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公开(公告)号：US20080193691A1
公开(公告)日：2008-08-14
申请号：US11911215
申请日：2006-04-12
申请人： Philippe Bussi , Annett Linemann , Benoit Brulle
发明人： Philippe Bussi , Annett Linemann , Benoit Brulle
CPC分类号： B32B1/08 , B32B27/08 , B32B27/18 , B32B27/34 , B32B2250/24 , B32B2264/104 , B32B2264/108 , B32B2307/21 , B32B2307/3065 , B32B2307/412 , B32B2307/54 , B32B2307/546 , B32B2307/5825 , B32B2307/71 , B32B2307/7242 , B32B2439/60 , B32B2439/62 , B32B2553/00 , B32B2597/00 , C08G69/36 , C08L77/02 , C08L77/06 , F16L9/12 , F16L11/04 , F16L2011/047 , Y10T428/139 , Y10T428/1397
摘要： The present invention relates to a structure made of at least one layer containing a polyamide MXD.10/Z in which: MXD. 10 is the product of condensation of a blend of xylylenediamines containing 70 to 100% of meta-xylylenediamine and of sebacic acid, Z is a repeating unit chosen at least among the repeating units resulting from the polycondensation of a lactam monomer, from an alpha-omega carboxylic aminoacid, the repeating unit X1. Y1 where X1 designates the repeating unit resulting from the polycondensation an aliphatic, arylaliphatic, cycloapiphatic, or aromatic diamine and Yl designates the repeating unit resulting from the polycondensation of a aliphatic carboxylic, cycloaliphatic or aromatic diacid, and the weight ratio Z/(MXD+10+Z) is between 0 and 15%. The structure of the invention can either be made of one layer of this polyamide or either can contain a layer containing the polyamide MXD.10 and at least one layer of another material. The invention also relates to bottles, tanks, containers, pipes, tubes and many types of containment devices made using the previous structure. This structure can also be used into films to produce goods packaging. All these objects have good barrier properties. The invention also relates to these objects as well as the use of these structures and objects.
摘要翻译： 本发明涉及由含有聚酰胺MXD.10 / Z的至少一层制成的结构，其中：MXD。 10是含有70-100％间苯二甲胺和癸二酸的苯二甲胺的共混物的缩合产物，Z是选自至少在由内酰胺单体缩聚产生的重复单元中的重复单元， ω羧酸氨基酸，重复单元X1。 Y1，其中X1表示缩聚产生的重复单元，脂族，芳基脂族，脂环族或芳族二胺和Y 1表示由脂肪族羧酸，脂环族或芳族二酸缩聚而得到的重复单元，Z /（MXD + 10 + Z）为0〜15％。 本发明的结构可以由一层该聚酰胺制成，也可以包含含有聚酰胺MXD10的层和至少一层其它材料。 本发明还涉及瓶，罐，容器，管，管以及使用先前结构制造的许多类型的容纳装置。 这种结构也可以用于制作商品包装的薄膜。 所有这些物体具有良好的阻隔性能。 本发明还涉及这些目的以及这些结构和对象的使用。
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2.发明申请BLENDS OF TRANSPARENT AMORPHOUS POLYAMIDES BASED ON DIAMINES AND ON TETRADECANEDIOIC ACID AND SEMICRYSTALLINE POLYAMIDES 审中-公开基于DIAMINES和十四烷酸和半结晶聚酰胺的透明非晶性聚酰胺的共混公开(公告)号：US20110135860A1
公开(公告)日：2011-06-09
申请号：US13016042
申请日：2011-01-28
CPC分类号： C08G69/26 , C08G69/265 , Y10T428/139
摘要： The present invention relates to a transparent amorphous polyamide which results from the condensation of at least one diamine chosen from aromatic, arylaliphatic and cycloaliphatic diamines, of tetradecanedioic acid or of a mixture comprising at least 50 mol % of tetradecanedioic acid and at least one diacid chosen from aliphatic, aromatic and cycloaliphatic dicarboxylic acids. The invention also relates to a composition comprising, by weight, 1 to 100% of the preceding polyamide and 99 to 0% of a semicrystalline polyamide. The invention also relates to the objects composed of the composition of the invention, such as panels, films, sheets, pipes, profiles or objects obtained by injection moulding. The invention also relates to objects covered with a transparent protective layer composed of the composition of the invention.
摘要翻译： 本发明涉及透明无定形聚酰胺，其由选自芳族，芳基脂族和脂环族二胺，十四烷二酸的至少一种二胺或包含至少50mol％十四烷二酸和至少一种二酸的混合物缩合而得到 来自脂族，芳族和脂环族二羧酸。 本发明还涉及一种组合物，其包含按重量计1至100％的前述聚酰胺和99至0％的半结晶聚酰胺。 本发明还涉及由本发明的组合物构成的物体，例如通过注射成型获得的面板，膜，片，管，轮廓或物体。 本发明还涉及由本发明的组合物构成的透明保护层所覆盖的物体。
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3.发明申请Transparent amorphous polyamides based on diamines and on tetradecanedioic acid 审中-公开基于二胺和十四烷二酸的透明无定形聚酰胺公开(公告)号：US20050272908A1
公开(公告)日：2005-12-08
申请号：US11127623
申请日：2005-05-12
CPC分类号： C08G69/26 , C08G69/265 , Y10T428/139
摘要： The present invention relates to a transparent amorphous polyamide which results from the condensation of at least one diamine chosen from aromatic, arylaliphatic and cycloaliphatic diamines, of tetradecanedioic acid or of a mixture comprising at least 50 mol % of tetradecanedioic acid and at least one diacid chosen from aliphatic, aromatic and cycloaliphatic dicarboxylic acids. The invention also relates to a composition comprising, by weight, 1 to 100% of the preceding polyamide and 99 to 0% of a semicrystalline polyamide. The invention also relates to the objects composed of the composition of the invention, such as panels, films, sheets, pipes, profiles or objects obtained by injection moulding. The invention also relates to objects covered with a transparent protective layer composed of the composition of the invention.
摘要翻译： 本发明涉及透明无定形聚酰胺，其由选自芳族，芳基脂族和脂环族二胺，十四烷二酸的至少一种二胺或包含至少50mol％十四烷二酸和至少一种二酸的混合物缩合而得到 来自脂族，芳族和脂环族二羧酸。 本发明还涉及一种组合物，其包含按重量计1至100％的前述聚酰胺和99至0％的半结晶聚酰胺。 本发明还涉及由本发明的组合物构成的物体，例如通过注射成型获得的面板，膜，片，管，轮廓或物体。 本发明还涉及由本发明的组合物构成的透明保护层所覆盖的物体。
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公开(公告)号：US08642716B2
公开(公告)日：2014-02-04
申请号：US11113762
申请日：2005-04-25
申请人： Annett Linemann , Thierry Briffaud
发明人： Annett Linemann , Thierry Briffaud
IPC分类号： C08G69/02
CPC分类号： C08G69/02 , C08G69/04 , C08G69/26 , C08G69/265 , C08G69/36
摘要： The present invention relates to branched polyamides comprising unsaturated ends comprising: at least one unit originating from a multifunctional monomer (A) having more than two functional groups, at least sequences resulting from the condensation, in the presence of at least one unsaturated monoacid, either of at least two different lactams, or of at least one lactam, at least one dicarboxylic acid and at least one diamine, or of a lactam or of an α,ω-aminocarboxylic acid, or of a diamine and of a diacid. The invention also relates to thermofusible adhesives comprising these branched polyamides comprising unsaturated ends, and to the use of these branched polyamides comprising unsaturated ends in sheathing electrical cables.
摘要翻译： 本发明涉及包含不饱和末端的支链聚酰胺，其包含：至少一种源自具有多于两个官能团的多官能单体（A）的单元，至少一个由缩合产生的序列，在至少一种不饱和一元酸存在下， 的至少两种不同的内酰胺，或至少一种内酰胺，至少一种二羧酸和至少一种二胺，或内酰胺或α，ω-氨基羧酸，或二胺和二酸的至少一种。 本发明还涉及包含这些包含不饱和末端的支化聚酰胺的热熔粘合剂，以及在护套电缆中使用包含不饱和末端的这些支化聚酰胺。
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5.发明申请公开(公告)号：US20070106034A1
公开(公告)日：2007-05-10
申请号：US11591232
申请日：2006-11-01
IPC分类号： C08G69/48
摘要： The present invention relates to a process for preparing, by condensation, copolymers having polyamide blocks and polyether blocks in which polyamide blocks having dicarboxylic chain ends are mixed with: a polyether having two OH chain ends (a polyetherdiol), and a polyol having at least 3 OH functions. The copolymers have a higher molecular weight, higher mechanical properties (impact, processing, filmification etc), remain linear or only weakly branched. The multifunctionality of the polyol is only used for kinetic aspects. As regards the process, there is a reduction of cycle time, reduced technical requirements on the catalyst and vacuum system and a reduction of degradation which means a better colour stability. The invention also relates to these copolymers having polyamide blocks and polyether blocks and comprising in its chain the residues of a polyol having at least 3 OH functions.
摘要翻译： 本发明涉及通过缩合制备具有聚酰胺嵌段和聚醚嵌段的共聚物的方法，其中将具有二羧酸链末端的聚酰胺嵌段与具有两个OH链末端的聚醚（聚醚二醇）和至少具有至少 3 OH功能。 共聚物具有较高的分子量，更高的机械性能（冲击，加工，成膜等），保持线性或仅有弱分支。 多元醇的多功能性仅用于动力学方面。 关于该方法，循环时间减少，催化剂和真空系统的技术要求降低，降解降低，这意味着更好的颜色稳定性。 本发明还涉及具有聚酰胺嵌段和聚醚嵌段的这些共聚物，并且在其链中包含具有至少3个OH官能团的多元醇的残基。
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公开(公告)号：US20060074158A1
公开(公告)日：2006-04-06
申请号：US11243532
申请日：2005-10-05
IPC分类号： C08K5/43
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide Al of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.
摘要翻译： 本发明涉及一种组合物和具有由所述组合物制成的层的结构，其中所述组合物的总重量为100％：50至100％的至少一种式XY / Z或6的聚酰胺Al。 Y2 / Z，其中：X表示具有6至10个碳原子的脂族二胺的残基，Y表示具有10至14个碳原子的脂族二羧酸的残基，Y2表示具有 15〜20个碳原子，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基，Y1表示 脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比在0〜15％之间; 0〜40％的增塑剂; 0至50％的抗冲改性剂; 和0〜50％的聚酰胺A2。
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公开(公告)号：US07750110B2
公开(公告)日：2010-07-06
申请号：US11243532
申请日：2005-10-05
IPC分类号： C08G69/08
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.
摘要翻译： 本发明涉及一种组合物和具有由所述组合物制成的层的结构，其中所述组合物的总重量为100％：50至100％的至少一种式XY / Z或6的聚酰胺A1。 Y2 / Z，其中：X表示具有6至10个碳原子的脂族二胺的残基，Y表示具有10至14个碳原子的脂族二羧酸的残基，Y2表示具有 15至20个碳原子，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基，Y1表示 脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比在0〜15％之间; 0〜40％的增塑剂; 0至50％的抗冲改性剂; 和0〜50％的聚酰胺A2。
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公开(公告)号：US20080221272A1
公开(公告)日：2008-09-11
申请号：US11631690
申请日：2005-07-06
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material. The inventive polymer material can be extruded, co-extruded, injected, blown, moulded, overmoulded, calandered, thermoformed. It can be used to produce articles such as tubes, films, plates, extruded strings, bottles, containers. The inventive polymer material can also be mixed with other materials such as other polymers, thus it is used for example as impact modifier or rheology regulator. The invention further concerns the use of said polymer material as compatibility agent in a composition comprising among others at least two polymers belonging to different classes of polymers.
摘要翻译： 本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种或多种 能够被氢键和一个或多个能够与聚合物骨架形成共价键的反应性基团结合的更多缔合基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均为1〜 10个咪唑烷酮基团。 引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。 本发明的聚合物材料可以挤出，共挤出，注射，吹塑，模塑，包覆成型，压延，热成型。 它可用于生产诸如管，薄膜，板，挤压线，瓶，容器等物品。 本发明的聚合物材料也可以与其它材料如其它聚合物混合，因此其用作例如抗冲改性剂或流变调节剂。 本发明还涉及所述聚合物材料作为相容剂在包含至少两种属于不同类型聚合物的聚合物的组合物中的用途。
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公开(公告)号：US07388048B2
公开(公告)日：2008-06-17
申请号：US10909503
申请日：2004-08-02
CPC分类号： C08L77/02 , B32B27/08 , C08G69/36 , C08K5/0008 , C08L23/00 , C08L23/02 , C08L25/00 , C08L51/00 , C08L51/06 , C08L53/02 , C08L77/00 , C08L77/06 , H01B3/305 , C08L2666/14 , C08L2666/02 , C08L2666/06 , C08L2666/24
摘要： The present invention relates to a flexible semiaromatic polyamide composition with a low moisture uptake comprising, by weight, the total being 100: 60 to 99.5% (preferably 70 to 93%) of at least one copolyamide of formula X/Y,Ar in which: Y denotes the residues of an aliphatic diamine having from 8 to 20 carbon atoms, Ar denotes the residues of an aromatic dicarboxylic acid, X denotes either the residues of aminoundecanoic acid NH2—(CH2)10—COOH, of lactam-12 or of the corresponding amino acid, or X denotes the unit Y,x, residue from the condensation of the diamine with an aliphatic diacid (x) having between 8 and 20 carbon atoms, or X denotes the unit Y,I, residue from the condensation of the diamine with isophthalic acid, −0.5 to 40% (preferably 7 to 30%) of at least one product chosen from plasticizers, nanofillers, polyolefins, crosslinked polyolefins and additives.
摘要翻译： 本发明涉及一种具有低吸湿性的柔性半芳族聚酰胺组合物，其包含总重量为100:60至99.5％（优选70至93％）的至少一种式X / Y，Ar的共聚酰胺，其中 ：Y表示碳原子数为8〜20的脂肪族二胺的残基，Ar表示芳香族二羧酸的残基，X表示氨基十一烷酸NH 2 - （CH 3） 内酰胺-12或相应的氨基酸的2或2个COOH，或X表示单元Y，x是二胺与脂族二酸缩合的残基（x ）或X表示单元Y，I，二胺与间苯二甲酸缩合的残基，-0.5至40％（优选7至30％）至少一种选自增塑剂的产品， 纳米填料，聚烯烃，交联聚烯烃和添加剂。
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10.发明申请公开(公告)号：US20050165210A1
公开(公告)日：2005-07-28
申请号：US10690824
申请日：2003-10-23
申请人： Frederic Malet , Annett Linemann
发明人： Frederic Malet , Annett Linemann
摘要： The present invention relates to copolymers having polyamide blocks and polyether blocks, in which: the polyether blocks essentially consist of PTMG having a number-average molar mass {overscore (M)}n of between 200 and 4000 g/mol; the polyamide blocks are formed from a linear (noncyclic, nonbranched) aliphatic predominantly semicrystalline monomer and from a sufficient amount of at least one comonomer to reduce their crystallinity, while remaining immiscible with the polyether amorphous blocks; and the shore D hardness is between 20 and 70. These copolymers are useful for manufacturing many articles and in particular sports shoes.
摘要翻译： 本发明涉及具有聚酰胺嵌段和聚醚嵌段的共聚物，其中：聚醚嵌段基本上由具有数均摩尔质量的PTMG组成（超滤（MnNN）为200-4000g / mol 聚酰胺嵌段由直链（非环状，非支化）脂族主要是半结晶单体和足够量的至少一种共聚单体形成，以降低其结晶度，同时保持与聚醚无定形嵌段不混溶;并且岸D硬度在20 这些共聚物可用于制造许多制品，特别是运动鞋。
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