公开(公告)号：US20060237326A1

公开(公告)日：2006-10-26

申请号：US11390206

申请日：2006-03-28

申请人： Ming-Der Ger ,  Chin-Lung Chang ,  Yuh Sung ,  Niann-Tsyr Wen ,  Wei-Kun Chen

发明人： Ming-Der Ger ,  Chin-Lung Chang ,  Yuh Sung ,  Niann-Tsyr Wen ,  Wei-Kun Chen

IPC分类号： C25D11/00

CPC分类号： C25D11/30

摘要： A method for surface treatment is disclosed. The method is achieved by forming a MgO film on a metal surface through anode processing of Mg or Mg alloy in an alkaline solution. The alkaline solution includes a hydroxide, a thickening agent, and a film adjusting agent. As the method is performed, the target object is immersed in the alkaline solution, and the target object is connected to an anode with an average electric current density of 1˜5 A/dm, at a temperature of 0˜30° C., and within a time period of 10˜120 minutes to form a film of 5˜25 μm. The forming rate of the film of the method of the present invention is fast, and the formed film is of little stress.

摘要翻译： 公开了一种表面处理方法。 该方法通过在碱性溶液中通过Mg或Mg合金的阳极处理在金属表面上形成MgO膜来实现。 碱性溶液包括氢氧化物，增稠剂和膜调节剂。 进行该方法时，将目标物浸在碱性溶液中，在0〜30℃的温度下，将目标物与平均电流密度为1〜5A / dm的阳极连接， 并在10〜120分钟的时间内形成5〜25毫米的薄膜。 本发明方法的薄膜的成型速度快，成型薄膜几乎没有应力。

公开(公告)号：US20100075026A1

公开(公告)日：2010-03-25

申请号：US12289542

申请日：2008-10-30

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Pin Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Pin Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： C08K3/08 ,  B05D3/10 ,  H01C17/00

CPC分类号： H05K3/182 ,  C23C18/1608 ,  C23C18/168 ,  C23C18/1893 ,  C23C18/2086 ,  C23C18/32 ,  C23C18/38 ,  H05K3/422 ,  H05K2203/0709

摘要： A copolymer deposited with particles of catalytic metal is disclosed in the present invention, which is formed from an ethylenically unsaturated monomer and a hydrophilic monomer, and the catalytic metal is Au, Ag, Pd, Pt or Ru. The copolymer is hydrophilic when the temperature is lower than a specific temperature, and will become hydrophobic when the temperature is greater than the specific temperature. The present invention also discloses a method for forming a metal layer on a substrate via electroless plating, which includes contacting the substrate with an ink composition, drying the ink composition on the substrate, and contacting the dried ink composition with an electroless plating solution, wherein the ink composition contains the copolymer of the present invention in an aqueous phase. The present invention further discloses a method for forming metal conductors in through holes of a substrate.

摘要翻译： 在本发明中公开了由烯属不饱和单体和亲水性单体形成的催化金属颗粒的共聚物，催化金属是Au，Ag，Pd，Pt或Ru。 当温度低于特定温度时，共聚物是亲水性的，当温度大于特定温度时，共聚物变得疏水。 本发明还公开了一种通过化学镀在基板上形成金属层的方法，该方法包括使基材与油墨组合物接触，干燥基材上的油墨组合物，以及使干燥的油墨组合物与化学镀溶液接触，其中 油墨组合物含有本发明的水相共聚物。 本发明还公开了一种用于在基板的通孔中形成金属导体的方法。

公开(公告)号：US20090041941A1

公开(公告)日：2009-02-12

申请号：US11979760

申请日：2007-11-08

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D1/36

CPC分类号： H05K1/095 ,  H05K3/182 ,  H05K3/246 ,  H05K2201/0347 ,  H05K2203/0709 ,  H05K2203/072 ,  H05K2203/121

摘要： A method for forming a metal pattern on a substrate via printing and electroless plating is disclosed, which includes printing a pattern on the substrate with an ink composition, drying the printed pattern, and contacting the dried pattern with an electroless plating solution. The ink composition either contains components (i), (ii) and (iii), components (i) and (iv), or components (i) and (v), which are dissolved or dispersed in a solvent, wherein (i) is a binder; (ii) is a sulfate terminated polymer of an ethylenically unsaturated monomer; (iii) is a catalytic metal precursor; (iv) is a polymer of an ethylenically unsaturated monomer deposited with particles of catalytic metal; and (v) is a copolymer of an ethylenically unsaturated monomer and a hydrophilic monomer deposited with particles of catalytic metal. The binder (i) is a water swellable resin. The catalytic metal may be Au, Ag, Pd, Pt or Ru.

摘要翻译： 公开了一种通过印刷和化学镀在基板上形成金属图案的方法，其包括用油墨组合物在基板上印刷图案，干燥印刷图案，并将干燥图案与化学镀溶液接触。 油墨组合物中含有溶解或分散在溶剂中的组分（i），（ii）和（iii），组分（i）和（iv）或组分（i）和（v）），其中（i） 是一种粘合剂; （ii）是烯键式不饱和单体的硫酸封端聚合物; （iii）是催化金属前体; （iv）是沉积有催化金属颗粒的烯属不饱和单体的聚合物; 和（v）是烯属不饱和单体和沉积有催化金属颗粒的亲水单体的共聚物。 粘合剂（i）是水溶胀性树脂。 催化金属可以是Au，Ag，Pd，Pt或Ru。

公开(公告)号：US20060228489A1

公开(公告)日：2006-10-12

申请号：US11246174

申请日：2005-10-11

申请人： Yuh Sung ,  Ming-Der Ger ,  Yu-Hsien Chou ,  Jinn-Luh Ou

发明人： Yuh Sung ,  Ming-Der Ger ,  Yu-Hsien Chou ,  Jinn-Luh Ou

IPC分类号： B05D1/18 ,  B05D3/02

CPC分类号： C23C18/1676 ,  C23C18/1607 ,  C23C18/1651 ,  C23C18/1879 ,  C23C18/31 ,  C23C18/34 ,  C23C18/405 ,  C23C18/44 ,  H01L21/288 ,  H01L21/76877

摘要： The present invention discloses a method for forming a metallic microstructure on a patterned surface of a substrate by a nonisothermal deposition (NTID) in an electroless plating solution. The substrate is immersed in the solution being heated by a heating device mounted on a bottom of an electroless plating reactor while the heated solution being cooled by a cooling device provided in the reactor, and thus a seed layer is formed the patterned surface of the substrate. The substrate is then immersed in an electroless plating solution with a back surface of the substrate lying on the bottom of the reactor, so that the exposed seed layer is thickened to form the metallic microstructure.

摘要翻译： 本发明公开了一种在化学镀溶液中通过非等温沉积（NTID）在衬底的图案化表面上形成金属微结构的方法。 将衬底浸入被安装在化学镀电镀反应器底部的加热装置加热的溶液中，同时通过设置在反应器中的冷却装置冷却加热的溶液，从而种子层形成衬底的图案化表面 。 然后将衬底浸入无碱电解溶液中，其中衬底的背面位于反应器的底部，使得暴露的种子层变厚以形成金属微结构。

公开(公告)号：US08318254B2

公开(公告)日：2012-11-27

申请号：US12289542

申请日：2008-10-30

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D1/36 ,  B05D5/00

CPC分类号： H05K3/182 ,  C23C18/1608 ,  C23C18/168 ,  C23C18/1893 ,  C23C18/2086 ,  C23C18/32 ,  C23C18/38 ,  H05K3/422 ,  H05K2203/0709

摘要： A copolymer deposited with particles of catalytic metal is disclosed in the present invention, which is formed from an ethylenically unsaturated monomer and a hydrophilic monomer, and the catalytic metal is Au, Ag, Pd, Pt or Ru. The copolymer is hydrophilic when the temperature is lower than a specific temperature, and will become hydrophobic when the temperature is greater than the specific temperature. The present invention also discloses a method for forming a metal layer on a substrate via electroless plating, which includes contacting the substrate with an ink composition, drying the ink composition on the substrate, and contacting the dried ink composition with an electroless plating solution, wherein the ink composition contains the copolymer of the present invention in an aqueous phase. The present invention further discloses a method for forming metal conductors in through holes of a substrate.

摘要翻译： 在本发明中公开了由烯属不饱和单体和亲水性单体形成的催化金属颗粒的共聚物，催化金属是Au，Ag，Pd，Pt或Ru。 当温度低于特定温度时，共聚物是亲水性的，当温度大于特定温度时，共聚物变得疏水。 本发明还公开了一种通过化学镀在基板上形成金属层的方法，该方法包括使基材与油墨组合物接触，干燥基材上的油墨组合物，以及使干燥的油墨组合物与化学镀溶液接触，其中 油墨组合物含有本发明的水相共聚物。 本发明还公开了一种用于在基板的通孔中形成金属导体的方法。

公开(公告)号：US20080248430A1

公开(公告)日：2008-10-09

申请号：US11826791

申请日：2007-07-18

申请人： Yih-Ming Liu ,  Yuh Sung ,  Ming-Der Ger ,  Yun-Chih Fan ,  Yu-Hsien Chou ,  Chun-Tin Lin

发明人： Yih-Ming Liu ,  Yuh Sung ,  Ming-Der Ger ,  Yun-Chih Fan ,  Yu-Hsien Chou ,  Chun-Tin Lin

IPC分类号： B05D5/12 ,  C23C14/34 ,  G03F7/20

CPC分类号： H01J9/025 ,  C23C18/54 ,  H01J2201/30469

摘要： A nano-carbon material field emission cathode plate is prepared by an oxidation-reduction reaction, which includes immersing a substrate having a first metal layer thereon in a solution of a second metal salt with a nano-carbon material dispersed therein. A difference between the two standard redox potentials of the first metal and the second metal is so great that ions of the second metal in the solution are reduced to elemental metal while the first metal is oxidized, and thus a layer of the second metal is formed on the first metal layer with the nano-carbon material partially embedded in the second metal layer.

摘要翻译： 通过氧化还原反应制备纳米碳材料场致发射阴极板，其包括将其上具有第一金属层的基板浸渍在第二金属盐与分散在其中的纳米碳材料的溶液中。 第一金属和第二金属的两种标准氧化还原电位之间的差异非常大，使得第一金属被氧化时溶液中的第二金属的离子被还原为元素金属，因此形成第二金属层 在第一金属层上，其中纳米碳材料部分地嵌入第二金属层。

公开(公告)号：US08323739B2

公开(公告)日：2012-12-04

申请号：US11979760

申请日：2007-11-08

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： C23C18/18 ,  C23C18/30 ,  C23C18/34 ,  C23C18/40 ,  B05D5/00

CPC分类号： H05K1/095 ,  H05K3/182 ,  H05K3/246 ,  H05K2201/0347 ,  H05K2203/0709 ,  H05K2203/072 ,  H05K2203/121

摘要： A method for forming a metal pattern on a substrate via printing and electroless plating is disclosed, which includes printing a pattern on the substrate with an ink composition, drying the printed pattern, and contacting the dried pattern with an electroless plating solution. The ink composition either contains components (i), (ii) and (iii), components (i) and (iv), or components (i) and (v), which are dissolved or dispersed in a solvent, wherein (i) is a binder; (ii) is a sulfate terminated polymer of an ethylenically unsaturated monomer; (iii) is a catalytic metal precursor; (iv) is a polymer of an ethylenically unsaturated monomer deposited with particles of catalytic metal; and (v) is a copolymer of an ethylenically unsaturated monomer and a hydrophilic monomer deposited with particles of catalytic metal. The binder (i) is a water swellable resin. The catalytic metal may be Au, Ag, Pd, Pt or Ru.

摘要翻译： 公开了一种通过印刷和化学镀在基板上形成金属图案的方法，其包括用油墨组合物在基板上印刷图案，干燥印刷图案，并将干燥图案与化学镀溶液接触。 油墨组合物中含有溶解或分散在溶剂中的组分（i），（ii）和（iii），组分（i）和（iv）或组分（i）和（v）），其中（i） 是一种粘合剂; （ii）是烯键式不饱和单体的硫酸封端聚合物; （iii）是催化金属前体; （iv）是沉积有催化金属颗粒的烯属不饱和单体的聚合物; 和（v）是烯属不饱和单体和沉积有催化金属颗粒的亲水单体的共聚物。 粘合剂（i）是水溶胀性树脂。 催化金属可以是Au，Ag，Pd，Pt或Ru。

公开(公告)号：US20110311432A1

公开(公告)日：2011-12-22

申请号：US12818940

申请日：2010-06-18

申请人： Nen-Wen Pu ,  Chung An Wang ,  Yuh Sung ,  Ming-Der Ger

发明人： Nen-Wen Pu ,  Chung An Wang ,  Yuh Sung ,  Ming-Der Ger

IPC分类号： C01B31/02

CPC分类号： B82Y40/00 ,  B82Y30/00 ,  C01B32/19 ,  Y02P20/544

摘要： A method for manufacturing graphene is disclosed, which comprises the following steps: putting graphite material and an organic solvent, a surfactant, or a combination thereof in a reaction tank and introducing a supercritical fluid in the reaction tank to allow the organic solvent, the surfactant, or the combination thereof to dissolve in the supercritical fluid and to permeate into the graphite material; and removing the supercritical fluid by depressurization to form graphene. The method of the present invention has simple steps and reduced consumption of manufacturing time, and also can promote the quality of the resultant graphene in large-scale manufacturing.

摘要翻译： 公开了一种制造石墨烯的方法，包括以下步骤：将石墨材料和有机溶剂，表面活性剂或其组合物放入反应槽中，并在反应槽中引入超临界流体，使有机溶剂，表面活性剂 或其组合以溶解在超临界流体中并渗透到石墨材料中; 并通过减压除去超临界流体以形成石墨烯。 本发明的方法具有简单的步骤，降低了制造时间的消耗，并且可以在大规模制造中提高所得石墨烯的质量。

公开(公告)号：US20100015338A1

公开(公告)日：2010-01-21

申请号：US11497308

申请日：2006-08-02

申请人： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D3/10

CPC分类号： C08J3/215 ,  C08F12/30 ,  C08F112/08 ,  C08F112/14 ,  C08F220/06 ,  C08F220/14 ,  C08J2325/00 ,  C08F212/08

摘要： A process for preparing a metal styrene polymer composite having nano metallic particles deposited thereon is disclosed, which includes a) undergoing free radical polymerization of styrene and an optional co-monomer in the presence of a persulfate initiator and a chain transfer agent; and b) contacting the resulting styrene oligomer or copolymer of styrene and the co-monomer from step a) with an aqueous solution containing a noble metal ion dissolved therein, so that the noble metal ion is reduced to element form particles and deposit on the styrene oligomer or copolymer of styrene and the co-monomer by sulfates on the oligomer or copolymer in the absence of a reducing agent.

摘要翻译： 公开了一种制备其上沉积有纳米金属颗粒的金属苯乙烯聚合物复合物的方法，其包括：a）在过硫酸盐引发剂和链转移剂的存在下进行苯乙烯和任选的共聚单体的自由基聚合; 和b）使得到的苯乙烯低聚物或苯乙烯共聚物与来自步骤a）的共聚单体与其中溶解有贵金属离子的水溶液接触，使得贵金属离子被还原为元素形式的颗粒并沉积在苯乙烯 在不存在还原剂的情况下，低聚物或共聚物上的苯乙烯和共聚单体的低聚物或共聚物由硫酸盐组成。

公开(公告)号：US07553542B2

公开(公告)日：2009-06-30

申请号：US11889375

申请日：2007-08-13

申请人： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

发明人： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

IPC分类号： B32B5/66

CPC分类号： C08F292/00 ,  B01J13/14 ,  C08F257/02 ,  C08F285/00 ,  C08L51/003 ,  C08L51/10 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/2998 ,  C08L2666/02

摘要： The present invention discloses a two-stage process for preparing functionalized magnetizable microspheres. The first stage includes forming an inner shell of styrene polymer or styrene copolymer around magnetizable nano particles having a monolayer of a non-water-soluble dispersing agent coated thereon. The second stage includes forming an outer shell of styrene polymer or styrene copolymer with sulfate (SO4−) bounded thereto around the inner shell by free radical polymerization. Preferably, nano particles of a noble metal are deposited on the surface of the outer shell. The magnetizable microspheres prepared by the process of the present invention have a size of 100-1000 nm, and the thickness ratio of the inner shell to the outer shell ranges from 10:1 to 1:10.

摘要翻译： 本发明公开了一种用于制备官能化可磁化微球的两阶段方法。 第一阶段包括在其上涂覆有非水溶性分散剂的单层的可磁化纳米颗粒周围形成苯乙烯聚合物或苯乙烯共聚物的内壳。 第二阶段包括通过自由基聚合在内壳上形成与硫酸盐（SO 4 - ）结合的苯乙烯聚合物或苯乙烯共聚物的外壳。 优选地，贵金属的纳米颗粒沉积在外壳的表面上。 通过本发明的方法制备的可磁化微球的尺寸为100-1000nm，内壳与外壳的厚度比为10:1至1:10。