摘要:
The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, owing to its excellent chemical and thermal properties, be used for a variety of purposes and is particularly suitable as a polymer-electrolyte membrane (PEM) for the production of membrane electrode units for so-called PEM fuel cells.
摘要:
The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, owing to its excellent chemical and thermal properties, be used for a variety of purposes and is particularly suitable as a polymer-electrolyte membrane (PEM) for the production of membrane electrode units for so-called PEM fuel cells.
摘要:
A method for producing a proton-conducting, polyazole-containing membrane, in which A) a composition containing polyphosphoric acid and at least one polyazole and exhibiting a solution viscosity in the range from 10 Pa·s to 1000 Pa·s, measured to DIN 53018 at the temperature at the orifice during production of the membrane, is pressed through an orifice at a temperature in the range from 25° C. to 300° C., and B) the composition is then solidified.
摘要:
A method for producing a proton-conducting, polyazole-containing membrane, in which A) a composition containing polyphosphoric acid and at least one polyazole and exhibiting a solution viscosity in the range from 10 Pa·s to 1000 Pa·s, measured to DIN 53018 at the temperature at the orifice during production of the membrane, is pressed through an orifice at a temperature in the range from 25° C. to 300° C., and B) the composition is then solidified.
摘要:
Mixtures containing vinyl-containing phosphonic acid, polymer electrolyte membranes comprising polyvinylphosphonic acid and their use in fuel cells. The present invention relates to a proton-conducting polymer membrane based on polyvinylphosphonic acid obtainable by a process comprising the steps A) Mixing a polymer with vinyl-containing phosphonic acid, B) Forming a two-dimensional structure using the mixture according to step A) on a carrier, C) Polymerisation of the vinyl-containing phosphonic acid present in the two-dimensional structure according to step B). A membrane according to the invention may on account of its outstanding chemical and thermal properties be used in a wide range of applications and is particularly suitable as a polymer-electrolyte membrane (PEM) in so-called PEM fuel cells.
摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
Catalyst ink comprising one or more catalyst materials, a liquid medium and polymer particles comprising one or more proton-conducting polymers, an electrode comprising at least one catalyst ink according to the present invention, a membrane-electrode assembly comprising at least one electrode according to the invention or comprising at least one catalyst ink according to the present invention, a fuel cell comprising at least one membrane-electrode assembly according to the invention and also a process for producing a membrane-electrode assembly according to the present invention.
摘要:
The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.
摘要:
A membrane electrode assembly, comprising at least one phosphoric acid-containing polymer electrolyte membrane and at least one gas diffusion electrode, said gas diffusion electrode comprising: i. at least one catalyst layer and ii. at least one gas diffusion medium having at least two gas diffusion layers, the first gas diffusion layer comprising an electrically conductive macroporous layer in which the pores have a mean pore diameter in the range from 10 μm to 30 μm, the second gas diffusion layer comprising an electrically conductive macroporous layer in which the pores have a mean pore diameter in the range from 10 μm to 30 μm, the gas diffusion medium comprising polytetrafluoroethylene, the first gas diffusion layer having a higher polytetrafluoroethylene concentration than the second gas diffusion layer.
摘要:
The present invention relates to a novel proton-conducting polymer membrane based on aromatic polyazoles which contain sulfonic acid groups and in which the sulfonic acid groups are covalently bound to the aromatic ring of the polymer and which can, owing to their excellent chemical and thermal properties, be used for a variety of purposes. Such materials are particularly useful for the production of polymer electrolyte membranes (PEMs) in PEM fuel cells.