Catalyst for oxidative dehydrogenation of paraffinic hydrocarbons and
use of this catalyst
    7.
    发明授权
    Catalyst for oxidative dehydrogenation of paraffinic hydrocarbons and use of this catalyst 失效
    用于链烷烃的氧化脱氢的催化剂和使用该催化剂

    公开(公告)号:US6130183A

    公开(公告)日:2000-10-10

    申请号:US860934

    申请日:1997-07-09

    摘要: Disclosed is a novel catalyst and process using the novel catalyst for the oxidative dehydrogenation and cracking of C.sub.2 to C.sub.5 paraffins (homogeneous hydrocarbons or mixtures such as liquified gas to C.sub.2 to C.sub.5 olefins in the presence of an oxygen-containing gas and water vapor. The novel catalyst has the following formulaX.sub.a Y.sub.b Z.sub.c A.sub.d O.sub.x,where, referring to the Periodic System,X is an element of Group II and/or IV b (Mg, Ca, Za, Ti, Zr . . . )Y is a Lanthanide and/or an element of Group IVa or Va (Ce, La, Nd, Dy, Sn, Pr, Sb, Pb . . . );Z is an element of Group I (Li, Na, K . . . );A is an element of Group VII (Cl, Br, I . . . );O is oxygen; anda is 0.4 to 0.9,b is 0.005 to 0.3,c is 0.05 to 1.5,d is 0.05 to 0.8, andx is determined by the valance requirements of metals and halogens.The catalyst is used in the form of pressed spherical pellets or extrudates with added binder or deposited on a carrier material of one of the aforementioned oxidic components or of a separate carrier material. The weight-related space velocity, relative to the hydrocarbons used, is in the range of 0.1 to 20 h.sup.-1 and the temperature is 400 to 700.degree. C.

    摘要翻译: PCT No.PCT / DE95 / 01840 Sec。 371日期1997年7月9日第 102(e)日期1997年7月9日PCT 1995年12月15日PCT PCT。 公开号WO96 / 22161 日期1996年7月25日公开是一种新型催化剂和方法,使用新型催化剂对C2至C5链烷烃进行氧化脱氢和裂化(均相烃或混合物,如含氧气体存在下的C2至C5烯烃的液化气体 新型催化剂具有以下分子式XaYbZcAdOx,其中,参考周期系统,X为II族和/或IV b(Mg,Ca,Za,Ti,Zr等)的元素,Y为镧系元素 和/或IVa或Va族元素(Ce,La,Nd,Dy,Sn,Pr,Sb,Pb ...); Z是第I族元素(Li,Na,K ...); A 是VII族元素(Cl,Br,I ...); O是氧; a是0.4〜0.9,b是0.005〜0.3,c是0.05〜1.5,d是0.05〜0.8,x是 催化剂以压制球形颗粒或挤出物的形式使用,加入粘合剂或沉积在上述氧化组分之一的载体材料上或分离 速率载体材料。 相对于所使用的烃的重量空间速度在0.1〜20h -1的范围内,温度为400〜700℃。