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公开(公告)号：US20090232720A1
公开(公告)日：2009-09-17
申请号：US12408437
申请日：2009-03-20
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
IPC分类号： C01B33/26
CPC分类号： B01J35/0013 , B01J29/041 , B01J35/023 , B01J35/10 , B01J35/1023 , B01J37/0045 , C01B39/02
摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。
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公开(公告)号：US20090029847A1
公开(公告)日：2009-01-29
申请号：US11889891
申请日：2007-08-17
申请人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
发明人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
IPC分类号： B01J29/06
CPC分类号： C01B39/04 , B01J20/08 , B01J20/16 , B01J20/18 , B01J20/28007 , B01J20/28083 , B01J29/041 , B01J29/08 , B01J29/40 , B01J29/60 , B01J29/7007 , B01J29/80 , B01J2229/62 , B82Y30/00 , C01B39/48
摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.
摘要翻译： 由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％ 涉及具有1至30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10um。 所述介孔结构的基质也可以含有氧化硅。 介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。 还描述了所述材料的制备。
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公开(公告)号：US20060292054A1
公开(公告)日：2006-12-28
申请号：US11159384
申请日：2005-06-23
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
IPC分类号： C01B33/26
CPC分类号： B01J35/0013 , B01J29/041 , B01J35/023 , B01J35/10 , B01J35/1023 , B01J37/0045 , C01B39/02
摘要： A mesostructured aluminosilicate material is described, constituted by at least two spherical elementary particles, each of said spherical particles being constituted by a matrix based on silicon oxide and aluminium oxide, having a pore size in the range 1.5 to 30 nm, a Si/Al molar ratio of at least 1, having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. A process for preparing said material and its application in the fields of refining and petrochemistry are also described.
摘要翻译： 描述了由至少两个球形基本粒子构成的介孔结构的硅铝酸盐材料，每个所述球形颗粒由基于氧化硅和氧化铝的基体构成，孔径在1.5至30nm的范围内，Si / Al 摩尔比至少为1，具有厚度在1至20nm范围内的非晶壁，所述球形基本颗粒的最大直径为10μm。 还描述了制备所述材料的方法及其在精炼和石油化学领域的应用。
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公开(公告)号：US20060030477A1
公开(公告)日：2006-02-09
申请号：US11165570
申请日：2005-06-24
申请人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
发明人： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Patrick Euzen , Cedric Boissiere , David Grosso
CPC分类号： C01B37/02 , B01J29/005 , B01J29/0308 , B01J29/035 , B01J29/06 , B01J29/40 , B01J29/7003 , B01J37/0045 , B01J2229/62 , C01B39/04 , C01B39/40
摘要： A material with a hierarchical porosity is described, constituted by at least two spherical elementary particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. the matrix based on silicon oxide may contain aluminium. The preparation of said material is also described.
摘要翻译： 描述具有分层孔隙率的材料，由至少两个球形基本粒子构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有 孔径在1.5至30nm的范围内，并且具有厚度在1至20nm范围内的非晶壁，所述球形基本粒子的最大直径为10μm。 基于氧化硅的基体可以含有铝。 还描述了所述材料的制备。
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公开(公告)号：US07807598B2
公开(公告)日：2010-10-05
申请号：US11889891
申请日：2007-08-17
申请人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
发明人： Patrick Euzen , Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
IPC分类号： B01J29/06
CPC分类号： C01B39/04 , B01J20/08 , B01J20/16 , B01J20/18 , B01J20/28007 , B01J20/28083 , B01J29/041 , B01J29/08 , B01J29/40 , B01J29/60 , B01J29/7007 , B01J29/80 , B01J2229/62 , B82Y30/00 , C01B39/48
摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.
摘要翻译： 由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％ 相对于具有1〜30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10μm。 所述介孔结构的基质也可以含有氧化硅。 介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。 还描述了所述材料的制备。
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6.发明授权Inorganic material that has metal nanoparticles that are trapped in a mesostructured matrix 有权具有被捕获在介孔结构基质中的金属纳米颗粒的无机材料公开(公告)号：US08226740B2
公开(公告)日：2012-07-24
申请号：US11889890
申请日：2007-08-17
CPC分类号： C01B39/48 , B01J23/002 , B01J23/10 , B01J23/52 , B01J23/745 , B01J23/75 , B01J29/044 , B01J29/46 , B01J29/89 , B01J35/0013 , B01J35/10 , B01J35/1057 , B01J35/1061 , B01J35/1085 , B01J35/109 , B01J2229/18 , B01J2229/42 , B01J2523/00 , C01B37/02 , C01B39/04 , Y10S977/777 , Y10S977/779 , Y10T428/12042 , B01J2523/3706 , B01J2523/3712 , B01J2523/845 , B01J2523/41 , B01J2523/48 , B01J2523/31 , B01J2523/842
摘要： An inorganic material that consists of at least two elementary spherical particles, each of said spherical particles comprising metal nanoparticles that are between 1 and 300 nm in size and a mesostructured matrix with an oxide base of at least one element X that is selected from the group that consists of aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium is described, whereby said matrix has a pore size of between 1.5 and 30 nm and has amorphous walls with a thickness of between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 10 μm. Said material can also contain zeolitic nanocrystals that are trapped within said mesostructured matrix.
摘要翻译： 由至少两个基本球形颗粒组成的无机材料，每个所述球形颗粒包含尺寸在1至300nm之间的金属纳米颗粒和具有至少一种元素X的氧化物碱的介孔结构基质，所述元素选自基团 描述了由铝，钛，钨，锆，镓，锗，锡，锑，铅，钒，铁，锰，铪，铌，钽，钇，铈，钆，铕和钕组成的组合物， 孔径在1.5和30nm之间，并且具有1至30nm厚度的非晶壁，所述基本球形颗粒的最大直径为10μm。 所述材料还可以含有被捕获在所述介孔结构基质内的沸石纳米晶体。
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7.发明申请Inorganic material that has metal nanoparticles that are trapped in a mesostructured matrix 有权具有被捕获在介孔结构基质中的金属纳米颗粒的无机材料公开(公告)号：US20080072705A1
公开(公告)日：2008-03-27
申请号：US11889890
申请日：2007-08-17
IPC分类号： B22F9/00
CPC分类号： C01B39/48 , B01J23/002 , B01J23/10 , B01J23/52 , B01J23/745 , B01J23/75 , B01J29/044 , B01J29/46 , B01J29/89 , B01J35/0013 , B01J35/10 , B01J35/1057 , B01J35/1061 , B01J35/1085 , B01J35/109 , B01J2229/18 , B01J2229/42 , B01J2523/00 , C01B37/02 , C01B39/04 , Y10S977/777 , Y10S977/779 , Y10T428/12042 , B01J2523/3706 , B01J2523/3712 , B01J2523/845 , B01J2523/41 , B01J2523/48 , B01J2523/31 , B01J2523/842
摘要： An inorganic material that consists of at least two elementary spherical particles, each of said spherical particles comprising metal nanoparticles that are between 1 and 300 nm in size and a mesostructured matrix with an oxide base of at least one element X that is selected from the group that consists of aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium is described, whereby said matrix has a pore size of between 1.5 and 30 nm and has amorphous walls with a thickness of between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 10 μm. Said material can also contain zeolitic nanocrystals that are trapped within said mesostructured matrix.
摘要翻译： 由至少两个基本球形颗粒组成的无机材料，每个所述球形颗粒包含尺寸在1至300nm之间的金属纳米颗粒和具有至少一种元素X的氧化物碱的介孔结构基质，所述元素选自基团 描述了由铝，钛，钨，锆，镓，锗，锡，锑，铅，钒，铁，锰，铪，铌，钽，钇，铈，钆，铕和钕组成的组合物， 孔径在1.5和30nm之间，并且具有1至30nm厚度的非晶壁，所述基本球形颗粒的最大直径为10μm。 所述材料还可以含有被捕获在所述介孔结构基质内的沸石纳米晶体。
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8.发明申请MESOSTRUCTURED ALUMINOSILICATE MATERIAL MADE OF SPHERICAL PARTICLES OF SPECIFIC SIZE 有权特殊尺寸的球形颗粒的结构化铝氧化物材料公开(公告)号：US20110105300A1
公开(公告)日：2011-05-05
申请号：US12935335
申请日：2009-02-26
CPC分类号： C01B39/04 , B01J20/18 , B01J20/28004 , B01J20/28019 , B01J20/28057 , B01J20/28083 , B01J21/12 , B01J29/041 , B01J35/1057 , B01J35/1061 , B01J35/109 , Y10T428/2991 , Y10T428/2993
摘要： A mesostructured aluminosilicate material is described, which consists of at least two elementary spherical particles, each one of said spherical particles consisting of a matrix based on silicon oxide and aluminium oxide, said matrix having a pore diameter ranging between 1.5 and 30 nm, a Si/Al molar ratio at least equal to 1 and amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a diameter D such that 10
摘要翻译： 描述了介质结构的硅铝酸盐材料，其由至少两个基本球形颗粒组成，每个所述球形颗粒由基于氧化硅和氧化铝的基体组成，所述基体的孔径范围为1.5至30nm，Si / Al摩尔比至少等于1，厚度范围在1至30nm之间的非晶壁，所述基本球形颗粒的直径D使得10
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9.发明授权Mesostructured aluminosilicate material made of spherical particles of specific size 有权由具有特定尺寸的球形颗粒制成的中等结构的硅铝酸盐材料公开(公告)号：US08563135B2
公开(公告)日：2013-10-22
申请号：US12935335
申请日：2009-02-26
CPC分类号： C01B39/04 , B01J20/18 , B01J20/28004 , B01J20/28019 , B01J20/28057 , B01J20/28083 , B01J21/12 , B01J29/041 , B01J35/1057 , B01J35/1061 , B01J35/109 , Y10T428/2991 , Y10T428/2993
摘要： A mesostructured aluminosilicate material is described, which consists of at least two elementary spherical particles, each one of said spherical particles consisting of a matrix based on silicon oxide and aluminium oxide, said matrix having a pore diameter ranging between 1.5 and 30 nm, a Si/Al molar ratio at least equal to 1 and amorphous walls of thickness ranging between 1 and 30 nm, said elementary spherical particles having a diameter D such that 10
摘要翻译： 描述了介质结构的硅铝酸盐材料，其由至少两个基本球形颗粒组成，每个所述球形颗粒由基于氧化硅和氧化铝的基体组成，所述基体的孔径范围为1.5至30nm，Si / Al摩尔比至少等于1，厚度范围在1至30nm之间的无定形壁，所述基本球形颗粒的直径D使得10（D）（mum）@ 100。 还描述了制备所述材料及其在精炼和石油化学领域中的应用的方法。
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公开(公告)号：US20110039102A1
公开(公告)日：2011-02-17
申请号：US12676707
申请日：2008-08-18
IPC分类号： C01B37/02 , C01B39/40 , C01B37/00 , C01B33/113
CPC分类号： C01B39/00 , B01J20/0288 , B01J20/18 , B01J20/28019 , B01J20/28057 , B01J20/2808 , B01J20/28083 , B01J20/28085 , B01J20/28092 , B01J21/08 , B01J21/12 , B01J29/035 , B01J29/08 , B01J29/40 , B01J29/7007 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/0045 , B01J37/033 , C01B37/00 , C01B37/02 , C07C4/18 , Y02P20/52 , Y10T428/2982 , C07C15/04 , C07C11/06
摘要： Material with hierarchical porosity consisting of at least two elementary spherical particles having a maximum diameter of 200 microns, at least one of said spherical particles comprising at least one matrix based on silicon oxide, said material having a macropore volume measured by mercury porosimetry ranging between 0.05 and 1 ml/g, a mesopore volume measured by nitrogen volumetric analysis ranging between 0.01 and 1 ml/g and a micropore volume measured by nitrogen volumetric analysis ranging between 0.03 and 0.4 ml/g, said matrix having amorphous walls. The preparation of said material is also described.
摘要翻译： 具有分层孔隙率的材料，其由至少两个最大直径为200微米的基本球形颗粒组成，所述球形颗粒中的至少一种包含至少一种基于氧化硅的基体，所述材料具有通过水银孔率测定法测量的大孔体积为0.05 和1ml / g，通过氮体积分析测量的介孔体积在0.01至1ml / g之间，通过氮容积分析测量的微孔体积在0.03至0.4ml / g之间，所述基质具有无定形壁。 还描述了所述材料的制备。
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