuhiko Oshimi ,  Takao Sunaga ,  Kazuma Inoue

发明人： Kouichi Kawai ,  Katsuhiko Oshimi ,  Takao Sunaga ,  Kazuma Inoue

IPC分类号： C07C45/74 ,  C08L63/00 ,  C09D163/00 ,  C08G65/40

CPC分类号： H01L23/296 ,  C07C49/753 ,  C07C49/84 ,  C08G59/08 ,  C08J5/24 ,  C08J2363/00 ,  H01L23/295 ,  H01L2924/0002 ,  H01L2924/00

摘要： A phenolic compound which can be obtained by reacting the compound of the formula (1): wherein R1 groups are each independently present and represent a hydrogen atom etc. with the formula (6): wherein R4 groups are each independently present and represent a hydrogen atom etc.; and k represents the number of R4 groups and is an integer of 0 to 4 and an epoxy resin which can be obtained by reacting the phenolic compound with an epihalohydrin are excellent in solvent solubility and also of which cured product has an excellent thermal conductance.

摘要翻译： 可以通过使式（1）所示的化合物反应得到的酚类化合物：其中R 1基团各自独立地存在并且表示与式（6）的氢原子等：其中R 4基团各自独立地存在并且表示氢 原子等 k表示R4基数，为0〜4的整数，通过使酚类化合物与表卤代醇反应可以得到的环氧树脂的溶剂溶解性优异，固化物的导热性优异。

公开(公告)号：US20080032154A1

公开(公告)日：2008-02-07

申请号：US11630813

申请日：2005-07-08

申请人： Yasumasa Akatsuka ,  Katsuhiko Oshimi ,  Masataka Nakanishi

发明人： Yasumasa Akatsuka ,  Katsuhiko Oshimi ,  Masataka Nakanishi

IPC分类号： C08G65/38 ,  B05D3/00 ,  B32B15/092 ,  B32B25/08

CPC分类号： C08G59/621 ,  C08G59/063 ,  C08G59/5033 ,  C08G59/688 ,  C08J5/24 ,  C08J7/047 ,  C08J2363/02 ,  C08J2367/02 ,  C08J2379/08 ,  C08J2463/00 ,  C09D163/00 ,  Y10T428/12569 ,  Y10T428/31511 ,  C08L2666/04

摘要： An epoxy resin represented by formula (1) below: wherein the ratio of the component having two nuclei accounting for 25% or less in terms of the area corresponding to the component in a gel permeation chromatogram.

摘要翻译： 由下式（1）表示的环氧树脂：其中具有两个核的组分的比例占凝胶渗透色谱图中对应于组分的面积的25％或更小。

公开(公告)号：US08198381B2

公开(公告)日：2012-06-12

申请号：US12083030

申请日：2006-10-16

申请人： Masataka Nakanishi ,  Katsuhiko Oshimi ,  Kazuyuki Ohhashi ,  Toru Kurihashi

发明人： Masataka Nakanishi ,  Katsuhiko Oshimi ,  Kazuyuki Ohhashi ,  Toru Kurihashi

IPC分类号： C08K5/07 ,  C08K5/16 ,  C08K5/523 ,  C08L61/14 ,  C08L63/00

CPC分类号： C08G59/245 ,  B32B5/26 ,  B32B15/08 ,  B32B2260/023 ,  B32B2260/046 ,  B32B2262/0261 ,  B32B2262/0276 ,  B32B2262/10 ,  B32B2262/101 ,  B32B2262/106 ,  B32B2307/206 ,  B32B2307/306 ,  B32B2307/50 ,  B32B2307/546 ,  B32B2307/718 ,  B32B2457/04 ,  B32B2457/08 ,  C08J5/24 ,  C08J2363/00 ,  Y10T428/31511

摘要： Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (α) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin. 50≦1000×(A−B)/B≦250 (α).

摘要翻译： 公开了一种苯酚芳烷基环氧树脂，其具有以下结构，其中在满足下述条件1的同时，通过使用芳烷基作为连接基团和式（1）表示的结构，至少使苯酚或萘酚结合。 该环氧树脂在组合物的制造中的加工性优异，容易控制质量。 条件1：通过将等当量的苯酚相对于环氧当量添加而得到的酚改性环氧树脂的羟基当量（根据JIS K 0070测定）满足以下关系式（α） 环氧树脂，B为环氧树脂的环氧当量。 50＆nlE; 1000×（A-B）/ B＆nlE; 250（α）。

公开(公告)号：US07521100B2

公开(公告)日：2009-04-21

申请号：US10552183

申请日：2004-04-06

申请人： Masahiro Imaizumi ,  Toyofumi Asano ,  Naoyuki Ochi ,  Masahiro Hirano ,  Sumio Ichimura ,  Masaru Kudo ,  Katsuhiko Oshimi ,  Masataka Nakanishi ,  Yasumasa Akatsuka ,  Eiichi Nishihara ,  Masayuki Itai

发明人： Masahiro Imaizumi ,  Toyofumi Asano ,  Naoyuki Ochi ,  Masahiro Hirano ,  Sumio Ichimura ,  Masaru Kudo ,  Katsuhiko Oshimi ,  Masataka Nakanishi ,  Yasumasa Akatsuka ,  Eiichi Nishihara ,  Masayuki Itai

IPC分类号： C09K3/10 ,  G02F1/1339 ,  C08L63/02 ,  C08G59/04

CPC分类号： C08L63/00 ,  C08G59/04 ,  G02F1/1339 ,  Y10T428/10 ,  Y10T428/1059 ,  Y10T428/1073

摘要： The present invention relates to a sealant for liquid crystals having extremely low contamination nature to a liquid crystal, excellent coatability and bondability to a substrate, long service life and pot life and high adhesive strength. A sealant for liquid crystals of the present invention is characterized by comprising (a) an epoxy resin represented by general formula (1): (wherein a represents an integer of 2 to 4; n represents 0 to 3 (average value); R represents a divalent hydrocarbon group of 2 to 6 carbon atoms; A represents a polyvalent aromatic group; and G represents a glycidyl group, provided that when n is 0, (a) an epoxy resin represented by general formula (1) is a bisphenol S-type.), (b) a thermo-curing agent, (c) and a filler having average particle diameter of not larger than 3 μm.

摘要翻译： 本发明涉及一种液晶污染性极差的液晶密封剂，对基材的涂布性和粘接性，使用寿命长，使用寿命长，粘结强度高的特点。 本发明的液晶密封剂的特征在于：（a）由通式（1）表示的环氧树脂：其中a表示2〜4的整数，n表示0〜3（平均值），R表示 如果n为0，（a）由通式（1）表示的环氧树脂为双酚S-基，则表示2〜6个碳原子的二价烃基; A表示多价芳基; G表示缩水甘油基， 型），（b）热固化剂，（c）和平均粒径不大于3μm的填料。