公开(公告)号：US20090232720A1

公开(公告)日：2009-09-17

申请号：US12408437

申请日：2009-03-20

申请人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

发明人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

IPC分类号： C01B33/26

CPC分类号： B01J35/0013 ,  B01J29/041 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1023 ,  B01J37/0045 ,  C01B39/02

摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.

摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。

公开(公告)号：US20090029847A1

公开(公告)日：2009-01-29

申请号：US11889891

申请日：2007-08-17

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Cedric Boissiere ,  David Grosso

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Cedric Boissiere ,  David Grosso

IPC分类号： B01J29/06

CPC分类号： C01B39/04 ,  B01J20/08 ,  B01J20/16 ,  B01J20/18 ,  B01J20/28007 ,  B01J20/28083 ,  B01J29/041 ,  B01J29/08 ,  B01J29/40 ,  B01J29/60 ,  B01J29/7007 ,  B01J29/80 ,  B01J2229/62 ,  B82Y30/00 ,  C01B39/48

摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.

摘要翻译： 由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％ 涉及具有1至30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10um。 所述介孔结构的基质也可以含有氧化硅。 介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。 还描述了所述材料的制备。

公开(公告)号：US20060292054A1

公开(公告)日：2006-12-28

申请号：US11159384

申请日：2005-06-23

申请人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

发明人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

IPC分类号： C01B33/26

CPC分类号： B01J35/0013 ,  B01J29/041 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1023 ,  B01J37/0045 ,  C01B39/02

摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.

摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。

公开(公告)号：US20060030477A1

公开(公告)日：2006-02-09

申请号：US11165570

申请日：2005-06-24

申请人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

发明人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

IPC分类号： B01J29/04 ,  B01J29/06 ,  B01J29/87

CPC分类号： C01B37/02 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/7003 ,  B01J37/0045 ,  B01J2229/62 ,  C01B39/04 ,  C01B39/40

摘要： A material with a hierarchical porosity is described, constituted by at least two spherical elementary particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. the matrix based on silicon oxide may contain aluminium. The preparation of said material is also described.

摘要翻译： 描述具有分层孔隙率的材料，由至少两个球形基本粒子构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有 孔径在1.5至30nm的范围内，并且具有厚度在1至20nm范围内的非晶壁，所述球形基本粒子的最大直径为10μm。 基于氧化硅的基体可以含有铝。 还描述了所述材料的制备。

公开(公告)号：US07807598B2

公开(公告)日：2010-10-05

申请号：US11889891

申请日：2007-08-17

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Cedric Boissiere ,  David Grosso

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Cedric Boissiere ,  David Grosso

IPC分类号： B01J29/06

CPC分类号： C01B39/04 ,  B01J20/08 ,  B01J20/16 ,  B01J20/18 ,  B01J20/28007 ,  B01J20/28083 ,  B01J29/041 ,  B01J29/08 ,  B01J29/40 ,  B01J29/60 ,  B01J29/7007 ,  B01J29/80 ,  B01J2229/62 ,  B82Y30/00 ,  C01B39/48

摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.

摘要翻译： 由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％ 相对于具有1〜30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10μm。 所述介孔结构的基质也可以含有氧化硅。 介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。 还描述了所述材料的制备。

公开(公告)号：US07851320B2

公开(公告)日：2010-12-14

申请号：US12408437

申请日：2009-03-20

申请人： Alexandra Chaumonnot ,  Aurélie Coupe ,  Clément Sanchez ,  Patrick Euzen ,  Cédric Boissiere ,  David Grosso

发明人： Alexandra Chaumonnot ,  Aurélie Coupe ,  Clément Sanchez ,  Patrick Euzen ,  Cédric Boissiere ,  David Grosso

IPC分类号： C01B33/00 ,  C01B33/26

CPC分类号： B01J35/0013 ,  B01J29/041 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1023 ,  B01J37/0045 ,  C01B39/02

摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminum oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.

摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本粒子的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。

公开(公告)号：US07994085B2

公开(公告)日：2011-08-09

申请号：US11165570

申请日：2005-06-24

申请人： Alexandra Chaumonnot ,  Aurélie Coupe ,  Clément Sanchez ,  Patrick Euzen ,  Cédric Boissiere ,  David Grosso

发明人： Alexandra Chaumonnot ,  Aurélie Coupe ,  Clément Sanchez ,  Patrick Euzen ,  Cédric Boissiere ,  David Grosso

IPC分类号： B01J29/06

CPC分类号： C01B37/02 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/7003 ,  B01J37/0045 ,  B01J2229/62 ,  C01B39/04 ,  C01B39/40

摘要： A material with a hierarchical porosity is described, constituted by at least two spherical elementary particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. the matrix based on silicon oxide may contain aluminium. The preparation of said material is also described.

摘要翻译： 描述具有分层孔隙率的材料，由至少两个球形基本粒子构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有 孔径在1.5至30nm的范围内，并且具有厚度在1至20nm范围内的非晶壁，所述球形基本粒子的最大直径为10μm。 基于氧化硅的基体可以含有铝。 还描述了所述材料的制备。

公开(公告)号：US20090188834A1

公开(公告)日：2009-07-30

申请号：US11663497

申请日：2005-09-20

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Magalie Roy-Auberger ,  Partick Bourges ,  Tivadar Cseri ,  Maryline Delage ,  Nathalie Lett

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Magalie Roy-Auberger ,  Partick Bourges ,  Tivadar Cseri ,  Maryline Delage ,  Nathalie Lett

IPC分类号： C10G47/20 ,  B01J27/19 ,  B01J27/188 ,  B01J27/185 ,  B01J21/12 ,  B01J21/02

CPC分类号： B01J21/12 ,  B01J21/02 ,  B01J23/883 ,  B01J23/888 ,  B01J27/1853 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/20 ,  B01J37/28 ,  C10G49/02 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).

摘要翻译： 本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。 该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。

公开(公告)号：US08002970B2

公开(公告)日：2011-08-23

申请号：US11722610

申请日：2005-12-13

申请人： Patrick Euzen ,  Patrick Bourges ,  Christophe Gueret ,  Carole Bobin ,  Alexandra Chaumonnot ,  Hugues Dulot

发明人： Patrick Euzen ,  Patrick Bourges ,  Christophe Gueret ,  Carole Bobin ,  Alexandra Chaumonnot ,  Hugues Dulot

IPC分类号： C10G47/00

CPC分类号： B01J37/0009 ,  B01J21/12 ,  B01J29/146 ,  B01J29/166 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/14 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).

摘要翻译： 本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素， 在24.40×10-10 m至24.15×10-10m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝， 。

公开(公告)号：US20060070915A1

公开(公告)日：2006-04-06

申请号：US11221416

申请日：2005-09-08

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Carole Bobin ,  Patrick Bourges ,  Christophe Gueret ,  Hugues Dulot

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Carole Bobin ,  Patrick Bourges ,  Christophe Gueret ,  Hugues Dulot

IPC分类号： B01J21/12 ,  B01J27/187 ,  B01J21/02 ,  B01J27/182 ,  C10G47/02

CPC分类号： B01J37/28 ,  B01J21/02 ,  B01J21/12 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/888 ,  B01J23/8885 ,  B01J23/8993 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J37/30 ,  C10G49/04 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).

摘要翻译： 本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。 催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素 以及含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的二氧化硅 - 氧化铝基底的非沸石基材。