公开(公告)号：US07312363B2

公开(公告)日：2007-12-25

申请号：US10502803

申请日：2003-02-06

申请人： Michael Stoesser ,  Edward Bohres ,  Georg Heinrich Grosch ,  Wilfried Sager

发明人： Michael Stoesser ,  Edward Bohres ,  Georg Heinrich Grosch ,  Wilfried Sager

IPC分类号： C07C41/03 ,  B01J27/26

CPC分类号： C08G65/2696 ,  B01J27/26 ,  C08G65/2663

摘要： The present invention relates to a process for reacting epoxides with an initiator compound in the presence of a double metal cyanide compound as a catalyst, said process having a shortened induction period, and the double metal cyanide compound being activated by adding the epoxide to a mixture of double metal cyanide compound and initiator compound at an internal reactor pressure of less than 1 bar, and also to the polyethers themselves obtainable by such a process.

摘要翻译： 本发明涉及一种在双金属氰化物化合物作为催化剂存在下使环氧化物与引发剂化合物反应的方法，所述方法具有缩短的诱导期，并且双金属氰化物通过向混合物中加入环氧化物而被活化 的双金属氰化物化合物和引发剂化合物，其内反应器压力小于1巴，以及可通过这种方法获得的聚醚。

公开(公告)号：US07470823B2

公开(公告)日：2008-12-30

申请号：US10506601

申请日：2003-03-10

申请人： Michael Stoesser ,  Edward Bohres ,  Georg Heinrich Grosch ,  Wilfried Sager ,  Marc Walter

发明人： Michael Stoesser ,  Edward Bohres ,  Georg Heinrich Grosch ,  Wilfried Sager ,  Marc Walter

IPC分类号： C07C41/03 ,  C10L1/185

CPC分类号： C10L1/1985 ,  C08G65/2609 ,  C08G65/2663 ,  C10L1/143 ,  C10L1/2383 ,  C10L10/04

摘要： The present invention relates to polyethers which are obtainable from 1 -butene oxide and an alcohol using a double metal cyanide compound as a catalyst and have a content of unsaturated components of 6 mol% or more, to a process for preparing such a polyether and also to the use of a polyether according to the invention as a carrier oil or in a carrier oil formulation, in particular in additive packages for gasoline fuels, and furthermore also to carrier oil formulations and also to fuels comprising a polyether according to the invention.

摘要翻译： 本发明涉及可由1-丁烯氧化物得到的聚醚和使用双金属氰化物化合物作为催化剂并且具有6mol％以上的不饱和成分含量的醇与制备这种聚醚的方法 涉及使用根据本发明的聚醚作为载体油或载体油制剂，特别是用于汽油燃料的添加剂包，以及载体油制剂，以及包含根据本发明的聚醚的燃料。

公开(公告)号：US07348460B2

公开(公告)日：2008-03-25

申请号：US10527529

申请日：2003-04-25

申请人： Christian Wulff ,  Michael Stoesser ,  Georg Heinrich Grosch ,  Kai-Uwe Baldenius ,  Edward Bohres

发明人： Christian Wulff ,  Michael Stoesser ,  Georg Heinrich Grosch ,  Kai-Uwe Baldenius ,  Edward Bohres

IPC分类号： C07C41/03 ,  C08F4/02

CPC分类号： C11D1/72 ,  B01F17/0021 ,  B01F17/0028 ,  B01J27/26 ,  C07C41/03 ,  C08G65/2609 ,  C08G65/2663 ,  C07C43/11 ,  C07C43/13

摘要： The present invention relates to a process for preparing at least one alkoxylate, which comprises bringing at least one alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide, pentylene oxide and decene oxide into contact with at least one starter compound in the presence of at least one double metal cyanide compound, with the reaction being carried out at a temperature of from 130° C. to 155° C., to the alkoxylates, in particular ethoxylates, themselves and to the use of such ethoxylates as emulsifier, foam regulator or as wetting agents for hard surfaces.

摘要翻译： 本发明涉及一种制备至少一种烷氧基化物的方法，其包括使至少一种选自环氧乙烷，环氧丙烷，环氧丁烷，环氧丁烷和氧化烯的环氧烷与至少一种起始化合物 在至少一种双金属氰化物化合物的存在下，反应在130℃至155℃的温度下进行至烷氧基化物，特别是乙氧基化物本身，以及使用这样的乙氧基化物如 乳化剂，泡沫调节剂或作为硬表面的润湿剂。

公开(公告)号：US07342140B2

公开(公告)日：2008-03-11

申请号：US10526937

申请日：2003-09-11

申请人： Edward Bohres ,  Hartmut Hibst ,  Michael Stoesser ,  Raimund Ruppel ,  Eva Baum

发明人： Edward Bohres ,  Hartmut Hibst ,  Michael Stoesser ,  Raimund Ruppel ,  Eva Baum

IPC分类号： C07C43/00

CPC分类号： C08G65/2645 ,  C08G65/266

摘要： The present invention relates to a process for preparing a polyetherol which comprises reacting at least one alkylene oxide with at least one starter compound in the presence of a catalyst of the formula I: M1p[M2qOn(OH)2(3-n)]x,  (I) and to the polyetherols prepared by such a process and to their use for the synthesis of polyurethanes, as fuel additive or as surfactant.

摘要翻译： 本发明涉及一种制备聚己二醇的方法，该方法包括在式I的催化剂存在下使至少一种环氧烷与至少一种起始化合物反应：<？in-line-formula description =“In-Line Formulas “end =”lead“？> M （I）<？in-line-formula description =“In-line Formulas”end =“tail（”）“（OH）2（3-n） “以及通过这种方法制备的聚醚酯，以及它们用于合成聚氨酯，作为燃料添加剂或作为表面活性剂的用途。

公开(公告)号：US07279517B2

公开(公告)日：2007-10-09

申请号：US10492192

申请日：2002-10-18

申请人： Ulrich Mueller ,  Michael Stoesser ,  Raimund Ruppel ,  Eva Baum ,  Edward Bohres ,  Marcus Sigl ,  Lisa Lobree ,  Omar M. Yaghi ,  Mohamed Eddaoudi

发明人： Ulrich Mueller ,  Michael Stoesser ,  Raimund Ruppel ,  Eva Baum ,  Edward Bohres ,  Marcus Sigl ,  Lisa Lobree ,  Omar M. Yaghi ,  Mohamed Eddaoudi

IPC分类号： C08L75/00 ,  C07C67/26

CPC分类号： C08G65/266 ,  C08G18/48

摘要： The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least one alkoxylating agent in the presence of a catalyst system, wherein a polyether alcohol is obtained. The catalyst system comprises a metallo organic framework mate-rial comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion. Furthermore it relates to polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.

摘要翻译： 本发明涉及有机化合物的烷氧基化方法，包括在催化剂体系存在下使至少一种有机化合物与至少一种烷氧基化剂反应，其中获得聚醚醇。 催化剂体系包括金属有机骨架材料，其包含孔和至少一种金属离子以及与所述金属离子配位结合的至少一种至少二齿有机化合物。 此外，它涉及可通过使用制备的聚醚醇作为原料获得的聚氨酯或聚氨酯泡沫。

公开(公告)号：US07332465B2

公开(公告)日：2008-02-19

申请号：US10527959

申请日：2003-04-25

申请人： Christian Wulff ,  Kai-Uwe Baldenius ,  Martin Scholtissek ,  Michael Stoesser ,  Norbert Wagner ,  Edward Bohres

发明人： Christian Wulff ,  Kai-Uwe Baldenius ,  Martin Scholtissek ,  Michael Stoesser ,  Norbert Wagner ,  Edward Bohres

IPC分类号： C11D1/722 ,  C11D3/02 ,  C11D7/02

CPC分类号： C11D1/722

摘要： The present invention relates to compositions at least comprising one alkoxylate of the formula RO(A)n(B)mH, to processes for the preparation of such compositions, in particular in the presence of double-metal cyanide compounds as catalyst, and their use as emulsifier, foam regulator or as wetting agents for hard surfaces. Moreover, the present invention also relates to the use of such compositions in detergents and surfactant formulations.

摘要翻译： 本发明涉及至少包含一种式RO（A）N（B）m H的烷氧基化物的组合物，特别是制备这种组合物的方法 在作为催化剂的双金属氰化物化合物的存在下，它们用作乳化剂，泡沫调节剂或作为硬表面的润湿剂。 此外，本发明还涉及这种组合物在洗涤剂和表面活性剂制剂中的用途。

公开(公告)号：US20100210461A1

公开(公告)日：2010-08-19

申请号：US12669215

申请日：2008-07-18

申请人： Michael Stoesser ,  Rainer Berghaus ,  Gerhard Krennrich ,  Markus Kummeter ,  Guenter Oetter ,  Jurith Montag

发明人： Michael Stoesser ,  Rainer Berghaus ,  Gerhard Krennrich ,  Markus Kummeter ,  Guenter Oetter ,  Jurith Montag

IPC分类号： A01N63/00

CPC分类号： A01N25/30 ,  A01N37/46 ,  A01N37/50 ,  A01N43/32 ,  A01N43/40 ,  A01N43/54 ,  A01N43/653 ,  A01N43/76 ,  A01N43/88 ,  A01N43/90 ,  A01N2300/00

摘要： The present invention relates to agrochemical compositions which comprise certain alcohol alkoxylates of the amphiphilic type, and the use of the alcohol alkoxylates as activity-improving adjuvant in the agrochemical sector, and in particular in the plant protection sector. The alcohol alkoxylates take the form of alkoxylated alcohols of the formula (I) R—O—[(CnH2nO)x-(PhC2H3O)y—(CmH2mO)z]co—H  (I) in which R represents a hydrocarbon radical having 1 to 30 carbon atoms; n, m independently of one another represent a value of from 2 to 16; x represents a value of from 0 to 100; y represents a value of from 0.5 to 100; z represents a value of from 0 to 100; and x+y+z corresponds to a value of from 2 to 100, where at least one of x or z is greater than 0.

摘要翻译： 本发明涉及包含两亲型某些醇烷氧基化物的农用化学组合物，以及在农业化学领域，特别是植物保护领域中使用醇烷氧基化物作为活性改进助剂。 醇烷氧基化物采用式（I）R-O - [（CnH2nO）x-（PhC2H3O）y-（CmH2mO）z] co-H（I）的烷氧基​​化醇的形式，其中R表示具有1 至30个碳原子; n，m彼此独立地表示2至16的值; x表示0至100的值; y表示0.5〜100的值; z表示0至100的值; x + y + z对应于2至100的值，其中x或z中的至少一个大于0。

公开(公告)号：US20100305018A1

公开(公告)日：2010-12-02

申请号：US12675472

申请日：2008-08-28

申请人： Christian Bittner ,  Juergen Tropsch ,  Rolf-Dieter Kahl ,  Michael Stoesser ,  Markus Kummeter

发明人： Christian Bittner ,  Juergen Tropsch ,  Rolf-Dieter Kahl ,  Michael Stoesser ,  Markus Kummeter

IPC分类号： C11D1/825 ,  C11D1/68 ,  C11D1/722

CPC分类号： C11D1/825 ,  C08G65/2609 ,  C08G65/2648 ,  C08G65/30 ,  C08G65/332 ,  C08L71/02 ,  C11D1/72 ,  C11D1/722 ,  C11D1/74 ,  C11D3/0026

摘要： The present invention relates to low-foam surfactant mixtures comprising esters of the general formula (I) and alcohols thereof of the general formula (Ia) where R is a branched or unbranched alkyl radical having from 8 to 22 carbon atoms; Ra, R1 are each independently hydrogen or a branched or unbranched alkyl radical having from 1 to 5 carbon atoms; R2 is a branched or unbranched alkyl radical having from 5 to 17 carbon atoms; l, n are each independently from 1 to 5 and m is from 38 to 70, and where the ratio of the molar amounts of the esters (I) to the alcohols (Ia) is at least 17:3. The invention further relates to the process for preparing them and to their use and to washing and cleaning composition formulations comprising them.

摘要翻译： 本发明涉及包含通式（I）的酯和通式（Ia）的醇的低泡表面活性剂混合物，其中R是具有8-22个碳原子的支链或非支链烷基; R a，R 1各自独立地为氢或具有1至5个碳原子的支链或非支链烷基; R2是具有5至17个碳原子的支链或非支链烷基; 1，n各自独立地为1至5，m为38至70，并且其中酯（I）与醇（Ia）的摩尔量之比至少为17:3。 本发明还涉及制备它们的方法及其用途以及洗涤和清洗包含它们的组合物制剂。

公开(公告)号：US20100048935A1

公开(公告)日：2010-02-25

申请号：US12524005

申请日：2008-01-21

申请人： Darijo Mijolovic ,  Markus Kummeter ,  Michael Stoesser ,  Stephan Bauer ,  Stephan Goettke

发明人： Darijo Mijolovic ,  Markus Kummeter ,  Michael Stoesser ,  Stephan Bauer ,  Stephan Goettke

IPC分类号： C07C68/04

CPC分类号： C08G64/0208 ,  C08G64/34 ,  C08G65/2603 ,  C08G65/2606 ,  C08G65/2663

摘要： The invention relates to a process for preparing polyether carbonate polyols by addition of alkylene oxides and carbon dioxide onto H-functional starter substances using DMC catalysts, wherein one or more starter substances are initially placed in the reactor and one or more starter substances are metered continuously into the reactor during the reaction.

摘要翻译： 本发明涉及通过使用DMC催化剂将氧化烯和二氧化碳加入到H官能起始物质中制备聚醚碳酸酯多元醇的方法，其中一个或多个起始物质最初置于反应器中并且一个或多个起始物质连续地计量 在反应期间进入反应器。

公开(公告)号：US20110260101A1

公开(公告)日：2011-10-27

申请号：US13140653

申请日：2009-12-18

申请人： Frank Rittig ,  Ulrich Steinbrenner ,  Wolfgang Spiegler ,  Michael Stoesser ,  Inge Langbein ,  Richard Baur

发明人： Frank Rittig ,  Ulrich Steinbrenner ,  Wolfgang Spiegler ,  Michael Stoesser ,  Inge Langbein ,  Richard Baur

IPC分类号： C09K3/00

CPC分类号： B01F17/0092 ,  C11D1/72 ,  C11D1/8255

摘要： The present invention relates to a surfactant mixture comprising (A) a short-chain component comprising the alkoxylation product of alkanols, where the alkanols have 8 to 12 carbon atoms and the average number of alkoxy groups per alkanol group in the alkoxylation product assumes a value from 0.1 to 30, the alkoxy groups are C2-10-alkoxy groups and the alkanols have an average degree of branching of at least 1; and (B) a long-chain component comprising the alkoxylation product of alkanols, where the alkanols have 15 to 19 carbon atoms and the average number of alkoxy groups per alkanol group in the alkoxylation product assumes a value from 0.1 to 30, the alkoxy groups are C2-10-alkoxy groups and the alkanols have an average degree of branching of at least 2.5; and/or phosphate esters, sulfate esters and ether carboxylates thereof. The present invention also relates to formulations comprising such surfactant mixtures, to methods of producing the surfactant mixtures and to their use.

摘要翻译： 本发明涉及一种表面活性剂混合物，其包含（A）包含烷醇的烷氧基化产物的短链组分，其中烷醇具有8至12个碳原子，并且烷氧基化产物中每个烷醇基团的烷氧基的平均数呈现值 0.1至30，烷氧基为C 2-10 - 烷氧基，链烷醇的平均支化度至少为1; 和（B）包含烷醇的烷氧基化产物的长链组分，其中链烷醇具有15至19个碳原子，烷氧基化产物中每个烷醇基团的烷氧基的平均数为0.1-30，烷氧基 是C 2-10 - 烷氧基，而链烷醇的平均支化度至少为2.5; 和/或其磷酸酯，硫酸酯和醚羧酸盐。 本发明还涉及包含这种表面活性剂混合物的制剂，制备表面活性剂混合物的方法及其用途。