摘要:
A method for manufacturing a catalyst layer for a fuel cell support for a catalyst layer comprises the steps of vapor-growing a carbonaceous porous material having a nano-size structure, such as carbon nanowalls (CNWs), and supporting and dispersing a catalyst component and/or an electrolyte component on the support for a catalyst layer. The method simplifies the process for manufacturing an electrode layer for fuel cells and improves the dispersibility of the catalyst component and the electrolyte, whereby the generation efficiency of a fuel cell can be improved.
摘要:
A fuel cell structure comprises a diffusion layer and/or a catalyst layer which are made of a carbonaceous porous material having a nano-size structure, such as carbon nanowall (CNW). A method of manufacturing the structure is also disclosed. The structure and method simplify the process of manufacturing a fuel cell electrode comprised of an electrode catalyst layer and a gas diffusion layer. The electrical conductivity of the catalyst layer is increased and the diffusion efficiency of the diffusion layer is improved, whereby the electricity generation efficiency of the fuel cell can be improved.
摘要:
A positive electrode (10) for a lithium secondary battery, including a positive electrode collector (20), and a positive electrode active substance layer (30) that is supported on the positive electrode collector (20) and includes carbon nanowalls (32) which are formed on the positive electrode collector (20), and a positive electrode active substance (36) which is supported on the carbon nanowalls (32).
摘要:
A fuel cell structure comprises a diffusion layer and/or a catalyst layer which are made of a carbonaceous porous material having a nano-size structure, such as carbon nanowall (CNW). A method of manufacturing the structure is also disclosed. The structure and method simplify the process of manufacturing a fuel cell electrode comprised of an electrode catalyst layer and a gas diffusion layer. The electrical conductivity of the catalyst layer is increased and the diffusion efficiency of the diffusion layer is improved, whereby the electricity generation efficiency of the fuel cell can be improved.
摘要:
To improve the crystallinity of carbon nanowalls.The method of the invention for producing carbon nanowalls, includes forming carbon nanowalls on a surface of a base in a plasma atmosphere containing hydrogen and a raw material containing at least carbon and fluorine as its constituent elements, oxygen plasma is added to the plasma atmosphere. The hydrogen plasma was generated through injecting, to the plasma generation site, hydrogen radicals generated at a site different from the plasma atmosphere. The raw material is at least one member selected from among C2F6, CF4, and CHF3.
摘要:
Provided is a method for controlling a carbon nanowall (CNW) structure having improved corrosion resistance against high potential by varying the spacing between the carbon nanowall (CNW) walls so that its surface area and crystallinity are controlled. Also provided is a carbon nanowall (CNW) with a high surface arca and a carbon nanowall (CNW) with a high crystallinity, both of which have a controlled structure. According to the present invention, provided are: (1) a carbon nanowall, characterized by having a wall surface area of 50 cm2/cm2-substrate·μm or more; (2) a carbon nanowall, characterized by having a crystallinity such that the D band half value width in the Raman spectrum measured with an irradiation laser wavelength of 514.5 nm is 85 cm−1 or less: and (3) a carbon nanowall, characterized by having not only a wall surface area of 50 cm2/cm2-substrate·μm or more but also a crystallinity such that the D-band half value width in the Raman spectrum measured with an irradiation laser wavelength of 14.5 nm is 85 cm−1 or less.
摘要翻译:提供了一种通过改变碳纳米壁(CNW)壁之间的间距来控制其表面积和结晶度来控制具有改善的高电位耐腐蚀性的碳纳米壁(CNW)结构的方法。 还提供具有高表面积的碳纳米壁(CNW)和具有高结晶度的碳纳米壁(CNW),两者都具有受控的结构。 根据本发明,提供:(1)一种碳纳米壁,其特征在于,具有50cm 2 / cm 2以上的基板的壁面积以上; (2)碳纳米壁,其特征在于具有结晶度使得以514.5nm的照射激光波长测量的拉曼光谱中的D带半值宽度为85cm -1以下:(3)碳纳米壁,其特征在于, 通过不仅具有50cm 2 / cm 2以上的壁面积等于或大于50的壁面积,而且结晶度使得以14.5nm的照射激光波长测量的拉曼光谱中的D带半值宽度为85cm -1 或更少。
摘要:
An object of the present invention is to provide a sample substrate for laser desorption ionization mass spectrometry for LDI-MS which substrate enables mass spectrometric analysis of a sample correctly at high sensitivity without generating interference peaks upon irradiation of the sample to laser light and uniform application of the sample onto a base. Another object of the invention is to provide a mass spectrometer (device) employing the sample substrate.In the sample substrate for laser desorption ionization mass spectrometry, the sample substrate is formed of a base and carbon nanowalls having wall surfaces onto which a sample to undergo mass spectrometry is applied, wherein the carbon nanowalls are formed on the base so as to stand on the base. The surfaces of carbon nanowalls serve as an ionization medium and hydrophilized. By use of the sample substrate, mass spectrometry of a sample having a wide range (high to low) molecular weight can be reliably performed at high precision and sensitivity.
摘要:
A negative electrode (10) for a lithium secondary battery, including a negative electrode collector (20), and a negative electrode active substance layer (30) that is supported on the negative electrode collector (20) and includes carbon nanowalls (32) which are formed on the negative electrode collector (20), and a negative electrode active substance (36) which is supported on the carbon nanowalls (32).
摘要:
A negative electrode (10) for a lithium secondary battery, including a negative electrode collector (20), and a negative electrode active substance layer (30) that is supported on the negative electrode collector (20) and includes carbon nanowalls (32) which are formed on the negative electrode collector (20), and a negative electrode active substance (36) which is supported on the carbon nanowalls (32).
摘要:
To provide a novel method for producing carbon nanowalls and an apparatus suitable for carrying out the method. A source gas 32 containing carbon is introduced into a reaction chamber 10. The reaction chamber 10 includes a parallel plate-type capacitively coupled plasma (CCP) generator 20 including a first electrode 22 and a second electrode 24. The irradiation of electromagnetic waves plasmatizes the source material 32 to create a plasma atmosphere 34. In a radical-generating chamber 41 disposed outside the reaction chamber 10, hydrogen radicals 38 are generated by decomposing radical source gas 36 containing hydrogen using RF waves or other waves. The hydrogen radicals 38 are introduced into the plasma atmosphere 34, whereby carbon nanowalls are formed on a substrate 5 disposed on the second electrode 24.